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By I Sucholutsky, D M. First, D Mogilny, F Yusufali

Machine learning is creating value in all facets of the mining industry, from exploration to production. The authors provide an accessible, high-level introduction to artificial intelligence (AI), machine learning (ML), and deep learning (DL); the latter being widely recognised as one of the most powerful forms of ML. In particular, the authors will introduce deep learning models known as convolutional neural networks (CNNs), how they are applied, and the economic considerations necessary for determining when DL may be the right solution to de-risking complex block modelling problems. The authors present preliminary results from the mineral resource modelling study of the Jundee orogenic gold deposit, Yandal belt/gold province, Western Australia. The primary goal was to identify the direction and location of the narrow gold veins more accurately and demonstrate how non-linearly correlated elements are used as direct inputs to the resource model to assist with the target element’s grade prediction. This demonstrates that: (1) existing techniques for finding correlations between assayed elements do not adequately reflect the complex geology of the asset, (2) nonlinear correlations that are difficult to model as simple mathematical functions are representative of geological patterns in a deposit, and (3) non-linearly correlated assayed data, fed as inputs, increase the performance of the resource model as reconciled through blind tests. To conclude, the authors hypothesise that the patterns represented by the DL block models may be revealing the results of overprinting geological processes that generated mineral deposits. For example, the primary hydrothermal processes that deposited metals created depositional patterns that become particularly complex as a result of being overprinted, in part or in whole, by secondary physicochemical processes. This may explain why non-linear geochemical relationships have the capacity to generate more accurate block models of mineral deposits.

May 24, 2023

By A A. Latscha, D O’Connor

Increasing orebody complexity, restrictions in ground access, and longer lead times for disturbance approvals, have generated the need for the Resource Development Team within Rio Tinto Iron Ore (RTIO), to explore optimised drill design techniques that deliver resource conversion value while maximising program outcomes. In response to this challenge, the Team initiated a case study to produce an AI assisted/designed drill program using a non-machine learning AI. The case study involved the assessment and implementation of an AI generated drill program at one of RTIO’s Pilbara iron ore deposits, located in the Hamersley Province of Western Australia. The Mineral Resource is currently classified as 100 per cent Inferred. Access constraints inherent to topography, and the presence of exclusions zones have prevented adequate drilling coverage, resulting in lower resource confidence and a poor definition of the orebody extents and geometry. The drill campaign, planned in Q1 2023, needs to consider access constraints, complex topology and the limitations related to additional ground clearance, while addressing the requirement of improving orebody knowledge. The drill plan had to address two objectives. The first and main aim of drilling was to upgrade the Resource Classification to allow for possible conversion to Ore Reserve. The input for this objective was a volumetric representation of the areas currently not meeting pre-defined quantitative Resource Classification upgrade criteria. The second objective was to better define the orebody extents and geometry. For the second objective, the input to the drilling optimiser was a volumetric representation (blocks) of the areas of high uncertainty in the mineralisation/waste boundary, which were defined using an indicator conditional simulation technique. The drilling optimiser output was a range of compliant drill plans. A set of KPIs based on economic and orebody knowledge criteria were used to assess the plans and to select the most optimal drill design to be drilled in 2023. The geology and management teams were able to make better informed, objective decisions using the trade-off between cost and orebody knowledge gained. As part of the assessment, the AI generated plans were compared to our current planning practises. The AI assisted plans, when gauged against the project KPIs, showed clear and measurable improvements in both meeting project objectives and in managing operational risk.

May 24, 2023

By H Arvidson, V Chamberlain, J Joughin, N Pollock, F Cessford, T Flitton, T Rowl

Environmental, social and governance issues (ESG) have become a defining feature in the marketplace to differentiate preferred investments. With the sustainability commitment and reporting landscape anticipated to evolve exponentially, it is now imperative to rapidly develop the approach taken by mineral companies to adequately identify and address ESG risks and opportunities in the reporting of Mineral Resource and Mineral Reserve (MRMR). MRMR cannot be effectively reported as technically and financially assured and realistically executable, if ESG is not integrated into the strategy, business model, input assumptions and process that defines and drives robust MRMR public reporting. Regulatory reporting codes across the globe are presently in various stages of being updated and modified to ensure ESG factors are appropriately covered as a key part of diligent and transparent disclosure. Security exchanges are making it clear that companies must not omit ESG risks from reports to investors. This paper discusses associated challenges for MRMR reporting and suggests avenues for improvement. Key themes include: the importance of procedure rather than prescription and checklists; how ESG criteria impact Modifying Factors and determination of Reasonable Prospects for Economic Extraction (RPEE); the need for financial models to account for material ESG commitments; the uniqueness of each mineral asset; the need for education, upskilling and accreditation of both ESG experts about MRMR reporting and equally Competent Persons in ESG matters; and the need for clear and balanced reports that meet the needs of end users. (RPEE is adopted here for simplicity and consistency, recognising that some reporting codes still include ‘Eventual’ in the term (ie RPEEE). Whilst RPEE and RPEEE are subtly different the intent is to point to the process of assessing ESG factors in determining reasonable prospects.) The principles of transparency, materiality and competence remain paramount when considering the impact of ESG matters on MRMR reporting, and this necessitates an inclusive, cohesive, and integrated approach to assessing ESG issues to ensure the necessary expertise and diligence is applied.

May 24, 2023

By D Clarke, I Minniakhmetov

The Olympic Dam deposit is truly a world-class IOCG-Ag deposit, the world’s fourth largest deposit of copper and the world’s largest known single uranium deposit. Traditional and non-traditional methods have been used to accurately model the geology and mineralisation of the Olympic Dam deposit. Conditional simulation models have long been used as the most robust method for estimating risk and uncertainty in mine planning decisions at other mines around Australia and the world. There are many challenges associated with simulating the Olympic Dam deposit at a selective mining unit size sufficient for underground mine planning purposes. These include the size of the deposit, resulting in hundreds of millions of grid blocks; the disseminated nature of the zoned sulfide mineralisation. And lastly the direct relationship of the relative abundances of the sulfide mineral species that are crucial to the Olympic Dam smelter performance. Several geostatistical techniques have been utilised in the workflow for the Olympic Dam Conditional Simulation model to address these challenges. The key techniques are: • Projection Pursuit Multivariate Transform to de-correlate the main elements before simulation. • Pluri-Gaussian implicit boundary simulation method to simulate the mineralisation domains. • Spectral simulation method of de-trended and de-correlated attributes with account of local varying variance. The resulting conditional simulation models have been validated against histograms, grade-tonnage curves, cross-plots and assessed for variogram reproduction. This paper presents how the final conditional simulation models compare to benchmarking models created using alternate estimation techniques of ordinary kriging and local uniform conditioning. It also presents a validation process using historical samples to test final estimate accuracy of the simulation models.

May 24, 2023

By M P. Murphy, C M. D Barton

When developing a new underground mine, the geological interpretation that guides the mineral resource is crucial to the preparation of a reliable ore reserve. In preparing a robust geological model to underpin a resource estimate, practitioners must weigh the comparative risk of accepting a relatively wide-spaced drill hole pattern, versus a more close-spaced pattern that ensures a high local geological confidence for mine planning but may have an exponentially increased time and monetary cost. This paper details the authors’ investigations into the geological uncertainty of IGO’s Odysseus Deposit, which is approximately 645 km north-east of Perth, Western Australia. At Odysseus, the komatiitic nickel sulfide mineralisation is irregularly cross-cut by nickel-barren pegmatites that have intruded and offset its thick ultramafic orebodies. These pegmatites generate significant uncertainty in the precision of Odysseus’ resource volume and tonnage estimates, as well as the subsequent quantification of pegmatite mining dilution in its ore reserve. To quantify the geological uncertainty in the pegmatite interpretations, IGO’s mineral resource practitioners prepared several geological risk studies over the Odysseus North lode, which is the lode most affected by the pegmatites. These studies included categorical conditional simulation of the pegmatites, preparing implicit geological models with alternative algorithms, trialling a machine learning application to prepare a maximum likelihood geological model, and finally assessing the early results of the pre-production close-spaced drilling to these different models. To assess the precision of the different single-outcome models, the authors’ compared the estimated pegmatite content of each model to the range of possibilities modelled by categorical conditional simulation within the planned stopes at Odysseus North. An estimation confidence score for each modelling method was then prepared for each alternative single-outcome modelling method. From these studies IGO concluded that a close-spaced drill pattern is essential at Odysseus, supporting the view of the Competent Person in 2017 who proposed a 25 m drill spacing in areas affected by pegmatite which had been partially classified as Inferred.

May 24, 2023

By Mustafa Kumral, Yu Cheng Yang, Zhixuan Shao, Young Bin Moon

Since the discoveries of favorable deposits are becoming increasingly difficult, mining operations shift to lower grade and deeper deposits. The viability of these operations is sensitive to many factors, such as commodity prices and operating costs. Given that a mining corporation has no power to set prices, the focus is directed on minimizing the operating costs. Underground mining operations require a network infrastructure, including shaft, ramps, declines, levels, cross-cuts, raises, winzes, and adit. The design of this network is a costly process. As such, it has a significant potential to reduce development and haulage costs. Furthermore, network design is a continuous process along with development, production, and maintenance throughout mine life. Under the constraints of the turning radius, the gradient, and the obstacle avoidance for haulage network of underground mines, this paper first demonstrates network design and optimization approaches using Dubins path combined with the Hierarchical Density-Based Spatial Clustering of Applications with Noise (HDBSCAN) algorithm. A threshold-based model is developed, providing viable solutions to the network design when the number of declines is high. Furthermore, a three-dimensional Rapid-exploring Random Tree (RRT) algorithm combined with Dubins path is employed as a heuristic solver for obstacle avoidance purposes in the network. Various case studies are conducted to show the applicability of the proposed methods.

May 24, 2023

By Guodong Li, Chenlin Wang, Zibiao Yu, Bo Xu

Abandoned coal mines have many underground space resources, such as roadways, shafts, and gobs. Among them, abandoned roadways are the best gas storage space for underground compressed air energy storage (CAES). However, CAES caverns have high air pressure and strict sealing requirements. Therefore, the stability and sealing of abandoned roadways under high internal pressure must be analyzed. Afterward, the suitability of abandoned roadways used for CAES caverns should be evaluated. In this study, the numerical simulation software FLAC3D was used to calculate the stress, deformation, plastic zone volume, and pore pressure of surrounding rock in an abandoned roadway under 10 MPa internal pressure. The influence of buried depth, surrounding rock grade, and in situ stress state on roadway stability and the effect of surrounding rock permeability on roadway sealing were analyzed. Results showed that the stress, displacement, and plastic zone volume of surrounding rock were affected by high internal pressure when the buried depth was less than 300 m, but high internal pressure had little effect on them when the buried depth was more than 300 m. The suitable range of buried depth was more than 300 m. The optimal choice of surrounding rock grade was I and II, followed by grades III, IV, and V. The optimal choice of in situ stress state was σH > σh > σv, followed by σH > σv > σh and σv > σH > σh. The sensitivity of the stability evaluation parameters was ranked in descending order as follows: buried depth, surrounding rock grade, and in situ stress state. When the surrounding rock permeability was less than 1 × 10− 14m2, the 24-h air leakage rate of the roadway was less than 1%. The suitable range of surrounding rock permeability was less than 1 × 10− 14m2.

May 23, 2023

By Abhishek Kumar, T. G. Sitharam, Surender Singh

The height of tailings pond (TP) embankments is frequently raised to accommodate the ever-increasing volume of tailings released by the mining industries. Excess pore water pressure (EPWP) may develop during the height-raising operations, which can affect the overall stability of TP. This article presents a detailed stability analysis for the embankments of an existing TP, the height of which was increased twice utilizing downstream (D/S) and upstream (U/S) construction techniques. A rigorous two-dimensional transient fully coupled-stress-pore pressure analysis is performed in the finite element-based package RS2 to examine the build-up of EPWP during different stages of construction. Furthermore, an attempt is made to investigate the feasibility of future height raising, with due consideration given to the influence of embankment raising rates. Results from the analysis show a development of higher EPWP within the tailings deposit in comparison to the embankments of TP, indicating the development of an undrained-like condition. The study further reveals that the development of EPWP is highly affected by the rate at which embankments of TP are being raised. A higher rate of embankment-raising results in the development of greater EPWP in comparison to a lower embankment-raising rate, which may lead to the ultimate collapse of TP. Furthermore, based on the stability analysis, the height of existing TP can be further raised by 4 m (two lifts of 2 m height) utilizing the U/S construction technique. A thorough cost and benefit analyses are however required before implementing the results of the current analysis since the storage capacity of TP is reduced while raising by the U/S method.

May 16, 2023

By Kaige Zheng, Hongwei Wang, Tong Wang, Yanjun Li, Yongping Wu, JIANQIANG JIAO, Baolin Jiang

Due to the influence of economic development on the demand growth of coal resources, many mines in China have gradually entered deep mining. When the roof of deep coal seam is hard rock, it is easy to cause strong ground pressure with the advance of the working face, which seriously threatens the safety of coal mining. Taking 31,104 working face of a mine as the engineering background, this paper studies and compares the deformation characteristics and stress transfer evolution law before and after the presplitting of the hard roof through the combination of physical similarity simulation, numerical calculation, and field measurement, based on the analysis of the interaction relationship between the breaking and collapse of the composite hard roof, and verifies the treatment effect of hydraulic presplitting through field measurement. The results show that: (1) In the early stage of mining under the composite hard roof, the lower roof is mainly subjected to tensile failure, the voussoir beam structure formed is relatively unstable, and the stope is prone to impact. When the mining distance of the working face is large, the breaking rotation of the upper hard roof voussoir beam causes pressure damage to the lower hard roof, causing the lower hard roof voussoir beam structure to slide and lose stability, resulting in strong ground pressure in the working face. (2) After presplitting of composite hard rock stratum, in the early stage of mining, the range and degree of rock stratum damaged by presplitting are small except for the hard rock stratum itself, and the presplitting effect is not significant. When mining to the first square position, the roof is damaged in advance by presplitting, the overall plastic damage range increases, the damage form area increases, and the damage degree deepens. The vertical displacement of the composite hard roof increases rapidly, and the presplitting effect is remarkable. (3) The evolution characteristics of roof principal stress transfer show that under the dual effects of mining and presplitting, the roof tensile stress area above the goaf is large, the rock failure horizon rises, and the roof failure height is high and the failure degree is deep. The stress concentration degree of the coal mass in front of the goaf is reduced, and the stress concentration range is transferred to the rock mass in front. With the advance of mining, the hard roof in front can break and caving in time, so as to avoid rock burst disaster caused by large suspended roof area. The field ground pressure monitoring shows that the average periodic weighting interval, weighting range, peak value before weighting, and peak value during weighting of the working face after presplitting decrease by 53.5%, 38.03%, 8.63%, and 5.96%, respectively, which effectively reduces the weighting intensity and ensures the safe and efficient mining of the working face.

May 16, 2023

By Vhutali Carol Madanda, FHATUWANI SENGANI, François Mulenga

The first introduction of fuzzy theory in the nineteenth century created room for continuous research and application in various fields. Fuzzy set theory has been globally applied in geotechnical engineering, and research in this field continues to date. The fuzzy inference system is considered to be one of the most popular techniques adopted to resolve some of the geomechanical challenges faced in both surface and underground excavations. This paper unpacks fuzzy theory-based approaches in mine geomechanics with the aim of expanding the innovative application of the same approach specifically in tunnel geomechanics. This aim was achieved by conducting a review of recent successful and unsuccessful applications of fuzzy inference systems in underground excavations/tunnelling geomechanics. Indeed, this review has outlined some cardinal points associated with the ability of the technique to solve complex geomechanics problems. However, the success of the technique was accompanied by a few limitations associated with the methodology. Finally, a future outlook associated with the technique has been established.

May 15, 2023

By H. Y. Sohn

Considering the two most important issues the ironmaking industry faces today, i.e., energy consumption and greenhouse gas emissions, it would be advantageous to utilize the concentrate-size raw materials directly without pelletizing or sintering, especially without the use of coke. This plenary lecture describes two such processes developed at the University of Utah. One is the Flash Ironmaking Technology (FIT) and the other is a moving-bed process for continuous ironmaking with gaseous reduction of iron ore concentrate (MBIT). These technologies are designed to produce iron directly from iron concentrate without requiring pelletization/sintering and cokemaking in two significantly different temperature ranges. They take advantage of the high reactivity of the concentrate particles and will considerably reduce energy consumption and carbon dioxide emissions compared with the current processes. The process of the development from the conception of the idea, to kinetic feasibility establishment, to laboratory flash furnace, and finally to the operation of a prototype facility for the development of the FIT is discussed. The development of the MBIT also started with the formulation of the process concept, followed by kinetics feasibility establishment, and the design of a potential industrial reactor. The results of economic analyses on the FIT are briefly described.

May 12, 2023

By Robert Gordon, Leduar Ramayo

This paper reviews the application of the magnetotellurics method for deep earth imaging, specifically its recent use to better understand original mineral emplacement processes. Resistivity information from newer innovative applications of the technology for nearer surface imaging also provides valuable insights into near surface structure, which in some cases has led directly to new discoveries.

May 10, 2023

By Ayokunle Adewale Akinlalu, Sunday Bayode, Sherif Olumide Sanusi, Joshua Oluwagbenga Adeboye

Gold occurrences have been reported in Alagbede, southwestern Nigeria, but a mineral potential map (MPM) to guide academics and investors in the area is still needed. As a result, geophysical methods (aeromagnetics and aero-radiometry) have been used to assess the potential for gold minerals in the area. Several enhancement filters, such as reduction to the equator, upward continuation, analytical signal, second vertical derivative, and power spectrum analysis, were applied to the aeromagnetic data to understand the subsurface geology better. The enhancement filters applied to airborne radiometry data are K/eTh, ternary color composite, F parameter, and deviation from the ideal K values (Kd). Geophysical data analysis was used for structural mapping and geological reconstruction, while aero-radiometric data was used for hydrothermal alteration mapping. The primary trend observed in the area’s magnetically inferred structural framework map is NE-SW, while a few are in the NW–SE and E-W trends. These observed trends show that the study area suffered at least three deformation episodes. Geological evidence of gold mineralization, such as favorable lithology, geological structure, and hydrothermal alterations, has been fused to produce a reliable MPM of the area. The geographical location of the existing mineral sites in the investigated area agrees with the geological structures and the MPM produced there. Thus, the systematic approach adopted in this study can be extended to other supracrustal belts of a typical Precambrian basement complex worldwide to ensure the reliability of orogenic gold mapping and resource management.

May 9, 2023

By D. F. Malan, P. M. Couto

We propose a layout design for the UG2 Reef where weak geological alteration layers are present. The collapse of the Everest platinum mine in South Africa indicated that these layers substantially weaken the pillars. The popular Hedley and Grant pillar strength formula cannot be used where these alteration layers are present. Underground investigations at Everest mine and numerical modelling of the layout were conducted using the TEXAN code and a limit equilibrium model. Simulations of a collapsed area and an intact area allowed for a preliminary calibration of the model. This was subsequently used to explore modified layouts for these ground conditions. An alternative is to compartmentalize the blocks of ore using barrier pillars. The numerical modelling predicted that the barrier pillars appear to remain stable even in the case of large-scale collapses, provided their width exceeds 25 m. Main access routes into the mine can be protected by a double row of pillars at least 15 m wide to provide a safe travelling way. As a cautionary note, these conclusions are based on the model calibration and this needs to be refined in future. Calibration of the limit equilibrium model remains a challenge owing to the large number of parameters involved.

May 3, 2023

By D. F. Malan, T. E. Oates

A recent experimental pillar extraction project at a UG2 bord-and-pillar mine presented a unique opportunity to compile a new pillar database. Currently, the South African hard rock bordand- pillar mines are designed using the Hedley and Grant formula with a modified K-value. This empirically derived formula was developed for uranium mines in the Elliot Lake district of Canada. The use of this formula for the design of pillars in South Africa is questionable. Very few pillar failures have nevertheless been observed and its current calibrations for the various reef types are possibly too conservative. A new UG2 pillar database of 66 pillars, of which seven are classified as failed, was compiled by the authors. This enabled a revised ‘first-order’ calibration of the K-value for the Hedley and Grant formula. The new estimated value for the UG2 is K = 75 MPa. This gives a pillar strength that is more conservative than the PlatMine formula. This work should nevertheless be considered as only a preliminary calibration as the database was small. Further work is also required to determine whether the exponents in the formula for the width and height parameters are appropriate for UG2 pillars.

May 3, 2023

By D. F. Malan, J. C. Esterhuyse

In this study we explore the use of a novel numerical modelling approach to study the effect of pillar reinforcement on pillar stability. Case studies in the literature indicate that tendons, strapping of the pillars, and shotcrete or thin spray-on liners are commonly used to reinforce pillars. No clear methodology exists to select the type of support or to design the capacity of the support required, however. This has led to ongoing collapses in some mines in spite of heavy support being used to reinforce unstable pillars. A limit equilibrium model with confinement on the edge of the pillar was used to simulate the interaction of the support with the failing pillar. The model correctly predicts that an increase in confinement will lead to a decrease in the extent of pillar failure. As the displacement discontinuity boundary element method allows for the efficient solution of largescale bord-and-pillar layouts, the effect of pillar confinement can now be studied on a mine-wide scale. Accurate calibration of the limit equilibrium model is, however, required before this method can be used for the design of effective pillar support.

May 3, 2023

By Deep Foundation

Whenever an organization launches an initiative, the question arises whether that initiative has staying power. Or is the initiative, as is quite often the case, merely a fad; that is, just an activity that suddenly becomes popular, but which does not stay popular for very long. When the Federal Highway Adminis- tration (FWHA) started its Advanced Geotechnical Methods in Exploration (A-GAME) initiative, that question was addressed, especially considering the fact that up to 50% of major infrastruc- ture projects suffer impacts to schedule or cost due to geotechnical issues. Many of these issues relate to risks identified directly or indirectly to the scope and quality of site character- ization work. Effective site charac- terization is critical for recognizing. potential problems that may affect design and construction and for ensuring safe, well-performing and cost-effective projects. Grounded on that, knowledge of all available site investigation methods should continue to be shared widely and the application of those methods should be encouraged on an ongoing basis throughout the project lifecycle. The A-GAME initiative covers five technologies: Cone penetration testing (CPT), monitoring while drilling (MWD), electrical geophysical methods, seismic geophysical methods, and optical and acoustic televiewers. Of these, three soil and rock investigation methods were highlighted that are underutilized not only here in the U.S., but also in many places around the world: CPT: a well proven and established method for soil characterization that turned 90 last year, in which continuous in-situ data are col- lected quickly and consistently. Geophysics: the science that assesses the physical properties of the soils and rock using seismic and electrical techniques, which con- tinues to advance in leaps and bounds as the application of well- understood technologies become more powerful.

May 1, 2023

By Brian McGlynn

There are many factors that can result in a site characterization being limited. For example, a client may undervalue the importance of a good geotechnical report, or an owner may feel that it would take too much time to perform an appropriate investigation among other reasons. For this project, neither was the case. The challenge was that the construction sequence of work required wick drains to accelerate the settlement of soil that had yet to be placed, resulting in the need to create a wick drain bid package based on unknown settlement parameters. This wick drain project took place in Long Beach, California, at the Long Beach Middle Harbor Re- development. For much of the past decade, the Port of Long Beach undertook a $1.5 billion redevelopment of two outdated terminals to create the Long Beach Container Terminal (LBCT). To achieve this goal, the existing terminals were demolished and the slip that serviced one of the older terminals was designed to be infilled to create the new area that would allow for the LBCT to manage 3.3 million TEUS (a commonly used freight term meaning twenty-foot equivalent unit) of cargo each year. Ultimately, the construction of the LBCT would be performed under multiple contracts to allow the new terminal to begin operation in a phased approach. Menard performed the wick drain installation under two out of three contracts, and this case history focuses on the challenges anticipated and faced under the second of these awarded contracts.

May 1, 2023

By Ashley Shirer

Have you heard a geotechnical engineer rail against using the word "dirt"? The typical maxim is: "It's not dirt, it's soil!" This axiom is so prevalent that it is joked about on the construction site. How did we get to the point in our profession that soil is too technical to understand, while dirt is not viewed as important? Take a moment and think about the images that come to mind by the word soil. Responses range from the sand at a playground to the mud that sticks to the bottom of your shoe, the dark loam found in gardens to the firm earth under your feet. But do you know where the term soil originated? Or how it was intended to be used? This article looks at how word choice can lead to very different motivations for owners, designers and constructors.

May 1, 2023

By Muhammed Şener, Ahmet Gültek

The flotation chemicals are important in mineral processing, and new progress is made in this area day by day. For sanidine purification, some commercial collectors, which can be harmful to the environment, are used. In that respect, the poly(amidoamine) (PAMAM) dendrimers, which are non-toxic for the environment, are good candidates for flotation applications. In this study, the second-generation PAMAM dendrimer was used as a collector to remove magnetite from sanidine by microflotation method, and obtained results were compared with commercial collectors. The results showed that the PAMAM dendrimer is an efficient and selective collector for magnetite. PAMAM adsorption mechanism was determined by zeta potential and FTIR spectra. According to the microflotation results, 87.76% of magnetite recovered at pH 8 by using PAMAM as a collector. It was found that the flotation recovery with the PAMAM dendrimers is similar to the Aero 704 between pH 2 and 6 but less between pH 6 and 9 and more between pH 9 and 12. All experiments were carried out five times and the standard deviation of all results was evaluated with p = 0.05 confidence interval. The second-generation PAMAM dendrimers can be an alternative flotation chemical to the commercial ones concerning usability at a wide pH range, recovery potential, and environmentally benign.

Apr 28, 2023