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"The last thirty years have seen enormous changes in all aspects of the gold industry, from the technologies of mining and extracting gold to the role it has played in the fiscal policies of nations. In this time, the market price of gold has increased ten fold and mine production has more than doubled. However, the cost of mining and extracting gold has also increased exponentially, and the industry has struggled with declining ore grades and increasingly refractory ore bodies.With the major economic powers of the world shrugging off the uncertainties of the post cold war era and moving into a period of unprecedented political stability, economic growth and low inflation, gold is also losing its lustre as a hedge against inflation and a backing for national currencies. Consequently, countries that had accumulated and hoarded gold for decades are now disposing of these non-performing assets, resulting in major swings in supply of the metal. Fortunately, this has coincided with the end of communism in many parts of the world and a tentative move to free market economies in most of the developing nations. As a result, people are becoming wealthier, and this is creating more demand for gold, principally in the form of jewelry.On balance, the shift in the role of gold, from one in which a significant portion of new gold production lay dormant in bank vaults as insurance against political or fiscal instability, to one in which most new gold is now freely traded as an industrial commodity, responding to normal market forces of supply and demand, has had a negative impact on the price of gold over the last fifteen years. In that time, the gold price has declined from a peak of $850/oz in 1980 to an average price of about $400 through the rest of the l 980's, to a price of -$320/oz today (1997). In large measure, this has been due to the enormous inventory of gold metal that was held by central government banks in vaults around the world, and which has been dumped on the market as soon as the price has started to trend upwards. Even today, after ten years of fairly steady selling by central banks, about 3 0, 000 tons of gold (or -8 years' supply at the present rate of consumption) is still retained in vaults (Murray et al., 1997).The downward pressure on the price of gold has created exciting opportunities for the development and implementation of new technology. Increasing the efficiency of gold recovery from more and more refractory ore bodies, whilst at the same time lowering production costs, have become critical to survival in this industry. These challenges have been met by the development and implementation of new technologies such as heap leaching, carbon in pulp, resin in pulp and the sulphide ore pre-treatment process of pressure leaching, bacterial leaching and fluid bed roasting. For an industry that saw very little technological change in the first seventy years of the twentieth century, the pace of change over the last thirty years must have seemed bewildering at times."

Jan 1, 1998

By Vincent Jourdain

Located in the James Bay Territory of Quebec (figure 1), the Clearwater property is jointly owned by SOQUEM Inc. and Eastmain Resources Inc. Exploration on the property since the early 70's has resulted in the discovery of several gold showings. Exploration work by the joint venture since 1995 has led to the definition of the Eau Claire Zone containing an indicated resource of 540 000 tonnes grading 11.1 g/t Au (8.7 g/t Au cut at 34.28 g/t Au). Hosted by the archean Eastmain Greenstone Belt, the property geology is dominated by mafic volcanics containing thin horizons of felsic volcanics and/or sedimentary rocks (figure 2). The sequence is metamorphosed to the amphibolite facies and contains two small toalitic intrusions. Regionally, the structural trend is oriented E-W but in the area of the Eau Claire Zone a second trend oriented NE-SW is also present. The first exploration work on the property was conducted by SEREM and SDBJ from 1973 to 1976. It consisted of an airborne electromagnetic survey and a ground follow-up program on several grids. This program, comprising geological mapping, geophysics and drilling, led to the discovery of the Natel showing where a drill intersection returned 8.89 g/t Au over 2.65 m. From 1978 to 1985 the area was withdrawn from staking because of the hydroelectric projects of the James Bay. In 1985, Westmin Resources Limited and Eastmain Resources began an exploration program based on a helicopterborne electromagnetic survey. Once again, a ground follow-up program was conducted on several grids. This program included a soil geochemical survey that identified a strong (up to 10 g/t) gold anomaly. Drilling of the anomaly led to the discovery of the Eau Claire Zone where resources were estimated at 270 000 tonnes grading 6.1 g/t Au at the end of 1990. In 1995, SOQUEM Inc. took an option to gain a 50% interest on the property and obtained its interest in 1998. Since 1995, two principal mineralization zones were identified on the property. The "Rosemary Zone" consists of veinlets and disseminations of pyrite and chalcopyrite within a magnetite-rich amphibolite. The mineralized zone was identified by stripping within an area of 1000 by 500 metres. Drilling indicates copper grades up to 0.32 % Cu over 49.2 m. with locally grades of 0.75 % Cu over 5.9 m. The mineralised zone is associated with QFP dykes and corresponds to a strong magnetic anomaly and a strong copper and molybdenum soil anomaly. The "Eau Claire Zone" consists principally of a set of gold bearing quartz-tourmaline veins oriented E-W and dipping at 45-50??to the south (figure 3). More than ten different veins are recognised in the zone and up to eight veins were observed in a single trench (figure 4). The host rock between the veins shows a degree of deformation similar to the regional volcanosedimentary rocks. Each vein is hosted by a unit of actinolite-tourmaline-biotite schist up to one meter thick. The veins and their hosting schist clearly cross-cut the schistosity of the hosting lithologies and the contacts between amphibolites and felsic to intermediate rocks. Usually, the veins are less than a meter thick and are composed of quartz, tourmaline and calcite. The proportion of quartz and tourmaline varies from 0 to 80% within a single vein. The veins commonly show massive, banded or brecciated texture. Sulphides, mainly pyrite, pyrrhotite and chalcopyrite, generally form less than 5% of the vein material.

May 1, 2001

By X. J. Guo, H. X. Li

The biological heap leaching at Zijin copper mine is currently the largest industrial application of biohydrometallurgy and one of the earliest mines to develop biological metallurgy technology in China. Since 2001, through demonstration plant and different expansion stages, it has been developed to produce 20,000 tons cathode copper annually. However the ore grade of heap leaching gradually decline year by year with copper grade average at around 0.23% now. The copper mineral is mainly the secondary copper sulfide, and symbiosis with higher content pyrite, the sulfur and iron contents is about 15 times as copper in the ore (S/Cu>15), so the acid and iron treatment of leachate, extractant and acid mine waste water is a great challenge. Combined with located in the rainy area of southern China, huge amounts of over 10 million cubic meters acid drainage need to be treated every year, so the recovery of copper from waste water as well as low grade ore is one of the characteristics of this process. This paper in general introduced the operation of heap leaching, solvent extraction, stripping and electrowinning process in Zijin mine, summarized the experience of production and technical practice, and discussed the methods of heap construction, leaching rate enhancement, third phase formation and treatment, mine effluent treatment, resource recovery and heap slope reclamation. INTRODUCTION The Zijinshan gold and copper mine is located in southeast China, Fujian province, and the typical distribution characteristics of gold and copper deposit are "upper gold and lower copper", both are large porphyry deposits. By the end of 2017, the accumulated proven reserves of available gold resources were 318 tons, copper are 2.15 million tons, and the prospective reserves of copper are more than 5 million tons. The gold mining is open pit while the copper mining is open pit and underground. The cut-off grade of gold mining is 0.15 g/t, and that of copper mining is 0.15%. A large number of very low-grade gold ores (grade <0.30 g/t) adopt a combined ore-dressing process of “partial crushing/ore washing/reprocessing/heap leaching (overlying)/ carbon slurry" independently developed, while flotation and bio-heap leaching are adopted for copper mine. Among them, copper ore with more than 0.25% copper content enters the flotation system to produce copper concentrate, while that of less than 0.25% copper content is processed by bio-heap leaching, solvent extraction and electrowinning. Zijin biological heap leaching plant is the first mine in China to achieve the scale of annual output of ten thousand tons of cathode copper since 2006. In 2008, the solvent extraction and electrowinning system were expanded, now with a daily processing capacity of 20,000 tons of ores, an annual output of 20,000 tons of cathode copper, the expanded plant is the largest biohydrometallurgy plant in China.

Jan 1, 2019

By K. D. Peaslee, J. M. Soto, IéDé Smith, A. D. Saikia

Spinel-forming refractories reduce penetration of metal and slags through a tightening of the lining resulting from the volume expansion associated with spinel formation. Sintered spinel is often added to reduce the overall volume increase that results. Tests were carried out to evaluate the difference between performance in spinel¬forming and spinel-containing refractory mixes. Eight refractory linings, one (1) pure magnesia, three (3) magnesia-base spinel-forming and four (4) alumina-base spinel- containing dry vibratable mixes, were tested for four hours in contact with a low-carbon, low-manganese steel in a coreless induction furnace at temperatures in excess of 1600°C. Afterwards, sample were cut, and wear and penetration were measured. For magnesia-based mixes wear was minimized using 20-30wt. spinel formation although further experiments are required to determine the optimal value. For alumina-based mixes, there seemed to be an optimal ratio of spinel added to spinel formed that minimized penetration and wear at the slag line. Sidewall accretion occurred and the accretion was the highest for the mix with the ratio of spinel formed to spinel added near the optimum value. Therefore to design an optimum refractory mix the benefits of higher ratios of spinel added to reduce penetration and wear at the slag line will need to be balanced with the tendency to form accretions on the sidewalls of the furnace.

Jan 1, 2004

By M. Specht, D. Pörzgen, W. Lorenz, A. /. Buhr, R. P. Racher

The introduction of the near net-shape casting process at CORUS Staal IJmuiden in January 2000 required changes of secondary metallurgy processes including a development towards more aggressive slag compositions in the steel ladle. Therefore the steel ladle lining has been changed from fired andalusite bricks to magnesia-carbon bricks and, most recently, to fired spinel bricks to withstand the severe slag conditions. In comparison to the andalusite bricks the new steel ladle linings have a higher thermal conductivity. This requires the capability to keep the lining warm by ladle preheaters to sustain the overall thermal stability of the steel ladle in case of interruptions during hot cycling of the ladles.

Jan 1, 2004

By Michel Dagbert, Mohammed Harfi

"Abstract - The Draa Sfar polymetallic deposit, at about 16 km NW of Marrakech in Morocco, is a massive sulfide zone at the contact between an underlying volcanic and an overlying clastics sequence. The mineralized body is a flat lens with schistosity and "boudinage," tilted to the west and with a strong dip to the east. The lens extends over a strike length of about 2 km and from surface to a depth of about 1 km, with thickness varying from 1 m to almost 30 m. It has been intersected by about one hundred surface drill holes and, in its south part, by about thirty underground fan holes from two exploration levels at depths of 300 m and 400 m. On these two levels, the massive sulfide zone has been channel sampled over a cumulative length of about 0.7 km. Results from drill and channel samples are used to estimate the resources of the orebody according to several methods: sections, polygons around intercepts on a longitudinal plan, grids on the same longitudinal plan with various distance weighting methods including kriging and, finally, a 3D grid with the same range of interpolators. A comparison of the various estimates delineates the important factors in deriving resources for this type of deposit. Those factors are mostly geological and related to the interpretation of the geometry of the two limiting surfaces of the zone. For the 3D gridding, the authors have devised a new and original method that constrains the interpolation of blocks from samples to a geometry of limiting surfaces. The resulting model shows internal grade variations that parallel fluctuations of zone thickness and orientation without having to re-orientate the search window in each block. Résumé - Le gisement polymétallique de Draa Sfar, situé à environ 16 km au NW de Marrakech est un horizon de sulfure massif au contact d’une formation volcano-sédimentaire de base et d’une formation détritique sur-jacente. Le corps minéralisé se présente sous forme d’une méga-lentille aplatie, schistosée, boudinée et déversée vers l’ouest avec un fort pendage vers l’est s’étendant sur une longueur de 2 km et une profondeur de près de 1 km avec une épaisseur variant de moins d’un mètre à près de 30 m. Il a été reconnu par plus d’une centaine de sondages de surface et, dans sa partie sud, par une trentaine de trous souterrains en éventail à partir de deux niveaux à des profondeurs respectives de 300 m et 400 m. Sur ces mêmes niveaux, des traçages ont permis de rainurer le minerai sur une longueur cumulée de 0.7 km. Les données de sondage et de rainurage ont servi à estimer les ressources du gisement selon plusieurs méthodes : sections, polygones sur longitudinale, grille sur longitudinale avec différentes pondérations en fonction des distances incluant le krigeage et enfin grille tridimensionnelle avec le même éventail de pondérateurs. La comparaison des estimés obtenus permet de mettre en évidence les facteurs importants dans l’estimation des ressources de ce type de gisement. Ces facteurs sont essentiellement géologiques et relatifs à l’interprétation de la géométrie des limites des corps minéralisés. Pour l’estimation sur grille tridimensionnelle, on a mis au point une technique originale qui calque l’interpolation des blocs à partir des échantillons sur cette géométrie des surfaces de contact. Le modèle résultant montre des variations internes de teneurs qui épousent les fluctuations d’épaisseur et d’orientation de la zone sans qu’il soit nécessaire de ré-orienter les fenêtres de recherche dans chaque bloc."

Jan 1, 2002

By Gerhard W. Heinrich, Gerald V. Schroeder, Daniel A. Murphy, Daniel F. Suarez, Jamie B. Beauchamp

"Washwater 'Finger' sprays were installed and tested in the copper/nickel separation circuit at Strathcona Mill to improve flotation capacities and related metallurgical performances. The new spray design features submerged sideways introduction of wash water into the flotation froth through nozzles at the end of vertical pipes which are suspended from a header above the froth. This maximizes the effective cross sectional area of flotation vessels while maintaining effective froth cleaning and a desirably high density of the concentrate slurry. The plant tests gave increases of copper concentrate production rates of 17% to 20% for conventional cells and 16% to 20% in column flotation at target grades of 29% to 30% copper and of less than 0.5% nickel. Basic considerations and concepts of tests and evaluation procedures are described.IntroductionMeeting flotation concentrate grade targets at maximum production rates and recoveries is a challenge all too familiar to operators of base metal ore concentrators. Frothwashing is an option to improve grade/recovery performance by minimizing entrainment of impurities into the concentrate, which is commonly known since the sixties (Kaya & Laplante, 1989). It has been recommended for the flotation of sulphides and industrial minerals alike (Kaya & Laplante, 1989; Miller, 1969; Heinrich, 1989) and has found its ultimate application in flotation columns (Finch & Dobby, 1990). The washwater addition in a flotation column is most evenly distributed over the column's cross-sectional area thus ensuring almost complete displacement of feed water from the froth by a countercurrent washwater flow -provided, a positive bias is maintained. Therefore, flotation columns are ideal for cleaning flotation. However, there is usually less room for boosting the concentrate production capacity by increasing airflow or slurry level then with conventional cells because of the smaller cross-sectional area available."

Jan 1, 1994

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By Réal Marcotte

L&apos;industrie minière représente un apport économique important pour le Québec ; cette production est très diversifiée et répartie dans plusieurs régions. Hormis les forges du St- Maurice au XVIIe siècle, l&apos;industrie minière québécoise commence en 1862 dans la Beauce avec l&apos;exploitation de placers aurifères dans les affluents de la rivière Chaudière; à la même époque, on met en production les mines de cuivre Eustis, Albert et Capelton, près de Sherbrooke1; à partir de 1881, les mines d&apos;amiante et de chromite au voisinage d&apos;Asbestos et de Thetford commencent à voir le jour. Dans les années ?20, l&apos;extraction de métaux précieux et usuels débute en Abitibi- Témiscamingue; durant les années &apos;50, le fer et l&apos;ilménite de la Côte Nord, ainsi que le cuivre de Murdochville et Chibougamau, commencèrent à être mis en valeur. Plus récemment, soit durant les années &apos;80, le sel des Iles-de-la-Madeleine et le graphite des Hautes Laurentides s&apos;ajoutèrent aux produits que nous commercialisons. Finalement, soit en 1998, le Québec devenait un important producteur de nickel avec le démarrage de la mine Raglan, au Nunavik. L&apos;exploitation d&apos;une mine peut nécessiter l&apos;extraction de grandes quantités de roches stériles, particulièrement lorsque la production se fait à partir d&apos;une fosse à ciel ouvert. De plus, étant donné que les minéraux et les métaux mis en marché ne constituent qu&apos;une fraction du minerai extrait, il faut le concentrer : on se retrouve alors avec des proportions plus ou moins importantes de résidus finement broyés. Ces deux types de rejets totalisent bon an mal an environ 100 millions de tonnes. Lorsque cela est possible, ceux-ci sont, soit valorisés comme matériaux de construction ou retournés dans leur lieu d&apos;origine afin de soutenir les murs des excavations. Toutefois, une bonne partie est accumulée en surface dans des aires aménagées spécifiquement à cette fin ; comme le montre la figure 1, la superficie utilisée à cette fin a progressé parallèlement aux booms miniers que nous venons de mentionner pour atteindre actuellement environ 15,600 hectares, dont environ la moitié sont situés sur des aires encore en activité.

Nov 1, 2002

By B. Garitte, O. K. Mahabadi, P. Marschall, A. Lisjak, H. R. Müller, T. Vietor, G. Grasselli

Numerous research studies have shown that clay rock formations exhibit favourable characteristics for the deep geological disposal of radioactive waste. However, one main concern is that the favourable long-term isolation properties of the intact rock mass could be negatively affected by the formation of an excavation damaged zone (EDZ) around the underground openings. The goal of this paper is to present new rock mechanics insights into the phenomena involved in the EDZ formation and evolution processes in Opalinus Clay, a clay shale currently being assessed as a potential host rock for an underground repository in Northern Switzerland. More specifically, discontinuum-based computer simulations, using a hybrid finite-discrete element method (FDEM) approach, were applied to two case studies considering circular excavations in an anisotropic Opalinus Clay formation. In the first case study, numerical modelling was applied to the HG-A experiment, a long-term in-situ test carried out at the Mont Terri underground rock laboratory to investigate the hydro-mechanical response of a backfilled and sealed microtunnel. A mechanistic analysis of the fracturing processes involved in the EDZ formation was carried out. In the second case study, the long-term effect of the bentonite backfill swelling on the EDZ around an emplacement was numerically analyzed. Overall, the simulation results highlight short-term distinctive rock failure kinematics due to the bedded rock structure, as well as a long-term reduction of the excavation-induced fracture porosity in response to mechanical loading.

Jan 1, 2015

By Michel Aubertin

Les rejets miniers sont communément utilisés, depuis plus de 60 ans, comme matériau de remblayage des chantiers souterrains. Les roches stériles et les rejets de concentrateur sont employés comme remblais car ils sont disponibles sur les sites miniers à un coût réduit pour aider au support de terrain. Le remblayage des ouvertures est également avantageux car il permet de réduire la quantité de rejets entreposée en surface. Dans les mines souterraines, le remblai des chantiers doit aider à maintenir un espace de travail sécuritaire, tout en favorisant la récupération du minerai et le contrôle de la dilution. Il est alors essentiel d&apos;évaluer précisément les pressions exercées par le remblai sur les murs et sur les barricades installées près de la base des chantiers. Dans cette présentation, des solutions existantes pour évaluer les pressions dans les chantiers sont brièvement revues. Les auteurs présentent ensuite des solutions analytiques récemment développées à cette fin, qui permettent de tenir compte du transfert des contraintes du remblai aux parois des chantiers et des galeries. Les solutions proposées, qui sont basées sur la théorie de l?effet d?arche, prennent en compte l&apos;influence de la géométrie des ouvertures et de la position des barricades. La méthode de calcul permet aussi de calculer l?effet des pressions d?eau pour un remblai partiellement ou totalement submergé. Les solutions s&apos;appliquent au cas d?un remblai récemment mis en place, alors que l?effet de la pression interstitielle ne peut pas être négligé, et aussi à plus long terme sous une condition drainée. Des résultats expérimentaux et des simulations numériques sont utilisés pour valider les équations proposées. Les résultats analytiques et numériques montrent notamment que la pression totale sur une barricade peut être grandement augmentée par la pression d?eau, tandis que la contrainte effective peut être réduite par les pressions interstielles (par rapport à la condition drainée ou sèche). On discutera aussi des implications pratiques de ces résultats pour l?application des remblais souterrains.

Nov 1, 2008

By Kenneth Williamson

La découverte de nouveaux gisements métallifères constitue le point de départ du développement de l&apos;industrie minérale. Or, au cours de ces dernières années, le nombre de ces découvertes a fortement diminué dans les territoires classiquement explorés, entraînant une recrudescence de l?exploration dans les terrains géologiques de grade métamorphique élevé (e.g., Province de Grenville, Grand Nord du Québec). Ces derniers ont été traditionnellement considérés comme stériles à cause (i) de la monotonie apparente des gneiss qui les composent, (ii) de la difficulté d?identifier leurs protolites, (iii) des changements importants dans l?apparence des gîtes recherchés reliés au fort degré de déformation et de métamorphisme et (iv) des théories qui prônent un lessivage important des cations et des métaux d?intérêt économique par les processus de déshydratation des roches lors du métamorphisme régional (Weaver et Tarney, 1985; Vokes, 2000). Cependant, l?avancée des connaissances dans la compréhension des gîtes métallifères et de leurs terrains hôtes gneissiques intensément métamorphisés, montre que les systèmes géochimiques des roches altérées demeurent robustes (p. ex. ; Trägårdh, 1991; Craig et Vokes, 1993; Geringer et al., 1994; Schandl et al., 1995; Zaleski et Peterson, 1995; Vokes, 2000; Blein et al., 2003, sous presse). Bien sûr, les sulfures peuvent être localement remobilisés et même fondre, mais cette remobilisation n?implique pas forcément la disparition du gîte hôte (Williams, 1990) et peut s?avérer, bien au contraire, bénéfique pour la rentabilité d?un gîte en augmentant sa teneur en minerais (Marshall et al., 2000). Jusqu?à présent, dans les terrains métamorphiques, les contextes sédimentaires et plutoniques ont été reconnus et respectivement explorés pour les gîtes de type SEDEX et les gîtes magmatiques de Ni-Cu. L?étude de gîtes de métaux de base et précieux intensément métamorphisés (faciès des granulites) et leur comparaison avec des gîtes équivalents peu on non métamorphisés a permis d?établir, au cours des dernières décennies, des outils pour l?exploration des terrains de haut-grade métamorphique (Vokes, 1991, 2000; Slack et al., 1993; Spry et al., 2000). Ces outils sont basés sur la reconnaissance de roches diagnostiques d?une circulation ou d?une exhalation de fluides hydrothermaux telles que les méta-exhalites (formation de fer, coticules, tourmalinites, roches riches en quartz-gahnite, en apatite, en barite ou en staurolite zincifère) (Spry, 2000; Spry et al., 2000). Ils sont utilisés constamment dans les ceintures supracrustales riches en roches métasédimentaires.

May 1, 2003

By Eamonn F. Maher

Superconductivity is one of the most remarkable scientific phenomena ever investigated. It is the phenomenon whereby some materials exhibit zero resistance to the passage of an electric current when cooled to low temperatures, and requires a quantum mechanical explanation. Four Nobel prizes in physics have been awarded specifically on the subject of superconductivity, with many more enabled by superconducting technology. For example, particle beams are generated in accelerators and manipulated in ?particle beam lines? in the ?Big Physics? projects around the world eg. at CERN, Geneva, leading to major discoveries in fundamental particle physics. Similarly, at the JET Propulsion laboratory near Oxford, U.K, controlled nuclear fusion has been demonstrated, and magnetic containment of plasmas is key. In the chemical and biological sciences high field NMR spectroscopy has become indispensable for examining organic matter, revealing the mysteries of the workings of cells, genetics, and in the development of new polymers and pharmaceuticals. With all these very advanced uses for superconducting magnets, it is easy to forget that superconductivity is big business, not just a scientific curiosity. MRI (Magnetic Resonance Imaging) superconducting magnets, the key component of high resolution body scanners, use approximately half of the world?s superconducting wire ? the other half being mostly used in accelerator magnets. The MRI market is about 3 billion dollars per annum, and one MRI magnet uses 200km of wire. New applications for superconducting magnets are now appearing including ?Catheter steering?, enabling much shorter timescales for life-saving brain tumour removals and ?Functional MRI?, a whole new area in patient diagnostics. Whilst the use of low temperature superconductors (LTS) is now well established commercially in superconducting magnets and niche electronic applications, the application of LTS in electric power distribution and transport has been very limited to date. It is now more than fifteen years since the so-called High Temperature Superconductor (HTS) materials were discovered: these can be operated at liquid nitrogen temperatures rather than liquid helium temperatures. However, materials processing and scale-up issues have prevented their widespread use, and in particular the required price/performance criteria are only beginning to be reached except in certain niche markets. BSCCO (Bismuth Strontium Calcium Copper Oxide) tapes up to one km long are now readily available, and have been demonstrated in high current cables for power distribution networks, but the general consensus is that 1) it is difficult to reduce the price much further because of the silver matrix required and 2) in applications where coils are required eg. motors, generators, transformers etc the properties of BSCCO are rather poor because of the critical current dependence on magnetic field. Magnetic fields are always associated with coils and windings, and such fields are of course fundamental to the operation of all electrical machines. YBCO (Yttrium Barium Copper Oxide) however, has good characteristics in field and for the last few years there has been intensive research and development costing several tens of millions of dollars worldwide into the scale-up of production of so-called ?coated conductor?. This ?second generation? tape can be produced by any of many different film deposition techniques, with more or less success for short lengths, but as yet it is unavailable in lengths more than a few tens of metres.

Oct 1, 2003

By R. A. L. Drew, J. P. Immarigeon, F. Jalilian, M. Jahazi

In the present work TLP bonding of Inconel 617 is investigated. The influence of the main processing parameters i.e. time and thickness of the interlayer were studied with optical and scanning electron microscopy. Boron containing interlayers with two different thicknesses were used and the influence of various holding times from 5 min to 24 hours on the microstructure of the bond region was investigated. The results indicated that, for the testing temperature of 1065°C and holding times above 2 hours with an interlayer of 25.4 microns thick no liquid phase was observed. The same phenomenon occurred only after 6 hours for a 76.2 microns thick interlayer. Precipitate growth started at grain boundaries and continued inside the grains. The composition, size and morphology of the precipitates were studied using electron microprobe analysis. No noticeable changes were observed in the grain size of the base metal with increasing holding times.

Jan 1, 2004

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Burden of Occupational Cancer in Canada Project Team, Demers P. A., Kim J., Arrandale V. H., Jardine K.

"In 2012 diesel engine exhaust (DEE) was classified as a human carcinogen by the International Agency for Research on Cancer (IARC) and is one of the most common workplace carcinogens internationally. We estimate that approximately 2.4% of lung cancers (n=560) and a suspected 2.7% of bladder cancers (n=200) are attributable to occupational exposure to DEE annually in Canada. High levels of exposure to DEE in mining results in a disproportionate number of cancers in this sector (approximately 220 lung and 20 suspected bladder cancers annually). These could be prevented by reducing the number of workers exposed and level of exposure. KEYWORDS Bladder cancer, Diesel engine exhaust, Economic burden, Lung cancer, Mining, Occupational cancer, Prevention, Regulation INTRODUCTION Diesel engine exhaust is a complex mixture of gases and particulates containing known and suspected carcinogens such as benzene, polycyclic aromatic hydrocarbons (PAHs), and metals. Approximately 900,000 Canadians are exposed to diesel engine exhaust at work, making it the most prevalent occupational lung carcinogen in Canada (CAREX Canada). Diesel engine exhaust is recognized as one of the most common workplace carcinogens in the world, but its classification as a human carcinogen by the International Agency for Research on Cancer (IARC) was relatively recent. In 2012, after decades of mounting evidence, diesel engine exhaust was upgraded from a probable (IARC Group 2A) to a definite human carcinogen (IARC Group 1) (IARC, 2014). The IARC evaluation was based on strong evidence in humans for an increased risk of lung cancer, as well as strong evidence in animal studies. The key human evidence considered by IARC was from epidemiologic studies of workers in truck transportation, rail transportation, and mining industries, where the use of diesel engines is widespread. These studies provided strong sufficient evidence for an increased risk of lung cancer, as well as limited evidence for bladder cancer. The human studies used particulate matter, generally measured as elemental carbon (EC) or total carbon, as a surrogate for diesel engine exhaust to assess the risk associated with level of exposure. The animal studies reviewed by IARC showed sufficient evidence for cancer with exposure to whole diesel exhaust and the particulate matter fraction of diesel exhaust, but not for the gas phase components."

Jan 1, 2019

By M. Mahdi, L. So, A. MacMillan, D. Metcalfe, J. Woloshyn, D. Sauter, N. Uys, JP. Janse van Rensburg

For city smelters, with limited real estate, efficient slag cleaning furnaces followed by water granulation to produce an iron silicate product is the preferred process approach. Water granulation, however, consumes large volumes of water and requires high maintenance due to abrasive slag/water slurries. Air granulation offers an alternative to water granulation, which eliminates water use and has low maintenance requirements. Although full-scale operation has not been implemented for copper slags, full-scale operation for platinum group metal (PGM) converter slag has been implemented. A review of full-scale air granulation performance for PGM converter slag is provided. Based on PGM converter slag granulation performance, parallels to copper slag granulation are drawn and full-scale operation for copper slag is modelled using computational fluid dynamics (CFD). INTRODUCTION Typical slag management practices in the copper industry include dumping, slow air cooling, and water granulation, as shown in Figure 1. Dumping is the most commonly used slag handling method for most metal production plants, but presents challenges including the requirement for a large slag pit, requirement for expensive/high-maintenance “hot” mobile equipment, risks associated with transportation of molten slag, and no value recovery from slag as a sellable by-product or from slag as a source of heat.

Jan 1, 2019

By Sigmund J. Andersen, Eva A. Mørtsell, Jostein Røyset, Randi Holmestad, Oddvin Reiso, Yanjun Li, Øyvind Paulsen, Calin D. Marioara

"With the purpose of increasing the extrudability of lean alloys, we reduce levels of the alloying elements Mg and Si in a 6xxx extrusion alloy. To avoid sacrificing strength, we investigate the compensating effect of smaller amounts of lithium and germanium, alone and in combination. Recent studies by atomically resolved high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with density functional theory (DFT) calculations have demonstrated that while Li replaces Mg, Ge substitutes Si in the columns in the hardening ß’’-phase. Several studies have shown that Ge replaces Si in other precipitates as well, and that both Li and Ge promote precipitation and can improve macroscopic properties, like strength and thermal stability. The scope of the current work has been to investigate and document the combined effect of the two alloying elements. Of the investigated alloys, the one containing both elements displayed highest hardness, corresponding with a significant increase in precipitate number density. We used HAADF-STEM to determine the extent of Li and Ge in the precipitate structures.INTRODUCTION The two most important alloying agents, with respect to age hardening of the 6xxx alloy series, are Mg and Si. In general, 6xxx alloys are formed into their final shapes by rolling or extrusion, before being age-hardened at elevated temperatures around 180°C. The hardening effect during this stage is due to the formation of metastable, semi-coherent, precipitate needles along the three < 001>Al directions generally following the precipitation sequence (Marioara, Nordmark, Andersen, & Holmestad, 2006): Supersaturated solid solution ? atomic clusters ? Guinier-Preston-zones (pre-ß”) (Edwards, Stiller, Dunlop, & Couper, 1998) (Marioara, Andersen, Jansen, & Zandbergen, 2001) ? ß” (Andersen, et al., 1998) (Hasting, et al., 2009) ? ß’ (Vissers, Huis, Jansen, & H. W. Zandbergen, 2007), U1 (Andersen, Marioara, Vissers, Frøseth, & Zandbergen, 2007), U2 (Andersen, Marioara, Frøseth, Vissers, & Zandbergen, 2005), B’ (Vissers, Marioara, Andersen, & Holmestad, 2008) ? ß, Si (stable)"

Jan 1, 2018

By Michel Aubertin

Les activités minières peuvent produire de grandes quantités de roches stériles, qui sont typiquement entreposées dans des empilements de surface, au dessus la nappe phréatique. Ces haldes peuvent occuper une superficie de plusieurs dizaines d?hectares, et s?élever à plus de cent mètres. Pour des exploitations en roches dures, les roches stériles ont usuellement une granulométrie qui contient des particules de la taille d?un sol silteux jusqu?à des cailloux et blocs de taille métrique. La structure interne d?une halde construite sur une surface relativement plane comprend généralement deux zones principales. La première zone se trouve au coeur de l?empilement, et elle est formée par la présence de plusieurs stratifications subhorizontales (avec des couches denses et lâches) due à l?effet des équipements lourds qui compactent et brisent les grains. La deuxième zone se trouve aux endroits où les stériles ont été déversés en crête, par des camions ou des butoirs, ce qui induit une ségrégation des particules sur les flancs, le long de la pente. Selon la séquence de mise en place, la distribution granulométrique et la hauteur des bancs, un grano-classement plus ou moins développé se produit, avec les particules les plus grosses au bas de la pente et les particules plus fines au sommet ; on observe aussi une stratification inclinée due à l?avancement latéral du front de déposition. Ces éléments de la structure interne d?une halde influencent la distribution et le mouvement de l?eau (et de l?air). Pour évaluer la distribution des propriétés des matériaux dans une halde, on doit usuellement avoir recours à une combinaison de techniques qui fournissent des informations sur les caractéristiques hydrogéologiques et géochimiques des roches stériles. A cet égard, certaines techniques géophysiques sont particulièrement intéressantes car elles permettent une cartographie tridimensionnelle des variations des propriétés. Les informations obtenues de diverses techniques de mesures utilisées conjointement peuvent alors être employées afin de construire un modèle numérique qui permet d?analyser les écoulements non saturés de l?eau et le transport réactif des contaminants. De telles simulations aident à mieux comprendre la réponse de la halde dans son état actuel et futur, ce qui fournit des arguments pour ajuster la séquence de déposition pour élaborer le plan de fermeture et pour sélectionner la stratégie d?instrumentation et de suivi de l?empilement. La présentation inclura un survol des diverses techniques qui ont été développées afin de caractériser les propriétés des matériaux en laboratoire et sur le terrain, et pour obtenir un portrait global de la structure interne d?une halde. Des résultats additionnels sur la modélisation du transport réactif seront aussi montrés afin d?illustrer l?influence de la structure interne d?un empilement sur sa réponse hydro-géochimique et environnementale.

Nov 1, 2008