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By K. G. Tan

Widely available silver and arsenic bearing concentrates can be smelted to produce a discardable slag, a base metal speiss, and a crude silver button which is easily separated from the other phases after solidification. This paper discusses the development of a novel process as an alternative to existing nitric acid leach methods for the production of high purity silver from the raw silver button. Direct electro-refining of the raw silver anode in a sulphate medium is integrated with downstream purification and recycling modules that are customized to allow efficient recovery of silver and saleable by­products. The test results, flowsheet alternatives and process details are presented and discussed in terms of overall technical feasibility, economical viability and environmental compliance considerations.

Jan 1, 1999

By Ken Deter

My recent experience has been with wet tropical environments, which address a different set of concerns than Nevada, for example. Spraying rather than drips are required in most cases just to assist the water balance requirement, and my comments address those situations. Most tropical operations are faced with both extremely wet and very dry seasons, with some having multiple cycles during the year. A heap leach operation must address the rate of solution building up within the ponds and how long the volume must last until the next rainy season. It may be easier to construct sufficient pond volume to permit yearlong operation than by discharging excess solution now, and searching for water later. Pond capacity requirements can help with the following: Consider using the solution that could be locked up in the pads during leaching to assist water balance problems. Spray excess solution continuously onto spent ore that would not be normally be sprayed again to "soak up" the excess solution, and stop spraying when the water balance is low, allowing the solution in the spent ore to return back into the system-with or without cyanide added. In a multiple lift system, if intermediate HDPE liners are planned for solution grade control, have drips placed before the HPDE liner is in place. The drips can distribute excess precipitation throughout the lower lifts to control the water balance, while the most current lifts are being leached and sent directly for the preg pond. With only 2 million tonnes (2.2 million tons) of spent ore involved, up to 200,000 cubic meters (53 million gallons) of solution could be moved into or out of the water balance system, if proper methods are designed and installed. That is equivalent to one meter (40 inches) precipitation falling on a 200,000 square meter (2.2 million square feet) pad area. You may even get a little bit more gold recovered as the solution drains from the earlier pads, as well.

Jan 1, 1999

By Jean Rainville

Gold was first discovered in the central region of French Guiana in the mid 1860's. Production was based strictly from placer mining of the various rivers in the region. At the moment, a number of companies are actively engaged in hard rock gold exploration, concentrated in the northern and central regions of the country. The Franc-Or/BRGM joint venture in the Sophie-Repentir region of Central French Guiana offers an exceptional opportu­nity for the discovery of one or more million-plus ounce deposits of gold owing to a highly favorable structural setting in Precam­brian greenstones that host several known vein gold occurrences, some of which appear to occur near the border of a potassic granitoid intrusion. At this point in time, based mostly on predecessors' work, mineable reserves could be estimated to be in the 500,000 ounces range over the length of the property. The exploration campaign under way has the objective to delineate probable reserves of at least 2 million ounces that could be mined by open pit mining methods in the area. The program should be completed in the next 18-24 months. In order to efficiently and effectively evaluate this very large property area, all of the necessary camp, mechanical and drilling equipment has been purchased and is being transported to the property. Most of that equipment was purchased in Canada. The first drill target is the Repentir sector because of its access and the amount of detailed work that has been done by BRGM on that concession, but geological evidence suggests that many areas on the property could offer even more potential.

Jan 1, 1995

By John G. Banker

Titanium/steel clad has been selected as the material of construction for six pressure acid leaching autoclaves for nickel production from laterite ores. These six pressure vessels are now in production service in western Australia. Titanium provides reliable corrosion protection in the nickel laterite pressure leaching environment. Clad metal construction offers a significant cost reduction for equipment of this type in comparison to solid titanium. Clad metal construction offers superior durability and reliability in comparison with non-metal or titanium loose-lined equipment. Experiences in titanium clad equipment construction and performance are reviewed. The presentation addresses aspects of design, fabrication, and testing which are necessary to assure reliable equipment. The explosion cladding proces and titanium alloy selection considerations are also discussed.

Jan 1, 2000

By Pierre Louis, Jacques Duparque

ACTIRED is a new process for gold and silver elution from activated carbon based on the addition of hydrazine, needing no extra investment and which generates a systematic increase in elutions kinetics. This process either operates at a lower temperature and maximizes financial gain or reduces elution time or operates at a compromise between these two options taking into account the needs of each plant. Industrial use of the process at SNC Lastours, France (Zadra elution column 3,5 bars -125°C) has proved at 95 ° C the following points:

Jan 1, 1995

By Gordon Hubbard, John D'Acierno

The Randgold Resources Ltd. mine operation in Syama Mali performs whole ore roasting followed by CIL gold recovery to produce gold. The roaster has operated continuously since the plant was first commissioned in 1994. The roaster design throughput is 216 tons per hour (5,184 TPD). Roasting provides for the oxidation of the· refractory components, organic carbon and sulfides. The energy balance for the system requires auxiliary fuel oil to be burned in the Circulating Fluid Bed (CFB) reactor. Energy from the 1200-1350 degree F roasted product stream is recovered and recycled back into the CFB using two fluidized bed coolers; one to directly heat the secondary air and the other to indirectly heat the primary fluidizing air. The basis of the design for the roaster was an extensive pilot plant test program, the results of which were scaled up to the full scale plant design. Due to variation in the feed at the mine a number of roaster modifications were necessary following the initial plant start up. During 1998 ore flotation capability was added to reduce the operating cost for the roaster and increase plant throughput.

Jan 1, 1999

By David Lunt, Paul Messenger, Peter Allen

The Rawas Gold Project in Indonesia has a high silver ore with a ratio of approximately 25:1 Ag/Au. Four process flow­sheets were considered during the development phase, ie. full Merrill Crowe, CIP, CIP with zinc cementation of eluate and a hybrid Merrill Crowe - CIP circuit. The process plant was constructed using a CIP circuit with zinc cementation of eluate. Unusual aspects of the design include an elution circuit designed to strip three batches of car­bon per day and an elution column designed to operate with either upward or downward solution flow. Significant improvements implemented since starting up the plant include the use of local materials and labour for relining the mill, a change from lime to caustic soda for pH modification and the elimination of caustic soda dosing to the elution pre-soak step.

Jan 1, 1998

By Jerry Kolstad

The Stillwater Mining Company Base Metals Refinery (BMR) leaches a PGM bearing nickel/copper smelter matte to produce a concentrated platinum/palladium filtercake. The BMR employs a two-stage sulfate based leaching process. The first stage (nickel atmospheric leach circuit) leach is performed under atmospheric conditions at elevated temperature to leach the majority of the nickel present in the matte feed. Approximately 85% of the solids mass fed to first stage leach report to the second stage (pressure leach circuit) leach. The pressure leach circuit consists of two batch autoclaves in parallel. Each autoclave has a separate feed tank. This paper will describe the second stage leaching process and report associated operating costs.

Jan 1, 2000

By John Keay, Douglas R. Shaw, Gregory J. Olso

Rhodes Mining NL, Perth, Australia, is developing the Lahoca Gold Project which is located in Hungary, about 30 km from the town of Eger. The preliminary resource is estimated to contain approximately 1.5 million ounces of gold. The project is being evaluated for an annual process capacity of 2 million tonnes. The test samples contain just over 2 g Ault and 6% sulfur as sulfide. Copper and arsenic levels are approximately 0.2 and 0.1 %, respectively. The ore is refractory due to submicroscopic gold occurrences and structural associations with pyrite. A small amount of the gold is finely encapsulated in quartz. Approximately 30% of the gold in the crushed ore is soluble in cyanide and up to about 55% is cyanide-recoverable with ultra­fine grinding. The ore has little preg-robbing ability. Metallurgical test work done by Colorado Minerals Research Institute (CMRI) and other investigators has shown that as much as 85 to over 90% of the gold was recovered by the relatively severe conditions of pressure oxidation or roasting of the whole ore or a flotation concentrate. The Lahoca ore responds to flotation with gold recoveries of 87% into a low grade concentrate. Subsequently, with a view toward defining a process route with potentially more attractive economics, Rhodes Mining and CMRI conducted an extensive review of biooxidation technologies and concluded that, in particular, heap biooxidation methods promised lower process costs which normally are associated with heap leaching. Based on the study, which included the analysis of the closely related practices of copper dump/heap bioleaching now well established in that industry, CMRI conducted simulated heap biooxidation experiments which evaluated factors such as ultra fine ore crushing, agglomeration techniques, heap design, forced aeration oxygen supply, and whether or not the heap is irrigated. Separate flask biooxidation tests at Little Bear Laboratories showed that the finely crushed ore is biooxidized readily, with a near linear relationship between sulfide oxidation and gold cyanide solubility. Gold recoveries of as high as 66% have resulted after biooxidation of crushed ore. This paper highlights the metallurgical developments of the Lahoca project, and focuses on recent biooxidation laboratory test work aimed at enhancing the treatment of crushed ore.

Jan 1, 1997

By Daniel W. Kappes

The 1.8 million tonne Itos tailings deposit is the result of sever­al years of processing by Comibol of the San Jose and ltos Mine ores at Oruro Bolivia. The historic flowsheet consisted of a flotation circuit in which silver-bearing galena and stibnite were concentrated. Approximately half the silver in the ore was not recovered, and the existing tailings contain slightly over 200 grams silver per tonne, in the form of complex sulfides of silver, antimony, lead, and other metals coating grains of pyrite. An extensive laboratory program was conducted to exam­ine conventional processing l)lethods such as cyanide leaching and regrinding followed by flotation. However, the silver-bear­ing sulfides are in intimate contact with the pyrite and the pyrite comprises 30% of the total tailings weight. Cyanide leaching recovers only 40% of the silver and the cyanide consumption is uneconomically high. Flotation produces an upgraded, but still uneconomic, concentrate. For this reason, chloride leaching had been evaluated by Comibol, and in the mid 1980's Comibol undertook an innova­tive test consisting of two 300 tonne field heap leaches using a cold chloride solution. The tests were partially successful, but could not be applied to the bulk of the tailings which are already ground to 50% minus 200 mesh. In 1992, Kappes, Cassiday & Associates undertook to develop a hot agitated chloride leach flowsheet, and is current­ly constructing a treatment plant under a turnkey contract from a Bolivian company, Baremsa, S.A. Using this process, 85% of the remaining silver can be recovered, with significant by-prod­uct credits from antimony and lead. The project features hot, agitated acidic chloride leaching, filtration, crystallization of lead chloride, and precipitation of metals using iron scrap. Arsenic is removed from the precipitate by caustic leaching, and minor metals by furnace refining. Antimony is recovered as the oxide by cupelation, and silver is poured as <lore from the cupel. Production rate will be 600 tonnes per day. Startup is scheduled for late 1995.

Jan 1, 1996

By Peter W. Willcocks

The Cyanide Regeneration Process (CRP) was developed by Golconda Engineering and Mining Services and installed at Golconda's Beaconsfield Gold Tailings Retreatment Project situated in Tasmania, Australia. The Tailings Project is a 1000 ton per day carbon-in-pulp treatment plant, feed for which consists of tailings material which is dredged from the Tamar River. The pulp is screened to remove debris, then cycloned to form two products. Underflow pulp is stored in a 350 ton bin and cyclone overflow passes to a thickener. The coarse pulp material is fed to the grinding circuit then rejoins the thickened slimes in the cyanide leach circuit. Gold is extracted by carbon-in-pulp techniques. The plant is sited in rolling, hilly country approximately 200 meters from the Tamar River. The residue disposal area is quite small consisting of four dams, totalling 42 acres. The regional climate is cool and wet with little evaporation; therefore, we anticipated a net increase in contained liquor, and subsequent storage problems. Our plan was to remove cyanide from the liquor prior to returning the detoxified solution to the river system. Such treatment was not required until midway through the second year of the project. Initial testwork on sample material indicated that destruction of cyanide by chlorine was the simple solution. Subsequent follow-up on actual plant liquor indicated a huge chlorine requirement due, we believe, to the substantial degradation of vegetable matter plus organic content from the marine environment. The cost of cyanide destruction could not be justified.

Jan 1, 1998

By Allen H. Gipson

Innovative thinking has led to the development of safe, environmentally sound, and cost effective methods for expanding existing tailings storage facilities (TSF). Three case histories are discussed here to demonstrate methods that have recently been used or are being considered for such expansions. Maintaining the integrity of the structure and reducing costs were primary goals in each case.

Jan 1, 1997

By Jock McGregor, Deepak Malhotra, Leonard Harris

After more than 100 years, alkaline cyanide leaching of gold and silver ores, either directly in the case of oxidized ores, or after pretreatment of refractory ores by roasting, pres­sure leaching or bacterial leaching, remains the dominant r leaching method to extract the precious metals f om ores. Leaching with halides (chlorine, bromine and iodine) and with thiourea and thiosulfates is less common but prac­ticed in some cases to dissolve the precious metals both from ores and jewelry and electronic scrap. Cyanide solutions can contain from 1 ppm Au to 30,000 ppm Au. According to the source, i.e., agitated tank leach­ing, heap leaching, eluates from stripping activated carbon or waste electroplating solutions. Similar variations occur with silver which can have a profound influence on the recovery method. The presence of other elements in the leach solu­tions, particularly mercury and copper, likewise play an important role in the procedures required to recover the gold r and silver values f om solution. The same circumstances are found when lixivants other than cyanide are used to dissolve the precious metals. For decades, the preferred method of recovering gold and silver values from alkaline cyanide leach solutions was by zinc dust precipitation according to the Merrill Crowe process developed in the late 19th century. Finely ground gold and silver ores or concentrates were either leached directly or after roasting, in agitated tanks or Pachucas and subjected to solid/liquid separation by filtering or by treat­ment in counter-current-decantation washing thickeners (CCD). This solid/liquid separation step was often very dif­ficult especially when ores containing high quantities of clay were treated which caused filtration or thickening problems. Following testing and development by the U.S. Bureau of Mines (USBM) in the late 60s, the introduction of carbon­in-leach (CIL) or carbon-in-pulp (CIP) plants to recover gold and silver from leach pulps was one of the greatest opera­tional and cost saving improvements made in the industry in South Dakota and quickly spread around the world to be the most common process to recover gold and silver from cyanide solutions.

Jan 1, 2000

By A. Giblett, J. Shuttleworth, R. Dunne

In a previous paper (Dunne, Martins, Goulsbra, Chittenden 1997), the new gravity circuits at Telfer Gold Mine, which incor­porate Knelson centrifugal separators in both the sulphide and oxides, are described. The advantages of the new circuits over the replaced spiral ( oxide circuit) and jig (sulphide circuit) were discussed, as were the improvements in gravity gold recovety. It is of note that the installation of the centrifugal separators in themselves did not result in increased gold recovery. The realisa­tion that changes in gold room practices are required to take advan­tage of the increased fine gold recovery from the Knelson concen­trator was an important step towards improved gravity gold recov­ery. This was achieved by increasing the time taken to treat the Knelson concentrate on the shaking table in the gold room. Although this increased gold recove1y, it was found that the table tailings, especially from the sulphide circuit, still contained high values of gold. In an effort to ascertain ways in which gravity gold recovery could be fu1iher improved, a sample of the sulphide table tailings was sent to the Oretest Laboratory in Perth for testwork. The results from this program are discussed in this paper.

Jan 1, 1998

By Dewey W. Marino

Conventional remote sensing applications for the exploration of natural resources has largely been the domain of low resolu­tion Earth orbiting systems such as Landsat™ which can sample a broad range of the spectrum. As the classic application of remote sensing, it has proven its worth through the discovery of numerous mineral deposits worldwide. Often this technique relies more on the spectral content of the imagery for narrowing potential sites on the ground, but often cannot reveal the detailed context of the observed response. As the dawn of the new era in remote sensing grows closer, high-resolution imagery is proving its worth for the definition of mineral potential and its cost sav­ing advantages for mine management.

Jan 1, 1998

By Norbert Patzelt, Johann Knecht

Future ore reserves of major gold producers in North America and elsewhere will consist of refractory gold ores. About 60 % of the current U.S. gold production is mined in Nevada. Several of the large gold operations in this state indicate that 40 to 90 % of their future ore feeds will contain refractory gold. To com­pound problems, average head grades for refractory U.S. gold ores had fallen from 8 - 9 g/mt to about 4 g/mt by 1991. In Latin America, 52 % of the gold operations will require milling for optimal recovery. Deeper reserves are, like in North America, refractory. Therefore a special treatment process is needed in order to allow for the gold ore to be leached downstream in a conven­tional cyanidation process for a high gold recovery. There are several options available for this oxidation process like treat­ment of the gold bearing ore in pressure oxidation, in a biooxi­dation or in a roasting plant depending on the reason for the refractoriness. If organic carbonaceous matters and sulfides are the prima­ry reasons for the refractoriness, whole ore roasting is a pre­ferred method for the treatment of this type of ore. Since dry ore is to feed to the roaster, a dry grinding mill is advantageous. For the dry grinding system, the moisture content and the ore char­acteristic is of importance. Those parameters decide the mode of the grinding system. For autoclave systems common wet grind­ing systems can be applied. This paper deals with technical aspects for dry grinding plants and gives an outlook on and pos­sibilities for new grinding systems.

Jan 1, 1996

By Ron Parks

High Pressure Grinding Rolls (HPGR) was introduced to the mineral processing industries in the mid-SO's as a tool for comminuting raw and processed materials. This tool made its an impact in the Cement Industry where it was used as a pre-grinder on existing ball mills, raw and finish grinding in a mill circuit and other various applications. This concept was a big success where the cost of power was high along with the desire to increase capacity. The HPGR reduced the power requirement and increased the capacity in the ball mill due to the finished product produced by the HPGR and the micro fractures in the coarse rock, which reduces the power required to finish grind the rock. This unit has found acceptance in many other industries including diamonds, iron and other selective applications. The diamond industry uses this tool for selective grinding purposes since the kimberlite rock is considerably softer than the actual diamonds. Therefore within a bed of material, kimberlite is crushed to fines and the diamonds are liberated and unharmed. The iron industry primarily uses this tool for concentrate comminution; however, there are installations using this tool as a pebble crusher and in an AG-pebble mill circuit.

Jan 1, 2000

By W. H. Jay, F. Lawson, D. F. A. Koch

Ion exchange resins may in the future displace activated carbon in gold plants where cyanidation is practiced. Recently patented technology based on interpenetrated polyurethane polymers shows that these new materials offer significantly improved loading kinetics over both activated carbon and commercially available ion exchange resins. These polymers are not restricted either in particle size or in density and therefore offer the gold industry the potential for a further technological advancement.

Jan 1, 1995

By Keith J. Henley, Nicholas C. Clarke, Paul Sauter

A detailed investigation of the stability in cyanide solutions of native gold and gold-silver tellurides in a flotation concentrate from the Golden Mile, Kalgoorlie, has been undertaken to assess whether leaching under different conditions can be used to quantify the distribution of Au between native gold and gold-silver tellurides, as suggested by, for example, Chryssoulis and Cabri (1990). The leaching was carried out on +20 µm native gold and gold-silver tellurides separated from a high-grade flotation concentrate and then diluted with barren quartz. The material leached assayed 270 ppm Au and 118 ppm Te and the leach conditions used were:- Stage 1: Leaching in dilute cyanide (0 .1 % ) at pH 9 .5 for 24 hours to dissolve native gold but not gold-silver tel­lurides. Stage 2: Leaching the residue from Stage 1 in strong cyanide (2%) and pH 12.5 for 96 hours to dissolve gold-silver tellurides.

Jan 1, 1995

By Morris Beattie

Arseno Processing Ltd. has developed process technology for the extraction of gold from refractory ores and concentrates. These ores, which do not respond to conventional extraction processes, are rapidly becoming the primary targets for mining companies wishing to become significant gold producers. It has recently been estimated that by the mid 1990's, the annual gold production from the Pacific Basin Epithermal Arc in southeast Asia could be as high as 550 tonnes. Within this area the Porgera deposit under development by Placer, Renison and MIM, and the Lihir Island deposit under development by Kennecott have been shown to be refractory and require pretreatment before the gold can be extracted. The additional deposits which are now starting to be developed in this area are also expected to require such pretreatment. The Arseno process promises to be an economical pretreatment for these ores and to result in the maximum achievable gold recovery. Numerous refractory deposits are also known in Australia, North America, China and other parts of the world. Samples from many deposits throughout the world have been tested using the Arseno process conditions and the consistently successful results have demonstrated its widespread application. The samples which have been tested include ores in which the gold is locked in pyrite, marcasite or arsenopyrite. The process is insensitive to the sulphur content of the feed. Feed materials containing from 1 % to 50% sulphur have been tested successfully with the process. In the Arseno refractory gold process, sulphide minerals are dissolved so that the contained gold becomes accessible for subs7qu7nt gold recovery. This gold recovery is achieved by cyamdat1on of the process residue. For many of the materials which have been tested, gold extractions in excess of 95% have been achieved.

Jan 1, 1998