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By B. Nemutudi, X. Zhang, B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, S. Pikinini

The comparison study on adsorption of potassium normal butyl xanthate (PNBX) and sodium (nbutyl) dithiocarbamate (SNBDTC) on sperrylite mineral forms a basis in understanding the floatability improvement and paves a way for the design of collectors that may impact on a wide range of arsenide minerals. This study used a computational density functional theory (DFT) and experimental microcalorimetry approach to determine the adsorption energies of PNBX and SNBDTC collectors onto a sperrylite mineral surface. From a computational aspect, we considered the most stable surface plane of (100) surface, which had been found to give the lowest surface energy, compared to the other surface planes. It was observed that the PNBX and SNBDTC preferred to bridge on the As and Pt atoms through the S atoms. These findings showed that the collector adsorbed on the surface through both Pt and As atoms and indicated that the As atoms were significantly active in the adsorptions. We found that the adsorption energies were in the order: SNBDTC (–278.38 kJ/mol) > PNBX (–270.92 kJ/mol), indicating that the dithiocarbamate had stronger exothermic adsorption than the xanthate. From the microcalorimetry test it was also found that the SNBDTC was more exothermic than the PNBX and the adsorption energies were: SNBDTC (–473.50 kJ/mol) > PNBX (–331.13 kJ/mol). These results showed that the nitrogen atom in the SNBDTC collector had a great influence on the adsorption strength of the collector on the mineral surface. This is due to the electron deposition behaviour of nitrogen atoms compared to the electron withdrawing character of oxygen and as such the SNBDTC showed better collecting ability than the PNBX. These results paved the way for the design of collectors for sperrylite and other arsenide minerals and suggested that nitrogen in a collector may significantly improve the ability of the collector for improved recovery. Keywords: Computational modelling, microcalorimetry, SNBDTC and PNBX collectors, adsorption energies

Jan 1, 2020

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, Gary O’Connell, Denis Shishin, Jeff Chen, Francis Letarte

"Knowledge of slag properties is required for the optimisation of smelting operations. The phase equilibria and viscosities of the Al2O3-CaO-FeO-Fe2O3-MgO-MnO-NiO-Cr2O3-SiO2 slags at conditions of interest to Koniambo Ni-laterite smelting operations have been investigated. High-temperature re-equilibration phase equilibrium experiments of industrial slags followed by rapid quenching and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) have been undertaken in the olivine and pyroxene primary phase fields at temperatures between 1475 and 1600°C and SiO2/MgO weight ratios between 1.57 and 2.09. Phase equilibria predictions were performed using FactSage thermodynamic software. A slag viscosity model available in the FactSage thermodynamic package has been used to calculate the viscosities of the liquid slags. The Einstein-Roscoe equation combined with the predicted phase equilibria data have been used to estimate the viscosities of the slag slurries (slag + solids). The information provided can be used to assist in the evaluation of the furnace performance, to assess further optimisation of slag composition and to explore possibilities of targeted feed changes.INTRODUCTION One of the key steps in the production of ferronickel from nickel laterite ore at Koniambo Nickel SAS involves reduction and smelting of pre-dried nickel-bearing saprolitic ore (high Mg and Si) in an electric furnace at temperatures up to 1650°C. The characterisation of the slag properties as functions of key operational parameters, such as, temperature and composition, including liquidus, the proportions of solids and viscosity, is essential for improving control and optimisation of the operations. The slag produced in the smelting process is a complex oxide system with the major chemical components including Al2O3, CaO, Cr2O3, “FeO”, MgO, “MnO”, “NiO” and SiO2. Characterisation of these multi-component systems using a solely experimental approach becomes increasingly complex as the number of components is increased."

Jan 1, 2017

By Godfred Amponsah, Mehrdad Razavi

Slope failures very commonly occur during a long period of heavy rainfall and groundwater rise. The failures pose a substantial risk to people, infrastructure, and equipment downslope. In the recent past, the mining industry has faced an increase in tailings dam failure due to several reasons including pore pressure increases in the dams. Many failures have been observed to occur during times of water level fluctuations but the critical factors that influence the initiation of slope failures still need to be adequately clarified. To investigate these factors, laboratory experiments were conducted on model sandy slopes to determine pore pressure-induced slope failure initiation. This study also presents a method to examine water seepage through soil slopes using an ultraviolet (UV) dye and a UV flashlight. The small-scale model test simulation demonstrated failures induced by either water percolation from the upslope tank at a constant level or by raising the water level at intervals. A bottom chamber fully filled with water to replicate groundwater rise was also simulated. The soil slope was monitored at every stage to study the deformations and behavior until failure occurred. Results gathered from the controlled laboratory conditions were useful for the verification of the numerical modeling method created in the computer program Slide. The analysis showed that slope failure always occurred when the toe was fully saturated. High pore pressures and seepage forces reduce the shear force at the toe to almost zero causing it to slide. A comparison of slope height to water level also indicated an average of 96% water level to cause a failure. At this point, the soil slope is fully saturated and has no matric suction. The findings in this study show that, by monitoring the moisture content of slopes, failures can be predicted.

Feb 1, 2024

By Xin Wang, He Shao, Wenpu Li, Yiyi Zheng, Xi Chen, Yurong Gao

This study utilized experimental and numerical simulation methods to investigate and analyze the atomization characteristics of three internal air–water mixed atomizers under different operating conditions. By comparing the research results, the effective dust control working parameters for the application of the selected atomizer in the engineering field were determined. Firstly, the atomization characteristics of the three atomizers were studied using a customized experimental system. The results indicated that nozzle 2 had a wide atomization range, a small atomization distance, and small droplet size; nozzle 3 had a narrow atomization range, large droplet size, and fast atomization speed; and nozzle 1 not only had a large atomization range but also could produce droplets of dry mist size with fast atomization speed, meeting the dust reduction requirements of the Majiliang Coal Preparation Plant. Secondly, Fluent software was used to simulate the atomization process and particle size distribution of the three internal mixed atomizers, determining the working conditions of the atomizers, the required number of atomizers, and the application angle of the atomizers in the internal mixed dust removal system. Finally, the atomized dust control system was applied on-site, achieving a total dust removal efficiency of 90.72% and a respirable dust removal efficiency of 89.75%.

Mar 9, 2024

By I. V. Filippova, Y. Foucaud, M. Badawi, L. O. Filippov, S. Lebègue

To optimize the flotation of Ca-minerals, their separation contrasts were investigated by coupling experimental and theoretical techniques. We showed that they mainly rely on structural properties such as the Ca-Ca distance on their exposed surfaces but also on the ability to control the intermolecular interactions. An optimized composition of the carboxylic collector by calculating the collector-mineral and the intermolecular interactions was developed. Blending the saturated acids and non-ionic molecules with a fatty acid collector significantly increases the flotation selectivity between scheelite (CaWO4) and fluorite (CaF2). The theoretical results were validated by experimentally improving the separation contrast between Ca-minerals. After the tests of several depressants and collectors, the best depression of gangue Ca-minerals (fluorite, apatite and vezuvianite) was found by combining sodium silicate and sodium carbonate. Keywords: Ca Minerals, Fluorite, Scheelite, Carboxylic acids, Unsaturated Acid, Fatty acids

Jan 1, 2020

By Øystein Sture, Kurt Aasly, Ben Snook, Sigurd A. Sørum

INTRODUCTION Efficient exploration methodologies for base metal deposits have huge benefits for future deep sea mining endeavours, and underwater hyperspectral imaging (UHI) has been variably demonstrated to have applications in the identification and characterisation of mineralisation on the seafloor for both nodules and seafloor massive sulphides (SMS) (Dumke et al., 2018 and 2017 respectively). Due to growing resource requirements (Singer, 2017), SMS deposits are considered to be increasingly significant sources of copper and zinc, as well as silver and gold. This style of mineralisation is currently occurring at active hydrothermal vents (black and white smokers) but now-inactive sites also have the potential to be large mineral deposits. As such, the development of novel methodologies to detect both on-going and extinct mineralisations are of high importance. Geological setting During the MarMine cruise (Ludvigsen et al., 2016), non-mineralised host rock, low grade ore and high grade ore grab samples (Snook et al., 2018) was collected by ROV from the Loki’s Castle deposit (Pedersen et al., 2010), located on the Mohn’s/Knipovich junction on the ultra-slow spreading Arctic Mid-Ocean Ridge (AMOR), at a depth of approximately 2300 m. This material has been characterised as part of the MarMine project (e.g. Snook et al., 2017), and, by imaging compositionally constrained material, the measured hyperspectral responses can be used to generate a library for identification of deposits on the ocean floor. UHI technology Remote sensing with hyperspectral and multispectral technologies has seen wide use in prospecting for ores and hydrocarbons on land (Van der Meer et al., 2012). Iron oxides and sulphides have low blue reflectance and high red reflectance in the visible spectrum. The ratio between these two pairs has been used in exploration for terrestrial deposits of hydrothermal origin (Sabins, 1999). This discrimination typically also includes wavelengths exceeding the visible spectrum (1.5µm – 2.5µm). These wavelengths are typically not utilised underwater because infrared wavelengths and higher are rapidly attenuated in water. However, discrimination based on the full shape of the spectral response in the visible light (350nm – 800nm) may still be possible (Bolin and Moon, 2003). Resolving the endmembers from the spectral responses requires prior knowledge about the optical properties of the materials, i.e. their reflectance. These reflectances can be obtained in a controlled environment, where the spectra of the lamps, wavelength- dependent attenuation in water and scattering of light can be accounted for (Johnsen, 2013).

Jan 1, 2018

By R. J. Sweigard

Stabilization of slopes on abandoned mine land (AML) invariably involves some channelization to control surface drainage. Typically, these channels are lined with riprap or gabions, depending on gradient and expected flow rate. The conventional treatments pose a problem since they require frequent maintenance and replacement at times. Soil bioengineering presents an alternative to the conventional measures. In soil bioengineering, living woody plant material forms the main structural component in systems designed to prevent shallow mass slope failures, surface erosion, and channel bank erosion. An experimental application of soil bioengineering techniques was designed and implemented at an AML site in eastern Kentucky. The design consisted of live fascines and live stakes using willow branches installed with coir geotextile. Channel gradient, length, and cross-section were considered in the design.

Jan 1, 1998

By D. Neuschiltz, M. Witthaut, R. Cremer

"Metastable (Ti,Al)N coatings with fee structure have been shown to exhibit superior performance as compared to TiN under conditions of wear at elevated temperatures due to their better oxidation resistance and hardness. The oxidation resistance of these coatings increases significantly with increasing Al-content. However, the deposition of (Ti,Al)N films with Ti/ Al ratios below about 30/70 leads to a hexagonal structure which is not suitable for tribological coatings. Only little is known about the location of the cubic to hexagonal phase transition and hence about the optimum composition of (Ti,Al)N hard coatings.To determine the position of this transition, Tii-xAlxN films with different Ti/Al ratios were deposited on high speed steel at substrate temperatures between 100 and 700 °C by means of reactive MSIP. The composition of the films was determined by electron probe microanalysis (EPMA) and X-ray photoelectron spectroscopy (XPS), the crystallographic structure by thin film X-ray diffraction (XRD).It could be shown that in case of deposition temperatures of 300-700 °C a two-phase region exists in the metastable TiN-AlN phase diagram, which expands with increasing temperature, wheras at 100 °C substrate temperature no two-phase region was observed. But in opposition to the phase diagram known from literature, which is based on thermodynamic estimations, the detected two-phase region is narrow for typical PVD temperatures, thus allowing the deposition of cubic single-phase Al-rich (Ti,Al)N hardcoatings for tribological applications. Based on these results, a new Ti1-xAlxN film with x = 0.62 has been developed, which showed an increase of oxidation resistance by a factor of 4."

Jan 1, 1998

By E. L. Burwell

Preliminary results of an in situ oil shale retorting experiment conducted by the Bureau of Mines in a shallow bed of Green River oil shale at Rock Springs, Sweetwater County, Wyo., are described. Eleven wells were drilled into a 20-ft-thick section of the shale lying between 68 and 88 It deep, and attempts were made to connect the wells through the shale with a fracture system created by application of high-voltage electricity (electro-linking), hydraulic fracturing, and explosive fracturing. Ignition of the shale through the central well was easily achieved with a propane burner, and shale oil began to collect in three wells within 3 hours. Propane injection was discontinued after 7 days, and combustion continues, although attempts to control the direction of the combustion front have been unsuccessful. Production rates as high as 4 ½ barrels of nil per day have been recorded, but too little is known about underground conditions to permit an estimate of recovery efficiency at this time.

Jan 1, 1969

By Courtney Black, Paul F. Ziemkiewicz, Eberhard Werner, Matthew Daly, Joseph J. Donovan, Jeff Frazier

Injection of alkaline waste-lime slurry was performed at a West Virginia surface coal mine site, to attempt neutralization of acid springs by an alkaline recharge method. Deep trenching (>5 m) using an excavator yielded the most effective injection into the aquifer. Water from two springs, 90 m from the deep trench, showed 70%-80% reduction in acidity in response to injection. Neutralization persisted >170 days after treatment, with pH between 5.1-5.7 and metal acidity from 25-60 mg/L. A minor fraction of lime introduced was consumed. The sustained neutralization is attributed to reaction of acid water with subsurface lime, entrained below the wafer table by macropore infiltration. Characteristics of groundwater transport are critical in determining recharge structure location.

Jan 1, 2000

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

By Minna Rämä

Iron containing leach residues like jarosite and goethite from electrolytic zinc production contain many valuable metals and harmful substances. These metals and substances should be removed in order to obtain an acceptable, stable and reusable product, and maximize economic feasibility as well as minimize environmental footprint. In this work, the processing of jarosite leach residue was studied in laboratory scale experiments under oxidizing and reducing conditions at high temperatures. First, the pretreated material was melted and oxidized to produce a melt of metal oxides. Second, the oxide melt was reduced in CO–CO2 atmosphere. Target after the reduction step was to obtain a clean slag and a liquid metal or speiss phase that collects the valuable metals, such as silver. The kinetics of the thermal processing were studied for determining optimal times and conditions for the aforementioned process steps. The preliminary results show that the process is thermodynamically feasible, and the desired phases can be obtained in the experimental conditions investigated.

By Neel Gupta, Brijes Mishra

Coal mining activity disturbs the natural equilibrium of in situ stress state such that the induced stresses deform the surrounding rock mass. Although the installation of roof supports typically prevents rock deformation, rock mass failure may still occur in bolted roof. The erratic failure of rock mass after few days to months and years of excavation is the result of time-dependent deformation of roof rock under constant surrounding stresses. In the current research, the triaxial laboratory creep experiments proved that Marcellus shale exhibits time-dependent deformation under constant stress that was smaller than the failure strength. However, unlike conventional experimental results, the time-dependent deformation did not depend on the level of constant stress. The often-neglected initial state of specimens and intrinsic heterogeneity highly influenced the time-dependent failure of Marcellus shale.

Jul 27, 2021

By H Masoumi, I Canbulat, Y Zhao, J Oh, H Lin

Borehole breakout is a drilling induced phenomenon caused by overstress of rock around the borehole. Its depth usually aligns with the minimum horizontal principal stress direction. For this reason, it has been used to determine stress orientations and a series of researchers also argued its dimensions can be indicative of stress magnitudes. If the stress dependencies of breakout geometries are well understood, it is possible to estimate stress magnitudes based on these data. This paper investigates the influences of critical parameters on breakout dimensions, including absolute stress magnitudes, stress ratios and borehole diameter. Several experiments have been conducted on cubic (120 x 120 x 120 mm3) sandstone samples with pre-drilled holes (22 mm and 30 mm) under true tri-axial loading conditions using UNSW self-designed equipment. Experimental results confirm the increasing maximum horizontal principal stress magnitudes result in larger angular span and longer breakout depth at constant minimum horizontal and vertical principal stresses. There is also a considerable discrepancy observed between experimental results and the analytical model. Findings of this study imply a potential on the estimation of stress magnitudes using borehole breakout. CITATION:Lin, H, Oh, J, Canbulat, I, Masoumi, H and Zhao, Y, 2018. Experimental investigation on borehole beakout and its implication on stress magnitudes, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 266–273 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By Kenneth Gavin, Weichao Li, Paul Doherty

"The lateral load capacity is one of the most important issues to be considered in designing piles to resist berthing loads, ship impact forces and for monopiles used in the offshore wind sector. A number of semi-empirical design approaches are available to calculate the ultimate soil resistance and assumed soil reaction profile along the piles’ embedded depth. In order to investigate the response of monopiles to lateral loading, a series of field experiments were conducted on instrumented steel pipe piles. Two lateral loading tests were performed on model piles with a diameter, D, of 340 mm and embedded depth, Lem, of 2.2 m, giving a Lem/D ratio similar to those adopted in the offshore wind sector. The piles were driven into dense sand at the University College Dublin geotechnical test bed site in Ireland. 10 pairs of strain gauges were installed on each model pile along the embedded depth at 10 levels to capture the load transfer and bending moment within the piles. The deflection and rotation at the model pile head were measured by Linear Variable Differential Transformer (LVDT) and inclinometers. The tests results were used to perform a detailed evaluation of current design methods. In the final section, discussion on the determination of the ultimate lateral load capacity for monopile design was conducted. IntroductionA pile’s lateral load capacity is determined, for design purposes, by two conditions: 1) the ultimate lateral load, Fu, divided by an appropriate safety factor; and 2) the load according to the maximum lateral deflection that the support structures can sustain. In view of the first condition, design methods to calculate the ultimate load were developed for piles used in the offshore oil and gas sectors, which tend to be much more slender than monopiles used in the wind industry. The purpose of this study was to investigate whether these design methods provide reasonable estimates of ultimate capacity, for short rigid monopiles.The methods to determine the ultimate lateral load generally follow three steps: 1) determine the ultimate soil resistance, Pu, along the pile embedded depth; 2) adopt the most appropriate soil reaction profile, Pz, along the piles embedded depth when the pile subjected to the ultimate lateral load condition (four of the most popular ones are depicted in Figure. 1); and 3) ensure equilibrium of lateral forces (see Equation 1, symbols are listed at the end of the paper) acting on the pile and bending moments (see Equation 2) about a point in pile is employed to determine the ultimate lateral load."

Jan 1, 2015

By Peng-Fei He

CT scanning tests were used to detect the pre-existing fracture systems of 36 cubical coal blocks. Systematic procedures were developed to construct the pre-existing fracture geometry of the cubical coal blocks from the CT images. Based on the constructed fracture systems, the fracture tensor components were calculated to capture the directional effects of the fracture system of the cubical coal blocks. The effect of the pre-existing fracture system and different combinations of confining stresses on the strength and deformability of coal masses was investigated at a preliminary level using some true triaxial test results and the computed fracture tensor components. The strength of the cubical coal blocks in the loading direction was found to be closely related to the summation of the fracture tensor components in the two perpendicular directions to the loading direction and the level of the confining stress system. The deformability of cubic coal blocks in the loading direction was found to be correlated to the fracture tensor component in the same direction.

Jan 1, 2014

By D. E. Hilts, R. P. Miller

A large coal-fired power plant is to be built jointly by Pacific Power & Light Co. of Portland, Ore., and by The Washington Water Power Co. of Spokane, Wash., at a site about six miles northeast of Centralia, Wash. (Fig. 1 inset). Coal will be mined from nearby open-pit strip mines that will require cut slopes up to 250 ft in height. Coal will be removed from a seam approximately 50 ft thick, located at the bottom of the mine slopes. The coal fields are located in a geologically complex area that has been subjected to intense folding and faulting. As a result, the soils and rock comprising the overburden are highly fractured, jointed, and faulted. Classical approaches to slope stability based solely on the physical proper- ties of the overburden appeared to offer little assurance that theoretically stable slopes would remain stable. Further, the scope of the exploration program that would be required to provide a reasonable evaluation of the primary and secondary structural features from which a statistical evaluation could be developed was considered impractical. As part of the development of an overall mining plan, an experimental Pilot mine excavation, about 225 ft high and about 400 ft long at the base, was made within the coal field. This experimental cut was to provide firsthand knowledge of cut slope behavior. Our purpose at the Pilot mine was to observe the cut slopes as the excavation proceeded. To accomplish this purpose, the highwall of the experimental cut was instrumented to measure face movements and movement at depth behind the face. In addition, a detailed geologic map of the soil and rock conditions exposed in the highwall was prepared, and continual visual observations of the mine were made, noting significant events as they occurred.

Jan 1, 1970

Four actual coal mine waters were used in various phases of the research program. All were from the Sewickley Creek area In Westmoreland County, Pennsylvania. The BCR designations, site locations, and nature of the mine water samples are described briefly in the following paragraphs.

Jan 1, 1971

By Vladimir E. Vigdergauz

"Bubble-mineral complexes could be formatted by an attaching of hydrophobic particles to the surface of air bubbles or by an evolution of bubbles from solution onto hydrophobic surfaces. Measurements of contact angles, detachment forces (DF), induction times (IT), evolution pressures (EP) and flotation recoveries (FR) for the studying of minerals wettability at various pH and electrochemical potentials were used. An analysis of the obtained IT results show that a process of bubble attachment to a mineral surface is a rather slow one and it will scarcely be enough for bubble-mineral complex formation under the conditions of real flotation.The ranges of adhesion potentials obtained by DF measurements, Figure 1, correlate with the data of floatability-potential for pyrite. The ranges of adhesion potentials obtained by DF measurements for galena (-1 ÷0.2V) and chalcocite (-0.5÷1.2V) correlate with the potential ranges of floatability for galena (<0.2V) and chalcocite (>-0.4V). An increase of the DF and the cathodic limit of the adhesion potential with increasing length of the hydrocarbon chain were observed. EP-pH curves for sulfides are a mirror-like to the DF-pH curves, Figure 2. Structure of solid-liquid and liquid-gas borders has a determinative importance for formation of bubble-mineral complexes and subsequently flotation results. Under vacuum on the mineral surface there are produced micro bubbles and preferably they will be appeared on the hydrophobic sites. Water structure breaks near a hydrophobic surface facilitate water mass destruction and formation of gaseous phase embryos under decompression in the impeller zone. It simultaneously reduces a probability of produced micro bubbles dissolution as a result of pressure increasing owing to constant fluctuation of liquid densities into impeller zone. Comparison of Taggart’s evaluation of the suction behind blades of the impeller of an agitation-froth machine and ABEP data on galena, Figure, shows that gas evolution will be observed in the range of 1300-2700 revolutions of impeller per minute for hydrophobic and hydrophilic surfaces successively."

Jan 1, 2003