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By Z. H. Khan, A. K. Saha, D. D. Akerkar

The possibility of extracting nickel from a low-iron, highly siliceous nickel ore of Indian origin using roast reduction followed by an ammonia leaching process has been examined. The ore used in the investigation contained 0.82 wt% Ni, 6.20 wt% Fe3O4, 12.04 wt% MgO and 60 wt% SiO2. Phase changes in the constituent minerals on heating were studied by differential thermal analysis which revealed endothermic peaks at 110 and 695 degrees C and an exothermic peak at 810 degrees C. Significant process variables in studies of roast reduction include the amount of reductant, the temperature of reduction and chemical kinetics. Maximum nickel extraction was achieved by reducing the ore with 10 wt% fuel oil at 750 degrees C. The reduced ore was given a preconditioning treatment in concentrated ammonium hydroxide solution to oxidise most of the metallic iron and was then leached in aqueous ammoniacal solution at ambient temperature to dissolve nickel. This gives 88.5% extraction of nickel as soluble ammine complexes.

Jan 4, 1992

By J. A. Saunders, E. L. Rowan

It is now widely accepted that the metal-rich waters found in the oil wells are possible present-day analogues of the mineralising solutions that formed the Mississippi Valley-type (MVT) deposits throughout mid-continental USA and elsewhere. A study characterising the trace-metal content provides additional circumstantial evidence for a genetic link between sediment-hosted mineral deposits and basin brines: Ag, Co, Ni, As and Mo, detected in the scale, are locally present in accessory minerals in MVT deposits and the levels of Ag found in the wells support the conclusion that sedimentary sources for silver should be considered in evaluating the origin of Pb-Zn-Ag deposits in sedimentary terrains

Jun 12, 1905

By J. M. Smith

This resume provides an account of the work of the Bureau and it's establishment by an Act of Parliament in August 1916. The Medical Bureau is concerned solely with the administration of the medical provisions of the Act. Its main functions are to conduct and to direct or control the medical examinations provided for in the Act. The paper covers the changes in type of silicosis, classification into the three legal stages of silicosis, cancer of the lung and tuberculosis.

Jan 1, 1947

By R. W. Ruddle

The present state of knowledge on this subject may briefly be summarized as follows: (1) The copper content of the slag increases with the grade of the matte in contact with it; on the other hand, the proportion of copper lost decreases as the matte grade increases, because as a general rule a smaller volume of slag is produced when a high-grade matte is made. (2) The presence of CaO and MgO in the slag decreases the copper content of the slag, and the presence of ZnO increases it; the presence of A1203 seems to have little effect. The influence of the silicate degree is not yet clarified, but on theoretical grounds it seems likely that the copper content increases with the silicate degree of the slag. (3) High slag viscosity, high magnetite contents and low density difference between matte and slag all tend to increase the copper loss. The volume of slag is also an important factor. (4) The effect of bath temperature on the copper loss is not clear and further investigation of this point is needed. (5) It appears possible to recover a large part of the copper in the slag by adding FeS, CaS and other sulphides

Jan 1, 1953

By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By E. H. W. Hornbrook, P. W. B. Friske

Paper presented at the 28th International Geological Congress, Washington DC, July 1989 (International geochemical mapping sessions). The objective of the programme is to establish and maintain a nationally consistent geochemical drainage database. Towards this end systematic surveys have been conducted since 1973. To date more than 200 surveys have been completed to the required standards, representing 180 000 sites and covering about 2 100 000 km2 throughout Canada

Jun 13, 1905

By Winmill T. F.

The previous papers have been concerned only with the atmospheric oxidation of coals from the Barnsley Seam, for which it has been shown that an adequate explanation of the origin and nature of gob-fires can be based on the reaction between the coal itself and the oxygen of the air without the intervention of any other substance. It becomes of importance, therefore, to ascertain how far a similar explanation will hold good for spontaneous heating in other seams, and with this object in view samples including anthracite and lignite have been taken from a considerable number of pits in different parts of the UK (south Wales, Northumberland and Durham, north Staffordshire, Portrush and Ayrshire), some liable to fire, others not. There is abundant evidence to support the commonly-accepted view that spontaneous heating is due to the heat evolved during the absorption of oxygen from the air by coal or pyrites. The quantity of heat produced by the reaction has been measured and it has been shown that the observed rate of heating of a sample of coal agrees with the rate calculated from the heat of reaction and the rate of absorption of oxygen

Dec 1, 1916

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

By J. H. Chesters

The main, though rarely mentioned advantage, is likely to be the standardisation of best practice and product. In a batch process conditions vary cyclically, but with a continuous process they would, at least ideally, remain the same for long periods of time. The other main advantages of continuous over batch processes are likely to be reduced operating and capital costs, the improved possibilities for automatic control, and more consistent product quality. Recent developments are surveyed for ironmaking and steelmaking with reference to blast furnaces; solid-product and molten-product direct reduction; the trough-type processes of Thring, Worner, the Japanese National Research Institute for Metals and Glinkov; basic-oxygen furnace (LD) variants; spray steelmaking; continuous casting and vacuum degassing; rolling; and coating. Encouragement in the devleopment of continuous processes may be drawn from the way unexpected difficulties, such as trouble with sulphur and refractories, were tackled and overcome to achieve the float glass process

Dec 1, 1971

By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

By R. Macleod, G. G. Bursey, T. R. C. Aston, J. E. Gale

In 1991 the problems of water inflow at the mine were addressed by a three-phase study. A three-dimensional finite-element computer code, CFEST (Coupled Fluid, Energy and Solute Transport), was used to model the system of groundwater flow around the mine, allowing assessment of the nature of the hydrological regime and of the various recharge mechanisms and sources of inflow. A regional (111 km2) model was used to simulate conditions of low to average mine inflow and provide boundary conditions for the subsequent local (16.8 km2) model. The regional model produced inflows of 0.26 m3/s and the local model 0.25 m3/s. With the use of constant head conditions to simulate a saturated flood plain along the Gays River and on doubling the rate of surface recharge, the local model produced a maximum mine inflow of 0.255 m3/s, in contrast to a measured peak mine inflow of 0.37 m3/s. The discrepancy suggests that during periods of high river level surface water gains access to features with high permeability, such as sinkholes, that may be connected directly or indirectly to the mine workings. Improved simulation of high inflow conditions can probably be achieved by determining the hydraulic conductivity of the river-bed and flood-plain sediments and modelling known sinkholes as discrete units. Possibilities for controlling the amount of inflow to the mine include sealing the flood plain with dykes, checking regularly for new sinkholes, which should be filled and capped, maintaining adequate mine drainage, and monitoring well levels and pressures on a continuous basis.

Jan 12, 1993

By R. J. Bridges

Mining operations on the Witwatersrand are conducted for the most part in rocks of highly quartzitic character. They comprise the following types: Conglomerates, grits, and quartzites, to which on the Far East Rand must be added fine-grained quartzitic shales and shales. In addition, vein quartz occurring as small veins, veinlets and fissure fillings, and igneous rocks forming dykes, must be mentioned, although they constitute only a small percentage of the rock broken. The following is an account of the character and mineralogical composition of the various types.

Jan 1, 1947

By R. G. Siddall, W. Gale

In the UK the development of the science of strata control has been strengthened by a resurgence of interest in the specialism of roofbolting and its associated techniques. The evolution of the theories and practices of strata bolting in roadway stabilisation is discussed. Practical experiences are considered, principally the use of Australian techniques, the relationship between bond strength and annulus and the effects of stress in the ground. Areas of new technology such as cable bolting, injection anchors and on-board bolters are also discussed. The recent advances in computer technology and rock testing equipment and methods have provided the opportunity to simulate ground behaviour under various conditions. Computer modelling developments and the use of techniques to predict ground behaviour are described.

Jan 4, 1992

By J. Laskowski, J. Lekki

"The mechanism of joint action of a frother (alpha-terpineol) and a collector (ethyl xanthate) in the flotation of chalcocite has been examined. In order to study the dynamic effects of frother and collector in bubble-particle collisions, the following aspects were investigated : determination of zeta-potential. Measurements of the thickness of fluid film on the surface of chalcocite and adsorption of xanthate, as influenced by alpha-terpineol, induction time and flotation versus concentration of alpha-terpineol and ethyl xanthate.The mechanism of the adsorption-desorption phenomenon on chalcocite with regard to non-ionic molecules, e.g. a-terpineol, has been considered, and the influence of this on the stage and thickness of the intervening wet layer between a bubble and a particle, changing the probability of collision and attachment, is suggested."

Dec 1, 1971

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

By R. N. Pryor, S. H. Shaw, D. L. Dowie, S. H. U. Bowie, M. J. Cahalan, S. F. Gandar

It is concluded that land-based mineral resources will be adequate for most minerals in the immediate future, but in the long term more minerals will come from offshore locations. Because the oceans are international and can transport pollution, international control of offshore workings will be necessary. In the UK and similarly highly developed areas, the working of low-value bulk minerals will create increasing problems in urban development and countryside preservation. Much more information should be published on standards to be adopted and their costs, if emotional social pressures founded on ignorance are to be avoided. The Town and Country Planning Acts have greatly improved the environmental quality in Britain in relation to mineral working. In the long term conservation of some minerals in short supply may be necessary on a national or international basis. Much research is required for the determination of adequate criteria and standards for the preservation of environmental quality in the mineral industry. New local, national and international legislation will be required and the adoption of voluntary standards by trade associations should be encouraged wherever appropriate

Dec 1, 1971

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By S K. Das

An intensive investigation into modern roof support technology, including hy draulic and control systems, has been carried out against the perspective of global development and support behaviour on longwall faces across the Indian sub-continent. The wide ranging study examined various types and designs of modern supports used in seams of varying thickness and inclination where caving and stowing were practised. Consideration has been given to structural analysis, support resistance, the various forces acting over and on the powered supports and to support compatibility. The examination of the phy sical parameters has been allied to field experience and, together, have led to the formulation of standard designs for both the powered support structure and structural systems. A realistic mathematical model has been formulated for calculating the capacity of roof support requirements resulting from the actual behaviour of the immediate roof stratum. As a result of the work, it should be possible to readily select the most appropriate type of support sy stem for the conditions and longwall mining method that is to be employed.

Jan 4, 1997