Vapour pressure-temperature relation for sulphur up to the critical point

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point