Characterization of composition of mineral surfaces by laser-probe microanalysis

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.