Search Documents

By Stratton-Crawley R., G. E. Agar

"A study has been done of the scale-up of laboratory bench-scale flotation to continuous plant circuit performance. It was found that the impellor speed and the air flow rate influenced the results and in this case extreme values of these operating variables were required in order to reproduce the plant rougher results in the laboratory. Despite the experimental uncertainty introduced by these extreme values, it was demonstrated that the plant performance could be predicted and experimentally reproduced with bench-scale tests.IntroductionThe mineral processing industry relies heavily on batch flotation testwork to design flowsheets, evaluate reagent s and compare various types of ore. The batch tests are generally regarded as being directly comparable within themselves, but quite often they relate poorly or not at all to continuous circuits. Obviously this dilemma generates considerable uncertainty with wide-ranging ramifications. One of the manifestations of this unfortunate situation is the commonly expressed opinion that ""it may work that way in the laboratory, but it will never work that way in the plant"".In a previous publication, a method was described whereby the results of batch bench-scale tests could be used to simulate a locked cycle flotation test series. The work to be described here is a continuation of that investigation with an extension to the simulation of an actual plant circuit. It would have been preferable to progress from laboratory batch data to a continuous pilot plant and then finally to a full-scale plant operation. However, because that possibility did not present itself, an attempt will be made to show that the performance of an existing plant circuit can be successfully simulated from batch data. The success of the procedure can be judged by the agreement among the plant results, a locked cycle test and the predicted results based on batch tests."

Jan 1, 1982

By Malcolm J. McPherson, Michael Hood

Sunnyside Mines, owned and operated by the Kaiser Steel Corporation, are situated near the city of Price, Utah. The complex comprises three adjacent mines, named simply Nos. 1, 2 and 3, all connected underground. Two seams, the upper and lower Sunnyside have been worked. These dip at about 10 percent to the north-east. The surface cover is variable due to the mountainous nature of the topography. The Sunnyside upper seam varies from 5 1/2 ft (1.7m) to 9 ft (2.7m) In thickness whilst the lower seam remains at about 6ft (1.8m). The separation between the two seams has ranged from 7 to 45 ft over the mined area (2 to 14m). Longwall mining has been practiced at Sunnyside for over 20 years due to difficulties of roof control encountered when using the roan and pillar system. Number 3 mine is bounded on the north and south sides by mines Number 1 and 2 respectively. Whilst current production is concentrated into Number 1 mine, much of the future of the complex lies in the further development of deeper reserves in Number 3 mine. Workings in this latter mine were curtailed in 1978 due to difficulties in ventilation. Present developments are ventilated partially from the neighboring Number 2 mine where no workings are in progress. The layout of Number 3 mine is illustrated on the schematic Figure 1. Trunk airways extend down dip from the surface at No. 2 Canyon and the Water Canyon for a distance of some 9,600 ft. (2930m). The area between the two sets of trunk airways has been worked extensively in both seams as have the corresponding reserves on either side in the connected adjacent mines. At the present time exhausting fans are sited at the top of a shallow shaft in No. 2 Canyon and an 8 ft (2.4m) diameter shaft sunk to a depth of 1013 ft (310m) closer to the current developments (Figure 1). The current airflow system, even with an additional 116,000 cfm (55m3/s) entering from No. 2 Mine, is adequate only for the development work now in progress but will be unable to support new longwall faces further downdip. The basic ventilation problem of this mine may be stated quite simply. In a situation where all intake and return airways pass through extensive old workings, a ventilation system design was required that would be effective, efficient and economic for the foreseeable future of the mine. ORGANIZATION OF THE PLANNING PROCEDURE The procedure followed during the study is illustrated on Figure 2. Initial ventilation surveys established the current state of the airflow system and provided the necessary data for setting up a Basic Network File in a computer store. The data in this file was a mathematical model of the ventilation system of the mine. The basic network was analysed by a ventilation network analysis program in order to correlate the measured and computed airflows and to establish the basic network as a true representation of the mine as it stood at the time of the surveys. The network model could then be extended to simulate the future development of the mine and alternative ventilation designs investigated. The remaining sections of the paper outline the work involved in each of these main phases of the planning procedure. VENTILATION SURVEYS Conduct of Surveys Two types of measurements were conducted simultaneously throughout the air-carrying routes of the mine: (i) Airflow measurements were made by anemometer traverse or smoke tube at 221 selected stations. Anemometer traverses were repeated at each station until at least three gave results to within 5 per cent. (ii) Pressure drop measurements were made across ventilation doors, regulators and, wherever possible, across stoppings. Additionally, frictional pressure drops were measured along airways where such pressure drops were significant (above 0.01 inches of water gauge or 2.5 Pa over a 100m distance). The trailing hose method was used to determine these frictional pressure drops. This involved laying out 100m of abrasive resistant plastic tubing (3 mm internal diameter) with a 4 ft. pitot-static tube facing into the airflow at either end and a low range pressure gauge connected into the line. The trailing hose method was preferred to the alternative barometer technique for this study because of (a) the relative ease of access between measuring points and (b) the greater accuracy within individual airways. The anemometers used were Davis Biram Type A/2-3" (30 to 5,000 ft/min) and Airflow Developments AM-5000 digital (50 to 5,000 ft/min). The pressure gauges employed were Dwyer magnehelic instruments. These were preferred to liquid in glass manometers because of their portability and dependability under adverse mining conditions. A checklist of the equipment used in the survey is given in Appendix 1. The instruments were calibrated before and after the surveys in the mine ventilation laboratory at the University of California, Berkeley. The survey occupied two teams, each of three men, for ten working days. The work consisted

Jan 1, 1982

By A. L. Mular

Si define la simulación digital y las técnicas de simulación son revisadas. La metodologia tipica conlleva la selección de modelos, el ajuste o reajuste de los datos primarios, la selección de una estrategia de acoplamiento, la valoración de la precisión del modelo en un sentido estadistico, y el desarrollo de estructura de simulación ejecutiva. La simulación sirve de ayuda para los ingenieros de procesos para evaluar la viabilidad de un esquema de flujo propuesto y el efecto de la modificación de un flujograma ya existente. Por otro lado, la simulación juega un papel importante en la optimación "off-line" y en la evaluación de estrategias de control de circuitos alternativos. Son presentados varios ejemplos para ilustrar estas utilizaciones para la simulación, incluyendo aplicaciones en los circuitos de trituración, circuitos de molienda y circuitos de flotación. Es de opinión de los autores que, dentro de la próxima década, las plantas de proceso de minerales serán estudiadas rutinariamente a través de una simulación digital durante las etapas preliminares de diseño. La simulación constituirá un importante componente en la toma de decisiones de un proceso.

Jan 1, 1982

By Francis S. Kendorski

INTRODUCTION Drift design problems in caving operations are a re¬sult of the geologic factors contributing to the overall success of the system, of the engineering factors dictated by economic and technical considerations, and of ore production practices. Combining these factors, a rational underground sup¬port system of rock reinforcement, light steel channel section or welded wire fabric, and shotcrete can be de¬signed based on rock fracturing, rock load, abutment loadings, ground movement, expected repair and desired flexibility. The design concept uses the effect achieved by restraining, reinforcing, and maintaining some of the intrinsic strength of the fractured rock mass composed of interlocked blocks of intact rock and rock fractures. Three different examples of drift support design in hypo¬thetical mines using the caving system are given. Caving is a system of underground mining where ore is extracted by means of gravity after the ore body is allowed to fail by removing support from underneath. The rock mass of the ore body fractures and flows ver¬tically downward to let gravity do as much work as pos¬sible. Caving differs from many other mining systems in that blasting is used only to initiate the rock mass failure by removing the rock supporting the ore but not to break the ore itself. The initial movement of the rock mass dur¬ing failure and the consequent crushing and grinding during the continued movement serve to reduce the ore to particles of a manageable size, with only limited sec¬ondary blasting necessary. The broken ore is extracted from the bottom of the failed rock mass through funnels of some sort pre-excavated in the rock. Ore extraction must continue or the swell of the broken rock will even¬tually fill the cavity and stop further rock mass failure and movement. The excellent general discussion on block caving in the SME Mining Engineering Handbook (Julin and Tobie, 1973) adequately covers the principles and application of this type of underground mining. Many rock mechanics aspects of block caving have been covered by others (McMahon and Kendrick, 1969; Swaisgood, et al., 1972; Mahtab and Dixon, 1975; King, 1946) and will not be reviewed further. Maintaining the stability of production drifts is one of the most troublesome problems plaguing the mine manager in a caving operation. Many factors contrib¬ute to drift support problems, and identifying the causes of instability and producing a reasonable support design are two steps toward achieving stability consistent with the mine plan. This chapter sets forth a technique for the design of support systems for production drifts in caving opera¬tions. The basic support system elements employed are rock reinforcement, welded wire fabric, and shotcrete. Recognized as contributing to the design are the factors of rock load, additional load from mining activity, rock fracture characteristics, repair expected, and flexibility. It must be emphasized that the drift must first be stabilized as for a tunnel, and the additional strengthen¬ing for mining-induced loads cannot contribute to the initial premining stabilization, or the reserve of strength is used up. MINE PLANNING The efficient mine planning engineer not only must satisfy the economic, human, and environmental aspects of his task but must also consider the mechanical con¬sequences of his plan. The problems created for the mine by placing parallel drifts too close, by crossing drifts on different levels with inadequate, if any, separa¬tion, and by installing connections and crossovers in the haulage plan without regard for the effective spans cre¬ated, are only a few of the problems a mine planning engineer can create for himself and the mine. The effect on immediately adjacent mine areas when an area is caved is important to drift design because the removal of vertical support from a rock mass causes the weight of that rock mass to be shifted elsewhere. The adjacent rock mass will carry this load and reach a new equilibrium with the applied stress. The advancing front of stress increase that results from caving (and many other mining systems) is generally called the abutment load and is the increase in stress over the gravity or tec¬tonic stress that already exists, as shown in Fig. 1. In general, the abutment load will be similar in nature to the stress change found around an opening in rock and will be taken as causing an increase in the vertical prin¬cipal stress, due to an approaching caving boundary, so that

Jan 1, 1982

By John C. Brower

The purpose of this paper is to examine the Gays in which- the policies of the U.S. government, mining companies and third world countries affect each other with regard to the availability of minerals. The interaction involves U.S. policy towards the mining industry, the policies of the companies themselves, and the policies of third world countries towards the U.S. and multinational companies. It is assumed in this discussion that U.S. policy will continue to be to seek certain minerals from abroad rather than attempt to develop domestic sources for all its requirements. This would seem to make sense both from the standpoint of cost, and for preserving what domestic resources there are so as to maintain some degree of market leverage. In today's jargon, this means greater dependency on the "third world", which, for this discussion, includes virtually all the nations in Africa, South America and Asia. Concern for availability raises the important distinction between dependency and vulnerability, and as the Director of the Bureau of Mines has pointed out, the two are not the same. Dependency is not neccessarily a bad thing; it is vulnerability that counts (Norman, 1980)

Jan 1, 1982

By Keith E. Dyas, John Nelson, Ronald T. Johnson

GENERAL DESCRIPTION The Bruce mine of Cyprus Mines Corp. is located in Bagdad, AZ. The mining method used is open cut-and-fill. Of the annual production of 81 647 t (90,000 st), approximately 83% is taken from load-haul-dump (LHD) stopes and the balance from slusher stopes. All ore is produced from the area between the 1250 level and the 2300 level. The average travel time from the shaft pocket to the stope is approximately 5 min. GENERAL ORE BODY REQUIREMENTS AND LIMITATIONS Size, Shape, and Dip The Bruce ore body occurs in quartz-sericite schist with Dick rhyolite on the footwall and andesite on the hanging wall. Diabase dikes are found in the hanging wall; there is also a dike coming off the footwall and crosscutting the ore body. All of the rock types are of the Precambrian Yavapai series and have been subjected to regional metamorphism. A composite of the ore body is given in Fig. 1. The deposit is of massive sulfides occurring as a steeply dipping replacement body. On the upper levels the ore is veinlike with widths from 0.6 to 4.6 m (2 to 15 ft), dipping at 1.4 to 1.5 rad (80° to 85°). On the lower levels the ore is dipping from I to 1.2 rad (60° to 70°) with widths from 3 to 16.8 m (10 to 55 ft). The strike length varies between 107 to 183 m (350 to 600 ft). The rhyolite footwall generally has a knife-edge contact with the massive sulfides. The exceptions to this are the upper levels where there is a 1.5 to 3 m (5 to 10 ft) band of silicified sericite schist between the sulfides and the rhyolite. In the southern part of the ore body the hanging wall is tuffaceous andesite and andesite. In this area the contact is generally sharp and easy to follow. However, to the north there is a large chlorite schist zone that crosscuts the bedding and comes in contact with the massive sulfides. This is apparently due to hydrothermal alteration of the andesite. The chlorite schist is highly mineralized with chalcopyrite and pyrite and quite often forms economic pockets of ore. In the massive sulfides the chief ore minerals are sphalerite and chalcopyrite. Pyrite is the predominant sulfide with considerable pyrrhotite throughout. Bright arsenopyrite ouhedrons in fine grain massive sulfides are quite common. Occasionally small amounts of galena are seen, usually near the foot or hanging wall contacts. On rare occasions tennanite is associated with massive arsenopyrite. Minor amounts of quartz, calcite, and un¬replaced remnants of sericite schist occur, but essentially pyrite is the gangue in which the ore minerals occur. The ore values are in excess of 3.5% copper and 12.5% zinc with some silver and rare gold as byproducts. Ground Conditions The massive sulfides are generally self-supporting. One exception is in the 1850 stope where the ore body is 9 to 11 m (30 to 55 ft) wide and 152 m (500 ft) long. There are flat to shallow dipping slips and seams in the ore, creating extremely blocky ground. For support, old 25.4-mm (1-in.) hoist ropes were installed tensioned to 27 t (30 st), and then cement grouted over the entire length in longholes [14 to 15 in (40 to 50 ft) in length) drilled on 3-m (10-ft) centers from the level above. This has tied the formation together very successfully and virtually eliminated the blocky ground condition. Both the hanging wall and footwall are quite shaley in some areas. Reasons for Adopting Trackless Open Cut-and-Fill Methods First, any method other than open cut-and-fill would have caused too much dilution. The use of rubber-tired mining equipment in the pro¬duction stopes requires a footwall ramp. The inclines in ore will be mined out, so this ramp in the footwall will provide access to and from the stopes (Fig. 2). This incline is very expensive, but necessary to convert existing stopes to LHD mining. 'The final cost of ore mined by the LHD machines has not been determined. As of 1972, tons per manshift in the 2150 stope-the only one to complete a full cut-had increased from 7.58 t (8.36 st) to 12.83 t (14.14

Jan 1, 1982

By Matthew N. Rubin

This report summarizes the work performed under USBM Contract No. H0155155. The purpose of this work was to obtain operational data on retrofit noise control treatments suitable for use in coal preparation plants. This data was obtained by evaluating the performance of four categories of noise control treatments which were installed in a commercial coal preparation plant. The four categories of treatments were resilient screen decks, resilient impact pads, chute liners, and curtains. The selection, installation and initial evaluation of the treatments was documented in the Volume I report issued in 1977. This Volume II report summarizes the results of the long-term evaluation of the original treatments, as well as some additional tests which were conducted on elastomer-clad (resilient) screen decks. This project demonstrated the feasibility of a number of retrofit noise control treatments, some of which also proved to be quite durable over the long term.

Jan 1, 1982

By Perry JH, King RL

The Bureau of Mines in cooperation with Kaiser Steel Corporation conducted two methane drainage studies in an advancing section of the Sunnyside No. I Mine where production was being severely hampered by methane emissions. A total of six horizontal aoreholes were completed during the studies to an average length of 291 meters. Total gas production from the boreholes as of December 1981 has exceeded 6,088,800 m3. Methane emissions into the section were reduced by 40 pct as a result of the first drainage system. The second drainage system is currently producing 11,328 m3/day from four Doreholes. Mining of the section and cementing of the horizontal horeholes is expected to begin within 2 Years.

Jan 1, 1982

By David P. Lindroth

The Bureau of Mines has developed and successfully tested a hangup clearance module for use in clearing hangups in underground mine chutes and ore passes. The Bureau's tests showed that the hangup clearance module can be effectively used to clear mine hangups. Furthermore, it is believed that clearance using this module is quicker, safer, and more efficient than the method currently used. The hangup clearance module uses a ballistic disk explosive charge that can clear hangups located as far as 50 feet (15.2 m) from the position where the charge is detonated. Mine personnel can therefore set up the module and the charge it contains without being exposed to dangerous areas. This report describes the principles of operation of the module, provides data and drawings for its construction, and gives instructions for its setup and use. The report also summarizes the development of the module, briefly discusses preliminary and underground tests, and lists the current and potential applications of the hangup clearance module to underground mining.

Jan 1, 1982

By David A. Rice

This note describes a simple, rapid technique for measuring the apparent volume and density of individual bits of porous materials such as iron ore pellets or pieces of coke. The method consists of determining the weight recorded on a balance when a particle is depressed below the surface of mercury, and calculating the apparent volume from the known density of mercury. The apparent density is calculated after weighing the particle in air. The method is particularly well suited for applications where a great number of determinations are to be made. An additional benefit is the minimal handling of the mercury. In any event, the usual recommended safety precautions should be adhered to.

Jan 1, 1982

By Jalna R. Zatko

Coal-clay waste slurries were dewatered in laboratory-and small-scale continuous tests by the Bureau of Mines using polyethylene oxide (PEO) as a flocculant. Dewatering from a nominal 7-wt-pct solids to over 50-wt-pct solids was accomplished using 0.5 lb of PEO per ton of feed in small-scale continuous tests. Parameters such as pH, initial solids content, and PEO concentrations were investigated. Water recovered from dewatering was reused as dilutant for PEO solutions.

Jan 1, 1982

By Robert J. Timko, Edward D. Thimons

Sulfur hexafluoride (SF6) is an odorless, colorless, nontoxic gas that has found acceptance as a tracer gas in research on ventilation pat- terns, measurement of air leak rates, respirable dust reductions due to bagging hood modifications, and the study of airflows relating to gob boreholes. Following a short review of the SF6 sampling technique, this report describes recent Bureau of Mines projects in which SF6 was used successfully as a tracer gas, enabling researchers to acquire representative data quickly and inexpensively.

Jan 1, 1982

By D. F. Howarth, F. F. Roxborough

Some important aspects of the design of rock-cutting systems remain relatively unexplored. Two areas of practical significance in this context form the subject of this paper: cutting in jointed or fissured rock, and groove-deepening. A series of controlled laboratory experiments on the performance of disc cutters in jointed rock showed that the spatial and geometrical configuration of jointed rock masses needs to be taken into consideration in the design of mechanized rock excavating systems. One series of experiments showed that, under favourable geometric conditions, the energy required to cut in a jointed rock mass is at least half that required to cut otherwise intact rock. Groove-deepening-the progressive deepening of a groove by successive passes of a cutter-is a potential operational feature with most mechanized rock-excavating systems. Laboratory experiments revealed an important fundamental cycle of events associated with disc cutters when progressively deepening a groove in intact rock. Furthermore, in contrast to pick cutting, groove-deepening by discs is shown to be an efficient operation and one that should not necessarily be avoided. This can be directly attributed to increased interaction between the disc cutters as the result of an increase in magnitude of the lateral forces generated as a groove is deepened.

Jan 1, 1982

By Cyrus W. Field

Metalliferous sediments constitute an important component of the sedimentary veneer that overlies basaltic oceanic crust of the Nazca Plate and elsewhere. Although first collected more than one century ago near the East Pacific Rise during the Challenger Expedition and recognized for their anomalously high content of Fe and Mn, occurring as very fine-grained, yellow-orange, oxides, hydroxides, and oxyhydroxides, it was not until the more detailed studies of Bostrom and Peterson (1966) that their geologic significance and concentrations of other transition metals were fully appreciated. The Nazca Plate is a dynamic lithospheric unit bordered by the Peru-Chile trench and the East Pacific Rise to the east and west, and by the Galapagos Rift and the Chile Rise to the north and south (Fig. 1). Samples employed in this study were taken from piston core recovered from the Nazca Plate (Fig. 2), D. S. D. P. drill core from the northeast Pacific (Dymond and others, 1973), ferromanganese nodules from dredge-haul s at several locations, and from hydrothermal mineral deposits of the Andes. Our efforts have been largely sponsored by the National Science Foundation through its International Decade of Ocean Exploration Pro- gram. The metalliferous fraction of these sediments is widespread, but generally small. Sedimentation is dominated by biogenic silica in the equatorial latitudes, terrigenous debris adjacent to the South American Continent, and by biogenic carbonate elsewhere, except at depths below 3500 m in the central and northwest parts of the Nazca Plate near the East Pacific Rise. Contributions of these distinctive sediment types are shown by the distributions of Si02, A1203, and CaC03 given in Figure 3.

Jan 1, 1982

By James M. Spear

Sample results suggest the only mineral resources in the study areas are placer gold deposits along the South Fork Kern River in the Woodpecker RARE II unit (fig. 1). These deposits, in Rockhouse Basin, total 4.5 Figure 1.--NEAR HERE. million cu yds (3.4 million cu m) of indicated subeconomic gold resources in four deposits of "older" gravel. Gold value in samples averages $0.36 per cu yd ($0.47 par cu m) and is as much as $4.44 per cu yd 1/. Cost of mining the gravel and recovering the placer gold is estimated to be more than $2 per cu yd ($2.62 per cu m) for a deposit of this size and type. Additional inferred subeconomic placer gold resources with similar grade probably occur in four other deposits of "older" gravel on which no mining claims were located. Placer gold occurrences on upper Trout Creek contain gold worth as much as $4.50 per cu yd ($5.88 per cu m) 1/. Average grade is much lower, and only about 1,000 cu yds remain (760 cu m). These occurrences do not constitute a resource, but may attract hobbyists not dependent upon making a profit.

Jan 1, 1982

By Edward C. Heistermann

The Falkirk Mining Company, a wholly owned subsidiary of The North American Coal Corporation, is located 80 kilometers (50 miles) north of Bismarck, North Dakota. Falkirk is under contract to provide 5.08 mil- lion tonnes (5.6 million short tons) annually to the Coal Creek Generating Station, an 1100 mega- watt electric plant owned by the Cooperative and United Power Associations of Minnesota. Coal Creek is located 2.4 kilometers (1 ½ miles) south of the Mine. Electricity from the plant is transmitted to rural electric customers in Minnesota via a 400-kilovolt D.C. power line.

Jan 1, 1982

By John P. Coughlin

Software techniques developed by the Bureau of Mines Denver Research Center for real-time microseismic data analysis are presented. These techniques focus on the simple acquisition of P-wave arrival times and their use in event location. The paper discusses in detail software techniques to separate microseismic events from mining noise such as drilling and from very large events such as rock bursts. Incorporation of these techniques has enhanced the reliability and accuracy of computer-based monitoring of microseismic activity in ongoing research by the Bureau.

Jan 1, 1982

Provide a central source of subsidence reference in formation for industry, academia, and government agencies interested in improving subsidence prediction and analysis under U.S. mining conditions. Approach Develop a comprehensive bibliography about mining related surface subsidence and store this information in a computer file. Make specific references accessible through a key word retrieval program. Supplement these key word identifiers by entry of author's name, title of publication, subject of text, or sponsor of publication. How It Works Requests for subsidence in-formation are made by phone or mail to the Bureau of

Jan 1, 1982

By Firth B. A

The flotation of fine coal (minus 0.5 mm) often requires the addition of an insoluble hydrocarbon collector to apparently promote the adhesion of coal particles to air bubbles. A series of experiments was conducted using a radiotracer and narrow size fractions of clean coal to determine the effect of particle size distribution, collector addition rate, desliming of feed and emuIisification of collector on the distribution of collector between the different size fractions. The concentration of collector per gram of each size fraction was found to be approximately proportional to (average particle size)-2 except if the collector was emulsified prior to addition, the dependence altered to approximately (average particle size)-1. Mechanistic consequences are discussed.

Jan 1, 1982

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982