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By R. A. Frith, M D. Goodz

Ore-bearing minerals that are located along microfractures are always susceptible to loss during the breakage and sampling of the material. Further losses occur with on-site sample preparation and splitting prior to laboratory analysis. In these cases solid whole rock channel or core samples should be handled with due care to ensure all fines and loose particles are collected and included in the sample for total chemical analysis.Similarly open hole and reverse circulation drill methods are not usable in areas containing old mine workings, heavily fractured ground or highly degraded/oxidised mineral assemblages. Nor are these methods usable to assess a bulk mineable target where the enriched zones were peripheral to or between old mine cavities.

Jan 1, 1993

By Umetsu Y, Su Qing-quan

The electrical conductivity of electrolytes is very important in metal electrowinning and electrorefining processes as it has a very large influence on the energy consumption. There are few measurements of the electrical conductivity of zinc electrowinning electrolytes available. The electrical conductivity of zinc electrowinning electrolytes were measured over the following range of concentrations, 100 to 200 g/L H2SO4, 0 to 80 g/L Zn and 0 to 20 g/L Mg, at temperatures from 25 to 60 C. The specific conductivity of zinc electrowinning electrolytes may be expressed as a function of concentrations of sulphuric acid, zinc and magnesium and temperature by the following equation: k(S/cm) = 0.004 + 0.00115 t + 0.00282 [H2SO4] t - 0.00114 [M] t + 0.3442 [H2SO4] - 0.0451 [1-12SO4]2 - 0.1058 [M]ò[H2SO4] - 0.0224 (M] + 0.0286 [M] 2 where t is temperature (C), [H2S04](moI/L) is sulphuric acid concentration and [M](mol/L) is a sum of zinc and magnesium concentrations, ([Zn]+[Mg]). The specific conductivity of zinc electrolytes is a function of the concentrations of the hydrogen ion and free water molecule, which are calculated by taking into account the second ionisation constant of sulphuric acid and the stability- constants of zinc-sulphate and magnesium-sulphate complexes at 25 C.

Jan 1, 1993

By J. H. Hill

The globalization of mineral markets and intense competition in downstream mineral-consuming industries such as transportation, agriculture, and construction are requiring raw materials suppliers to innovate, improve quality, invest in new technology, and control costs. Mineral specifications are becoming more refined, and pressure to improve products is felt from increasing numbers of competing producers, substitute materials, customers, and regulators. As a result, engineered mineral products are becoming more like manufactured ones in terms of cost structure, differentiation, and the importance of market driven, customer specific product development. Engineered mineral products are defined as those where the costs of refining and upgrading outweigh those of conventional mining activities (blasting, crushing, classification, haulage etc.), and where close control of physical and chemical parameters is required for customers' processing and manufacturing applications. This includes industrial minerals such as calcium carbonate, kaolin, mica, specialty oxides, talc, and some metal powders. It excludes most metals and bulk commodity materials such as gypsum, lime, sulfur, and soda ash. Engineered mineral products are utilized in common household goods, and are at the forefront of industrial materials engineering in plastics, ceramics, composites, glazes, coatings, and construction materials. As a group, they introduce interesting questions to the minerals firm. Advanced materials or basic? Diversify or specialize? What are the implications of advanced materials and for mineral markets, and most importantly, where can the producer look for long-term value, volume, and profits?

Jan 1, 1993

By James L. Hendrix, R. Y. Wan, David W. Kappes, Jinrong Zhang, M. C. Fuerstenau, Terence E. Albert

A sulfidic flotation tailings ore, containing 1.14 gpt Au and 242.53 gpt Ag, was treated by low temperature chlorination roasting followed by cyanide or chloride leaching. Eighty per cent of Ag was recovered by cyanide leach when the ore was roasted at 350°C with 50 kg/ton calcium chloride. About seventy per cent of Au was made cyanide amenable by chlorination roasting at 400°C. A better Ag recovery, ninety per cent or over, was achieved by chloride (NaCl+HCl) leach. However, Au recovery was very poor by chloride leach. Ferric chloride, calcium chloride, and cupric chloride were compared as chlorinating agents for their effect on Au and Ag recovery. The study found that low temperature chlorination roasting is very effective for recovering Ag associated with stibnite and stannite. The best chlorinating agent for the test ore was found to be calcium chloride. Parallel roasting-leaching tests indicated that chlorination roasting was far superior over oxidation roasting for both gold and silver recovery.

Jan 1, 1993

By M. A. Ford

This paper reviews the history, sources, mineralogy, extraction metallurgy, conversion, and enrichment of uranium in South Africa. Over the past 40 years extraction plants were built at 27 sites, an9.over 140 kt of uranium have been produced. Older plants have had to adapt to changing market conditions, no single technology has had the opportunity to become entrenched, and costs have been reduced to a third of those of the original flowsheet. The research efforts aimed at developing the country s nuclear raw materials have been particularly rewarding, as they have enabled South Africa to become a world leader in the extraction of uranium from low-grade ores and to develop methods for uranium enrichment and the production of nuclear fuels.

Jan 1, 1993

By Robert W. Waytulonis

Miners working in underground mines where diesel equipment is used are exposed to exhaust pollutants. These include carbon monoxide (CO), carbon dioxide (CO,), nitric oxide (NO), nitrogen dioxide (NO2), sulfur dioxide (SO2), hundreds of different hydrocarbons (HC) and particulate matter. Evidence from animal inhalation studies and limited epidemiological investigations have led the National Institute for Occupational Safety and Health (NIOSH) to recommend that ‘... whole diesel exhaust be regarded as a potential occupational carcinogen ...’ NIOSH further stated that ‘... the excess cancer risk for workers exposed to diesel exhaust has not yet been quantified, but the probability of developing cancer should be decreased by minimizing exposure…’ The International Agency for Research on Cancer(IARC) reached a similar conclusion, saying that ‘... diesel engine exhaust is probably carcinogenic to humans.’ Before these declarations, there was insufficient evidence concerning the carcinogenicity of diesel exhaust. It was well known, though, that diesel exhaust caused less severe problems, such as headache, eye irritation and unpleasant odors. In 1988, a milestone was reached in the Mine Safety and Health Administration (MSHA) regulatory process. An advisory committee recommended a three-tier approach to regulating diesels used underground-approval of diesel equipment, safety and health. Diesel particulate matter may be specifically regulated. In addition, ambient air quality standards are being proposed that will establish a new standard for CO2 and lower the permissible exposure limits for the NO2, CO, SO2 and formaldehyde emissions that originate from diesels and other sources. Additional safety and emission restrictions are also proposed for diesel engines in coal mines. The goal of the US Bureau of Mines (USBM) diesel engine research program is to minimize the health and safety problems associated with underground diesel equipment use. Part of this program is focused on reducing exhaust emissions from diesel-powered equipment used in underground mines.

Jan 1, 1993

By T. R. A. Davey

Previous publications on the application of EIETSIM include the modelling of an electrolytic zinc plant and a copper flash smelter. In the present case METSIM has been used to model the desilverising of lead by the reagent zinc, whereby a silver-zinc intermetallic compound is formed, and floats out of the lead. This compound has a variable composition, depending upon the ratio of dissolved zinc/silver in the lead bath. Its solubility in lead decreases with falling temperature. A number of variations and modifications of the Davey Desilverising Procedure are modelled, and applied to a wide range of silver contents in lead bullions at several plants. METSIM uses both feed- back and feed-forward controls to simulate plant conditions, and a logic control to distinguish between different phases in the Zn-Ag system. Use is made of extensive (previously unpublished) fundamental data on the ternary Pb-Ag-Zn system, and of plant data, to establish certain operating parameters.

Jan 1, 1993

By S. Yabe

The reinforcement of the annual copper production capacity to 330,000 metric tons has been attained at Saganoseki Smelter & Refinery in 1991, which is one of the largest and most efficient custom smelters in the world. Many operational improvements and technology developments have realized the increase of smelting and refining capacity without adding main facilities to the existing process. The blister copper refining and anode casting process is composed of two 400 tonnes anode furnaces and one double-wheeled casting machine with the capacity of 80 tonnes per hour. The great innovations in this process such as the finding of essential issue on the extending of anode-mould life and the development of a new anode-mould casting machine have raised the operation efficiency by 14% Now, the process is producing 38,500 tonnes per month of best quality anode in well- controlled working condition, and anode productivity per worker increased by 52%. The progress in extending anode-mould life, the mechanism of the new anode-mould casting machine and the increase of efficiency in butane reduction, that were the principal parts of many technological improvements, are described in the present paper, including some operation results.

Jan 1, 1993

By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By R. E. Johnson, W. Kat, B. R. Palmer, van Sandwijk A., G. Van Weert, S. Honingh

In-plant recycling of dust from iron making BF's creates undesirable circulating loads of volatile trace elements such as zinc and lead. Disposal of such dusts creates environmental problems, hence a separate treatment is indicated. Since the bulk of the zinc and lead compounds occurs in the fine dust fraction; hydrocycloning the slurry from the BF gas cleaning operation results in upgrading the material for treatment. A process has been proposed, whereby the zinc and lead are solubilized from the fine fraction with spent hydrochloric acid from steel pickling. The stoichiometry of this autoclave oxidation process is adjusted to simultaneously precipitate, by oxyhydrolysis, most of the iron for recycling to the BF's. Lead and zinc are successively recovered from the filtrate as low chloride precipitates. This paper describes additional testwork, leading to the design of a pilot plant which was planned to begin operation in 1992.

Jan 1, 1993

Develop hydrometallurgical or pyrometallurgical recycling methods to recover valuable rare-earth compounds from various forms of NdFeB magnet scrap. Background The U.S. Bureau of Mines (USBM) has developed technology to treat and recycle a variety of wastes containing valuable and strategic metals. As part of this effort, the USBM developed a process to separate neodymium and other valuable rare earths from iron in NdFeB magnet scrap (fig. 1). Since this scrap typically contains nearly 30 weight percent neodymium and since the demand for neodymium is constantly increasing, cost-effective methods for scrap treatment could have a significant impact on industrial expenditure and materials supply in the expanding area of magnet manufacture. Approach A hydromctallurgical, H2SO4 dissolution-precipitation process provided the most effective treatment for separating rare earths from bulk NdFcB magnet scrap (fig. 2). Precipitation of neodymium-alkali sulfate double salt proved advantageous over direct precipitation of fluoride or oxalate products. This double salt is easily converted to a variety of useful rare-earth compounds, which eliminates many of the materials-handling and economic problems inherent with direct precipitation. Following rare-earth precipitation, dissolved iron was removed from the acid leach solution by precipitation as a jarosite.

Jan 1, 1993

By Fee BS

This paper describes four new families of collector products which are currently being introduced at the industrial level. A brief summary of the chemical basis behind each product family will be given. This is then followed by a selection of flotation examples which illustrate the more important use characteristics that have been observed to date. It is becoming more apparent with further testing that these four new product families can offer both technical and economic advantages to the industrial flotation process operator.

Jan 1, 1993

By F. F. Peng

Fine Coal Cleaning Processes including froth flotation, aggregative flotation or oil agglomeration, depend upon the wettability of coal particles in the aqueous solution. The wettability of coals of various ranks, hydrocarbon oil treated coals and oil-agglomerates have been measured using film flotation, induction timer, and froth flotation. Various hydrocarbon collector dispersion techniques are used to alter the surface wettability of coal particles. Change in wettability behaviors, measured by flotation responses, due to various ranks with or without of hydrocarbon collector modification are explained in terms of surface chemistry modifications as analyzed by induction time, film flotation as well as DRIFT Spectroscopy. The relationship between the wettability of coals and collector treated coals, and floatability are discussed.

Jan 1, 1993

By H. L. Monro

Al forward sales are made on the spot market, and are counter productive because they can only lower the price of gold, as one would expect from any additional supply of gold. Hedging against any further fall in the price of gold can be carried out on one of the World's Futures Exchanges in the same way as other commodities.

Jan 1, 1993

By David G. Dixon

A general, unsteady-state model for leaching of one or more solid reactant species from a non- reactive, porous, spherical pellet is derived in dimensionless form for the interpretation of leaching data, and for use in the design of coarse-ore leaching processes. The effects of diffusion rate, chemical reaction rate, variable reaction order, and competition between multiple solid reactants are examined using the concept of the effectiveness factor. It is shown that the model is capable of simulating both "reaction-zone" and "heterogeneous" kinetics, depending on the choice of three dimensionless parameters. Results of batch leaching tests of artificial ore pellets are presented, and their relationship to the model is discussed.

Jan 1, 1993

By Rao SR, Finch JA

Sphalerite flotation without Cu activation in the presence of iron ions has been reported and studied as a function of pH, dissolved oxygen content and pulp potential with both single mineral and ore samples (Leroux, Rao and Finch, 1987; Xu et al, 1992; Zhang, Rao and Finch, 1992). The flotation was attributed to ferric hydroxy xanthate. As a prelude to surface analysis to try to identify the species responsible, bulk precipitates formed from iron salt and xanthate solutions under different conditions were obtained and analysed. Analysis techniques included ultraviolet spectroscopy,infrared spectroscopy, X-ray diffraction and Mossbauer spectroscopy. It is tentatively concluded that the bulk precipitates contain three ferric components, two hydroxy xanthates (Fe(OH)2X and Fe(OH)X2) and iron oxide (FeO.).

Jan 1, 1993

By Larry Mirabelli, Gerard J. O'Brien

"The construction of the Third Harbor Tunnel is a key element of the Central Artery TunnelProject. The tunnel is to traverse Boston Harbor directly linking South Boston to EastBoston. The tunnel is a cut and cover tunnel as opposed to a bored tunnel. The cutdimensions are 95' wide, 110' deep and approximately 4000' in overall length."

Jan 1, 1993

By F. Gonzalez, A. Zambrano, J. Schwoebel, S. Kravits

Significant lost time delays were experienced by Carbonifera de Nueva Rosita, S.A. de C.V. ("CNR") during mining development of the Pasta de Conchos Mine ("the Mine") near Nueva Rosita, Coahuila, Mexico. Furthermore, methane gas concentration in the return air course had exceeded 1.0 percent. Resource Enterprises, Inc. ("REI") was contracted by CNR to recommend an approach to reduce methane emissions at the Mine. In order to recommend a degasification approach, REI and CNR obtained geologic and reservoir characteristics of the Double coal seam, Olmos Formation. A vertical core hole was drilled to obtain core samples to determine gas content (average 8.4 cm3/gm) and to conduct a slug test to estimate permeability (34 md). This information was used to simulate gas productivity and drainage effectiveness. The simulation indicated that underground horizontal boreholes would remove significant quantities of gas in advance of mining in a reasonable period of time. Based on the results of the simulation study, an underground degasification drilling program was initiated at the Mine. In a six month period, five long in-mine degasification boreholes were drilled in advance of CNR's three to five years mining projections. Peak gas production from the five boreholes (approximately 2,750 cumulative meters) had exceeded 45,000 m3/D. Results to date have indicated a general reduction in methane concentration in the return air course below 0.8 percent.

Jan 1, 1993

By Kirk P. Kinart

The mid to late 1980s saw a modern day global gold rush that largely focused on the mature mining countries of the United States, Canada and Australia. This gold rush led to a large number of new discoveries in these countries and phenomenal growth rates in annual gold production. For a variety of reasons, however, gold exploration and development activity appears to have peaked in these countries. The drive for mineral investment is, instead, growing in lesser explored countries (LEC). LECs, particularly those of Latin America, are currently enjoying greatly increased attention from North American mining companies. They are becoming major consumers of mineral investment capital and are important markets for exploration and mining skills. Through sole ownership, joint ventures and subsidiary companies, Battle Mountain Gold now operates or controls gold mines in the United States, Chile, Bolivia and Australia. And it has been or is an active participant in gold exploration or development projects in seven other countries, six of which classify as LECs. In selecting new country entries and opportunities for mineral investment, there are several factors to be considered and parties to be satisfied - shareholders, corporate management, financial institutions and host country governments. This article, though, focuses on some of the more practical concerns of the exploration unit as a whole and the exploration geologist in particular. The exploration unit's "new country" concerns primarily relate to exploration potential, ownership security, quality and availability of data and the ability to operate efficiently. The following material reviews each of these concerns and how they impact the new country entry decision, exploration strategy, chances of success and human experience.

Jan 1, 1993

By E. Açma

Sivas-Divrigi flotation plant has a capacity of 90,000 tpy. Beneficiation of the tailings of iron ore magnetic separator seems to be attractive, because of its Cu, Co, and Ni contents. In the experimental work, sulfidic flotation concentrate is produced from these tailings. A roasting-leaching-H2S precipitation procedure is used to treat this concentrate, containing 0.55% Cu, 0.51% Co, 0.74% Ni, and 0.027% Zn. Sulfatizing roasting is carried out in a rotary furnace at 690°C. Roasted product is leached with 10 gpl HzSOl at 70°C and 30% pulp density. For the precipitation of desired metal, H2S is bubbled through the concentrated solution of repeated leaching, under controlled temperature and pH. Final metal recoveries of 91% Cu, 91% Co, and 50% Ni, and 92% Zn are attained. Roasting gases with their 13% SO2 content are suitable for H2SO4 production and the leach residues can be integrated with the iron ore processing plant as they contain 57.4% Fe and very low non-ferrous metals.

Jan 1, 1993