Electrical Conductivity of Zinc Electrowinning Electrolytes

The electrical conductivity of electrolytes is very important in metal electrowinning and electrorefining processes as it has a very large influence on the energy consumption. There are few measurements of the electrical conductivity of zinc electrowinning electrolytes available. The electrical conductivity of zinc electrowinning electrolytes were measured over the following range of concentrations, 100 to 200 g/L H2SO4, 0 to 80 g/L Zn and 0 to 20 g/L Mg, at temperatures from 25 to 60 C. The specific conductivity of zinc electrowinning electrolytes may be expressed as a function of concentrations of sulphuric acid, zinc and magnesium and temperature by the following equation: k(S/cm) = 0.004 + 0.00115 t + 0.00282 [H2SO4] t - 0.00114 [M] t + 0.3442 [H2SO4] - 0.0451 [1-12SO4]2 - 0.1058 [M]ò[H2SO4] - 0.0224 (M] + 0.0286 [M] 2 where t is temperature (C), [H2S04](moI/L) is sulphuric acid concentration and [M](mol/L) is a sum of zinc and magnesium concentrations, ([Zn]+[Mg]). The specific conductivity of zinc electrolytes is a function of the concentrations of the hydrogen ion and free water molecule, which are calculated by taking into account the second ionisation constant of sulphuric acid and the stability- constants of zinc-sulphate and magnesium-sulphate complexes at 25 C.