Search Documents

By Arthur P. Chaves, Lauro S. Norbert Costa, Adão B. Da Luz

A series of bench-scale bleaching tests have been carried out on kaolin samples from the Rio Capim area( northern Brazil) at CETEM/CNPq. The whole sample has been homogenized and submitted to particle size separation, when the + 44 µm fraction has been discarded, prior to being bleached. The main objective of this series of tests has been to evaluate the possible effects of interactions among variables which are believed to play important roles in the bleaching operation on the efficiency of the process itself in terms of the brightness achieved in the final product The tests have been planned according to a classical four-variable, two-level factorial technique. The chosen variables have been the pH, sodium dithionite addition, aluminium sulphate addition and bleaching time. The study has shown that, apart of time, all other three variables are significant. None of the interactions among them have shown to be of significance. Brightness numbers close to 88 have been obtained in the products, which represents an improvement, since brightness for the non-bleached - 44 µm Rio Capim kaolin sample averages 83.

Jan 1, 1995

By D. S. McAllister, P. M. Rice, M. E. Fowler

The Westside Light Rail Project, a major 19.3-km (12-mile) extension of Portland, Oregon's light rail system, includes 4.6 km (2.8 miles) of twin 5.8-m (19-ft) diameter running tunnels, a binocular type station which, at 80 m (260 ft) below the ground surface, will be the deepest mass transit station in North America, two 9.4-m (31-ft) diameter station access shafts, and a 5.2-m (17¬ft) diameter ventilation shaft. The tunnels are being excavated by TBM and conventional rock, soft ground, and mixed-face methods. Geologic conditions, alignment, underground opening design, excavation method selection, and payment provisions for excavation and initial ground support are discussed.

Jan 1, 1995

The generation of acid mine water is? due to the oxidation and weathering of sulfide bearing tailings and overburdens. Ferrite precipitation prooess has been applied to treat acid mine water. The conventional ferrite preC1pitatlon requires air oxidation at high temperature, or long aging time or addition of magnetite powder ,as promoter. In this investigation, a modified ferrite, precipitation process is developed by which magnetic ferrite can be produced at an ambient temperature. Acid mine waters from Berkeley Pit (Montana, U. S. A.) and from Noranda Tailings (Quebec, Canada) were used. The co precipitation of heavy metals from these two acid mine waters is studied as a function of FeIM molar ratio, oxidation time and settling rate under applied magnetic field. The investigation indicates that the modified ferrite co precipitation can remove substantially all of the, dissolved metal ions from acid mine water. The ferrite product obtained after precipitation' is characterized by XRD, SEM, BET and saturation magnetization. The results show that spinel ferrite, precipitation can be achieved at room temperature and the saturation magnetization of ferrite product from,acid mine water is comparable to that of pure ferrites.

Jan 1, 1995

By Y. Wang, E. Forssberg, R. J. Pugh

The coagulation of dispersed ultrafine weakly-magnetic oxide mineral particles (e.g., natural hematite and chromite) in an external magnetic field can be described by interparticle forces. Essentially, coagulation occurs when the short-range London-van der Waals interactions and the long-range magnetic forces outweigh the stabilizing electrical double-layer repulsion. Using the classical colloid chemistry theory, the various components of the potential energy for different-sized particles at a series of ionic strengths and magnetic field intensities were calculated. The results of this theoretical analysis were then related to the results obtained from experimental studies in which the magnetic field-induced coagulation of the ultrafines of natural hematite and chromite in aqueous suspensions were investigated using a laboratory-scale electromagnetic solenoid. The experimental results relate the coagulation process (as determined by magneto-sedimentation analysis) to the particle size, the slurry pH and the external magnetic field. In the magnetic fields, the maximum coagulation occurred near the pH of zero-point-of-charge (pHzpc) of the minerals (where the electrostatic double layer repulsion was reduced to a minimum) enabling the particles to enter the "primary minimum" energy sink. On the other hand, in cases where the electrostatic repulsion was not suppressed, the long-range magnetic forces enabled coagulation to occur in the "secondary minimum." This caused the formation of chains that appeared to be relatively stable during sedimentation.

Jan 1, 1995

By Bearman R. A, Parkin R. M

Traditional quality control procedures for aggregates production within the quarry industry rely on off-line laboratory analysis, resulting in poor performance and inconsistent product quality. A high speed on-line aggregate classification system is described here. A product sampling system directs aggregate through an inspection chamber where a novel imaging system digitises the particle geometry. Data processing algorithms extract dimensional data and image features, while a neural network classifier assigns a qualitative shape descriptor to each rock particle. This system provides each sampled batch with a complete analysis of size and shape distributions, complementing a new generation of cone crusher technology to maximise product quality and plant efficiency.

Jan 1, 1995

By G. P. Dvoichenkova, E. A. Trofimova, M. V. Zaskevich, V. A. Chanturiya

The paper presents theoretical and practical aspects of directed adjustment of physicochemical properties (pH,Eh) and ion composition of recycle and mine water by electrochemical treatment. Treatment is run in the conditioners of diaphragm-type with production of alkaline catholyte of pH value up to 12 and acidic anolyte of pH up to 2. In process of water electrolysis the directed motion of Mg2+ and Ca2+ ions is observed from anode volume to cathode one, were they precipitate as hydroxides and carbonates; it leads to decrease of salt content in anolyte and catholyte. The anolyte has been concentrating anions, it is being saturated with oxygen, which reaches 20-35 mg/L. The results of experimental and industrial testing of electrochemical technique for mine and recycle water in flotation of diamond-containing and sulphide-scheelite, hematite, phosporite, apatite-nephelite, bauxite ores indicated the increase of recovery up to 2-1 5% and grade up to 0,5-2%, concurrent with decrease of reagent consumption from 15 to 50 %. Modules of industrial conditioners of different type capacity have been developed.

Jan 1, 1995

By Mauk JL, McOnie A, Simmons SF

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water, whereas the mineral assemblage of replacement calcite-interstratified illite - montmorillonite- kaolinite forms a carapace and reflects formation from a C02-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Brathwaite RL

The gold-scheelite-quartz lodes of the Wakamarina valley were the most productive of the mesothermal gold-bear in the Marlborough Schist. Most of the production came from the Empire City and Golden Bar mines which worked tug, Golden Bar lode. Only 134 m of its 1800 m strike length are accessible, in the No. 2 level of the Golden Bar Mine. A fau I has downthrown the Golden Bar Mine section by 2 47 m and displaced it left-laterally by 18 m. The lode is a typical ribbon-banded mesothermal vein, averaging c. 1.75 m wide, and enclosing narrow horses of schist country rock. It i composed of bands of milky "buck" quartz with thin laminae of schist. Scheelite occurs in short strings of grains withi quartz on the footwall side of the lode and also in small quartz-carbonate veinlets in the foot wall and hanging wall schist The lode quartz contains only localised traces of pyrite and arsenopyrite. They are more abundant in the wall-rock schist.

Jan 1, 1995

By Gregg PEH, Stewart RB

Reclamation field trials commenced in 1985, two years before the granting of the Mining Licence. The level of pasture production on varying soil depths (0 cm, 5 cm, 15 cm and 25 cm) overlying both tailings and oxidised waste overburden was assessed. After seven years, the rate of increase of N, C, P and S, losses of S and P and pH changes were investigated on the plots where grass seed was sown into bare tailings. It was determined that on these plots it would take approximately 24 years to reach the original carbon and nitrogen levels at the mine site.

Jan 1, 1995

By Jelenich L, Murray J. Rantanen J

The experience gained in the development of an Operator Guidance System (OGS) for on-line process control and fault diagnosis in a commercial scale sintering process will be discussed in this paper. The OGS development started with the specification of feasible control and support tasks, eg ratio control scheme, mass balance calculations. Next, minimum requirements for fault diagnosis and process control were defined and the adequacy of existing instrumentation was assessed. The OGS knowledge base consists of both quantitative and qualitative diagnosis methods. Quantitative models based on fundamental engineering principle are used first and any gaps in such quantitative knowledge are then filled with heuristic rules. The diagnostic rules for the knowledge base was developed based on the knowledge acquired from experienced operators and operations engineers and validated with plant data. A real time reasoning program was written using C language and data base software. The OGS has a human-computer interface which is the primary means of interaction between the OGS and process operator. The OGS development has been successful in assisting operators in decision-making in their routine tasks. Further enhancement to the existing system is currently underway.

Jan 1, 1995

By Hugo J. Garcia, M. C. Fuerstenau, D. M. Lupan, J. L. Hendrix

Biodegradation of cyanide by microorganisms isolated from solids previously exposed to cyanide has been investigated. The anaerobic cyanide biodegradation showed good, short-term removal of cyanide in the presence of nutrients (medium A). This system retained metabolic activity at cyanide concentrations up to 300 ppm at pH 10.5. Microscopic examination of stained specimens revealed that the bacteria were Gram-negative, rod-shaped bacilli. Strains capable of cyanide decomposition were identified as Pseudomonas and Alcaligenes. The kinetics of biodegradation were found to be first order with respect to cyanide concentration, and the overall reaction rate constant is k = 0.102 day-1. Studies with Na14CN showed that 17 % of 14C transformation went into the cells, 18 % into carbonate and 47 % into bicarbonate.

Jan 1, 1995

By Robert J. Timko, Lincoln Derick

This work is a follow-up to previous research that attempted to predict the location of spontaneous heating episodes in underground coal mine pillars. The objective of the original work was to see if the data obtained by commonly used detection methods could accurately predict spontaneous combustion episodes in coal pillars. Data accumulation during the study was enhanced when a spontaneously generated fire occurred within one of the pillars being examined. The fire provided researchers with realistic data that could be used to determine if fire prediction was possible. Results from the initial study found that the atmospheric status equations that were used provided little advance notice that combustion would occur where it did. This study reevaluated the accumulated data by applying it to recently developed equations and compared these results with previously obtained information to determine if a combination of these techniques could more effectively predict impending combustion.

Jan 1, 1995

By K. N. Han

The dissolution kinetics of cobalt in iodine/ iodide solutions were investigated using a rotating-disc technique. Variables studied included temperature, rotating speed, concentration of lixiviants and the pH of the solution. The overall dissolution reaction appeared to be limited by the mass transfer of tri-iodide through the diffusion boundary layer with an Arrhenius activation energy of <16.2 kJ/mol (4 kcal/mol) over the temperature range of 2 to 42ºC. The pH of the solution had little effect, as long as the pH of the solution was <8. However, when the pH of the solution became >8, the dissolution rate decreased dramatically, due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1995

By Silvia H. M. Grimaldi, Afonso H. Martins

The scope of this experimental work was to study the yttrium extraction and stripping behaviour in a solvent extraction system with mono(2-ethylhexyl)2-ethylhexylphosphonic acid (IONQUEST 801) in a chloride system The study was performed for only one contact between organic and aqueous phases The experiments were carried out according to a factorial design. Due to the statistical analysis and its experimental proof, the optimum conditions for maximum yttrium loading into the organic phase of the extraction stage were 16 minutes for time of contact between phases, 980 rpm of stirring intensity and pH=2.3 for the aqueous phase of the sovent extraction system. The optimized experimental conditions by the statistical approach for the stripping stage were: time of contact between phases equal to 20 minutes, 1050 rpm of stirring intensity and 1.75 M HCI into the stripping aqueous solution.

Jan 1, 1995

By William D. Riley

The U. S. Bureau of Mines has developed technology to recover by-product materials from aluminum scrap using engineered scavenger compounds (ESC). ESCs are structural oxides with a channel or tunnel structure that allows them to hold ions of a specitksizes and charges. The scavenging reaction is easily reversible allowing the ESC to be recharged for continued use and the ion is recovered as an electro deposit. Key features of this novel technology are; a) ESC ,systems are designed to have a high degree of selectivity for a desired ionic species. b) The recovered mater.ial requires little or no additional reprocessing prior to reuse. Two current uses for the ESC technology that are described in this paper are the removal and recycle oflithium (Li) from lithium aluminum (Li-AL) alloys; and, using ESCs as a replacement for the conventional demaging (magnesium removal) technology used by the secondary casting industry. Research indicates that the ESC technology proposed for both these applications has either &apos;distinct economic and/or environmental advantages over previously employed methods of recovering. metal values from aluminum scrap.

Jan 1, 1995

By F. Gray

Diamond tool fabricators expect strong growth in most applications for 1995 and 1996. Overall growth projects range from 8% to 10%. Diamond grinding is forecast to grow between 5% and 8%, while cubic boron nitride grinding should grow between 10% and 12%. A strong automotive industry is a major factor in this projected growth, as is continuing demand for other durables

Jan 1, 1995

By Shelley M. Burg, Dennis K. Poulton, Robert B. Gordon

This project includes the excavation and concrete lining of approximately 18 900 m (62 000 ft) of 5.5 m (18 ft) finished diameter subway tunnel for the Los Angeles MTA. The project required that four soft ground headings be excavated from a single shaft located near the mid point of the tunnels. The tunnels were classified "gassy" during the excavation phase. Because of the contract schedule requirements and the limited urban work site available, many logistical problems had to be overcome during the project while excavation was accomplished at a record setting pace. Some unique project features include the muck handling system and an access shaft using a high strength tieback support system. In order to accomplish the work, an extensive effort to plan and construct the main work site was required.

Jan 1, 1995

By A. C. Hitchins, C. N. Orssich

The Eagle zone is a gold-bearing, sheeted, quartz vein porphyry deposit hosted by the Cretaceous Dublin Gulch biotite granodiorite stock, located in central Yukon, 50 km north of Mayo. The deposit occurs at the western end of the stock and has been drill tested over a 1000 m by 500 m area, to a depth of 150m. Mineralization consists of 1 cm to 2 Cm wide, parallel, grey and white quartz veins with accessory gold, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, native bismuth, bismuthinite, and scheelite. Vein densities range from two to fifteen veins per metre and average approximately five per metre. The majority of the veins have potassic and or phyllic alteration envelopes. Alteration of the granodiorite becomes pervasive as vein densities increase. Mineralization outside of the Eagle zone, but spatially related to the Dublin Gulch stock, includes: (i) scheelite bearing sheeted quartz vein zones within the east-central portion of the stock; (ii) a swarm of gold-bearing quartz-sulphide veins up to a metre wide in a zone along the northern contact of the stock and extending 7 km further west; (iii) the Mar scheelite skarn located on the south side of the stock; and (iv) cassiterite-bearing breccias located 2 km north of the stock. A geological potential resource of 64.5 Mt tonnes at a grade of 1.03 g/t Au has been estimated for the Eagle zone from widely spaced core and reverse circulation drill holes. Mineralization is open at depth, on strike to the west and beneath the hornfels to the north.

Jan 1, 1995

By S. Kmet, A. Nguyen-Van, H. J. Schulze

The P/B collision and attachment interactions in fine particle flotation have been quantitatively analyzed. New models for attachment probability and kinetics of ‘true flotation’ have been developed. The results are given for both a single bubble and a bubble swarm. The mechanism of the attachment event is also examined. It is shown that (i) impact collision mechanism and rolling mechanism can be ignored in actual fine particle flotation and sliding mechanism is of importance for attachment of particle onto the bubble surface (ii) the attachment probability of fine particles is independent of bubble size and determined by the kinetic measure induction time of hydrophobicity. The theoretical predictions are also compared with the experimental data.

Jan 1, 1995

By G J. Corbett

Magmatic-related low sulfidation hydrothermal ore systems at plate margins exhibit distinct spatial and temporal zonations which can be used to aid mineral exploration and development. Low sulphidation systems at all crustal levels exhibit the same paragenetic sequence of events: early breccia formation, followed by quartz - secondary feldspar sericite/illite veining, then mineralisation, and final argillic overprint. This sequence of events is interpreted to reflect the initial emplacement of melts at high crustal levels, and the progressive cooling of that melt and release of magmatic constituents into a circulating hydrothermal system. &nbsp; Low sulphidation systems in the south-west Pacific region exhibit a vertical zonation in deposit types: from porphyry copper-gold at deep levels, quartz-sulfide-gold at mesothermal to deep epithermal levels, carbonate-base metal gold at mainly epithermal levels, and epithermal quartz silver-gold at shallow levels. It is interpreted that the characteristics of each of these styles of deposits is produced by mixing with circulating waters of different physio-chemical compositions.

Jan 1, 1995