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By Mark D. Cocker

Georgia?s Coastal Plain contains important sediment-hosted deposits of kaolin, bauxite, heavy minerals, sand and gravel, silica sand, carbonate rocks, and fuller's earth. Genesis, location, size, and quality of these deposits are related to terrestrial, marginal-marine, and shallow-marine depositional environments that evolved during development of the southeastern North American continental margin. From the Cretaceous to Eocene, kaolin and aluminous sediments, which contained mica and feldspar, were deposited in marshes, ponds, and bays located in deltas or behind barrier islands or spits. In the Cretaceous sediments, subsequent, intensive, in situ chemical weathering converted mica and feldspar to kaolin. Kaolin eroded from deeply weathered granitic rocks in the Georgia Piedmont was deposited in Paleocene to Eocene sediments. Subaerial exposure during the Paleocene and Eocene desilicated kaolin sediments to form bauxite. Sand and gravel, silica sand, and heavy-mineral deposits are found in Cretaceous to Eocene fluvial and shoreline sediments, some of which are associated with the kaolin and bauxite deposits. Source areas, intensive chemical weathering in the source areas, transportation by the major river systems, and deposition of these clastic sediments in similar or nearby depositional environments are common elements in the genesis of these resources. Eocene fuller's-earth deposits are opaline claystones in near-shore to shelf-marine sediments, which overlie the kaolin-bearing strata. These claystones consist of montmorillonite and opal/ cristobalite derived from alteration of diatom frustules. Favorable ocean currents provided nutrients for extensive planktonic growth. Oligocene and Miocene carbonate rocks were deposited principally in shallow-marine embayments. Miocene fuller's- earth deposits in south-central Georgia and adjacent parts of Florida contain palygorskite that formed through alteration of montmorillonite/bentonite clays. Deposition and subsequent alteration occurred in shallow, brackish-water lagoons under relatively high temperature and subtropical conditions. Middle and late Miocene phosphorites were deposited on a shallow carbonate-shelf platform and were concentrated proximal to anticlinal highs. Numerous marine transgressions and regressions since the beginning of the Pleistocene resulted in shoreline detrital deposits containing aggregate sand, silica sand, and heavy minerals on the Coastal Plain and on the Continental Shelf. Major river systems transported sand and heavy minerals from source areas in the Piedmont and Upper Coastal Plain. Deltaic deposits of heavy minerals were redistributed and concentrated by longshore currents, shoreline processes, and aeolian processes. River-terrace sediments, correlative with the Pleistocene shoreline deposits, contain sand-and-gravel and silica-sand deposits. Aeolian dune sands are associated with both Pleistocene fluvial and shoreline detrital deposits.

Jan 1, 1999

By I. S. Escobar

Copper, particularly the oxygen-free grade Cu-OFP, is a candidate material for containers for the long-term isolation and disposal of high-level radioactive waste (HLW) in underground repositories. After having been buried for a few hundred years, all oxygen will have been consumed in the repository, and corrosion of the copper will be caused entirely by contact with dissolved sulfides. Chloride is another potential corrodant, but in deep repositories where groundwater is neutral or slightly alkaline, the effect of chlorides can be ignored on thermodynamic grounds. Thus, the corrosion of copper in the presence of sulfide ion and under reducing conditions has been studied using cyclic voltammetry and Tafel slope measurements. It is possible to determine the effect of sulphide ion on copper corrosion resistance which is minimized at low temperature and also at low sulphide concentration. The presence of anions such as HCO3 under environmental conditions produces a beneficial effect because these ions are inhibitors.

Jan 1, 1999

By John W. Brown

"Adequate dust control in and around rock drills is a problem that must be solvedfor the health and safety of workers running the drill as well as those working around thedrilling operation This paper will discuss the designs available from most drill manufacturers todayand the effort ‘nvolved in keeping them effective on a productive basis."

Jan 1, 1999

By John Hartlen

"The 19th century was an ""age of gold"" and Nova Scotia experienced its share of early gold rushes. Gold mining activity in the province was focussed into three ""rushes"" which occurred, approximately, in the 1860s, 1890s and 1930s; a total recovery of 1.1 million oz. Au has been recorded. The purpose of this note is simply to chronicle the technical development of gold mining and processing in the province and to comment briefly on the recently renewed interest in this precious metal. The first public discovery of gold in Nova Scotia was made by a farmer in 1860 at Old Tangier or Mooseland, and this find sparked the province's first gold rush. The mining and milling methods of the 1860s were ingenious. Initially, arrastras, crude stone-hewn grinding mills, drawn by men, mules or horses, were widely used. Nova Scotia's first conventional stamp mill was installed at Mooseland by 1862; it was comprised of four wooden stamps and is believed to have been imported from Scotland. One of the largest waterwheels of the 1860s, reportedly 16 feet in diameter and 8 feet wide with a SO-horsepower rating, was used in the Renfrew Gold District to drive gold stamps. Steam power was also employed, and many of the engines were of native construction, as was the unit at Waverley's Lake Major Company, which had a piston 1 foot in diameter by 12 feet long and was connected to a 16-ftdiameter flywheel."

Jan 1, 1999

By J. S. Lee

A new high performance adsorbent is synthesized by the sol-gel method and applied to the removal of cadmium and mercury ions from aqueous solutions. Adsorbents based on metal oxides have been developed by immobilizing chelating molecules on the surface of the existing metal oxide networks and show ability for selective metal extraction from aqueous solutions. However, efficiencies of such adsorbents are limited due to low ligand density, and difficulty in pore accessibility. These difficulties are circumvented by synthesizing adsorbents using the sol-gel technique. In one example to be discussed, the sol-precursor possesses an organic moiety that binds cadmium, mercury, and copper ions. The capacities of 1.98mmol Cd(II-/gm and 6.40 mmol Hg/gm of this adsorbent are considerably higher than those of adsorbents prepared by the ligand immobilization technique. The scope of this paper is to discuss the development of the new adsorbent and its applications for cadmium and mercury removal from aqueous solutions.

Jan 1, 1999

By J. F. Leroux

The Gaspé smelter at Murdochville, Quebec, Canada introduced concentrate injection into elongated Peirce-Smith converters sized 1.96m x 12.5m (13 ft. by 41 ft.) in 1996, and commissioned a large, converter-like bath smelting vessel in April 1998. The new vessel, which is sized 4.27m x 16.1 5m (14ft. by 53ft.) has several interesting features designed to effectively utilize bath smelting technology for the requirements of the Gaspé smelter. For example, the vessel can operate on concentrate injection at upwards of 60-80 tph rate on an instantaneous basis, can operate as a large Peirce-Smith converter, while it is also fitted with matte and slag tapholes much akin to Noranda Process reactor, and includes a novel cold charge addition system. The new technology will eventually allow the capacity of the plant to increase from about 300,000 tonnes of concentrate per year to over 350,000 tonnes of concentrate per year while improving sulfur capture.

Jan 1, 1999

By Dale S. Preece, Stephen H. Chung

"In bench blasting, the distribution of loaded explosives with respect to the burden rock has strong effects on digging especially at the toe area. Blast design often focuses on other results such as percent-cast or fragmentation, sometimes leaving a diggability problem at the toe of the blast that is not discovered until excavation. A method for assessing the influence of blast design on diggability has been developed. This method relates the kinetic energy and rock displacement experienced by the material in the muckpile to its diggability. Simulation of the blast along with the calculation of kinetic energy and diggability is done with the discrete element computer program DMC_BLAST(DMC: Distinct Motion Code)."

Jan 1, 1999

By A. W. Laughlin

Analytical costs are a major part of exploration programs in developing nations which may lack adequate laboratories. Laser-Induced Breakdown Spectroscopy (LIBS), a variant of atomic emission spectroscopy, can reduce exploration analytical costs and can provide the analytical results in <1 minute. CPI is now marketing battery-powered, backpack mounted analyzers, using LIBS to analyze for many elements of interest to the explorationist. LIBS is well suited to the analysis of elements in industrial minerals. Limits of detection in ppm for some of these are: Li-1, Be-2, Na-100, B-33, Sr-10, Ba-300, Cs-1, K-500, Fe-500, Mg-500, and Ti-500.

Jan 1, 1999

By D. Kump

The Bullfrog Mine is an underground goldmine that uses the underhand-cut-and-fill mining method. The portal was established on June 18, 1991. Mining is expected to be completed by the summer of 1999. This paper starts by discussing what it took to get from nothing to 2000 tons-per-day backfill, and ends with a hindsight commentary on things that did and did not help.

Jan 1, 1999

By G. Biles

The Eskay Creek Mine, a high-grade gold and silver underground mine in northwestern British Columbia started operations in late 1994. For the first three years of operation, ore was crushed to minus 2 inch; blended to satisfy smelter terms and direct shipped to smelters in Japan and Canada. Before commencing the above operations, preliminary evaluations had indicated that an extremely complex metallurgical facility, requiring a large capital investment, would be required to recover the precious and other economic metals. Subsequently markets for raw ore were identified and underground mining and ore transportation operations, at a nominal production rate of 300 tonnes per day, were commenced. Exploration diamond drilling in 1995 and 1996 discovered additional lower grade mineralized zones, which are less economic or uneconomic as direct shipping ore. Testwork demonstrated that these lower grade zones could be upgraded to marketable concentrates in a simple flotation mill. The mill was built in 1997 and has been in operation since late 1997. The mining rate now has increased to 400 tonnes per day including 250 tonnes per day of the direct shipping ore and ISO tonnes per day of the mill ore. Prime Resources Group Inc. wholly owns the Eskay Creek Mine. Homestake Canada Inc. owns 50.6% of Prime&apos;s shares and manages and operates the mine on Prime&apos;s behalf. This paper discusses the mining and milling operations as well as ore shipment and smelter contracts&apos; administration.

Jan 1, 1999

By A. K. Kyllo

The use of Composite Furnace Module cooling systems has been shown to give improved refractory performance in a number of above bath locations in WMC flash furnaces. To test the behaviour of modules in contact with a melt, a set of instrumented modules have been installed in the reaction shaft of a. nickel flash furnace. The location was chosen to provide a suitably harsh environment to ensure rigorous testing, while still allowing relatively easy access for module installation. The modules were continuously monitored to provide information on the module performance, as well as the temperature in the shaft itself. The shaft temperature showed significant transient behaviour, which resulted in heat fluxes through the modules ranging from 10 to 92 kW m-2. The modules were capable of handling the highest heat flux with no risk of the coolant boiling. This paper details the design and operation of the modules over a period of seven weeks.

Jan 1, 1999

By S. Uihteenmaki

Pyhasalmi is a massive sulfide orebody located in central Finland. The mine has been in operation since 1962. The flotation concentrator produces Cu, Zn, Pb and pyrite concentrates. The plant has used an on-stream analyzer for process control since 1968. The original analyzer has overlived a few generations of minicomputers, but the analytical parts are essentially unchanged. The on-stream analyzer is a critical component in plant process control system, which has made Pyhasaltni one of the pioneers in the art of computer control and optimization of flotation plants. The paper summarizes the experiences gained from the use of the high performance elemental analyzer system and the proven benefits from the use of on-stream analyzers at a complex sulfide flotation. The aging analyzer is approaching the end of its useful life. A new state of the art analyzer system is undergoing testing at Pyhasalmi.

Jan 1, 1999

By Zajber A, Kulchen R, Letzel D, Weyer A, Schwellenbach J

The search for modem casting plant concepts today focuses more and more on the harmonisation and optimisation of overall concept lines to obtain a continuous quality control and reduce the cost of production (Figure 1). Fin I As far as continuous casting plant concepts are concerned, this specifically requires an optimal adaptation and flexible operation when converting liquid steel into a directly processable product without any in-between treatment. Continuous casters need to fully satisfy the requirements of both the upstream steelmaking facilities as well as the downstream rolling facilities.

Jan 1, 1999

By E. F. Schnitzer, P. J. Wampler

During 1996 and 1997, Oregon experienced flooding on a scale not seen in many years. Some gravel pits located near rivers experienced erosion and, in several cases, breaches between the gravel pit and the river. Initial evaluation of several sites that experienced breaches indicates that impacts to the river system are complex and vary significantly from site to site. The impacts to the adjacent river system may be viewed as both positive and negative. Several floodplain-mining sites in Oregon located in areas of historic river flow have reverted to active riverbed. In many cases, state and federal fisheries biologists and university researchers see the resulting increase in channel complexity and habitat as favorable. The Oregon Department of Geology and Mineral Industries – Mined Land Reclamation Program (DOGAMI-MLR) is performing additional studies of the impacts to the off-channel areas that resulted from the 1996 floods. More data is needed to make sound floodplain decisions regarding mining.

Jan 1, 1999

By G. Achurra

The products of the smelting of copper concentrates in an El Teniente Converter (CT) are a high grade matte, analyzing 74-76% Cu; and a highly oxidized slag, typically containing 15-20% Fe3O4 and 4-10% Cu. The El Teniente Division of CODELCO¬CHILE has developed a slag reduction-cleaning process, that is practised in a tilting, horizontal furnace, to recover copper from these slags. The El Teniente slag cleaning process has been successfully implemented at the El Teniente Caletones smelter and various other smelters in Chile: Today, eight such slag cleaning furnaces, each with a capacity of 800-1000 tonnes/day, are in operation in Chile. This paper discusses basic laboratory research and industrial tests that led to substantial reductions in the slag cleaning cycle time and the specific consumption of fuel and reductants. Simultaneously, the slag cleaning off-gas quality was improved. Based on the experimental results, recommendations were made to improve the practice of the El Teniente slag cleaning process. The recommended modifications have been fully implemented at the Caletones smelter.

Jan 1, 1999

By Larry M. Southwick

Extraction of gold and other metals from ores suspended in liquid slurries often involves gases (such as oxygen) as a participant in the reaction. An important factor then in setting the rate of extraction can be mass transfer of the gas into the liquid and/or solids. A number of recent studies have indicated that as solids loadings increase, mass transfer rates of gas into solid-liquid mixtures decreases. This would seem to imply that lower solids loadings would be beneficial to increased reaction rates. However, since it is the solids which are being reacted, a most intriguing paradox is created. More solids should lead to more surface area to react, but it seemingly also provides less gas to react. So is the reaction faster or slower as solids loadings increases? The creation of this paradox is imbedded in how mass transfer and reaction data is collected and measured, how it is analyzed and correlated, and finally on the rate controlling steps in the reaction. An alternative analysis of these studies is presented which clarifies and eliminates the paradox. The analysis applies to water slurries as used in gold or other metal leaching processes or in bio-hydrometallurgy, as well as to molten metal/solid/gas mixtures such as might be encountered in submerged gas injection.

Jan 1, 1999

By M. A. Vera

This paper proposes a simple two-parameter model for the typical inverse relationship between recovery and flotation concentrate grade. The model is based on the mineralogical limitations imposed by the material properties. One parameter (R*) describes the proportion of metal content which is floatable, and the other (b) is the rate at which the fastest floating particles are being contaminated by the other less valuable particles present in the mineral system. One significant feature of the recovery-grade curve is that initial recovery (i. e. R ? 0) is at the purest attainable mineral grade, (but as recovery rises the cumulative grade of the concentrate tends to the feed grade. The ideal recovery-grade curve for a particular mineralogical system can be obtained by release analysis: the release analysis curve determines the maximum or limiting separation efficiency. The model proposed in this work is similar to the linear recovery - cut-off grade model of Dell (1), but has the advantage of describing the whole curve.

Jan 1, 1999

By J. Marc Coolen

Marrowbone Development Company operates a large drift mining complex in the central Appalachian coal field. In 1997, five continuous miner supersections produced close to 9 million tons of raw plant feed. All production is from the Coalburg seam, a 5 to 10 ft thick coal seam with multiple coal benches and shale binders. The immediate roof lithologies consist of laminated shales, sandstones, or a mixture of sandstones and shales. The mine area is bisected by the regional Warfield anticline and associated Warfield fault. Mining conditions vary considerably due to frequent changes in seam and roof geology. The following geological categories can be distinguished: 1) presence of coal riders in the immediate shale roof, 2) excessive seam slopes around the Warfield fault, 3) splay faults associated with the Warfield fault, 4) zones of abundant slickensides, 5) abrupt roof lithology changes (sandstone - shale), 6) splitting and merging of different benches of the Coalburg seam, 7) sandstone washouts, 8) excessive roof dilution, 9) pillar sizing problems due to seam anomalies (soft fireclay binders). Several examples of these features are discussed in detail. Also, their relationship to roof fall occurrences is evaluated. Early recognition of potentially adverse geological conditions is of prime importance for the economic viability of the mining plans. Detailed core drilling in advance of the mining faces and coordination of the core data with underground mapping are the main forecasting tools.

Jan 1, 1999

A new system for granting access to mineral rights is proposed in the recently released White Paper, ?A Minerals and Mining Policy for South Africa?. Official policy states that ?Government?s long-term objective is for all mineral rights to vest in the State for the benefit of and on behalf of all the people of South Africa?. In order to achieve this objective, government is presently investigating the feasibility of imposing a financial or tax-related disincentive to holding mineral rights. The paper aims to present the pros and cons and to examine the alternatives which will cause minimal disruption to the minerals industry in the period during which mineral rights are transferred to the State. South Africa is a country whose economic and political history is embedded in the development of its mineral resources and has inherited a system which cannot simply be wished away. Hasty or radical decisions will compound the problem, rather than provide a lasting and widely acceptable solution. Mineral rights ownership and its impact on access to mineral deposits are discussed. Taxation as a possible economic disincentive is also evaluated. Finally, the value of mineral resource related information as a prerequisite to mineral policy decisions and as an alternative to mineral rights taxation is emphasized.

Jan 1, 1999

By Glenn A. Gruber

The conditioning of phosphate flotation feed with anionic flotation reagents was identified as a high- priority research topic during a beneficiation work- shop sponsored by the Florida Institute of Phosphate Research (FIPR). FIPR subsequently solicited research proposals to identify the mechanisms of reagent adsorption, to determine scale-up relationships for conditioner design, and to investigate the effect of conditioning variables on reagent adsorption and flotation performance. The two-year research project was awarded to Jacobs Engineering. Somasundaran, Inc., the University of Florida Mineral Resources Research Center, and the U.S. Bureau of Mines assisted Jacobs. Two mechanisms of anionic collector adsorption were detected by spectrographic analyses and confirmed by microcalorimetric measurements. The mechanisms provided a sound technical basis for the empirical practice of conditioning phosphate flotation feed at a high percent solids. Tests performed in laboratory and pilot-scale agitated tanks indicated that power intensity may be used as a reliable scale-up parameter for anionic conditioning of phosphate slurry. Excessive agitator speed during conditioning was found to be detrimental to anionic flotation performance. Some dimensional ratios of anionic conditioners were found to be consistent with good utilization of agitation energy. Laboratory conditioning and flotation tests demonstrated that adsorption of collector onto phosphate and the subsequent recovery of phosphate in anionic flotation were significantly influenced by the quantity and quality of water used in conditioning. Conversely, the quality of water used in flotation was more influential on the recovery of quartz in the concentrate. A comprehensive survey of anionic conditioners and conditioning practice in the Florida phosphate industry was also performed during this project. The study clearly showed that flotation testing with laboratory conditions typical of scientific research gives different results than laboratory testing with simulated plant conditions. The effects of test conditions on laboratory test results should be carefully considered by investigators planning and conducting applied research.

Jan 1, 1999