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By T. Tamagawa, I. Iwasaki, N. X. Fu, M. Kobayashi

A low-temperature-chlorination selective oxidation followed by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide was investigated for hydrometallurgical processing of a chalcopyrite concentrate. In this article, the selective oxidation phase of the process is described. The selective oxidation requires a temperature well above the CuCl-FeCl3 eutectic points. The test procedure was developed with a batch reactor and then tested with a continuous reactor. The process was initiated by adding small amounts of chlorinated samples to a fluidizing bed of dead-roasted sulfide concentrate micropellets. The selectively oxidized samples thus prepared were shown to fully dissolve copper, while virtually all the iron remained undissolved.

Jan 1, 2000

By Tom C. Palanglo, Norbert Maerz

Control of crushing and grinding circuits ideally requires continuous particle size measurements on both in- and outgoing streams. Until recently, size distributions could only be obtained by screening methods, which were neither cost effective, frequent enough, nor timely. Input streams are often composed of large fragments, making screening prohibitive. Optical image processing systems, such as the WipFrag System, have been developed to the point that they are an extremely valuable tool to characterize, control, and fine-tune the comminution process. Although accuracy is less than that of screening, measurements are precise enough to detect relatively small changes in size distributions.

Jan 1, 2000

By Joe F. T. Agapito

High stresses and adverse geology in deep coal mines in the state of Utah, USA, have caused numerous bumps. The larger bumps have been associated with seismic events with Richter magnitudes of 3.6 and greater, and in some cases have filled openings for lengths of 150 m. A better understanding of the mechanisms and stress levels involved in bumping is needed to help develop improved stress control design and bump mitigation methods. The geology of the area is notoriously bump-prone. The coal has poorly developed cleating and occurs in multiple seams that are often bounded by very strong roof and floor sandstone/siltstone beds. The overburden is formed by thick, competent strata with numerous sandstone channels This geology and deep cover are the major source of high stresses, causing bumps. This paper evaluates live common stress factors responsible for bump problems: depth, sandstone channels, arching, faults, and coal thickness. It uses ease study data from longwall panels with two-entry/yield pillar systems typical of deeper Utah mines. Results illustrate the importance of analyzing stress factor experience to allow a better understanding of the problem.

Jan 1, 2000

By Launa Mallett

This paper introduces a method for teaching workers to communicate necessary information when giving or receiving emergency warning messages. Research has shown that when an emergency occurs, people may not get the information they need to take appropriate action. Interviews conducted with 48 underground coal miners who had escaped mine fires revealed that the warning information provided was inadequate. In some cases, sufficient information was not provided to the endangered miners. At other times, miners failed to ask for information they needed to plan and execute effective escapes. Researchers from the NIOSH Pittsburgh Research Laboratory have been studying the content of emergency warning messages and have developed an emergency communication protocol. A training intervention that presents the protocol and related mental cues is being evaluated for effectiveness in improving the content of emergency messages. In this paper the protocol is presented and the training package described. The evaluation procedures and a summary of the analyses conducted to-date are also provided. The training package was developed for use with underground coal miners, but could easily be modified for emergency communications training in other settings.

Jan 1, 2000

By D. Duvris

Health and safety issues are a very important aspect of mining activities. Although the application of scientific research and current technology shields workers from many dangerous aspects of mining, accidents do happen. Many companies and institutions worldwide have committed to a continuous effort to minimize such occurrences. In this study, the health and safety data pertaining to the Greek mining and quarrying industry for the last 3 decades are presented and critically evaluated with respect to number of workers, annual production, etc. Appropriate indices are also calculated regarding the incidence and frequency of accidents. Health and safety issues specific to mining in Greek are also discussed.

Jan 1, 2000

By Vincent A. Scovazzo

Benchmarking is a business management process that seeks improvement through the study and reapplication of practices conducted by industry leaders. This discussion presents objectives and organization of benchmarking applied to mining geomechanics. Similar procedures have been successfully applied to mining companies, laboratories, and research organizations involved in mining geomechanics throughout the world. Benchmarking is a structured process that allows an organization to learn from the "best" in the field. The objectives of benchmarking vary depending on the company's targeted areas for improvements. Typical goals include ground control cost reduction, enhanced safety, optimization of geotechnical staffing, development of state-of-the-art design procedures, or the adoption of the "best in the field" geotechnical data management. Once the objective of the study is established and the practices and procedures to be benchmarked are identified, a benchmarking team is formed from internal and outside specialists. Benchmarking in geomechanics is fundamentally different than in most other fields because of the effects of local geologic conditions and regulations, both of which must be understood by all on the benchmarking team, before a comparative analysis can be made.

Jan 1, 2000

By A. C. Stevenson

"There are many critical application issues that affect all AC drives, but there are several that are absolutely mandatory for pulse width modulated (PWM) AC drives. If these rules are not followed, the drive system will have insulation, bearing EMI or noise problems. Pulse Width Output VoltageFigure 1 shows the output current of a typical pulse width modulated (PWM) drive. This is, of course, not a clean sine wave thus will have a lot of very significant harmonics. In fact, the harmonic spectrum is directly related to multiples of the carrier switching frequency plus side bands related to the basic output frequency. A typical spectrum for a PWM source bridge switching at 5 kHz is shown in Figure 2. Notice that the spectrum has multiples of the 5 kHz switching frequency and the number of side bands gets larger as the harmonic number increases.IGBT Switching TransientsWhenever we have PWM inverter switching, voltage transients are formed that propagate (usually at about half the speed of light) down the power cables to the motor just like in a radio frequency transmission line. If we do not terminate these transmission lines (motor cables) properly, the voltage pulses will be reflected when they reach the motor end and will be transiently increased up to twice their original amplitude.This transient voltage rise, shown in Figure 3, is important for three reasons:1. Insulation Voltage Stress — Higher voltage stress in the motor connecting cables and motor insulation will lead to a shorter insulation lifetime. If any of the voltage transient peaks exceed the insulation corona discharge level (partial discharge level), the insulation will gradually degrade with each voltage pulse. When it has been sufficiently degraded, it will then fail.Most new “inverter rated” motors have triple layer insulation which has a 1600 to 2000 volt partial discharge level. This will make them suitable to withstand the double voltage peak transient from a 600 volt inverter. It is wise to make sure of this fact, since a “standard” induction motor will only withstand about 1200 volts. Use of a standard motor in this application would shorten its life drastically. This can sometimes be as little as a matter of hours."

Jan 1, 2000

By Jay. M. Khodadadi, Josef Štetina, František Kavicka

"With the aid of the proper original numerical model of solidification the instruction for preparation of input parameters for numerical simulation of technological processes, with change of the phase or structure, will be presented. A method of calculation analysis of influence of therrpophysical properties of materials entering the system of casting-mould-cores environment, and also of boundary conditions on the required simulation accuracy will be suggested. For the cast material, the influence of heat .conductivity, specific heat capacity, density and latent heat of phase transformation also has been analysed. For metallic or non-metallic moulding material"" the influence of the see main parameters has been analysed and, furthermore, their combination, influence of thermal conductivity, and of heat storage. The order of influence of all quoted parameters of a casting and moulding material was established. For example heat conductivity in the liquid state is on the last place. From the boundary conditions the -most important influence on the total solidification time and · on the mechanism of forming of temperature field has the ·boundary condition on the casting mould boundary, then follows the boundary condition on the level of a molten metal. The negligible influence has the boundary condition on the mould frame and on the bottom.IntroductionThe original and universal mathematical model of solidification, cooling and heating has been set up and checked, in order to be capable of analysing a one- to three-dimensional steady or unsteady temperature field of the casting-mould-environment system and, namely, of the system as a whole or its arbitrary parts, during any industrial technological process whose individual processes could be solidification, cooling, heating, refrigeration and others, in any sequence or singly. The model enables the simulation of traditional and also non-traditional technologies of casting in foundries, metallurgical plants, forging operations, heat treatment processes, etc. If solidification is not the matter, the metal part of the system need not be called the casting but a component, a block, a forging and the like."

Jan 1, 2000

By S Jahanshahi, D R. Swinbourne

The classical metal-slag-gas equilibrium technique was used to study the thermodynamic activity of cobalt, iron and their oxides in iron silicate based slags containing under controlled oxygen potential (3.70 x 10-8 to 2.95 x 10-7 atm) at 1573 K. The measured activity of cobalt oxide in FeOx-25 wt per cent SiO2 slags showed positive deviation from ideal behaviour for melts with up to ten wt per cent CoO. At higher silica contents, the behaviour became closer to ideal and in accord with previous studies on silica saturated slags. The activity coefficient of FeO in these slags had virtually no dependence on the CoO content. Partial substitution of silica by lime resulted in an increase of the activities and activity coefficients of CoO, FeO, Fe2O3 and Fe3O4. The results indicate that saturation of the slag with a magnetite phase occurs at CaO contents of five wt per cent and higher. Phase equilibria studies SiO2-FeO-Fe2O3-CaO slags containing cobalt were also carried out using the drop-quench technique. Results from these experiments confirmed the formation of a magnetite solid solution containing about three wt per cent CoO at lime contents of five wt per cent and higher at 1573 K and 2.9 x 10-7 atm of oxygen.

Jan 1, 2000

By W Newton, J Price

This paper outlines the design, justification and performance of a gravity circuit upgrade at the Marvel Loch treatment plant. The design of the upgrade was simple but effective. The key components of the upgrade were the addition of a sluice and a second Knelson Concentrator. The sluice was installed as a pre-concentration step. The upgrade also included the purchase of a Mineral Cone to treat the increased quantity of gravity concentrate. The cost was low because of the use of mostly second-hand equipment. The result was that for a cost of $75 000 the gravity recovery doubled and the overall recovery increased by over one per cent. This paper shows that you do not need to spend millions of dollars to be innovative and successful.

Jan 1, 2000

By G. A. Irons, D. Colbert

Several electric arc furnace (EAF) shops have increased the zinc and lead grades of EAF dust by reinjecting it into their furnaces; however, the kinetics of this operation are poorly understood. To understand the kinetics, EAF dust was injected into 70 kg heats of iron or steel in an induction furnace. Supplemental additions of carbon and oxygen to overcome the heat load on the system were also investigated. In all cases, the dust was chemically transformed, and the zinc content increased from 16% Zn to 60 - 80% Zn. About 50% of the zinc in the EAF dust dissolved in the iron or steel. The zinc oxide in the dust is thought to be reduced by carbon and the zinc vapour subsequently dissolved in the iron. A kinetic model for the dissolution process is proposed, and the implications for EAF dust recycling are discussed.

Jan 1, 2000

This chapter focuses on smoke as it relates to escape from underground mine fires. Among the topics discussed are the measurement of visibility in smoke; smoke-related hazards such as the production of CO, hydrochloric acid (HCI), or other byproducts of combustion; and miners' personal experiences while escaping through smoke. Smoke Measurement and Visibility In general, smoke consists of hundreds of thousands of very small particles. These particles have some "size," usually expressed in terms of their diameters, and they have some concentrations, usually expressed either in the number of these particles per unit volume or the total mass of the particles per unit volume. Humans cannot see individual smoke particles because they are too small. Similarly, "umber concentrations" and "mass concentrations" of smoke particles do not have much meaning to people unless they are trained technically. Still, individuals know that they can see smoke, independent of all the technical jargon used to describe it. Also, they know that when the smoke level gets too high, it is no longer visible. In fact, nothing is visible because the smoke absorbs all of the light in its surroundings. The eye is only sensitive to light in the wavelength region from about 400 nm to about 700 nm. The maximum sensitivity of the human eye is to light that has a wavelength of about 555 nm. It is important to know how the eye responds to light because if its response is known, it is possible to use a light detector that has almost the same response as the eye. Such a detector can then be used to quantify the visible characteristics of smoke because it responds in the same manner as the human eye. Smoke is visible because it either scatters or attenuates (diminishes) light. In some instances, smoke is visible because the smoke particles reflect light which is then detected by the eye. The eye actually "sees" an intensity of light that has been reflected from a cloud of smoke particles. Imagine shining a flashlight into a cloud of smoke. Someone off to the side can actually "see" the beam of light as it traverses the smoke cloud. This is called scattering. Smoke is also visible be¬cause it attenuates light. Imagine having someone shine a flashlight into your eyes. As smoke begins to build up along the beam of the flashlight, the light begins to dim. The smoke is visible because it is now reducing the intensity of light that falls upon the eye. As the smoke level increases, it is said to obscure our visibility. When the beam is no longer visible, the smoke obscuration is said to be 100%. In other words, none of the light energy from the flashlight makes its way through the cloud of smoke. Another way of saying that the obscuration is 100% is to say that the transmission of light through the cloud is zero.

Jan 1, 2000

By Masanori Abe, Yoshitaka Kitamoto, Kazuhiro Nishimura

"Ferrite plating is a chemical processing which utilizes Fe2+ - Fe3+ oxidation to synthesizing polycrystalline films of ferromagnetic spinels (MFe20 4, M = Fe, Co, Ni, Zn, Al, Cr, TI, etc:) directly from an aqueous solution at 24 - 100°C. This low temperature process allows us to fabricate new ferrite film devices on · substrates of such non-heat-resistant materials as plastics, GaAs integrated circuits, and biomaterials. Synthesized from an aqueous solution the ferrite plated ·films are highly biocompatible. Thus various magnetic device and biomedical applications have been proposed and realized using ferrite-plated films. Ferrite-encapsulated polymer microspheres are applied to antibody carries for enzyme immunoassay, and also to toners/carriers for photocopying. Perpendicular magnetic recording media utilizing plated CoNi ferrite films are proposed. The low-temperature synthesized films of NiZn and Co ferrites are potentially used as soft-magnetic and/or insulating layers, respectively at high/microwave frequencies.IntroductionFerrite plating is a processing which facilitates the formation of crystalline spinel ferrite films with various compositions, (Fe, M)30 4 (M = Fe, Co, Ni, Zn, Al, Cr, TI, etc.), directly from an aqueous solution at 60 - 100°C [1]. This opened the door to fabricating novel ferrite-film devices using substrates of such non-heat-resistant materials as plastics and GaAs integrated circuits [2-4]; conventional ferrite film preparation techniques such as sputtering, vacuum evaporation, MBE, LPE, etc., require high temperatures(> -600°C) for crystallization of ferrites, which deteriorates the non-heat-resistant substrates. Recently we extended ferrite plating to be preformed at room temperature [5, 6]. This enables us to use as substrates such organic materials as biomaterials (e.g. enzymes) having very low heat-resistance."

Jan 1, 2000

By J. Pesl, U. Kemey, F. Sauert

"The CONTOP® smelting cyclone is a water-cooled, upright, high-intensity smelting reactor. The technology for the reactor was initially developed and brought into industrial-scale operation in the area of non-ferrous metallurgy. The two largest smelting cyclones were built with a capacity of 32 tons per hour of copper concentrate mix.The newest industrial CONTOP® plant treats up to five tons per hour of zinc-bearing residues including EAF dust. The highly concentrated zinc-lead oxide produced is sold to the zinc industry. The slag fulfills the leaching criteria and is used in waterway construction. The heat transferred to the cyclone cooling system and the off-gas boiler produces steam from which power is generated in a turbine.V AI has erected a new CONTOP® demonstration plant at MEFOS, Lulea, Sweden. A zinc volatilization rate of 90% was achieved during hot commissioning with Swedish EAF dust.Treatment costs in the range of 85 to 100 EUR per ton were estimated in a feasibility study on the treatment of 73,000 and 57 ,000 tons EAF dust for a group of steelmaking mills in Southern Europe."

Jan 1, 2000

By Bruno Bussière, Michael Aubertin, Robert P. Chapuis

Covers with capillary barrier effects (CCBE) have been used in recent years as gas barriers for the isolation of wastes, including reactive mine tailings. Capillary barrier effects help to maintain a high degree of saturation in the moisture retaining layer, which then reduces gas flux. Various factors affect the degree of saturation of the moisture retaining layer in a CCBE, such as the material water retention characteristics and layer thickness. Slope geometry can also influence the hydrogeological behaviour of a CCBE, but this factor has frequently been ignored in the past. In this paper, the authors show some results of a numerical study that illustrates the influence of slope on the behavior of capillary barriers made of different types of material. The numerical model calculations are based on an actual case of a CCBE constructed in northern Quebec. This investigation shows that the water content profile is greatly affected by the position along the slope. Thus, it is necessary to evaluate the influence of the geometry to properly establish the performance of a cover system.

Jan 1, 2000

By R F. Johnston, I D. Sommerville

This paper presents an overview of the researches carried out in our laboratory on the application of plasma in recovery of alloy elements from waste slags and the treatment of lean ores, which are examples of advanced materials processing. After briefly reviewing the early work on the reduction of nickel, chromium, manganese, vanadium and titanium oxides, and a short investigation of the reduction of titanium oxide from the slag resulting from the blast furnace smelting of a titanomagnetite ore, the paper concentrates on the more recent studies on the reduction of an Australian scheelite. In some of these experiments, aluminium was used in addition to carbon as a reductant, in virtually all cases complete reduction was achieved within a relatively few minutes even with carbon alone during plasma processing. It therefore appears that this technique provides a possible processing route to facilitate the recovery of valuable alloying elements from non-traditional sources, or to permit process step elimination.

Jan 1, 2000

By J. W. Merks

Spreadsheet software is an effective tool for simulating dynamic stochastic systems such as mineral processing plants. The two-product formula is used to show how to set up a Monte Carlo simulation in a spreadsheet template and how to calculate variances of dependent variables. The key to a reliable and realistic simulation model is to obtain unbiased estimates for all independent variables and variances in the set that defines the stochastic system. Monte Carlo simulation is also a powerful tool for optimizing sampling procedures, for applying sensitivity analysis and for designing and evaluating experiments.

Jan 1, 2000

By Eiichi Kuzuno, Atsushi Shibayama, Toyohisa Fujita, Kazuo Koike, Toshio Miyazaki, Hitoshi Masuda

"A solid sulfur is more useful to recover and store than a sulfuric acid as a by-product in the zinc hydrometallurgy. In this experiment a zin concentrate (sphalerite) was leached with ferric sulfate at about 373 K for 3 to 6 hours. Zinc was leached more than 95%. After a solid-liquid separation, the leached residue contained solid sulfur was obtained. The particles in the residue were dispersed by lignin and the solid sulfur of approximately 85% was recovered as float product by a flotation with frother in the pH 4. The dried float product was heated at 413K for 2 hours. The pure solid sulfur was recovered. On the other hand in the leached liquid a zinc oxide was ·added and ferrous .iron was oxidized to ferric iron by blowing oxygen. This ferric iron was returned to the zinc leached process after solid-liquid separation.IntroductionZinc concentrate is usually roasted as pretreatment in zinc hydrometallurgy and the produced S02 is changed to sulfuric acid. However, recently in Japan the utilization of sulfuric acid has been limited and it is more costly to store. Instead of producing sulfutic acid the solid sulfur recovery has been examined by direct leaching of zinc_ concentrate in this experiment.In the direct leaching, several kinds of effects have been studied for leaching of sphalerite in ferric sulfate solution. The addition of lignine siilfonate1 • 2) and fine· grinding3) increases the · speed arid leaching fraction of sphalerite. The leaching ratio depends on impurities in sphalerite ores4 • 5). Here, the zinc concentrate is leached ferric sulfate solution under atmospheric pressure at 373K. The solid sulfur in leached residue is separated as float products from other solids by sink-float separation and flotation. The sulfur in float products is purified by evaporation at 413K and recovered."

Jan 1, 2000

By Cadia Geology Team

The Cadia Hill Gold Mine, located near Orange in Central Western New South Wales, is owned and operated by Cadia Holdings Pty Ltd, a wholly owned subsidiary of Newcrest Mining Limited. Construction including pre-strip mining occurred from 1996 to 1998. The mine was officially opened in October 1998 following commissioning of the concentrator and mine fleet in June of that year. The Cadia Hill orebody is a porphyry related gold and copper system. The final pit has a strip ratio of approximately 1.3:1.0. Mining is undertaken on 15 metre benches using large capacity diesel hydraulic face shovels at an annualised rate of up to 70 Mtpa. The concentrator is currently rated at 17Mtpa and includes the worldÆs largest single line grinding circuit. The feasibility Mineral Resource was estimated at 352 Mt at 0.63 g/t Au and 0.17 per cent Cu. Initial reserves totalled 200 Mt at 0.74 g/t Au and 0.17 per cent Cu yielding a mine life of approximately 12 years. During the pre-production period mine geology systems were developed to support the operation. By design these systems were intended to add value to the business through minimisation of material miss-classification, provision of accurate and timely production information and mapping and reconciliation as a continuous model improvement tool. Variances that would prove to be material to the life of mine plan were recognised during the first year of production. These included identification of additional ore tonnes, higher copper grades and higher gold recoveries relative to the model. Gold grades and copper recoveries also reconciled favourably. Testwork was undertaken to determine the underlying causes of each variance. Re-modelling was then undertaken to capitalise on those variances. The Cadia Hill Gold Mine life of mine plan was re-evaluated with updated geology, grade, geotechnical, metallurgical and environmental inputs. Operating strategies were also reviewed and revised. Despite application of reduced metal prices in the evaluation, the outcome was one of extended mine life with more metal produced at lower cost. Development of robust mine geology systems, including a pro-active reconciliation process contributed to tangible improvement of the Cadia Hill Gold Mine operation. On-going system development and improvement initiatives are planned to add further value for the future.

Jan 1, 2000

By Mark R. Stanton

Geochemical and mineralogical analyses of 46 samples from six drill cores in the Mayday mine pile near Silverton, Colorado, demonstrate wide variability in trace metal contents with spatial location. This variability results from the original geochemical composition of mined rocks, mixing of ore and non- ore rocks during emplacement of the pile, and weathering since rocks were placed in the pile. Weathering reactions are controlled by factors such as pile thickness (depth), water availability, microbial activity, and mineral dissolution and formation kinetics. These factors result in variable redistributions of trace metals from primary (ore) to secondary (weathering products) minerals within each core.

Jan 1, 2000