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By Courtney Black, Paul F. Ziemkiewicz, Eberhard Werner, Matthew Daly, Joseph J. Donovan, Jeff Frazier

Injection of alkaline waste-lime slurry was performed at a West Virginia surface coal mine site, to attempt neutralization of acid springs by an alkaline recharge method. Deep trenching (>5 m) using an excavator yielded the most effective injection into the aquifer. Water from two springs, 90 m from the deep trench, showed 70%-80% reduction in acidity in response to injection. Neutralization persisted >170 days after treatment, with pH between 5.1-5.7 and metal acidity from 25-60 mg/L. A minor fraction of lime introduced was consumed. The sustained neutralization is attributed to reaction of acid water with subsurface lime, entrained below the wafer table by macropore infiltration. Characteristics of groundwater transport are critical in determining recharge structure location.

Jan 1, 2000

By Xue Yongpeng, Zhu Zhenhai, Zhu Ming

The purpose of the Solid Medium Controlled Blasting Technique and Its Applications is to have the inside of the vessel-shaped framework (e.g: oil tank , water pool, gas chamber, chimney, water tower, grain warehouse and etc.) or the one side of the thin wall-shaped structure(e.g: steel bar concrete wall and etc.), both of which are intended to be demolished, inserted with the required solid medium (e.g: soil , sand , coal, salt and etc.) ,in which there is a certain mass density, and then through which the blasting energy is transferred to fulfill the blasting task. For such a technique, it is necessary to bury the explosives into the inserted solid medium and then to start the explosion to blast the intended target into pieces. The filling of the solid medium may be done mechanically or by man. Compared with the water pressure blasting technique, this one has the characteristics of good effect. wide application, simplified construction procedure , safe and reliable operation and small vibration (less vibration than water pressure blasting by 80% to 90%)in particular without any flying stones, thus resulting in better and comprehensive social and economickfficiency.

Jan 1, 2000

By J. Wagner, P. Eger, G. Melchert

In 1991, LTV Steel Mining decided to close an open-pit taconite mine in northeastern Minnesota using a passive-treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. More than 50 Aft (55 million st) of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages. Before the closure, the annual median concentrations ranged from 1.5 to 50 mg/L. Copper, cobalt and zinc are also present but they are generally less than 5% of the nickel values. Median pH levels range from 5 to 7.5, but most of the stockpile drainages have pH levels greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential that a stockpile had to produce acid drainage, the lower the permeability of the capping material required Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to more than 90% for the plastic liner. Five constructed wetlands have been installed since 1992. They have removed 60% to 90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1 % of those for an active treatment plant. Because mine-drainage problems can continue for more than 100 years, the lower annual operating costs should pay for the construction of the wetland-treatment systems within seven years.

Jan 1, 2000

By N. Menad

. Electronic wastes are heterogeneous mixture, with mainly copper, aluminium and steel attached to or mixed with various types of plastics and ceramics. In general, small amounts of precious metals are incorporated in this mixture. Today, these components constitute an environmentally problematic fraction in disposal. Their physico-chemical characteristics have been investigated through chemical, x-ray diffraction, infrared spectroscopy, scanning electron microscopy and thermal analysis.

Jan 1, 2000

By Hal Palmer

A number of Articles contained in the United Nations Convention on the Law of the Sea III (UNCLOS) bear directly on legal issues related to the recovery of mineral deposits on the ocean floor. Mineral resources of the continental margin other than oil, gas and hydrates include, sand, gravel, shell, coral, gemstones and phosphorite. Jurisdiction over the exploration and exploitation of these deposits is determined either by the Territorial Sea claims of a coastal state or their recognized sovereign rights in the Exclusive Economic Zone (EEZ). At least 33 coastal states have the right under Article 76 (Continental Shelf regime) to claim seabed jurisdiction beyond 200 nautical miles (EEZ limit). In addition, several states have "Pioneer Investor" status with regard to seabed resources in international waters (The Area). A global maritime boundary database (GMBD) has been developed as a basic resource identifying the current claims of coastal states. It provides detailed information on existing boundaries and limits determined by the UNCLOS accords or by multi-lateral agreements which affect mineral exploration and exploitation. This paper will describe the GMBD and its construction and maintenance.

Jan 1, 2000

By S. K. Kawatra, S. J. Ripke

Finely disseminated iron ores compose much of today's reserves. After removing the silicate gangue, the resulting fine iron oxide concentrates require pelletization with a binder to enable transportation and reduction. Binders can be used more efficiently if their binding mechanisms can be completely understood. Typically, bentonite clay is needed as a binder to improve the strength of the pellets. Bentonite is an effective binder at a relatively low cost, but costs could be reduced further by replacing bentonite with even lower-cost binders, such as high-carbon Fly-Ash Based Binder (FBB). In this study, it was found that bentonite binds by a physical mechanism, while FBB binds by a chemical mechanism. These mechanisms were determined to be incompatible. Partial replacement of either binder with the other reduced dry magnetite pellet compressive strengths below the industrially acceptable value of 22.2 newtons (5 lbf). Activators and accelerators that activated the fly-ash deactivated the bentonite. The incompatibility of these two binders is explained.

Jan 1, 2000

By S. Ferlay

"The main purpose of the ZIMA VAL project (Label EUREKA EU1367 and LIFE ENV/F/000278) is to demonstrate industrial scale recovery and recycling of the main components of used dry batteries (zinc, manganese dioxide, mercury, and stainless steel) into high added value products. The originality of the ZIMA VAL process resides in:1- the use of hydrometallurgy2- alkaline treatment implementation (highly selective) for zinc and mercury3- electrochemical recovery of high quality products.4- the recycling of all the battery components (zinc, mercury, manganese dioxide, stainless steel) ·5- low operating and investment costs.The process consists of physical classification, mechanical dismantling, hydrometallurgy and electrochemistry. The purpose of the demonstration plant in FALAISE (Calvados - France) is to define the technical and technological parameters of an industrial unit for the treatment of 2400 tonnes per year of used batteries."

Jan 1, 2000

By A. Wedepohl

Selective leaching of phases in charge chrome is used in a variety of industrial processes for the production of chromium chemicals. A mineralogical study was made of a range of local charge chrome samples, at various stages of leaching in sulphuric acid (20g/l at 90°C), using mainly a scanning electron microscope (SEM) together with an energy-dispersive spectroscopy analyzer (EDS), and X-ray diffraction techniques. It was found that the leaching behaviour of the different types of charge chrome depends largely on the nature of the secondary phases, which in turn depends upon whether the silicon content is above or below 4 per cent by mass. The leaching behaviour of high-chromium ferrite is anomalous, and it is postulated that the process is analogous to the corrosion of brass by dezincification. Keywords: charge chrome leaching, scanning electron microscope

Jan 1, 2000

By Brian Littlechild

Whilst there is much innovative work being undertaken in South East Asia in the space allowed in this paper we have settled on describing in more detail the work that has been done with shaft grouting of deep foundations and piles founded in rock both in end bearing and socket friction. The paper is necessarily in two parts. The first part is about the application of shaft grouting since its introduction to the region some eight years ago. It describes, for the first time, much of the detail of the different techniques used and the construction and the design benefits achieved with shaft grouting in five countries in the region. The second part outlines the enhancements achieved in the design of piles founded in rock and brings together the results of 10 years of test loading. This includes the load testing of 1.2m to 1.5m diameter piles to a maximum of 30MN on granite and a recent programme of tests on a wide range of strong rock types in Hong Kong. The ground conditions for these deep foundations vary widely, from sedimentary soils to in situ weathered granite and meta-sedimentary rocks. The construction techniques include barrettes constructed using mill techniques and bored piles formed under bentonite and water using both oscillators and rotators.

Jan 1, 2000

By R. Menge, N. Basin, M. Sibony, J. Lecadet, S. Schmidt

In 1996, Metaleurop replaced its conventional sintering and blast furnace lead smelting activity in Nordenham, Germany by Sirosmelt/Ausmelt technology. Following some alterations to the process and the equipment, the bath smelting plant reached its design capacity for the treatment of lead concentrates, lead sulphate paste from spent batteries, secondaries and internal by-products. A reliable metallurgical process has been established, and thus higher process stability has been achieved, increasing simultaneously the refractory life. Nevertheless, improvements are needed to control the process with a better automation system and reliable expert-systems, because of the intensity of the smelting process. The introduction of the Sirosmelt process for the pyrometallurgical production of lead instead of the prior conventional process has also demonstrated the following advantages: reduced emissions of heavy metals and gaseous compounds, reduction of the specific energy consumption, minimization of residues and a reduction of staff and maintenance costs. The environmental performance of the plant meets the requirements of the German regulations.

Jan 1, 2000

By Takashi Nakamura, Kenji Oosumi, Kazuhisa Fujisawa, Takayuki Kogishi

"Recycling of used aluminum beverage cans(UBCs) is one of the important issues for aluminum manufacturer presently. The direct re-melting of UBCs shows two problems. One is a reduction in molten aluminum recovery and the other is a contamination of other metals such as Ti and Fe from paints. Both problems are caused by paints coated on the surfaces of aluminum cans. Removal technique of the paints, therefore, has been required. Although roasting and shot blast techniques have been developed, both were not successful in removing the paints effectively. A swell-peeling method has been applied to remove them using a methylene chloride solution with acids and it works very well. Small laboratory scale tests have been carried out to develop the commercial process and clarify the mechanism of the swell-peeling method in the present study.When the surface area of UBC is more than 10 cm2, peeling time is independent of the surface area, about 60 seconds, because swelling phenomenon is controlled by the penetration of the liquid through the fine pits on the surface of the paint. This is good for a commercial process. Peeling takes place when the swelling force generated by methylene chloride exceeds the adhesion force between the film and the surface of aluminum, that is weakened by the coexisting acid, especially halogenated acetic acid."

Jan 1, 2000

By D. Ducharme, J. Lenz

Operation of the Kidd electrolytic zinc plant commenced in 1972 with a cellhouse capacity of 105,000 tonnes of zinc cathode. The original cellhouse layout consisted of 42 parallel rows for a total of 588 cells. As leaching capacity increased, the cellhouse was expanded to 630 cells. Zinc cathode was manually stripped from plant start-up until the development of a mobile automated stripping system in 1994. Machine development continued until a second unit was placed in production in 1996, from which point, 60 % of the cellhouse was being stripped with the automated system. The final phase of the project was implemented in 1999 with the commissioning of two more automated strippers. This paper describes the implementation of the automated stripping system and its impact on cellhouse productivity.

Jan 1, 2000

By M. Olper, M. Maccagni, C. J. N. Buisman, C. E. Schultz

The key point of the CX-EWS process is the conversion of lead compounds, contained in the active mass of spent batteries, into lead sulphide. The obtained lead sulphide is leached with ferric fluoborate electrolyte to dissolve lead and oxidize the sulphur from sulphide to the elemental form. The lead-rich solution is fed into a diaphragm electrolytic cell depositing lead and regenerating ferric fluoborate. The introduction of sulphate reducing bacteria technology in the sulphidization step of the battery paste improves dramatically the economics of the CXEWS process, reducing the costs of chemicals, avoiding gypsum disposal and minimising the unit operations of the process. This paper describes in detail this technology change with reference to the economics of the process.

Jan 1, 2000

By Per Eriksson

For light buildings on clay, foundations on L/C-columns is in many cases a competitive alternative to piles when the thickness of the clay is moderate (<20 m). The method is applicable for the above mentioned depth when the clay is normally consolidated, and for thicker deposits when the clay is overconsolidated at depth. This case study concerns a shopping mall in Nordby, Sweden, founded on L/C-columns (5-15 m in length) and generally spaced 1.45-2.0 m (spacing 0.7 m was used below pillars). The base slab was built as a raft foundation, using fibre reinforced concrete.

Jan 1, 2000

By D. W. Park

The Longwall Strata-Control and Maintenance System (LoSCo-MS) is a software and data-communication system developed at the University of Alabama. This system integrates real-time shield monitoring, data presentation, analysis and the forecasting of forthcoming events. The main objective of this system is to provide stability information on longwall panels, including excessive shield load, low setting pressure, leg leakage, poor shield performance and imminent maintenance problems. Analyses of various mining and geological parameters were also performed to determine past and present roof characteristics and to forecast roof loading patterns for the following mining cycles, the next periodic weighting, etc. A local coal mine in the Warrior Coal Basin has adopted this system to provide daily evaluation of ground stability and maintenance problems in their longwall panels. Two years of experience with this system is covered in this paper.

Jan 1, 2000

By James P. Bennett, Jasper Kwong

As concerns about the environment and the disposal of industrial wastes increase, the utilization of spent refractories from electric arc furnaces (EAF) is receiving more attention. Longer service life of refractories in an EAF can be achieved by foaming MgO saturated slag. The refractory wastes removed from a melt shop can be utilized as a part of these slags. The Albany Research Center is conducting research on recycling spent basic refractory materials as EAF slag conditioners. A good foaming slag should be a creamy, MgO saturated slag, which contains some solid particles (MgO-FeO). A computer model was developed to calculate the dual saturated slag chemistry with respect to CaO and MgO, the MgO saturated slag chemistry, and the solid content in solution. The effects of C/S ratio, AhO3 and temperature on the MgOsaturated slag as calculated by the model will be discussed.

Jan 1, 2000

By J-P Franzidis

Hydrodynamic conditions such as gas dispersion, mixing intensity and solids suspension are known to govern the metallurgical performance of the flotation process. Understanding flotation cell hydrodynamics is therefore important for the optimisation of existing cells and for the design of the larger and more efficient cells which are needed to handle the finer, lower grade ores currently being mined. This paper presents the results of numerous studies that have been carried out to characterise the hydrodynamic conditions in a number of different types of flotation machines both in Australia and South Africa. Measurement techniques that have been developed to determine gas dispersion and other hydrodynamic properties in industrial flotation cells are described along with applications for their use. The results show distinct differences between the way flotation cells are operated in the two countries.

Jan 1, 2000

By P. Forbes

Mining and metallurgical processing companies that have adopted the principles of good environmental management often find it difficult to carry out an environmental assessment that yields meaningful opportunities for improved performance. This topic was investigated by means of a case study of a South African Base Metal Refinery (BMR) producing primarily nickel. A process-based Life Cycle Assessment (LCA) was carried out on the refining process, with the environmental impacts related to the production of reagents and utilities forming part of the assessment. The lifecycle inventory (LCI) was based on plant operating data spanning 31 months of production, from which a baseline environmental profile could be generated and interpreted to indicate the main sources of potential environmental impacts. Consequently, opportunities for improved environmental performance could be identified from the LCA model, which expressly related potential environ-mental liability to specific sub-processes in the assessed industrial operation. The on-site steam plant was found to be the primary source of potential environmental impacts in most of the impact categories considered. In closing, the paper discusses some of the limitations encountered in use of the LCA method. Keywords: life cycle assessment; LCA; life cycle inventory; LCI; base metal refinery; improved environmental performance; environ-mental management systems; nickel refining.

Jan 1, 2000

By Jing Lin, Yuan Xu, Qingcai Liu, Dengfu Cheng

"Smelting reduction technology has been developed greatly in recent years. But one of the key problems for this technology is about the refractory that used as lining material in the molten bath. Investigation and test shown that corrosion rate of refractory was much higher and the corrosion mechanism was much more complexity in the molten bath of smelting reduction with iron bath than that of the blast furnace and rotary furnace technology [l-5]. The corrosion behavior and corrosion rate of Al2OrC-ZrO2 series refractory in the melt of smelting reduction with iron bath have been studied by rotary immersion and quasi-static immersion test in this paper. The major factors that affect the interaction between the melt and refractory were investigated. The test results shown that the corrosion rate of AI2O 3-C-ZrO2 series refractory decreased with the ZrO2 increasing when ZrO2 content was from 3% to 10%. Ferrous oxides content, relative moving speed between the melt and refractory and temperature of the molten bath were the important factors that affect the corrosion rate. But the ferrous oxides concentration was the most important one. The corrosion rate was increased as a linear relation with the rising of ferrous oxides content of the melt. The corrosion rate in the quasi-static immersion was much less than that of the dynamic immersion (rotary immersion) for the Al2O 3-CZrO2 series refractory in the same testing condition. The corrosion mechanism of Al2OrC-ZrO2 series refractory is: graphite oxidized in advance, then interaction between the constituents of refractory and melt taken place and deteriorate layer of refractory and new compounds were formed, the properties of refractory was changed.IntroductionSmelting reduction with iron bath is a typical technology [3, 4, 6]. The obvious features of the melt for smelting reduction technology with iron bath are much higher ferrous oxides and much more complexity melt composition and structure than that of the blast furnace technology [2, 5-8]. The properties of the melt were changed dynamicilly and constantly in reduction process. On the other hand, the behavior of the melt depends on the activity and the reduction rate of ferrous oxides in the molten bath[9]. Because of the high concentration of ferrous oxides in slag and high reduction rate in the molten bath, the corrosion behavior and corrosion mechanism of the refractory lining by melt are an important factor in development of the technology of smelting reduction with iron bath. Up to now, improving refractory quality to anti-corrosion of melt and developing high quality and long term refractory used as the lining refractory materials in the molten bath of the final reduction furnace are also the most important questions for developing smelting reduction technology."

Jan 1, 2000

By G. Gillet

The conventional magnetic separators used in the mineral industry are equipped with traditional magnetic circuits or with permanent magnets (rare earth). However, when processing minerals with low magnetic susceptibilities or minerals of very small particle size, these separators are inefficient. In addition, a conventional magnetic circuit consumes considerable amounts of electricity to generate a relatively low magnetic field (~2 Tesla). The equipment is also heavy and bulky. Only a separator having a superconducting sole-noid can contribute in solving most of the problems, and only such a separator can produce high magnetic fields with low energy consumption. New developments and the experience acquired in using these superconducting magnets have resulted in new uses for magnetic separation, especially in the environmental area. This paper presents and describes a separation system that uses superconducting magnets that are completely automated and able to treat raw materials (concentration or purification) or liquid industrial effluents containing heavy metals in solution. Several industrial sectors, including the surface treatment, petroleum and chemical industries, are generating effluents containing heavy metal ions. The main metal ions found in such effluents include zinc, copper and vanadium. The purification of such effluents by magnetic separation is performed by adding a certain proportion of iron salts. The treated effluent passes through a superconducting separator where the flocs are retained in a matrix of steel wires. The efficiency of supraconducting high-gradient magnetic separation (HGMS) by this method exceeds 95%. Mineral separation and industrial-waste purification results are presented.

Jan 1, 2000