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By Robert J. Timko, Lincoln Derick

This work is a follow-up to previous research that attempted to predict the location of spontaneous heating episodes in underground coal mine pillars. The objective of the original work was to see if the data obtained by commonly used detection methods could accurately predict spontaneous combustion episodes in coal pillars. Data accumulation during the study was enhanced when a spontaneously generated fire occurred within one of the pillars being examined. The fire provided researchers with realistic data that could be used to determine if fire prediction was possible. Results from the initial study found that the atmospheric status equations that were used provided little advance notice that combustion would occur where it did. This study reevaluated the accumulated data by applying it to recently developed equations and compared these results with previously obtained information to determine if a combination of these techniques could more effectively predict impending combustion.

Jan 1, 1995

By K. N. Han

The dissolution kinetics of cobalt in iodine/ iodide solutions were investigated using a rotating-disc technique. Variables studied included temperature, rotating speed, concentration of lixiviants and the pH of the solution. The overall dissolution reaction appeared to be limited by the mass transfer of tri-iodide through the diffusion boundary layer with an Arrhenius activation energy of <16.2 kJ/mol (4 kcal/mol) over the temperature range of 2 to 42ºC. The pH of the solution had little effect, as long as the pH of the solution was <8. However, when the pH of the solution became >8, the dissolution rate decreased dramatically, due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1995

By Silvia H. M. Grimaldi, Afonso H. Martins

The scope of this experimental work was to study the yttrium extraction and stripping behaviour in a solvent extraction system with mono(2-ethylhexyl)2-ethylhexylphosphonic acid (IONQUEST 801) in a chloride system The study was performed for only one contact between organic and aqueous phases The experiments were carried out according to a factorial design. Due to the statistical analysis and its experimental proof, the optimum conditions for maximum yttrium loading into the organic phase of the extraction stage were 16 minutes for time of contact between phases, 980 rpm of stirring intensity and pH=2.3 for the aqueous phase of the sovent extraction system. The optimized experimental conditions by the statistical approach for the stripping stage were: time of contact between phases equal to 20 minutes, 1050 rpm of stirring intensity and 1.75 M HCI into the stripping aqueous solution.

Jan 1, 1995

By F. Gray

Diamond tool fabricators expect strong growth in most applications for 1995 and 1996. Overall growth projects range from 8% to 10%. Diamond grinding is forecast to grow between 5% and 8%, while cubic boron nitride grinding should grow between 10% and 12%. A strong automotive industry is a major factor in this projected growth, as is continuing demand for other durables

Jan 1, 1995

By Shelley M. Burg, Dennis K. Poulton, Robert B. Gordon

This project includes the excavation and concrete lining of approximately 18 900 m (62 000 ft) of 5.5 m (18 ft) finished diameter subway tunnel for the Los Angeles MTA. The project required that four soft ground headings be excavated from a single shaft located near the mid point of the tunnels. The tunnels were classified "gassy" during the excavation phase. Because of the contract schedule requirements and the limited urban work site available, many logistical problems had to be overcome during the project while excavation was accomplished at a record setting pace. Some unique project features include the muck handling system and an access shaft using a high strength tieback support system. In order to accomplish the work, an extensive effort to plan and construct the main work site was required.

Jan 1, 1995

By S. Kmet, A. Nguyen-Van, H. J. Schulze

The P/B collision and attachment interactions in fine particle flotation have been quantitatively analyzed. New models for attachment probability and kinetics of ‘true flotation’ have been developed. The results are given for both a single bubble and a bubble swarm. The mechanism of the attachment event is also examined. It is shown that (i) impact collision mechanism and rolling mechanism can be ignored in actual fine particle flotation and sliding mechanism is of importance for attachment of particle onto the bubble surface (ii) the attachment probability of fine particles is independent of bubble size and determined by the kinetic measure induction time of hydrophobicity. The theoretical predictions are also compared with the experimental data.

Jan 1, 1995

By Ching Wu, David A. Sutter, Peter Frobenius

The MUNI Metro Turnback (MMT) Project includes a 256 m (840 ft) twin tunnel section, which connects to the Embarcadero Station, and runs under Market Street in San Francisco. The tunnels go through a mixed face condition of fill at top and Bay Mud at bottom, and a significant number of buried timber piles. This paper presents the selection of tunneling equipment, excavation methods, excavation support and chemical grouting; specification of timber pile cutting methods; and steel lining analysis and design. This paper also reports on the initial phase of the tunnel construction.

Jan 1, 1995

By G. D. Hood, B. E. Davis

A fundamental study of the mechanisms involved in the conditioning of coarse Florida phosphate has led to some interesting discoveries. Studies by the US Bureau of Mines have shown that conditioning time and mixing intensity greatly affect the grades and recoveries of the phosphate minerals and quartz in the rougher concentrate. In particular, as the conditioning time or mixing intensity increased, the phosphate recovery remained constant while the amount of quartz floated decreased. This phenomenon is contrary to conventional wisdom and could lead to a more efficient coarse flotation circuit.

Jan 1, 1995

By N. Piret, B. Shoukry, S. Buntenbach

Traditional or artisanal goldmining, also known as small scale goldmining, has a strong and probably a negative environmental impact. The processing methods applied are very frequently a source of severe pollution due to the emissions of mercury by the extraction of gold by means of amalgamation as well as the emissions of cyanide through cyanide leaching of gold bearing ores. The emissions find their way into the environment and contaminate soils, sediments, water and atmosphere. Abnormal concentrations of mercury and cyanides in waterways are known to occur year after year destroying irreplaceable regions of the world. Mercury and cyanide compounds are highly toxic and may directly create permanent damage to the whole ecosystem. Existing methods for recycling of mercury and for decontamination of mercury and cyanide contaminated tailings are not customary applied in small scale mining and are ineffective as well. Based on investigations of traditional and small size goldmining, this paper presents: -processing methods of gold and discarded tailings under consideration of environmental protection; -figures on actual situation; -recommendations for equipment; -some decontamination methods for mercury and residual cyanide. Mineral Processing methods in traditional gold mining Gold is usually existing in its ores as the metal alloyed with metallic silver and perhaps copper. The element may occur in the form of: -native gold -inclusions also of microns or submicroscopic size metal sulfides (auriferous) such as pyrite, pyrrhotite, stibnite, arsenopyrite and galena -combined as telluride or sulphotelluride. The separation process selected depends on whether the gold can be freed from its unfavorable associations (e.g. gangue) at a sufficiently coarse grain-size, or whether it is carried in a heavy sulfide which can be freed similarly. The usual practice is to concentrate the goldbearing mineral at a relatively coarse grain-size and to regrind the ore if necessary. The gold content is concentrated by secondary or tertiary gravital methods or is extracted by chemical methods (amalgamation, cyanidation etc.) Gold, even when of fine grain-size, settle readily due to its high specific gravity from pulps in which the main gangue mineral is quartz or silicates. Amalgamation is the process of separating gold and silver from their associated minerals by binding (entrapping) them into a mixture with mercury. The cyanide process is applied to separate gold or gold-bearing compounds by dissolution from the finely ground ore (CIP, CIL, RIP), or as heap leaching. The dissolved gold is separated from the solids and the metal-rich or pregnant solution is then treated to recover its gold. Gold is also recovered by flotation methods. This process is widely used in treating base metal ores and in separating various sulfide components of ores, as well as in removing the barren gangue. The gold usually associates with a specific product in a sequence of flotation operations and is recovered subsequently in the smelting of the sulfide concentrates and refining of the metallic products, or by cyanidation of the roasted concentrates. Froth-flotation can be applied to separate gold and sulfide minerals from a finely ground pulp. The Amalgamation Process Amalgamation is the main method for the recovery of gold in traditional mining and is applied for the extraction of gold from placers as well as primary ores. The mineral technology used depends on the nature of ore deposits. In winning gold from solid ore, the matrix of minerals and rocks must be crushed and ground to sufficient fineness to liberate the gold. The liberated gold could be treated similar as free gold from placers. Gold is mainly separated from the valueless gangue (barren rock) by utilizing the difference between the density of the impure native metal (density about 16-19) and the gangue (density about 2.5). In simple operations the material is carried by a stream of water down a sluice generally equipped with small transverse barriers (riffles) against which the gold collects. The riffled sluice is the principal device used by artisanal gold miners. Nowadays, spirals as well as centrifuges, such as Knelson separator or Falcon separator, are occasionally applied for gold recovery. Gold may also be recovered from the pulp, by passing it over corduroycovered tables that catch the heavier particles - a method maybe as ancient as gold mining itself. In history, sheep skins were used to catch gold particles in this manner. Furtheron, gravity separation of gold is practiced on jigs, hydraulic traps, shaking tables and

Jan 1, 1995

By Daniel Hodouin, Claude Bazin, Sami Makni

A method is proposed to perform on-line data adjustment and inference of unmeasured variables, using measured flowrates and on-stream assays in mineral processing plants. The algorithm minimizes a weighted sum of squared residuals of the measured variables and squared species imbalances around the flowsheet nodes. The method is based on a trade-off between the material transient accumulation, evaluated by the imbalances, and the data inaccuracies, evaluated by the residuals (i.e. the adjustments brought to the measured values). A recursive algorithm is developed for on-line implementation of the method. It is a real-time extension of the hierarchical method for balancing steady-state data for bilinear mass conservation constraints. An illustration for a simulated flotation circuit is provided.

Jan 1, 1995

By K. N. Han

The adsorption of gold onto activated carbon in iodide solutions was studied. The adsorption rates were determined as a function of temperature, salt concentration and pH, as well as activated carbon concentration. A kinetic model was developed for the adsorption. The adsorption rate was believed to be controlled by a combined mechanism of film diffusion and pore diffusion with the film diffusion having the most significant effect. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1995

By R. L. Andrew

The southwest Pacific has produced at least four of the world’s premier porphyry copper-gold deposits, and the current level of exploration is likely to produce even more. An appreciable amount of gold is being produced with this copper, with obvious economic advantages. Gold content, in addition to their large size, makes the southwest Pacific’s porphyrycopper-gold deposits very attractive exploration targets. The recognition of telescoping and overprinting of porphyry systems has produced a greater awareness of the likely surface expressions, in particular the significance of advanced argillic lithocaps in porphyry exploration. The recognition of the spatial and genetic association of porphyry copper and epithermal gold systems (Sillitoe, 1972), as in other parts of the world, has had important implications for exploration in the Asia Pacific region.

Jan 1, 1995

By F. M. Doyle, S. Duyvesteyn, K. Sreenivasarao

Toxic metals entering surface or ground water from sources such as metal finishing shop spills and abandoned mines can pose a significant threat to public health and the environment. Ion flotation and similar foam separation techniques show great promise for treating dilute, metal-contaminated solutions, and could also be used to treat effluents from many minerals and metallurgical processing operations prior to discharge. In ion flotation, an appropriate collector is added to the solution to form hydrophobic complexes with the metal ions. These metal-bearing species are then removed by flotation, usually with trace addition of a frother to stabilize the foam. In an effort to better understand the underlying scientific and engineering principles that determine the performance of ion flotation, the removal of Cu(II), Pb(II), Cd(II), Cr(II) and Cr(VI) has been studied using laboratory scale flotation columns in batch mode. The effects of the superficial air velocity, solution and froth height, nature of the collector, collector: metal-ion ratio, ionic strength and several frothers at low concentrations on the flotation kinetics are reported. Finally, results are presented on methods that might allow regeneration of collector and recovery of by-product metal from the foam product.

Jan 1, 1995

By Viacheslav Lyakhov, Cornelis H. Iestra, Victor I. Beloborodov, Vitaliy Bogdanovich

The results of a study and effective use of flotation for processing of ores with complex mineral composition containing fine-disseminated minerals with high specific density are presented in the paper. The object of research was complex baddeleyite-containing ore from Kovdor deposit (The Kola peninsula, Russia). Baddeleyite is a valuable, rare mineral, natural Zirconium dioxide with 5.8 - 6.0g / cm density, grade content 0.15 - 0.17 and dissemination less than 0.2 mm. The authors carried out a thorough investigation of baddeleyite- containing products selected in different sites of gravity flowsheet. It was determined that due to similar specific weight some sulphide minerals (pyrite, pyrrhotite) come into concentrate together with baddeleyite and, also, minerals of pyrochlores group (hatchettolite). The results obtained revealed the possibility of use the flotation for retreating rough baddeleyite concentrate. he given gravity concentrate has a number of specific features, e. g. high density of its minerals which, in its turn, provides for high speed of sedimentation of solid phase in pulp, and for the presence of large amount of sulphide minerals (up to 10%) having good flotability. With these features being taken into account a technology for flotation of baddeleyite-containing products after their preliminary gravity concentration has been developed (up to 5 - 10% Zirconium dioxide). The technology has three flotation stages. At the first one the reverse flotation of baddeleyite is carried out during which "light" minerals (forsterite. apatite and carbonites) come into froth product and at the second one flotation of sulphide minerals and at the third one direct flotation of baddeleyite is performed from the underflow product. The following reagents were used for flotation: of phosphate type (sodium tripolyphosphate, mono and diethers of alkylphosphpric acid) and sodium xanthate as collector for sulphides. The given set reagents provides for high effectiveness of flotation due to selective of collectors and presence of froth layer with high carrying ability. New flotation technology of recovering of baddeleyite from complex ore was developed and applied at the Kovdor Mining Plant, using AKER flotation machines.

Jan 1, 1995

By F. Vincent, A. Boulet, M. Noaparast, F. Woodcock, A. R. Laplante

A novel methodology to estimate gold recovery by gravity is presented. It makes use of a population balance model which represents gold liberation, breakage and classification behaviour and applies pre-concentration and recovery data to gravity recoverable gold (GRG) to predict overall recovery. The methodology is designed for gravity circuits located in the circulating load of secondary grinding mills. Gold liberation is estimated by processing a sample of representative ore with a laboratory Knelson Concentrator (LKC) in three successive steps, each at a finer grind than the previous one. Breakage behaviour is represented by a matrix H, which redistributes GRG in the feed of the secondary mill in the various size classes of its discharge. Provision is also made to account for gold overgrinding, which decreases the overall amount of GRG. Classification, pre-concentration and recovery data are estimated from plant performance, and are represented by the diagonal matrices C, P and R. The methodology is demonstrated with case studies of greenfield, retrofit and optimization applications.

Jan 1, 1995

By W. G. Pariseau

Recent advances in rock mass mechanics and computational technology now allow for stability analysis of excavations in "wet" mines where mining-induced changes in rock mass deformation and fluid flow are coupled and time-dependent. All the usual dry mine parameters including the premining stress state and rock mass properties are taken into account, in addition to water pressure and flow in jointed, possibly porous, rock masses. Finite element analyses of shafts and tunnels as circular, elliptical, rectangular and arched-rectangular hole shapes excavated in an initially stressed and pressurized rock mass indicate that the usual guidelines for optimum shape and orientation of single openings apply. Here, optimum means maximizing the minimum wall safety factor, or equivalently, minimizing the peak stress concentration. The results also show that failure originates in elements at the wall and that the minimum safety factor at the wall in the wet case is always less than the dry case regardless of drainage time allowed.

Jan 1, 1995

By S. K. Kawatra, T. C. Eisele

A horizontal-baffle arrangement has been developed to prevent excessive axial mixing in flotation columns. These baffles have been shown in previous work to improve the grade/recovery performance of both a laboratory-scale column and a pilot-scale column (Kawatra and Eisele. 1993). In this paper, results are given for continuous on-line operation of the pilot-scale baffled column in a commercial coal- cleaning plant. These results show its ability to operate for extended periods without plugging, to produce a consistent-quality product even while the feed quality was fluctuating, and to remove much of the pyritic sulfur from the coal.

Jan 1, 1995

By Owen Kreilis

By the time coal was discovered in Newcastle, Australia in 1791, it was already a most important industrial commodity in European countries. Coal was the first mineral to be discovered in Australia and the first to be mined. Today, coal remains Australia&apos;s most important mineral in terms of local use and international trade. The first mechanized longwall in Australia began operation in 1963. It contained self-advancing hydraulic supports and was installed at Coalcliff Colliery, located in the Southern Coalfields of New South Wales. After nine months and production of 53 kt (58,000 st), the unit was withdrawn, largely because of uncontrollable roof weight and with the problems of airborne dust and large coal still unsolved. Basically, roof support was insufficient. The European design of the Coalcliff longwall was inadequate for Australian conditions. Another type of support with modifications was installed and began operation at Kemira Colliery at Wollongong, New South Wales, in 1964.

Jan 1, 1995

By L. S. Gourevitch, E. B. Kremer, A. Y. Fidlin, Y. M. Katsman, I. I. Blekhman

A new kinetic approach to simulation of fracture is given. The main object of the simulation is forecasting transformation of ore lumps size distribution in squeezing of ore layer between two planes. The approach rests on fundamental principles of energy and mass conservation and on new ideas about fracture physics connected with fractal geometry. On this base an integro-differen tial equation of layer crushing kinetics is formulated. This equation is similar to well-known kinetic equation of grinding, but here we use elastic energy density in place of time as an independent variable while selection function is considered by us to be dependent on this variable. Properties of the equation have been investigated by us and its analytical solution has been found. It allows to compute simultaneously both the evolution of the size distribution process of squeezing and force-displacement diagram. Results of theoretical calculations provide a good fit with experimental data.

Jan 1, 1995

By Thomas W. Camm

The U.S. Bureau of Mines has extensive experience estimating the cost of mining and mineral processing operations as an ongoing part of its information and analysis studies. With the increased interest in remediation of mine wastes, the USBM is developing a methodology to expand its cost estimating expertise to include costs of various remediation techniques applicable to mineral processing and mining wastes. By integrating waste remediation costs with existing USBM cost estimating systems for mine and mill operations, a comprehensive system for cost engineering studies will be developed.

Jan 1, 1995