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By R. L. Bruening, L. Navarro, R. M. Izatt, N. E. Izatt, S. R. Izatt

Green chemistry principles will be discussed, and examples will be given of the use of Molecular Recognition Technology (MRT) to selectively separate valuable metals such as rhenium and palladium from various copper refinery feed streams. Recovery of these metals has numerous advantages including (i) conservation of valuable resources, (ii) prevention of environmental damage, and (iii) elimination of capital and operating expenses due to re-processing or disposal of metal-bearing streams. INTRODUCTION Refining of copper ores has a long and successful story. The history of copper, one of the first metals mined in human history, illustrates the global challenges faced as a result of increased demand for major metals and for by-product specialty metals found with them in trace amounts (Izatt et al., 2014). Copper has valuable properties, which have sustained its use over the centuries. It is an ideal material for creation of novel materials. Some desirable properties of copper that have proved valuable in our high-technology society include suitability for alloying with many other metals; ease of joining by soldering and brazing; good combination of mechanical qualities; high resistance to corrosion; suitability for many artistic purposes; and, of great importance in the modern era, efficient and economic use as a conductor of electricity. Copper mining in the U.S.A. began in the late nineteenth century in Montana (Izatt et al., 2014). The estimated total amount of copper mined globally before 1800 is about 5 million tons, four times less than is mined in a single year today (Flanagan, 2018). Production of copper in the U.S.A. has remained fairly constant at about 1,300,000 to 1,400,000 metric tons per annum from 2013 to 2017. Specialty metals such as bismuth, rhenium, molybdenum, and others that have become essential in our 21st century technology, and precious metals such as silver, gold, and the platinum group metals (PGMs) are concentrated by geochemical processes in trace amounts in copper ores. These specialty and precious metals were discarded into tailings in early mining operations, since limited extractive technologies existed and uses for most of them were limited. Thus, economic benefits for recovering them were limited, primarily, to silver and gold. Today, copper processing is the main, and often the only, commercial source for certain of these elements (Izatt et al., 2014). For example, molybdenite (MoS2) is the predominant ore mineral of molybdenum mining (Pohl, 2011). Cu-Mo-Au porphyry ore deposits supply ~75% of the world’s copper, 50% of the molybdenum, nearly all of the rhenium, and 20% of the gold. Typical ore grades are 0.5–1.5% copper, 0.01–0.04% molybdenum, and <1.5 g/ton gold. Molybdenite is the primary source for rhenium, among the rarest of metals, which is an essential component of super alloys, such as turbine blades in the aerospace industry (Pohl, 2011). Most rhenium is obtained as a by-product of molybdenite from copper mines in Chile. The case of rhenium raises an important issue. Continued availability of rhenium, selectively concentrated in copper ores, depends on continued mining and processing of copper. Since the mining company’s main interest is typically in copper production, continued recovery of rhenium and other specialty elements present in the ore body is at risk. Dependence of specialty metal supply on continued mining of major metals exists in several additional cases including indium, gallium, selenium, tellurium, germanium and bismuth (Pohl, 2011). PGMs, on the other hand, are typically mined for their own value, which far exceeds that of associated base metals. However, copper ores often contain marketable amounts of platinum and palladium, making their separation of interest, if this can be done economically.

Jan 1, 2019

By G. W. Brooks

This short article is quite different to the general run of papers that are presented to the Institute, but no apology is offered because I consider that first-aid and mine-rescue work are of equal importance to many other subjects that are dealt with in our Transactions. Members of the Institute should be as much interested in the safety of persons engaged in the mining industry as they are in the practical methods of modern mining. We must not only do our best to conserve life and property by adopting every known device to that end, but we must also prepare ourselves so that we may take prompt and effective action when life is in danger, or when property is subject to loss. The need for such preparation in Alberta is perhaps greater than in most places where mining is carried on, and we must spare no effort to assemble at every mine men who are well trained in first-aid and mine-rescue work. The large area over which the mines are distributed renders central training stations out of the question, hence the need for local rescue-teams. Hospitals with skilled staffs, close enough to the mines to be convenient, also seem to be out of the question; therefore the greater need of a high standard of first-aid training for the people in our mining camps. The Government mine-rescue cars are supplied with the equipment necessary for training persons in this essential work and also for dealing with disasters should they occur. The question then arises: are there a sufficient number of men who are trained ? If so we can rest assured that what is possible to be done will be done. But if a sufficient number of trained men are not available much loss of life and damage to property is likely to result.

Jan 1, 1925

By G. Stokreef, B. R. Davis, M. Kadiyski, T. LeBel, Alvear Montenegro, R. Parra, V. Montenegro

A drop tower and methodology were developed to study the impact of mineralogy on the flash combustion behaviour of copper concentrates. Reaction shaft conditions of a flash furnace were simulated using a drop tower reactor and different molar ratios of oxygen gas to sulphur in the feed. Five feeds were tested in the drop tower including pure minerals chalcopyrite and pyrite as well as two mineralogically distinct copper concentrates and a blend of the two. The behaviour of each of these five feeds were evaluated through analysis of the solid combustion products for elemental sulphur, mineralogy and particle size. Desulphurization curves for each of the feeds were produced. It is thought that the desulphurization behaviour of pure minerals can be used to estimate the behaviour of a concentrate and that a blending recipe could be developed, which can optimize the chemical and mineralogical inputs to the flash furnace and guide operations on the optimum furnace conditions. Overall, the drop tower has proven to be a useful tool for studying flash combustion processes. Experimental results suggest that mineralogy has a significant impact on the conditions required for the production of matte with consistent grade. This finding is especially significant for custom smelters, which may see several different blends in a day. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process that is used to produce copper matte from copper sulphide concentrates. Dried concentrate(s), silica flux, and secondary materials are blended to a target chemical composition, typically given by the Cu/S ratio, before processing. This fine, dried feed is dispersed throughout the heated furnace reaction shaft with an O2-enriched reaction gas. The particles heat up in the shaft of the furnace, ignite and undergo reactions that pre-oxidize the iron sulphide and some of the impurities in the feed. Oxidation reactions in the shaft of the furnace desulphurize the feed and produce an SO2-containing off gas. The reacted particles fall into the furnace settler and separate into a Cu-rich matte and an iron-silicate slag, while the SO2-containing off gas is carried out of the furnace for heat and dust recovery, as well as H2SO4 production. Some concerns during operation of the furnace are dusting, over or under oxidation of the feed, and a stable flame.

Jan 1, 2019

By Xiao Huang, Jean-Francois Thibault, Ali Merati, Prakash C. Patnaik

Single-crystal nickel-based superalloys are the current state-of-the-art technology for the manufacture of turbine blades. This technological improvement of the turbine blade has brought a considerable increase in its cost. Repair and overhaul of service stressed single crystal turbine components is an economic necessity for life cycle cost reduction of engines since the cost associated with replacement is significantly higher than its counterpart polycrystalline component. This paper will first review the recently reported research in developing repair technologies used for DS and SX components. These techniques repair the crack or defect while at the same time ensuring that the mechanical properties do not deteriorate and, more importantly, that the single-crystal microstructure is not jeopardized. It will then be followed by a brief overview of the research conducted and initiated by the authors with regards to the repair of single crystal alloys.

Jan 1, 2004

By P. W. A. Mayer

"As the push toward the northern regions of Canada steadily increases to exploit the rich mineral reserves, interest is steadily rising in respect to accessibility and climatic conditions and the problems posed thereby. In twelve years of operation, the Iron Ore Company of Canada, and associated companies, have found, through advanced technology, ingenuity and, most of all. need, some of the answers to the running of a profitable year-round open-pit mining operation."

Jan 1, 1966

By A. R. Kinkel JR.

"The Buffalo Ankerite mine is in the southern part of the Porcupine gold district of northern Ontario. The mine has a history of exploration and development reaching back to 1911, and has been operated continuously since 1932. From 1932 to 1942 a total of 510,874 oz. gold was produced from the mine. In 1941 the production was 71,654 oz. from 448,621 tons of ore.With few exceptions, the ore-bearing veins did not crop out. They were discovered during the prospecting of the prominent outcrops of barren or low-grade quartz-carbonate breccia near the veins.GEOLOGICAL SETTINGThe Porcupine gold district lies in an area of folded and sheared Precambrian lavas, sediments, and intrusives. The Buffalo Ankerite mine is in the southern part of a large fold. The structure appears to be a continuation of the Vipond cross anticline and accompanying syncline described in earlier papers (1, 2). The orebodies lie along both flanks of the synclinal part of the fold, and are known as the north and south vein systems, respectively. No mineable veins have been found on the axis of the syncline (Fig. 1).The rocks found in the mine area are pillow lava, dacite, conglomerate, quartz porphyry, tuff, and fragmental lava. The tuff and fragmental lava are now largely altered to chlorite schist. Productive veins have been found only in pillow lava, dacite, and conglomerate, but a minor amount of gold occurs in some of the quartz porphyry. The Porcupine Creek fault, a zone of intense shearing over 1,000 feet in width, lies immediately south of the mine. A spur fault branches to the northwest from the Porcupine Creek fault, separating the north from the south vein systems ( Fig. 1) ."

Jan 1, 1954

By Nordau R. Goodman

T-he Ojibway Salt Mine near Windsor, Ontario, produces almost two million tonnes of97% pure rock salt annually. The salt is mined from the middle F horizon of the Silurian Salina Formation. The salt beds have a gentle dip into the Michigan depositional basin. There is no evidence of deformation. The rock salt is buff coloured and has a number of thin carbonateanhydrire bands. Secondary salt crysrallization occurs throughout the mine.

Jan 1, 1984

By Louise Laverdure

The Canadian mining sector has to be innovative and invest in the development of sustainable mining technologies to maintain its international leadership. Natural Resources Canada (NRCan) collaborated with the Canada Mining Innovation Council (CMIC) to define the Green Mining Initiative (GMI) and in order to focus its R&D activities on industry and other stakeholders? needs. The GMI was launched in 2009 to spur innovation in the mining sector and further enhance its environmental performance. The initiative, led by CANMET- Mining and Mineral Sciences Laboratories (MMSL), takes a holistic approach looking at the entire mining life cycle, from design to closure and beyond, through four innovation and research pillars: ? Footprint Reduction, ? Innovation in Waste Management, ? Mine Closure and Rehabilitation, and ? Ecosystem Risk Management. The Canada Mining Innovation Council has also been creating a new initiative on Sustainable Mining, which will bring further focus to environmental aspects of mining, and engaging wide range of research providers to develop research programs complementary to GMI goals.

May 1, 2011

The paper will cover the basic reasons for alkaline leaching, a brief description of the circuit and the reasons for the flowsheet used. Changes made to the flowsheet, including the use of mechanical agitation of pachuca slurry, the use of oxygen and its effect on extraction, the use of lime and its effect on process economy, and the environment, will be described. A brief description of a unique semi-autogenous mill and future circuit changes will be included.

Jan 1, 1979

By G. S. Hume

Dr. K. A. Clark: No one will doubt the statement of fact that, during drilling operations through the bituminous sand beds in the Mildred-Ruth Lakes area, the core-barrel was found to contain bitumen with minor amounts of sand instead of bituminous sand. But many will doubt the interpretation of this fact as meaning that beds of bitumen occur interstratified with the bituminous sand beds. They will prefer to hold faith in the laws of physics, which deny that sand will float on oil or that fluid under pressure will not flow away through a permeable medium, until it is proved that the appearance of the oil in the core-barrel was not due to circumstances surrounding the drilling of the bituminous sand beds. The implication of the interpretation that sand is floating on oil is clear and it is unacceptable. Bituminous sand is unconsolidated sand more&apos; or less saturated with a viscous oil. It is as difficult to conceive of bituminous sand lying on top of a body of the viscous oil as it is to conceive of unconsolidated sand more or less saturated with water lying on top of a body of water. The only difference between the two concepts is that the oil is viscous whereas the water is fluid. Oil-soaked sand placed on viscous oil would, when released, sink through the oil slowly, whereas water-soaked sand would sink through the water quickly.

Jan 1, 1947

By Brian Putland, Fred Kock, Leigh Siddall

Single stage semi-autogenous / autogenous (S/AG) milling has become a common design for a variety of ore types with the advantages of being comparatively low capital cost and flexible for future expansion. The single stage SAG/AG milling option is ideal for starter projects with significant exploration and expansion potential. Currently a number of the largest SAG mills designed are installed in single stage configuration. This paper discusses the challenges associated with the process design of single stage SAG/AG milling circuits, the design flexibility required to ensure a robust circuit and the operating techniques adopted at successful installations.

Jan 1, 2012

By Brett Triffett, Mark Weidenbach, Christopher Treloar

OZ Minerals owns and operates the Prominent Hill copper-gold concentrator in South Australia, built in 2008 and commissioned in early 2009. The concentrator operates via semi autogenous grinding in a thirty four foot ThyssenKrupp Polysius mill followed by a twenty four foot Polysius ball mill in closed circuit with hydro cyclones, designed for an ore throughput of eight million tonnes per annum. The main aspects of designing the circuit are discussed along with the issues faced in the early stages of operation. A review of the optimization strategy applied to the milling circuit such as cyclone optimization, advanced process control strategy implementation and reline management to improve availability is then discussed highlighting areas of significant process improvement that have seen the plant exceed nameplate throughputs above nine million tonnes per annum.

Jan 1, 2012

By J. G. MacGregor

At this, the opening meeting of the Western Quebec Branch of the Institute, it seems fitting that the first paper presented should embrace a survey of the known mineral deposits occurring in the area, and also a review of ?the exploration methods that have brought about their discovery. And since the study of geological structures must always be the guiding principle of an intelligent exploration campaign, it also seems to be the appropriate occasion to review the geological situation from the economic angle, in an attempt to arrive at a re-statement of the known facts governing the deposition of the mineral bodies . . It is not my intention to confine my remarks entirely to the geological problems involved, but rather to pass under review the exploratory methods that have been employed in the past and that are presently being used, and to offer a forecast of the type of exploration campaign that will be largely adopted in the future search for ore.

Jan 1, 1929

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By Roger Reed

It is well known that the performance and carbon emissions associated with the modern gas turbine engine depend critically upon the properties of the nickel-based superalloys, particularly those used in single crystal form. However, the design of all alloys in current use has been essentially empirical, or at best heavily reliant upon regression/neural network analysis of experimental datasets. In this paper, alloy design approaches [1] are described which are able to identify new alloy composition spaces which are worthy of experimental study. It is shown that a large amount of design data can be generated, which can be interpreted in different ways. Of course, the success of the approach depends heavily upon the accuracy of the underlying sub-models. Estimates of the creep resistance, cost, castability, density and oxidation resistance are made. It is demonstrated that these methods allow quantitative trade-offs to be made between the properties of interest.

Jan 1, 2010

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations addressing hoist safety, automatic hoisting, and shaft obstruction. The regulations are quite similar among provinces, with only slight differences. Risk-mitigation strategies used in other industries are discussed, including their applicability to mine hoists. The specific case of software safety is introduced through examples. The mitigation of software failure is based on the use of the software lifecycle as recommended by the International Electrotechnical Commission (IEC) 61508 standard. Finally, ways to improve hoist safety are proposed.RÉSUMÉ Le présent article compare entre elles les diverses réglementations provinciales canadiennes concernant la sécurité des machines d'extraction, le levage automatisé et les obstructions dans les puits. Les réglementations sont assez semblables entre les provinces, mais elles comportent de légères différences. Les stratégies d’atténuation des risques utilisées dans d’autres industries sont abordées, incluant la possibilité de les appliquer aux treuils de mines. Le cas spécifique de sûreté des logiciels est abordé par des exemples. L’atténuation de la défaillance des logiciels est basée sur l’utilisation du cycle de vie du logiciel, comme cela est recommandé par la norme 61508 de la Commission électrotechnique internationale (CEI). Des moyens d’améliorer la sécurité des treuils sont également proposés."

Jan 1, 2016

By Chan-ho Park

As the building has recently become bigger, higher, and freeform, a technology called BIM(Building Information Modeling), which is a key technology that integrates construction and IT(Information Technology), has been rapidly introduced and expanded. Because BIM technology offers various benefits, countries that introduced BIM early has been actively promoted. However, misperceptions of BIM are prevalent in countries such as South Korea that have adopted it relatively late, with lack of awareness of its fundamental purposes. Under these circumstances, transparent and quantitative performance assessment needs to be executed in order to eliminate the misperceptions, and to explain and revitalize the BIM introduction. These quantitative performance measure KPI (Key Performance Indicators) to be measured should be prioritized. As derive performance indicators in terms of the four types (financial, customer, internal processes, learning and growth), and performance management systems, Uses the BSC to seek a balance between short-term financial goals, values and the value of long-term goals. Uses the BSC(Balanced Scorecards) to derive performance indicators in terms of the four types (financial, customer, internal processes, learning and growth), and performance management systems, seeking a balance between the value of short-term financial objectives and the value of long-term objectives. Through this, the KPI (Key Performance Indicators) which is used for measuring the effect of the BIM will be generated and also the method that can determine whether the generated KPI figures are objectively inter-connected will be suggested as well.

Aug 1, 2013

By C. Graham

Mechanisation has been a predominant theme of the past 50 years in the mining industry, particularly underground mining. As the level of technology employed has increased, the anticipated productivity gains have not been realised and the differences are not explained by the demand for higher standards of safety and security. Now, mining costs are so high and productivity so low that the resultant return on investment for many Canadian operations has fallen to levels considered unacceptable in a competitive capital market. Simply continuing technological development cannot reverse this trend and its financial implications. The focus on technological development has distracted us from some basic truths. Systems that are more complex are more likely to fail and cost-effective processes depend on the continuity of productive activity and the flow of material. When putting these facts together, it becomes clear that in a system that has fixed external conditions, the single most crucial issue is the effective management of the operational cycle. By its nature, technology focuses our attention on what gets done and how it gets done, while the crucial issue is the increasingly longer periods in the operational cycle when nothing productive is being done. What is required is to match the level of technological complexity to the fixed system conditions, which are virtually unchangeable. This paper looks at the overall system and objectives and attempts to present an appropriate level of technology for the Canadian mining industry, now and in the foreseeable future.

May 1, 2004

It?s a pleasure to be with you in Vancouver today to reinforce the good work you and your companies do to develop and operationalize new technology as a lever to improve operational performance and reduce our impact on the environment in absolute terms. Although I will use the work we do at Shell to reinforce this perspective, the principles apply to all of us in this industry regardless of whether you are a producer or supplier. I?d like to help demystify the future of Canada?s oil sands based on Shell?s view of global energy developments, including forecasted demand. One of the incontrovertible truths of this era of global energy defines change as an unchangeable law of progress. Another tells us that the art of progress is to preserve order amid change and to preserve change amid order. These axioms help frame the increasingly public debate about the future of Canada?s oil sands. I hope to illustrate how Shell?s commitment and investments create positive progress that embraces change amid order in the oil sands. I?m going to spend a little time today to focus the spotlight on the future of the oil sands to help demystify Canada?s hydrocarbon energy future. To do that, I?ll identify the features of our future energy security, including three hard truths about global energy that drive Shell?s business imperatives. Then, it?s instructive to examine Canadians? current consciousness about oil sands sustainability.

Oct 1, 2009

By W. Holyk

"Although lead, zinc, copper, and iron sulphides have been known for many years in the Bathurst region, the existence of large massive deposits was not known until the discovery of the Brunswick orebody in 1952. This was followed by the discoveries of the Anacon orebody in 1953 and the American Metals orebodies in 1954. There is no question as to the great importance of these large massive sulphide deposits, and no doubt that other sulphide deposits are to be found. The problem, of course, is where and how to find them.The discovery of the Brunswick and Anacon orebodies is attributed to geophysical work. The original discovery of the American Metals deposit is generally attributed to a regional airborne electromagnetic survey.It is generally stated that the Bathurst area is a geophysical camp, and this is essentially true, but in this highly competitive search for orebodies it is obviously impossible for an individual company to cover the entire area by a comprehensive geophysical survey. Some means other than geophysics must be used to narrow the target. The quickest, cheapest, and simplest method is geological investigations.It has been stated that nothing can be accomplished by geology in the Bathurst region, since the camp is largely covered with overburden. This is true only insofar as detailed work on certain properties is concerned. It is not true of the larger regional picture. Outcrops are scarce, but angular float is abundant, and precedent shows that angular float has moved but a short distance from its source.GeologyAeromagnetic maps published by the Department of Mines and Technical Surveys are the best guides to the geology and structure of the area. These maps supply factual information concerning the underlying rocks. When coupled with field investigations, they are very useful in the interpretation of regional geology and the selection of favourable areas. The discussion of the geology is accordingly centred upon the aeromagnetic maps. The following is essentially a working theory, based on geological facts as best reconciled with all other available information,"

Jan 1, 1949