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By H. Yen, D. E. Walsh, H. K. Lin

"Comminution circuits are widely used in nonferrous and precious metals milling. Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) fines, are unavoidably produced and report to undersize products in the classification circuit, i.e., flotation or leach feed, while tramp grinding steel (TGS) reports to classification oversize products and returns to the grinding mill, building up in the circulating load. In laboratory studies, TGS reduced grinding efficiency significantly, the impact being dependent upon the size of the TGS present in the mill. Because iron fines adsorb flotation reagents effectively, iron fines increase reagent consumption and reduce flotation recovery. Iron fines are also capable of reducing gold recovery in cyanidation circuits via a cementation reaction. When using filtered gold solution from the cyanidation circuit of an Alaskan gold mine, the gold concentration in solution was reduced by 0.2 to 2.6% over various reaction periods when iron fines were present in the solution.IntroductionComminution circuits are widely used in copper, lead, zinc, nickel, cobalt, molybdenum and precious metal mills. Flotation and leaching processes are usually preceded by comminution (crushing and grinding) circuits in order to liberate valuable minerals for effective separation, concentration or dissolution by the subsequent flotation or leaching processes.Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) powder, are unavoidably produced and report to undersize products in the classification circuit (flotation or leach feed), while tramp grinding steel (TGS) reports to oversize productions during classification and returns to the grinding mill, building up in the circulating load. Variables affecting the amount of metallic iron powder and TGS produced in a comminution circuit include ore hardness, grinding mill operating conditions, comminution circuit design and the metallurgy of the steel used for manufacturing crusher liners, mill liners and grinding media. As one example, a comminution circuit product of 80% passing 200 mesh at the Pogo Mine, AK is estimated to contain approximately 2 kg/t of metallic iron. A finer grind will generally produce a comminution circuit product with higher metallic iron fines content."

Jan 1, 2015

By J. M. Ekenes, C. A. Caro

"New approaches that increase hydrometallurgical recovery from refractory minerals in below mill cutoff -grade sulfide copper ore can add significant value, improve profitability and increase ore reserves. This paper describes the development and implementation of an engineered heap (EH) approach to leaching low-grade, chalcopyritebearing ore at Freeport-McMoRan’s mine in Morenci, AZ. The technical evolution of the engineered heap concept is described together with the challenges and benefits following implementation. Introduction The Morenci ore deposit, located in eastern Arizona, has been mined for copper for 140 years. Mineralization in the Morenci district consists of sulfides and oxides. To process these ores, Morenci operates concentrator and leaching circuits. Leaching accounts for two-thirds of the copper produced in Morenci. More than one-half of this leaching-derived copper production comes from run-of-mine (ROM) stockpiles. The largest category of material moved in Morenci is destined for ROM stockpiles and waste dumps. Materials that are not economic to mill or leach are designated “waste.” However, this designation can change based on improvements in extraction technology and commodity prices. Chalcopyrite does not leach well due to its refractory nature. For predominant chalcopyrite mineralized ore, copper recovery during a typical leaching cycle may be as low as 5%. For this reason, chalcopyritedominant ores below mill cutoff grade have historically been classified as waste. By incorporating advanced leaching technology to improve metal recovery from previously leach-resistant ore types such as chalcopyrite, the Morenci Mine has been able to reclassify substantial amounts of this “waste” to “ore.” Process chemistry Chalcopyrite copper extraction is temperature, oxygen and ferric dependent. The temperature is achieved primarily by pyrite oxidation (Eq. (1)) and secondarily by oxidation of chalcopyrite itself (Eq. (2)). The regeneration of ferric in solution can be enhanced by providing the appropriate acid and oxygen levels according to Eq. (3). In the absence of microorganisms, this reaction is very slow."

Jan 1, 2015

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By Alan A. Campoli

"Pumpable crib support for longwall gates and ventilation bleeder entries is becoming more prevalent in United States coal mines (Figure 1). The pumpable crib selection and spacing design has been greatly refined by the full-scale testing conducted at the National Institute for Occupational Safety and Health (NIOSH) Mine Roof Simulator. The peak load on 24-, 27-, 30-, and 36- inch diameter J-Cribs is, on average, 300, 400, 450, and 650 kips, respectively. Standard J-Cribs have useful deformation of approximately 8 inches. The maximum useful deformation can be extended to 18–20 inches with an exterior reinforcement layer or an interior double wall, for all four J-Crib diameters. J-Crib diameter is primarily limited by a maximum 4.5:1 height-to-diameter aspect ratio. Spacing is controlled by immediate roof stability, anticipated pillar deformation, and roof bolting practice. Approximately 500,000 J-Cribs have been successfully placed in 18 different United States longwall coal mines. The selection and spacing of the J-Crib utilized to date is summarized for each mine.IntroductionLongwall productivity and safety depend on ground stability in gate and ventilation bleeder entries. Numerous support technologies have been developed and employed in United States longwall mines since the 1990s to replace traditional wooden cribbing. Many, if not all, of these technologies have been evaluated at the NIOSH Pittsburgh Research Laboratory since the mid-1990s (Mucho, et al., 1999). The NIOSH Mine Roof Simulator has a 3,000-kip vertical load and 24-inch displacement capacity, which has facilitated in-depth analysis of complex multimaterial support technologies like the pumpable crib. The extreme cost and human exposure risk associated with modern longwall mining prevent the trial and error development that would have been required absent the Mine Roof Simulator research. As a direct result of this research, pumpable cribs are becoming a major component of the standing support industry, providing the peak capacity and extended deformation characteristics necessary for successful gate and bleeder support. Recent research by Zhang, et al. (2012) and others have defined the required performance characteristics."

Jan 1, 2015

This paper will review some of the work conducted in the past at the Dynamic Effects Laboratory to examine the use of stress waves and fracture mechanics in understanding dynamic fracture and fragmentation in blasting applications. Along the way, we will use photoelasticity and high speed photography to better understand the mechanisms of fracture and fragmentation.

Jan 1, 2015

By Marco Quirion

The Daniel-Johnson dam, formerly named Manicouagan-5 (Manic-5), is located 800 km northeast of Montreal (Quebec) in Canada. This is the largest multiple-arch concrete dam in the world consisting in 13 arches and 14 buttresses. Since its construction in 1969, various type of cracks have appeared on both downstream and upstream faces of almost all the arches of this concrete dam. As a part of the Daniel- Johnson’s dam safety assessment program, Hydro-Québec is currently performing structural analysis of the dam with advanced numerical models to better understand and predict the dam behaviour. Because the buttresses transmit all the arch loads to the rock mass, determination of the properties of the dam foundation should not be neglected in dam global safety analysis and also to insure that reliable input parameters are used in the dam numerical simulations. This paper summarizes the past and the more recent investigations of this foundation used to assess its safety and stability. Moreover, the use of rock mass classification to estimate the deformation modulus, based on empirical equations, gives values in the range of 30 to 40 GPa that are higher than expected values. Using those values in the numerical simulations for dam structural analysis gives an excellent correlation with displacements monitoring of the buttresses.

Jan 1, 2015

By M. Santaluce

"The revamp of critical process assets that require a significant plant outage (shutdown) presents a unique and demanding set of challenges for plant operators. They are executed in a more complex Brownfield environment, typically with limited working space and often involve unknown conditions or scope. For plant operators, such a project is often a high cost event both in terms of opportunity cost of lost production and the resource cost of labor and materials. It can also be a high risk event in terms safety, environment, and future plant reliability/availability. This impacts current and future performance or Overall Equipment Effectiveness (OEE). In our experience, the sequential nature of the EPCM approach does not provide the proper framework to facilitate the level of coordination, stakeholder cooperation and detailed planning required to adequately address the construction and shutdown complexity of a critical asset revamp projects. This paper proposes a more integrated approach to handling shutdown revamps of critical assets. Its main thesis is to involve the key performing stakeholder groups early in the project lifecycle (engineering team, procurement team, construction team and plant operations) to form an integrated shutdown management team that is focused on ensuring delivered results are aligned with project objectives. In this model, the construction team executing the shutdown/construction is preparing the detailed shutdown/construction planning concurrently with detailed engineering and procurement planning. This allows construction/shutdown requirements to influence engineering and procurement, with the desire to optimize safety, speed, quality and cost. The paper also discusses how to overcome the procurement hurdle in applying such an approach. The outcome of this integrated approach is better planning, coordination, communication and alignment between the project stakeholders, a shutdown/construction driven planning approach that more fully addresses the challenges of these projects and delivered results that are aligned with project objectives."

Jan 1, 2015

By Zhiye Zhao, Jianping Sun, Zhipeng Xu

"The subsea rock cavern project is an underground storage facility. For cost-effective and safe excavation, the risk caused by the groundwater seepage into the rock cavern must be addressed. As one of the essential steps of the assessment work, the hydraulic conductivities of the fractured rock masses should be reliably determined based on the limited measured data and geological information from the few boreholes. On the basis of site investigation data and monitored water flow and water pressure data during excavation, this paper presents an estimation method for hydraulic conductivities of the rock masses containing water bearing zones.INTRODUCTIONIn the development of underground rock caverns/tunnels, the uncertainty of hydro-geological conditions plays a critical role in terms of construction cost and construction safety. Excessive groundwater seepage has been identified as one of the key safety factors which always lead to vast loss, such as the Seikan Tunnel in Japan which encountered sudden water inflow and then catastrophic face collapsing, tunnel flood during excavation (Xu et al., 2013). As a key factor in the risk management associated with the groundwater leakage into rock cavern, the hydraulic conductivity determination is very important for cost estimation, reliable water control and construction management.The case presented in this paper is an underground project consisted of a cluster of rock caverns/tunnels for storage of hydrocarbon products. These caverns are located in heterogeneous sedimentary bedrock, at a depth of 130 m beneath a basin, and the crowns of caverns are located at about 100 m below the sea bottom. The caverns/tunnels are designed at two levels, the water curtain tunnels are at the upper level, and oil storage caverns are at the lower level, as shown in Figure 1. A number of horizontal and vertical water injection holes drilled from the upper water curtain gallery tunnel will establish continuous horizontal and vertical water curtains for providing a stable pressure distribution around the caverns, to keep oil/gas inside the lower storage caverns. As the hydrostatic pressure of groundwater around the storage caverns is higher than the pressure of stored oil and gas, the stored oil and gas will not leak out of the cavern (Lu, 2010; Xu et al., 2015). Groundwater pressure gauges are installed in the water curtain gallery tunnels, and water from the operational and access tunnels is injected continuously into the curtains to maintain the pressure. Some monitoring data are recorded at different construction stages. This paper proposes suitable methods to predict the hydraulic conductivity in rock mass and to determine the hydraulic conductivity in the water bearing zones."

Jan 1, 2015

By Aidan Giblett

"It is important to make a clear distinction on the scope of work of the Global Mining Standards and Guidelines (GMSG) guideline for sampling grinding circuits. Many mineral processing practitioners are familiar with the sampling and surveying of comminution circuits, in particular grinding circuits, for performance diagnosis and the identification of optimization potential. These surveys often provide information for population balance modelling of individual comminution and classification unit processes, and consequently require a large amount of information to calibrate and validate the unit models. As a result, these surveys are labour intensive, somewhat expensive, depending on internal capabilities of the mine site or company and have a long time span from initial planning to final reporting. They also require a high level of expertise to process the survey data, simulate the circuit and make sensible recommendations on follow up actions.As a result of these factors, full grinding circuit surveys are not a common occurrence at a large number of processing facilities, and several years may pass before follow up surveys are conducted. In the ensuing gap between surveys, the efficiency of the grinding circuit must often be taken on faith, and this is considered an unacceptable lapse in an environment of strained natural resources and low commodity prices.To support the rapid and productive energy efficiency analysis being promoted by the ICE working group, a much simplified survey and analysis process is required. The process reflected in the GMSG guideline is indeed more conducive to frequent analysis, at a skill level that is well within the capabilities of the average plant metallurgist. As a result, it becomes feasible to conduct mini-surveys of plant performance, which can be used to quickly and precisely diagnose the high level impact of process changes. These methods can also be manipulated by an experienced practitioner to provide sufficient information for modelling of the circuit to estimate the impact of process changes, allowing an initial rate and rank exercise to focus plant optimization efforts."

Jan 1, 2015

By N. Andersen

During the preliminary design phases and feasibility study of a proposed vertical shaft, a vertical diamond drill-hole is normally drilled on the site. This paper outlines how rock mass characteristics, in-situ rock stress, rock strength, hydrological characteristics, and structural parameters can be determined using wireline logging of this borehole. In addition, a rock mass classification scheme is developed, based on published work, and in particular the Q-factor is adapted to assess the stability of raise-bored shafts. The ‘stick plot’ is introduced, which combines all geotechnical parameters applicable to the stability of a vertical shaft into a colourcoded format where cross-correlations can readily be made on a day-today basis during the shaft-sinking process.

Jan 1, 2015

By Erkan Bayrak, Serkan Erkara, Ozkan Duzgun, Ekin Gungor

This paper presents part of the outcomes of the drill and blast optimization project carried out at Kisladag Gold Mine in Turkey. Kisladag Gold Mine is the largest gold mine in Turkey with a low-grade, bulk-tonnage, open pit operation that uses heap leaching for gold recovery. After blasting, the ore is fed to a three-stage crushing circuit which prepares crushed ore approximately -10 mm (0.39 in) for heap leaching. Crusher downtime analysis showed that blocky material and insufficient feed are causing significant downtimes with the primary crusher. This was supported by the fragmentation data collected to date. It was decided to initiate a fragmentation project to understand the variation in the run-of-mine (ROM) size with a view to provide a consistent feed to the crushing circuit. The study includes the analyses of the ore strength and structure, image analysis of the fragmentation pictures acquired from blasts, blast auditing and quality assurance and quality control (QA/QC) analyses. During this project, over 200 fragmentation pictures were acquired from 47 blasts to optimize ore and waste blasts. Ore strength varies between 30 and 120 MPa and rock quality designation (RQD) ranges between 30 and 100. A site-specific fragmentation model was used to calibrate the fragmentation for blast domains formed. In addition, alternative cases were simulated to achieve blasts designs with consistent ROM fragmentation size distribution. Alternative blast designs that include stemming length and powder factor changes were suggested. Long stemming length, drill cuttings use, free faced blasts, small shot sizes and poor stemming length control were some of the key issues causing coarse fragmentation.

Jan 1, 2015

By Schmitz Stefan, Stephan Jee-Sun

"Due to the reunion of Western and Eastern Germany in the late 80’s, a multitude of infrastructure projects had to be executed. A good portion of these projects required improvement of the motorway system. In the southern region of Leipzig, in the eastern part of Germany, it was required to connect two existing motorways. Parts of the new motorway pass old strip mining areas. These strip mining areas consist of up to 70m thick backfill material. Especially the upper 20m are very inhomogeneous soil material with a very low bearing capacity. In order to increase the bearing capacity, to decrease the differential settlements and to homogenize the soil parameters, soil improvement using sand-gravel columns was required. Bauer Spezialtiefbau GmbH executed the installation of approx. 711,000 linear meters of columns with a length from 5 m to 25 m. For the project, 11 rigs with frame leads up to 40m were used to install the 43,000 columns with a diameter of 0.8m in 27 weeks.1. INTRODUCTION1.1 Site LocationThe construction site is located in the south-eastern part of Germany, in the south west of the city Leipzig.The area to be treated had a size of approx. 500,000 m² to allow the construction of dam/embankments and a highway bridge.1.2 Required WorkIn addition to the general earthworks and the installation of geogrids and fibre mats, a total amount of more than 710,000 linm of Gravel-Sand Columns with different lengths due to the given soil conditions had to be installed:•nos. 4,206 Columns length 5m ? 21,030 linm•nos. 4,581 Columns length 10m ? 45,810 linm•nos. 10,820 Columns length 15m ? 162,300 linm•nos. 19,634 Columns length 20m ? 392,680 linm•nos. 3,574 Columns length 25m ? 89,350 linmFor the installation of the columns Gravel-Sand with the grain size of 0/32mm was used. The total amount of Material was 580,000mt"

Jan 1, 2015

By J. Andres, M. Cross

"Freeport-McMoRan’s Sierrita operations has two natural gas-fired molybdenum roasters for converting molybdenum disulfide into molybdenum trioxide. When these roasters were compared to other similar units within the company during a benchmarking exercise, it showed that increased throughput from the roaster units at Sierrita was possible. A team of site metallurgists, technical experts from other sites, and engineers from the Climax Technology Center was formed to study the potential in more detail. The team investigated many parameters in the roaster, including temperature profiles, roaster chemistry profiles, rabble and drop hole patterns, and operational strategies. The results of these studies and the associated throughput improvements are described in this paper. INTRODUCTION Molybdenum, a vital component for the steel industry, is typically found in nature as molybdenum disulfide (MoS2). MoS2 is typically recovered via flotation processes and is purified through leaching processes. While molybdenum disulfide is a commercial product, it is not the form of molybdenum that the steel industry requires. They require molybdenum in the form of molybdenum trioxide, MoO3. There are multiple ways to refine molybdenum disulfide into molybdenum trioxide. The primary method is the oxidation of molybdenum disulfide in a multiple hearth roaster. The chemistry of converting molybdenum disulfide to molybdenum trioxide is very favorable at increased temperatures, oxidizing the molybdenum through a range of exothermic reactions to ultimately produce MoO3. The chemical reactions that occur in molydenum roasting occur in three zones. These three zones correspond with four different reactions."

Jan 1, 2015

By V. Maazallahi, A. Rouleau, A. Saeidi

"The geometry of the terrain topography before and after the failure are the essential factors for analyzing a landslide and for the design of remedial works. This paper presents a method to determine these factors, considering that the determination of the slide surface profile is difficult and costly using traditional methods and the pre-slide topography data is often not available. The presented method to locate the 3-dimensional geometry of the slide surface is based upon determining the slide surface in 2- dimensional vertical sections. This method utilizes post-slide topography of the area to determine the pre-slide topography and uses equations to estimate the pre-slide situation using a statistical process applied to points located on the sliding mass. This method is tested on the Maskun landslide in Iran. The results indicate the applicability of the proposed method to obtain the key factors for the back analysis of a landslide in a cost effective manner.INTRODUCTIONProbably the most reliable method of determining the strength of soil and rock mass is to back analyze a failed or failing slope (Caia et al. 2007; Wyllie & Mah, 2004). This method is used in geotechnics for estimating geotechnical parameters of the rock and soil mass (Sakurai et al., 2003; Frayssines and Hantz, 2009; Cepuritis et al. 2010), but it requires that the failure mode is well established and that there is complete and precise information available on the slide surface and the sliding mass (Sjöberg, 1996). Measurement of the slope profile before failure provides the basic information required for a back analysis (Hock & Bray, 1981). The post-slide topography is another key factor. The back analysis process for determining the actual strength parameters of soil or a decomposed rock mass after a landslide requires knowledge of the sliding mass geometry, both before and after the sliding event. Many studies are reported in the literature about the application of back analysis for determining geotechnical and geomechanical parameters of rock and soil mass (Sakurai et al., 2003; Cepuritis et al. 2010; Frayssines and Hantz, 2009, Hussain and Stark, 2011), but they generally present little information about the geometry of the slide surface, and the weight of rock and soil mass that slid, although these factors are the most important parameters for back analysis process. Liang and Xue-song (2012) determined the slip surface having the minimum factor of safety (called critical slip surface in deterministic analysis of slopes) and the slip surface with the minimum reliability index (called critical reliability slip surface), but they have not considered the actual profile and geometry of the slide surface. Rocscience (2013) proposes the back analysis option in the Slide software for slope stability study, but it requires an imposed slide surface as input; alternatively, one can estimate by a finite element analysis the surface with the minimum factor of safety. However, this estimated surface is very likely different from the actual sliding surface, considering the uncertainties in input data of the finite element method."

Jan 1, 2015

By Stefan Larsson, Jan Ekström, Jennie Kock-Larsen, Håkan Garin

"This paper describes the testing procedure (or protocols) for quality control of dry deep mixing columns in a major ground improvement project carried out in Sweden. Quality control was mainly based on column penetration tests performed at different stages in the project and on two occasions after installation. In the paper, the results from the tests are compared with tests on the unimproved clay. As expected, the results show that the correlation between undrained shear strength in the columns and in the unimproved soft soil depends mainly on the in-situ stress. However, the correlation probably depends on when the tests were performed after mixing. When the influence of the in-situ stress was excluded from the analysis, no significant correlation could be identified. This means that the undrained shear strength in the columns and in the unimproved soft can be considered to be uncorrelated when the strengths and the corresponding variability are evaluated with depth from groups of tests.INTRODUCTIONQuality control and quality assessment of deep mixing (QC/QA) constitute a key component in verification of the limit state design. Due to the complex mixing process and varying geological conditions, it is normally not possible to sufficiently assess the strength and deformation properties in advance. In Sweden, the most commonly used QC/QA method for verification of the limit state is the column penetration test (Axelsson and Larsson 2003; Bergman et al. 2013). The method works well but is time-consuming and requires many tests since property variability is normally high. The column penetration test can be used to assess the undrained shear strength Cu,col. However, it is not clear how the strength correlates to the undrained shear strength of the unimproved soil Cu,soil. There are common factors such as the in-situ stress state and the natural water content, which makes a positive correlation probable, i.e. as Cu,soil decreases, Cu,col also decreases and vice versa. The unimproved soil has a natural spatial variability, but it is not known if the improved soil follows the same variation. The mixing process has a substantial influence on the strength variability and may supersede the influence of other factors. However, if a sufficiently good correlation exists between Cu,col and Cu,soil, information from the geotechnical ground investigations can be used in the design and planning of QC/QA of deep mixing in a more stringent manner. Information about the correlation is also essential in reliability based design, where a strong positive correlation may have a negative influence on reliability. However, as discussed by Al-Naqshabandy and Larsson (2013), this correlation may be weak or insignificant for a representative failure domain where the mixing process may have a dominant influence on the strength variability. It is thus of interest to assess the correlation."

Jan 1, 2015

By J. Mizera, J. Zdunek, K. J. Kurzydlowski, A. Dobkowska

This work concerns comparison of corrosion resistance of the aircraft aluminum alloy composed of Al - 2.3%Li - 0.1% Zr. The alloy was hot rolled (HR) from 13 mm to a thickness of 4 mm (e = 2.4) and 1 mm (e = 5.2). Corrosion resistance was investigated by Potentiodynamic Polarization Test. The investigation relied on exposure samples in two different corroding medium: 0.5 M NaCl solution and 0.01 M Na2SO4 solution with added 0.01% of Cl- at room temperature. Furthermore, the microstructure was analyzed using the optical microscope with polarized beam. The hardness was measured on lengthwise profile. It was stated that alloy after the largest deformation (equivalent total strain e = 5.2) is characterized by the best mechanical properties and the best corrosion resistance. The alloys in initial state and after deformation to 4 mm (e = 2.4) are characterized by worse corrosion resistance. It is associated with microstructure and density of dislocation in analyzing material.

Jan 1, 2015

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By Filippo Maria Leoni, George Filz, Wesley Schmutzler, Matteo Bertoni

"The US Army Corps of Engineers selected the Deep Mixing Method (DMM) for the required stabilization at the LPV 111 Project (New Orleans, USA). DMM was used for ground improvement/foundation strengthening and consequently to stabilize and support the burden of the new levee. Two different technologies were used: Trevi Turbo Mix (TTM) and Contrivance Innovation Cement Mixing Columns (CI-CMC). LPV 111 is the largest soil mixing project to date in the USA with its more than 18,000 elements installed to a depth of up to 67 feet for a total of 1.7 million cubic yards of treated soil. The preparation and execution of the project presented many challenges from various points of view. The little time available to complete the job led to the simultaneous utilization of eight deep mixing rigs and batch plants which worked 24 hours per day, 5.5 days per week on a stretch of land approximately 5.3 miles long. Given the imposing geographical extent of the project, a four phase laboratory programme and five field validation test programmes, conducted in as many different areas of the project, were completed to design and optimize the grout mixes and the installation parameters. The massive quality control/quality assurance testing programme produced over 500 drilled core holes and over 5,000 tested specimens in order to determine unconfined compressive strength (UCS) and uniformity of the DMM elements. This paper has the purposes of describing the tremendous challenges encountered and providing valuableinformation that may be useful for other future projects, including details not previously published.INTRODUCTIONReach LPV-111 is part of the Lake Pontchartrain and Vicinity Hurricane Protection System designed to protect the city of New Orleans and the surrounding areas from the surge that would accompany a 100 year hurricane event. LPV-111 measures approximately 8.5 km (5.3 miles) long, of which 7.2 (4.5 miles) extend along the north bank of the Gulf Intracoastal Waterway (GIWW) and the remaining 1.3 (0.8 miles) run north and terminates at the CSX Railroad Gate. The Bayou Sauvage National Wildlife Refuge borders the levee on both sides (Fig. 1)."

Jan 1, 2015

By D. Mas Ivars, K. Suzuki, J. A. Vallejos

"A comprehensive geotechnical characterization has been undertaken at the El Teniente mine to describe and determine the rock mass behaviour strength properties of the primary copper ore. The Synthetic Rock Mass (SRM) modelling approach is used to simulate the mechanical behaviour of this heavily and unfractured rock mass. The micro-parameters of the model have been calibrated against mechanical properties and scaling laws for intact rock and veins, in order to represent virtual samples of four different geotechnical units. Results can be used to predict the rock mass scale effects, anisotropy, and brittleness properties that cannot be obtained using empirical methods.INTRODUCTIONThe primary copper ore at the El Teniente mine is described as very competent and massive, given that it exhibits a brittle behaviour (Rojas, Cavieres, Dunlop, & Gaete, 2000). This description is coherent with the geological description of the rock mass, which does not have discontinuities match as the definition provided by International Society of Rock Mechanics (ISRM, 1981). Only faults can be classified as discontinuities, but they are widely spaced. The primary copper ore has a high frequency of veins, where the cooper mineralization is hosted, these vein network structures are known as stockwork. Soft veins containing weak minerals as infill (chalcopyrite and anhydrite) control the disassembling of the rock mass during caving (Brzovic & Villaescusa, 2007).Presently, there are mainly two traditional methods used to estimate the strength of the rock mass: 1) determination of the strength envelope of the rock mass using scaling parameters from laboratory tests and 2) using numerical modelling based on back analysis of previous experiences of failure observed and measured in mining or civil excavations. The primary copper ore of El Teniente mine has no fractures; therefore, it is difficult to determine a rating that would enable to scale laboratory data, such as, RMR (Laubscher, 1977) or GSI (Hoek, 1994). This is the reason why the first option is not valid unless the entry data is manipulated or adjusted in order to obtain reasonable results. The second option requires, in general, a good characterization of a previous failure event in the rock mass, which is not always available. In recent years, new techniques of numerical modeling have been developed (PFC3D, ELFEN, Abaqus). Those methodologies are the third way to estimate the strength of the rock mass, but they are still in development. Particularly, the concept of SRM developed by Itasca is implemented in this study (Pierce, Mas Ivars, Cundall, & Potyondy, 2007; Mas Ivars et al., 2011), aiming to capture the real behaviour of the rock mass."

Jan 1, 2015

By Lon Santis, Bill Evans, John Tatom

Debris data from the Department of Defense Explosives Safety Board’s Project ESKIMORE full-scale explosives event test program are compared to quantity-distance (Q/D) standards and quantitative risk analysis (QRA) methods. The ESKIMORE test program involved quantities of explosives ranging from 1,000 to 60,000 pounds detonated in typically sized structures made of metal and concrete. Debris from these events was extensively surveyed and catalogued. The debris patterns from these events show varying degrees of directionality normal to the walls of the structures. These density patterns are overlaid an existing explosives storage site that is comparable to the test conditions. Analysis of the debris patterns in relation to Q/D standards shows that exposures located beyond the Q/D arc but along the normal to walls of potential explosion sites (PES) may have much higher debris density than exposures at the same distance on the corners of the same PES. Analysis of the debris patterns shows that predicted patterns using the QRA tool IMESAFR v2.0 closely match actual patterns. Additionally, IMESAFR based QRA methods are able to quantify the different risk levels of being exposed along the wall’s normal as compared to being exposed on the structure’s corner. Methods and decision making criteria to mitigate risk based on the directionality of PES debris are presented. Copyright ©

Jan 1, 2015