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By D. Nie, M. Ren, T. Mo

This paper studied the phenomenon of room temperature creep deformation at crack tip and its effect on fatigue crack growth rate of a X-70 pipeline steel using compact-tension (CT) specimen on a MTS 810 testing machine. Time-dependent deformation at the crack tip under constant load was observed in this steel at room temperature and the amount of deformation produced was seen to depend on loading rate and the magnitude of stress intensity factor. It is found that there exists a critical stress intensity factor below which the deformation decreases with time when the applied load remains constant. It is also found that the occurrence of room temperature creep obviously affects the subsequent fatigue crack growth rate. The observed behavior was explained based on dislocation theory.

Jan 1, 2005

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011

By E. M. De Souza, A. M. Coode

"Since potash was discovered substantial rock mechanics research has been done to develop the technology needed to cope with the unique conditions in Saskatchewan mines, to assure general mine safety and to assess the problems associated with mining potash at depth.The practical result of this research was the development of multiple entry systems incorporating yielding pillars for access ways and the chevron type layouts for production panels. These developments proved the viability of extracting potash from between 950 m and 1100 m depth using a high degree of mechanization. High extraction ratios could not, however, be achieved using the developed technology.The presence of a competent salt back is critical to mining the potash, and underground practice is governed by the presence of anomalous geological zones. These factors may be associated with the occurrence of brine inflows. One potash mine in Saskatchewan ceased its underground operations and was closed due to flooding of the entire mine. Two other potash mines in Saskatchewan had significant brine inflows. The costs involved in brine pumping, equipment relocation, bulkhead construction, grouting, and in auxiliary operations can run into the tens of millions of dollars.At Central Canada Potash, the use of stress relief and yielding pillars in the design of the mining layouts has resulted in over-all stable underground excavations and safe mining practices. There are two types of production room s, the chevron and the hybrid, which result in a planned block average extraction ratio of 35010. Mining activity has resulted in brine ingresses in two areas, and additional operating costs have been incurred over the years. These mining areas have demonstrated abnormally high closure rates, and rapid back deterioration. A program was established in those two areas to ensure the practice of safe mining procedures.The short-term perspectives inherent in the program included the elimination of all uncertainties associated with the possibility of an increase in brine inflow leading to flooding, the elimination of the abnormal ground behaviour and ground deterioration in the inflow areas, and the reduction of the long-term adverse effects of mining on regional mine stability. The program was also designed to provide means for developing alternative safe mine layouts which would improve the exploitation of potash resources. Details of the extensive work performed during the program are found elsewhere (E. De Souza, 1988).Grouting and salt backfilling are viable techniques to control brine inflows in underground excavations in potash mines. Detailed instrumentation of the backfilled test areas provides information on the long-term behaviour and effectiveness of the grout/backfill system, allowing for rational decisions on the complete abandonment of these mined out areas, thus resulting in considerable operational cost savings.This paper is presented in two parts: the first addressed the problems of diamond drilling , grouting and backfilling in Panel 209 and the second, addresses the problems of instrumentation and rock mechanics."

Jan 1, 1990

By L. A. Clark, G. H. R. Burrill

"Most unconformity-type uranium deposits in Saskatchewan occur within a few tens of metres above and/or below the basal unconformity of the 1,45-b.y. Athabasca Sandstone. Graphitic basement rocks coincident with post-Athabasca faulting or brecciation at or near the unconformity are important in localizing uranium deposits which form as tabular, ribbon-like bodies with grades averaging over 2 per cent uranium and containing up to 50,000 tonnes UJOs. Some of these deposits have similar contents of nickel and arsenic.In the genetic model proposed to explain these deposits, traces of uranium were leached from the sandstone and weathered basement rocks by oxidized formation waters sweeping through the sandstone and along brecciated faults. Over basement meta-petites, a thick clay regolith adsorbed uranium from the solution. Thus fixed, the uranium was reduced through an indirect reaction with graphite, possibly involving methane. The clay mineral surfaces were thus continuously cleared to allow further adsorption. Basement faults localized along weak graphitic units were re-activated, offsetting the sandstone formation, probably at the time of an early uranium deposition about 1.2 b.y. ago, and served as vents for spent ore solutions. Fluid convection was induced by topographic relief and/or crustal heating from radioactive decay in basement plutons or mantled Archean domes with uranium and/or thorium contents a few ppm above those of adjacent rocks. Heat from radioactive decay within the incipient uranium deposit would develop in about a million years. The self-generating convection cell would continue uranium deposition until all permeability was plugged by minerals. In some instances, convection was re-initiated after subsequent faulting and brecciation. While some deposits were further enriched, heavy flows of oxidized fluids re-dissolved and partially depleted other uranium deposits.The East Alligator Rivers uranium deposits in Northern Territory, Australia, occur within Middle Proterozoic quartzchlorite and quartz-muscovite schists overlain by sandstone. Highest grades occur in silicified breccias where carbonate beds were leached out. Mineralization ages are both pre- and post-Kombolgie Sandstone, but, to date, no significant uranium mineralization has been encountered in the sandstone. There are many general similarities with Saskatchewan deposits, but important differences in detail."

Jan 1, 1981

By Michael K. O’Leary, William D. Coplin

"Risks from political instability and government policies restricting equity ownership, local operations and transfers of payments affect the profitability of foreign mining ventures. More than seat-of-the-pants judgments and old-boy networks are required to anticipate these risks and to take actions appropriate to offsetting them. A system for making political forecasts, called the Prince System, and a series of charts relaying risk s to a production of key minerals will be presented.IntroductionFirm s with extractive operations outside their home country do not have to be told that political stability and government decisions play a big role in the success o f their operations. The takeover of copper firm s in Chile during the Allende administration in 1971 and the recent decision by Venezuela to reduce Reynolds Metals equity share in a smelting operation from 50% to 28% are two examples of hundreds of events that have determined the profitability of extractive operations over the past decade. Both risks and opportunities for international firms seeking to produce and market raw materials are heavily affected by political conditions. While news of political events travel much faster than in the past and host governments are more clever in shaping the risks as well as the opportunities, politics has always been part of the mining business.What has changed is the need to be more systematic in approaching the assessment of political conditions and how it affects business. The increasing costs of extractive operations, the need for long-range planning, the importance of financial arrangements and the world-wide scope of man y firm s' activities require that the assessment be updated continuously and be comparable across different countries and different types of investments. Political risk analysis, the assessment o f macro-political changes and specific governmental decision s on the operations of extractive industries needs to become as systematic and integrated into corporate decision -making as economic analysis has become over the past two decade s."

Jan 1, 1983

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By Michel Gauthier, Jacque Trottier

"ForewordA symposium on base metal deposits was held in Bathurst, New Brunswick, from June 10-13, 1990, sponsored jointly by the Geological Surveys Branch of the New Brunswick Department of Natural Resources and Energy, the New Brunswick Prospectors and Developers Association, and the Geology Division of the Canadian Institute of Mining, Metallurgy and Petroleum. Papers prepared for the symposuim are being published as a series of articles in the CIM Bulletin. This third paper (the first was by Fyffe, et al., in Vol. 83, No. 938, the second is in this issue) in the series presents an overview of the tectonic setting and geochemistry of base metal deposits in the Eastern Townships of Quebec.ABSTRACTIt is well known that the classification system of volcanogenic massive sulphides (VMS) is based upon their metal content. This metal content, the result of hydrothermal solutions circulating within strata underlying the deposits, is generally thought to be related directly to two parameters: (1) the nature of the underlying stratigraphic sequence; and (2) the physico-chemical conditions that existed at the time of the hydrothermal event. Furthermore, these two parameters are, in turn, related to the tectonic setting. One must bear in mind that these parameters are diachronous and evolve with time. These factors are considered in our analysis of the major VMS deposits of the southeastern Quebec Appalachians. This analysis will describe the time and environment of formation of these deposits and integrate them into an evolving paleotectonic model.VMS deposits in the southeastern Quebec Appalachians formed during three distinct metallogenic episodes. During the first episode, which involved early closing of the Iapetus Ocean and associated destruction of oceanic crust by subduction processes(Early Ordovician?), cupriferous VMS deposits hosted by pillowed, mafic (boninitic) lava flows were formed in immature island-arc systems (""Cyprus-type"", e.g. Huntingdon deposit).In the second episode, which also occurred during the closure of Iapetus but at a later stage (Early to Middle Ordovician), mature island-arcs formed and hosted polymetallic VMS deposits (""Kuroko-type"", e.g. Eustis deposit).Finally, during culmination of the Taconic and/or Acadian orogenies (Middle Ordovician and/or Devonian), transtensional basins, associated with tholeitic to transitional mafic volcanism began to develop. Major sedimentation occurred contemporaneous with volcanism, and within this framework polymetallic VMS deposits were formed (""Besshi-type"", e.g. the Memphremagog deposit).Although incomplete, the proposed paleotectonic model represents the sequence of the tectonic settings that prevailed during the formation of the VMS deposits of the southeastern Quebec Appalachians."

Jan 1, 1991

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990's. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount 'net proceeds' shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By M. Normandin

The performance of various polymers and other macromolecules used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocity and turbidity level, The Jar Test is widely used in the mineral industry to determine the efficiency of solid-liquid separation processes, particularly for gravity settler of the Bayer process. However, a high level of variability is found in the data obtained by this methodology, In this study, different parameters of the cylinder test procedure are evaluated to determine their role in the overall variability of the method, As demonstrated by laboratory testing, the overall variability can be considerably reduced by good laboratory practices.

Jan 1, 2005

By G. J. Hutchins

Precision surface mining is gaining traction in the iron ore, copper, iodine, limestone, bauxite, coal and gypsum markets. In this paper, we first address the possible improvements of a surface miner control using GPS techniques. An application in an iron ore mine in Western Australia is presented. The second item addressed is improvements of a new drum driving technique for a 100 ton surface miner. This technique involves installing a slow speed hydrostatic motor directly on the cutting drum rather than driving the drum through chain and sprockets. Details of the performance of this direct-drive versus the chain-drive are detailed. In addition to the 100 ton machine, we also present a 200 ton surface miner. This larger machine has 1600 hp (894.8 kg), and has been successfully introduced into a large iron ore mine in Western Australia. Performance of the 200 ton surface mining machine in various rock hardnesses is detailed. Some comments on the cost effectiveness of using a built-in loader versus loading with wheel loaders are included.

Aug 1, 2013

By Deni Côte, Marcel Vallée

"The Guide to the Evaluation of Gold Deposits reviews the successive evaluation steps in the domains of geology, engineering, and economics. The Guide analyzes, in a systemic perspective, the sequence of exploration, development, and evaluation work required to bring a mineral deposit to production. The aim is to identify the metal/mineralization losses and ore dilution that each work step contributes to the evaluation and mining process. The procedure allows one to maximize the income and profits of a mining operation, and to reduce the risks of financial losses tied to investment decisions in the mining sector. For greater efficiency, the criteria of reserve estimation and classification should be integrated with the evaluation steps and methods. At earlier stages of deposit development, when quantitative knowledge is available mainly on the geological axis, the term ""delimited mineral deposit"" should be used. The term ""reserve"" should be used only in an operating mine or in a mining project, when information in the geological, engineering, and economic domains is adequate to ensure technical and financial feasibility. ""Reserves"" are by definition ""mining reserves"". Each category of proven/probable reserves and measured/indicated deposits should be subdivided into two classes to express better the many steps of mineral valuation. The category of ""possible reserves"" shall be replaced by that of ""inferred mineralization"". This system, derived from the Australasian Code, can easily be integrated into current practices of the exploration and mining industry within a short timeframe. The proposal to develop the use of the margins of error of the estimates at a confidence level of90% should be viewed in a longer timeframe. Establishing the precision of the mineral inventories and distinguishing between categories and classes by means of the margin of error will require more work and a longer break-in period.SOMMAIRELe ""Guide d’évaluation des gisements d'or"" analyse, dans une approche systémique, les travaux d'évaluation et de mise en valeur des gisements minéraux dans l'axe de la géologie, dans l'axée l'ingénierie et dans I ‘axe de l'économique. L’objectif est d'identifier la contribution aux pertes de métal et à la dilution du minerai des diverses étapes de l'évaluation et de l'exploitation du gisement. Ceci aid erra à maximiser les revenus et les profits, et ainsi, à réduire les risques départe financière que comportent les décisions d'investissements dans le secteur minier. Pour atteindre ces objectifs, iI est essentiel de relier les critères d'inventorie et de classification des réserves aux méthodes d'évaluation des gisements. Aux stades antérieurs du développement minéral, lorsque les connaissances quantitatives ne s'étendent qu’à l'axe géologique, le terme ""gisement délimite"" sera utilisé. Le terme ""réserve"" ne sera utilisé que dans une mine en exploitation au dans un projet minier, lorsque l'information dans les axes de la géologie, de l'ingénierie et de l'économique sera appropriée pour en garantir la faisabilité technique et économique. Chaque catégories des réserves, prouvée et probable sera subdivisée en deux classes pour mieux qualifier les niveaux d'évaluation du projet. La catégorie actuelle des réserves possibles sera remplacée par celle des ""minéralisations inférées"". Plusieurs essais démontrent que le système propose, qui s'inspire du Code australasien, peut facilement et rapidement s'intégrer dans les pratiques de l'industrie. II pourrait également contribuer à une standardisation des méthodes et des nomenclatures à l'échelle internationale. La proposition d'utiliser les marges d'erreur des estimes au niveau de confiance de90%pour caractériser les estimations se situe dans une plus longue perspective. Cette application demandera des développement méthodologiques additionnels ainsi qu'une période de rodage."

Jan 1, 1992

By C. J. Rockingham

"A comparative study of sulphide textures has been carried out on samples from four Archean copper-zinc massive base metal sulphide deposits: Kidd Creek, Ontario; Lake Dufault -Norbec, Quebec; Hood River-41, N. W. T.; and Geco, Ontario. These deposits have undergone metamorphic recrystallization under a range of conditions, and results of this study indicate that certain sulphide textures may be used as qualitative indicators of metamorphic grade, whereas other cannot.The sulphide textures of most value in this regard are sulphide grain sizes, which increase with increasing metamorphic grade, and the presence or absence of sedimentary/diagenetic textures, which are destroyed at the lower amphibolite facies of metamorphism. Chalcopyrite and pyrrhotite intergrowths in sphalerite increase in size, in degree of coalescence and in the ratio of unmixed pyrrhotite to chalcopyrite inclusions with increasing metamorphic rank. With increased metamorphic grade, the pyrrhotite intergrowths change from rounded inclusions on grain boundaries to rod-like shapes along sphalerite twin planes. There is also a general increase in the relative proportion of pyrrhotite in the deposits. Textures that appear to have little value as indicators of metamorphic grade are sulphide deformation textures, and triple junction point angles and their standard deviations, which show little variation from the lower greenschist to the upper amphibolite facies of metamorphism. The presence or absence of myrmekite-like magnetite also has little value in determining the relative metamorphic history of these deposits, as it is a product of local contact metamorphism."

Jan 1, 1980