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By R. J. McLeod

"A new backfill plant was constructed in 1966 adjacent to the mill of Giant Yellowknife Mines. The reasons for the addition were to increase the storage capacity for sand fill, provide facilities for mixing cement with the fill for mine stope floors and provide a system for pumping fill to B -3 raise, a horizontal distance of 4700 feet from the mill. At the same time it was hoped to increase the density of the fill pumped underground.The plant consists of two only steel storage tanks of approximately 400 tons capacity of sand fill each. They are 17 feet in diameter and have conical bottoms. The cylindrical section is 28 feet high and the conical section 14 feet high. Each tank is fitted with water nozzles around the conical sections to remove solids at the required density. The water pressure on the nozzles is 150 lbs per square inch. The cyclones used to produce the sand back fill are located on top of the storage tanks. Five model Dl0B Kreb cyclones are used for this purpose. The vortex finders are 2 1/ 4 inch and the apex 1 1/4 inch. The cement silo or storage tank is located in the same building. It is a steel tank 17 feet diameter by 41 feet high with a conical bottom. The silo holds 250 tons of bulk cement, which is unloaded by air from a bulk highway carrier using 12 to 15 lbs air pressure. The cement is conveyed to the top of the silo, a distance of 70 feet from the ground by 450 lbs. of air.The mixing tank is a rubber lined steel tank 14 feet in diameter by 14 feet high. It is equipped with a Lightning Mixer supplied by Greey Mixing Equipment Ltd. The mechanism is driven by a 40 HP motor. The lower shaft is unsupported and is equipped with two 36 inch diameter axial flow turbine type rubber covered impellers. The backfill is discharged from the storage tank into the mixing tank by a 5"" x 4"" SRL-C pump powered by a 20 HP motor. A level control in the mixing tank regulates the rate of discharge of this pump through a Grinnell-Saunders automatic control valve. The cement silo is situated at such a height above the mixing tank to allow for a Rota-Lock, a small hopper and a cement feeder. The feeder is an Omega gravimetric belt type dry feeder with a Sensogram controller. The capacity of the cement feeder is 20 tons of cement per hour. The cement and backfill are mixed in the mixing tank at whatever ratio is required for the mine stope floors."

Jan 1, 1968

By A. Abadías Llamas, N. Bartie, M. Stelter

Evaluating the economic viability as well as the sustainability of the Circular Economy (CE) system requires a deep understanding of the distribution of all elements, compounds, alloys, materials etc. in flows. In this paper, the circularity of the copper value chain, including primary and secondary processing, is rigorously evaluated. The studied system comprises the metallic copper production from primary sources (from mineral to metal), copper-containing commodity production (copper is mixed with other metals) and copper recycling through secondary smelting to close the loop. This is linked to photovoltaic (PV) panels and battery storage. A simulation model of this system is created using HSC Sim, considering more than 30 elements (and its various compounds), 180 unit operations and 800 flows. From the mass and energy balances obtained through the simulation, an exergy analysis is conducted to evaluate the resource consumption from a second law (entropy) perspective. Additionally, these results are complemented through a Life Cycle Assessment (LCA), the recovery of technology elements and by-products is discussed, while quantifying the losses through the value chain. Through the digitalization of the complete system, a better CAPEX and OPEX understanding of the metal recovery and losses can be obtained, as well as the associated resource consumption and environmental impacts. New flowsheets and technologies can be evaluated. Several scenarios show how the resource consumption and the environmental impacts are affected by the recovery of different materials to produce different products. INTRODUCTION A key challenge of the circular economy (CE) is the linkage and optimization of both resource and energy efficiency of the (renewable) energy infrastructure and the resource cycle depicted by Figure 1 simultaneously. In addition, the CE requires the linkage of all stakeholders as shown by Figure 1. This has been discussed in some detail by Reuter and Bartie (2019) and Reuter et al. (2019). Copper and all its associated technology elements is one of the key enabling metals that is an economical copper colored thread through CE society (Reuter & Kojo, 2014). The Metal Wheel (Figure 2) shows the linkage of and recovery of various elements associated with copper and other carrier metals. This reveals that copper acts as an important carrier metal because of its properties i.e. the wealth of technology elements it carries from geological ores, but also its capacity to act as solvent of valuable elements and thence a key closer of various complexly connected element and material cycles when these technology elements are released during copper refining. The same applies to all other carrier metals of modern CE society as shown for example recently in a lead policy brief (Blanpain, Reuter & Malfliet, 2019).

Jan 1, 2019

By G. M. Proudfoot

IN June, 1940, a .Longyear 3420 blast-hole drill rig was purchased by the Hudson Bay Mining and Smelting Company for the purpose of experimental blast-hole drilling. The early work showed that the diamond drill could compete successfully with the Leyners then in use and by January 1st, 1941, the diamond drills were placed on contract. They may be considered to have gone into production at that date. Prior to the introduction of the diamond drill, our bench drilling was clone with Ingersoll-Rand S-70 and S-83 Leyner drills. Holes up to 40 feet were drilled, using coupled 1 1/4-inch round steel. Bits with a gauge of 3 inches were used in starting these holes, with a drop of 1/8-inch gauge for each 2-foot run. The holes normally ended with 1 1/2 or 1 5/8-inch gauge, though bits down to 1 1/8 inches were available for holes longer than normal or for holes drilled in abnormally abrasive ground. This method of drilling was very satisfactory and was a distinct improvement on the three-bench method of drilling used previously (1). During 1937 and 1938, when experienced miners were available, Leyner long-hole drilling was carried on with great efficiency. However, in 1939 and 1940, labour turnover in-creased and experienced long-hole drillers became scarcer. This resulted in a marked decline in the efficiency of the drilling operations, with increased costs and less tonnage drilled per shift. EXPERIMENTAL WORK The initial diamond drilling test work was carried on with a Longyear 3420 air-driven blast-hole drill rig, drilling a 1 3/16-inch hole. Tests indicated that diamond drilling could be successfully adapted to local conditions and that overall costs compared favourably with costs obtained with the Leyner long-hole method. Leyner long holes on stope benches usually bottomed at a larger diameter than the 1 3/16 -inch diamond-drill holes. More powder could therefore be introduced into the Leyner holes than could be placed in the diamond-drill holes. To achieve the same fragmentation, additional footage was required when diamond drilling. Diamond-drill holes of larger diameter were indicated.

Jan 1, 1943

By Arthur Brant

STEEPROCK LAKE (Figure 1) lies about two miles north of Atikokan, a village approximately one hundred and forty miles west of Fort William and one hundred miles east of Fort Frances on the Canadian National railway. The possible presence of hematite beneath the waters of Middle arm was inferred by early geological investigators (1890-1903) from the dense hematite float found on the southerly shores of this portion of the lake (1). A dip-needle survey of Middle arm, undertaken in the winter of 1930-31 by J. G. Cross, indicated two areas of high magnetic attraction which Mr. Cross thought might be due to magnetic iron oxides associated with possible hematite bodies. Bedrock could not be reached by the ineffectual hand-drilling so courageously attempted, and further work was abandoned. It was not until 1937 that Mr. Jos. Errington, of Toronto, convinced of the possibilities, determined to support Mr. Cross to the extent of several thousand feet of drilling. During the winter of 1937-38, holes Nos. 1, 3, 4, 5, and 13 were put down (see Figure 1). The first four of these holes demonstrated that the areas of magnetic attraction outlined by the dip-needle survey east of the Narrows and southwest of Elbow point were due to ash rock (2). As a result, Mr. Cross decided to investigate the bordering areas of low magnetic attraction and selected a location near the high ferruginous lime (3) point in the northeast of Middle arm. Dense, hard hematite beneath approximately 350 feet of water and clay was struck in the first hole, and, before the end of the winter's drilling, hematite had been encountered in holes Nos. 6 to 13 along a straight line 700 feet in length (see Figure 1). In the meantime, the Steerola ( 4) Exploration Company had been formed to continue development and already, in the spring of 1938, W. D. Neeland, the Company geologist, had come to the conclusion that the most probable location for possible hematite was at the ash-lime contact. Accordingly, during the summer, drilling was continued off-shore in holes Nos. 15, 25, and 27 (see Figure 2) toward possible hematite bodies inferred by Mr. Neeland.

Jan 1, 1940

By L. A. Clark, G. H. R. Burrill

"Most unconformity-type uranium deposits in Saskatchewan occur within a few tens of metres above and/or below the basal unconformity of the 1,45-b.y. Athabasca Sandstone. Graphitic basement rocks coincident with post-Athabasca faulting or brecciation at or near the unconformity are important in localizing uranium deposits which form as tabular, ribbon-like bodies with grades averaging over 2 per cent uranium and containing up to 50,000 tonnes UJOs. Some of these deposits have similar contents of nickel and arsenic.In the genetic model proposed to explain these deposits, traces of uranium were leached from the sandstone and weathered basement rocks by oxidized formation waters sweeping through the sandstone and along brecciated faults. Over basement meta-petites, a thick clay regolith adsorbed uranium from the solution. Thus fixed, the uranium was reduced through an indirect reaction with graphite, possibly involving methane. The clay mineral surfaces were thus continuously cleared to allow further adsorption. Basement faults localized along weak graphitic units were re-activated, offsetting the sandstone formation, probably at the time of an early uranium deposition about 1.2 b.y. ago, and served as vents for spent ore solutions. Fluid convection was induced by topographic relief and/or crustal heating from radioactive decay in basement plutons or mantled Archean domes with uranium and/or thorium contents a few ppm above those of adjacent rocks. Heat from radioactive decay within the incipient uranium deposit would develop in about a million years. The self-generating convection cell would continue uranium deposition until all permeability was plugged by minerals. In some instances, convection was re-initiated after subsequent faulting and brecciation. While some deposits were further enriched, heavy flows of oxidized fluids re-dissolved and partially depleted other uranium deposits.The East Alligator Rivers uranium deposits in Northern Territory, Australia, occur within Middle Proterozoic quartzchlorite and quartz-muscovite schists overlain by sandstone. Highest grades occur in silicified breccias where carbonate beds were leached out. Mineralization ages are both pre- and post-Kombolgie Sandstone, but, to date, no significant uranium mineralization has been encountered in the sandstone. There are many general similarities with Saskatchewan deposits, but important differences in detail."

Jan 1, 1981

By A. A. Nourbakhsha

During the last few years, low cement castable refractories found more application in industry, because of good low and high temperature mechanical properties.In the case of alumina based castables ,usually fume silica or reactive alumina are used as superfines in the matrix to form mullite at high temperature which depends to source of alumina . Mullite network formation improves the hot mechanical properties and thermal shock resistance of bodies. The mullitisation of andalusite (so called primary mullite) also produces a certain amount of rich silica glass, part of it being expelled out of the grain. This phenomenon restrict the application of andalusite low cement castable in pig iron ladle. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time and undischarged pig iron are the main ones.Therefore monolithic refractories such as castables which increase thermal shock resistance could be substituted. Regarding to ternary phase diagram of Al2O3-SiO2-CaO ,fumed silica was selected as fine particle.After optimization of particle size distribution by using of modified andreasen equation and rehological properties ,different mixture were composed with andalusite ,fume silica, reactive alumina,secar 71 ,SiC and kyanite.All aggregates system components were mixed dry for 1 min in hobart mixer .After water addition wet mixing was continued until getting flowing about 4 min.The ready mixes were poured in the moulds of of 25mm X 25mm X 140mm with vibrations .After demoulding the samples were cured for 24 hrs and dried at 110OC/18hrsand then fired at 1100-1500OC. Physical ,mechanical ,phase analysis(XRD) and microstructure studies (SEM)were carried out according to ASTM standards. Results showed that by addition of kyanite ,more mullite phase formed through the matrix but,because of expansion occured during this phase transformoration, some cracks formed and mechanical properties decreased.By SiC addition the silica film on the surface of SiC lead to improvement of mechanical properties at high temperature

Oct 1, 2011

By F. W. Wellmer

"This paper discusses the changing nature of reserve/consumption ratios, using data from Canadian operations and focussing particularly on copper.IntroductionStudies in world metal consumption and world metal reserves are done regularly by the U.S. Bureau of Mines, the German Federal Institute of Geosciences and Raw Materials, and other institutions. Formerly, on the basis of these data, the following figures were calculated:• a static lifetime of reserves-reserves at year end divided by the consumption of the previous year;• a semidynamic lifetime of reserves-reserves at year assumed constant growth rate.These figures were severely criticized because they were purely theoretical and did not consider the availability of the raw materials.Recent practice is to calculate reserve/consumption ratios (R/C ratios) for periods(1) or for different years(2,3) and to interpret the trend. For base metals, these R/C ratios are increasing (Table 1). This had led to the conclusion that today the relative availability of base metal reserves has increased as compared to 10 or 15 years ago(4,5) As there are normally numerous deposits for each commodity, the anticipated production rates of deposits are irrelevant to this conclusion as long as the statistical distribution of possible production rates does not change significantly.The above conclusion is only justified if the quality and the nature of the data base remain the same. This is certainly the case for the consumption data. It is also assumed for the quality of the reserve figures, which usually take into account only proven and probable reserves. For the nature of the reserve figures, however, this does not seem to be true.Undoubtedly, the reserves increased in absolute terms between 1966 and 1978. To put the absolute reserve figures into perspective, it is common, as said above, to compare them with the mine production, which increased in the free world between 1966 and 1978; e.g. for copper by 40%, for Pb by 17% and for zinc by 36%. However, the reserves are also influenced by other factors, such as average size of the mines, changes in the grade of the mined ore, price-to-cost relationships and the like.The purpose of this paper is to examine the nature of the reserve figures in more detail. Because the completeness of mining data published in Canada is rather exceptional, Canadian .data serve as an example and it is assumed that the conclusions can be extrapolated to other mining countries or at least to those with free market systems."

Jan 1, 1981

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013

By Z. Zhang, M. -Y. Liu, X. -G. Chen, F. Breton

"The microstructures of AlSi10Mg foundry alloy in permanent mould (PM) and high pressure vacuum die (HPVD) castings were analyzed and compared. The as-cast microstructures of two castings mainly consisted of eutectic silicon particles, primary Mg2Si and Fe-rich intermetallic phases. The surface layer in HPVD castings, which has a unique feature and different structures, was carefully characterized. The dimension variation of microstructural phases along the cross section in PM samples is less than that in HPVD samples, although the size of microstructural phases in PM samples was much larger than that in HPVD samples. The mechanical properties of PM and HPVD samples were evaluated on as-cast and T6-treated conditions. The tensile properties of HPVD castings are remarkable better than those of PM castings on the as-cast condition. The T6 heat treatment greatly improves the tensile strength of PM castings while it has limited impact on the tensile strength of HPVD castings.INTRODUCTION The AlSi10Mg alloys are widely applied to the high pressure die casting (HPD) and high pressure vacuum die casting (HPVD). In the HPD process, the melt is injected into the die cavity under a high speed (30–50 m/s in the gate velocity for aluminum alloys), and solidified under a high pressure (up to 200 MPa in the cavity) and with a high cooling rate (up to ~103 Ks–1) (Gourlay, Laukli & Dahle, 2007; Ji, Wang, Watson & Fan, 2013). This results in a unique microstructure feature that is different to other casting processes under gravity. One major concern in HPD castings is porosity due to trapped air in the cavity (Ji et al., 2013), which seriously restricts the application of a heat treatment on the improvement of mechanical prosperities because of the formation of blisters on casting surfaces. For the process improvement, the high pressure vacuum die casting was developed in 1980s (Uchida, 2009). In this process, the melt is injected into the die cavity under reduced pressure (vacuum), which greatly reduces gas porosity in castings due to effectively avoiding the trapped air. Consequently, HPVD castings are heat-treatable without the formation of blisters on castings surface during heat treatment. The HPVD process has been widely applied to produce high quality structural castings in recent years attributed to reliable vacuum system development (Uchida, 2009). However, the microstructure features of HPVD castings are not systemically characterized yet."

Jan 1, 2018

By C. M. Trigg

"PEC uranium deposit, 100 km southwest of Coppermine, was discovered by diamond drilling in 1976 following ground and airborne geophysical surveys, geological mapping, geochemical surveys and boulder prospecting that were initiated as the result of the discovery of uraniferous sandstone outcrops in 1969 by geologists of Aquitaine Company of Canada Ltd.The deposit is within gently northeasterly dipping medium to coarse-grained Unit 11 quartzitic sandstone of Neohelikian Dismal Lakes Group. The deposit is from 10 m to 70 m above the base of the sandstone which, beneath the deposit, non-conformably overlies weathered and altered Aphebian granite of Great Bear Batholith or unconformably overlies rubble breccia, conglomerate and medium-grained Unit 8 sandstone of Paleohelikian Hornby Bay Group.A northeasterly trending, 500 m wide graben, bounded by the steeply dipping northeasterly striking Imperial and Aquitaine faults, contains the deposit which is 1.1 km long by up to 340 m wide. The deposit overlies a post-Hornby Bay Group, pre-Dismal Lakes Group topographic high. Uranium principally occurs as stratabound, often peneconcordant bands; a lesser amount of uranium is fracture controlled.Stratabound uranium exists in gently easterly dipping, subparallel bands ranging in thickness from 1.5 m to 6.0 m. Pitchblende, coffinite and sooty black uranium oxides occur as interstitial disseminations and grain coatings subparallel to bedding; they also replace pyrite and form narrow veinlets.Small amounts of torbernite, carnotite and cuprosklodowskite coat pitchblende and are disseminated within mineralized bands. Pyrite, marcasite, chalcopyrite, chalcocite, cove/lite, digenite, azurite, malachite, arsenopyrite, glaucodot, niccolite, bravoite (? ), goethite, hematite and magnetite as well as quartz, barite, calcite, biotite, chlorite and clay minerals exist within the mineralized bands. Uranium grades of 0.1 % to 0.3 % U3O8 over thicknesses of 1 m to 2 m are typical.A steeply dipping fracture zone near the Imperial fault contains sooty black uranium oxides, torbernite, carnotite and cuprosklowdowskite as well as sulphides, cobalt arsenides, quartz and carbonate. The zone may reach 70 m long; its true width is about 1.9 m. Uranium grades range up to 5.18% up, over0.9m.Pitchblende and coffinite from PEC deposit have been dated at 1.08 ± .10 Ga with possible remobilization at .45 Ga. The deposit contains an inferred 3,150 tonnes of U3O8."

Jan 1, 1986

By Gordon E. Agar

"The effectiveness of two this compounds for copper sulphide depression in molybdenite flotation has been examined with batch bench scale tests.Both thioglycollate and trithiocarbonate proved to be good depressants producing results similar to those f or cyanide and hydrosulphide. Ferrocyanide was ineffective on the samplematerial tested.The depressing effect of thioglycollate was readily reversed by an addition of xanthate.IntroductionThe separation of molybdenite from copper sulphide minerals has been practised for a long time(1,2). The predominant scheme is to depress the copper sulphides while capitalizing on the ready floatability of molybdenite to effect the separation. There are many recipes for depressing the copper minerals(3), among them the addition of sodium cyanide, particularly if the copper is present primarily as chalcopyrite; some form of sulphide whether as sodium sulphide, sodium hydrosulphide or phosphorous pentasulphide when there is a mixture of copper sulphides such as bornite, chalcocite and chalcopyrite; potassium ferro cyanide may be used when chalcocite is the principal copper sulphide; peroxide or hypochlorite; as well as heating in the presence of lime. There are different mechanisms by which these reagent s depress the copper sulphides. Sodium cyanide and the sulphide-producing compounds apparently reduce the potential of the copper sulphides to the point where they ar e rendered unfloatable by xanthates . Another study(4) showed that after cyanide addition, chalcopyrite was rendered un floatabl e until the REDOX potential (measured with a gold electrode with a saturated calomel reference) had become more positive than -250 mY. If the chalcopyrite pulp was conditioned after the cyanide addition the REDOX potential increased slowly, whereas if air was introduced during the conditioning the potential r ose much more rapidly. The difference in time to reach the desired level of - 250 mV was as much as 20 minutes' 25 minutes being required when air was absent but less than 5 minutes when air was admitted . These observation s demonstrate some of the problems encountered when using cyanide to depress sulphides such as chalcopyrite . The system adjusts to counteract the depressing effect of the additive. To overcome this tendency it is necessary to either add an overdose at the beginning or to more or less continuously add the regulating reagent. In this study cyanide solution was added under automatic control to maintain a specified REDOX potential."

Jan 1, 1984

By A. B. Szwilski

"The various elements of longwall mine design are reviewed, particularly as they apply to condition s in the coalfields of the Plains region of Alberta. The following recommendations are made: (1) optimum panel lengths of 1000 to 2000 metres; (2) face lengths of 100 to 150 metres; (3) the use of retreat methods; (4) the restriction of floor undulations to less than 15 degrees. IntroductionThis article considers the elements of longwall mine design and is part of a short study that has been made of the feasibility of longwall mining in the Plains region, Alberta, Canada. The Plains region, with about 20 million tonnes, accounts for more than 80% of the coal resources of Alberta. The coalbearing strata in the Plains region cover an area of about 95,000 square miles. The geological formations dip very gently toward the southwest and, from a mining point of view, may be considered horizontal. The depth of the coal seams varies from several metres to over 650 metres. However, it is not anticipated that underground mining will be extended beyond the depth range of 25 to 250 metre s.The coal seams in the Plains region have been subject to many small mining operations in the past. The majority of these small mines were limited to a depth of about 50 metres, working mainly by room-and-pillar methods, although hand-filled longwall mining was often used.The development of new underground mining operations in the Plains region will have to be on a 'start-from-scratch' basis, especially regarding the installation of equipment. Longwall mining is more mechanized than any other method of mining and requires careful attention for the selection of new and expensive equipment. There have been many proven longwall advance and retreat systems in Europe and North America; mining conditions in the Plains region are more similar to those in the United States. Therefore, it will be essential for new mining pro jects in the Plains region to commence with proven system s and equipment; in time, perhaps an experimentation process could be attempted as experience is gained.Generally, the coal face is the key factor in mine productivity, which depends a great deal on equipment reliability, training and experience of the operators. The original design of coal faces must be flexible enough to cater for potential improvements so that running time can be increased."

Jan 1, 1980

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By F. Hashiuchi

In 1996, the Saganoseki custom smelter & refinery successfully shifted to a single flash smelting furnace operation and increased the copper production capacity to 450,000mtpy in 1998. As the next step, Saganoseki planned to further increase the productivity, especially in the area of P.S. converters and acid plant. As the results of modifications and operational improvements, the gas washing & cooling sections of the Saganoseki acid plant were consolidated from 3 to 2 lines, and increased the gas treatment capacity. The S02 converters in the acid plant were also modified to increase the acid production. By increasing the matte grade from 65 to 68%, six PS converters have been successfully integrated into four, while maintaining the production capacity and reducing the environmental burden in 2005. This paper discusses recent operational conditions and the results of implementation of technological improvements.

Jan 1, 2007

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale simulation method has been developed to study the material scratching processes on nanoscale single crystals. The model simultaneously captures the atomistic mechanisms near the free surface and the long range mobility of dislocations and their interactions, without the computational cost of full atomistic simulations. The method also permits the simulation of system sizes that are approaching experimentally accessible systems, albeit in 2D. Simulations are performed on single crystal aluminum to study the atomistic details, surface evolution, and generation and propagation of dislocations for a variety of scratching depths at room temperature. Simulations demonstrate the power of the developed method in capturing both long-range dislocation plasticity and short-range atomistic phenomena during tool advance. Variations of scratching normal and tangential forces are investigated and related to plastic deformation and dislocations generation during the simulation process.

Jan 1, 2006

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By T. S. Wanne

Tunnel sealing experiment (TSX) was conducted between 1997 and 2004 in the Canadian URL located in Manitoba. In the experiment, a tunnel was excavated parallel to the maximum principal stress direction, filled with sand and sealed with bulkheads at both ends. It was then pressurized and heated by injecting hot water. The rock mass response was monitored with seismic methods. The main interest in the numerical simulation was the damage formed during the heating phase. The large-scale PFC2D models replicated a central plane- strain section of the TSX chamber. The models captured the first-order phenomena observed in-situ displaying the difference in the damage in the roof and floor regions, respectively. This difference was due to the filling material confinement of about 100 kPa on the tunnel floor, which occurred in the course of the heated experiment.

May 1, 2009

By Chris Yellowega

The construction and startup of a new mine is a daunting task. To successfully locate, design, build and startup an immense human endeavour like a new mine, takes perseverance, planning, dedication and significant capital. The application of capital requires a thorough evaluation of risk and where that risk is most properly limited to create the risk/return profile. One area of significant capital and thus, significant risk is the selection and maintenance of the very machinery needed to deliver the creation of investor wealth. Albian Sands Energy is the operator of the new Muskeg River Mine located north of Fort McMurray in Alberta?s oilsands. The Muskeg River Mine is owned by a joint venture of three companies: Shell Canada, Chevron Canada Ltd.and Western Oil Sands. The mine is designed to run 400,000 tons per day, 365 days per year. The mine conditions vary from material as hard and of similar consistency to pavement to underfoot conditions as soft as saturated sands. Water cannot be drained below surface conditions, shovel teeth can disappear in less than 24 hours and the primary business is often constructing large civil structures that have little to do with the delivery of ore. The mine starts with the deposit (if it doesn?t exist, nothing else matters), moves into the design, the feasibility study and the approval. The evaluation of risk and the strategies surrounding the control of that risk truly lie after these stages are complete. The strategy and execution stage is where risk is eliminated or accommodated. The point at which the investors money is being spent is the point at which the decisions made cannot be reversed. It is of absolute importance that the execution of the decisions are consistent with the strategy agreed to, lest the investors need to be asked for more money. The key sources of risk identified for the Muskeg River Mine were recruitment of trained and experienced personnel and the delivery of ore to maximize early (<2yr) cash flow. The Muskeg River Mine personnel determined that to minimize risk, personnel would be recruited to operate the mine equipment yet, the requirements for maintaining the equipment would best be held by the manufacturer. The strategy was to obtain the correct equipment for the operation of the mine and leverage the supplier?s expertise to ensure the mine wasn?t training a maintenance organization at the same time as a mining organization. In essence the key strategy for the mine start up and early operation was to leverage the equipment suppliers to maintain and repair the equipment. Albian Sands would maximize the utilization of Maintain And Repair Contract?s.

May 1, 2003

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By D. M. Bastidas

The reduction of copper sulfide and copper oxides originated during artificial tarnishing of copper was studied using potentiodynamic potential/current density experiments. Six copper surface treatments were considered: mechanical polishing; indoor exposure for 7 days; chemical etching in 1.6 M nitric acid; chemical etching and heating at 160°C; and chemical etching and dipping in a 9x10-4 M or 0.9 M potassium sulfide (1(25) solution at 70°C. Cuprite (Cu20) and chalcocite (Cu2S) were the main compounds formed. A linear relationship with the square root of the scan rate (v) was obtained by plotting the potentiodynamic potential/current density for the tarnish dissolution processes. A relationship between potential and current density cathodic peaks was not obtained, according to Müller&apos;s model, showing a proportionality factor with the dimensions of a resistance.

Jan 1, 2007