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By Robert Hopler

THE KEYSTONE NATIONAL POWDER COMPANY is an Independent organization, incorporated under the laws of the State of Pennsylvania. It has three dynamite mills near Emporium, Pa., with a daily capacity of 165,000 pounds. It maintains branch offices in practically all the largest cities east of the Rocky Mountains, and has distributing magazines located in every section where there is a demand for high explosives, with facilities for wagon deliveries. Our mills are all of modern type and are equipped with the most improved machinery for the manufacture of high explosives. The efficiency of our laboratory in conjunction with the high class of labor employed, has enabled us to put on the market an explosive, the quality of which is the result of extensive research and scientific knowledge. Our modern and complete equipment for harbor and railroad transportation insures our patrons of prompt deliveries, which is an essential feature particularly to contractors and those whose facilities for storage are limited.

Jan 1, 2013

"The characterisation of resources and description of variability across different ore domains is key to accurate prediction of probable metallurgical performance. Such characterisation testwork often has limited drill-core from which to work and this immediately confines the characterisation method to smallscale. For flotation feeds, the JKMSI (Mineral Separability Indicator) is being developed as a potential characterisation tool, building on earlier work by Chudacek, (1990), which used shaken test tubes, and was called the EMDEE device. In addition, the consistency of flotation recovery for specified size fractions has shown to be preserved, irrespective of the amount of material in that size fraction obtained by different milling conditions, so that the overall recovery can be estimated from knowing the particle size distribution (McIvor and Finch, 1991; Bazin et al, 1994, Runge, 2007 and Wightman et al, 2010) The JKMSI unit uses less than 10 g of material per test in narrowly sized classes and results to date have demonstrated the value of the test. This paper discusses the potential of the test by demonstrating the link between JKMSI performance and mineralogy of five different ores from Laguna Seca, Escondida Minera Limitada as well as the correlation to plant scale performance obtained in an earlier survey (Coleman et al, 2006). Further work to tie down the proof of representatively of the small sample has been identified and is discussed and included in the paper. INTRODUCTIONSince the uptake of the flotation process at the turn of the twentieth century, small scale, laboratory methods have been sought to characterise flotation response. Although laboratory batch flotation tests are the most widely used method to evaluate reagents, characterise ore variability and obtain suitable model parameters using various scale up factors Runge (2101) other methods using less ore would be useful where ore samples were limited.A method using test tubes for testing ores’s flotation response to reagents was first developed by Ian Walk (Wark & Wark, 1935; Wark; 1938; Sutherland and Wark 1955). In these tests a 50 cc stoppered measuring cylinder served as a means for a qualitative experiment, the aeration being effected through violent shaking by hand. In these experiments about 10 g of mineral was ground by pestle and mortar under water after which the ground material was deslimed and adequately conditioned with the appropriate reagents."

Jan 1, 2013

By Dave Weymer

Falling timber in BC has always been a hazardous job. Huge, often rotting trees and steep, rugged terrain combine to create difficult and dangerous conditions. Death and injury rates are among the highest of any occupation in North America. In BC, the men that head out, saw in hand, are called fallers.

Jan 1, 2013

By Hadi Fanisalek

"Most industries attempted to conduct their energy consumptions in an optimized way for a few decades. This is because policymakers and top managements in industries have felt the critical situation of a possible energy shortage that could happen for them in the near future, even in countries with significant fossil fuel resources. Decisions related to energy consumption in any industry will have a long-term effect on different parts of the industry structure. In this way, energy decisions should be categorized as part of any industry's main strategic and long-term decisions, which should be made by top strategists. On the other hand, strategic management has many powerful tools to help the policymakers in industries to establish a long-term strategy for energy consumption and reducing or preferably eliminating the energy loss. This will be more important for industries in the Middle East, where they have just started to make an applicable strategy for their energy consumption and to design a long-term procedure for their energy management. Based on strategic management and by comparison we designed and offered a new model for establishing the main structure of energy management strategy in primary aluminum industry, which is a high consuming energy industry. This strategy, which we will call ESM (Energy Strategic Model) and has been applied for a typical primary aluminum industry in this paper, is similar to the practical models in the field of strategic management, which were developed for designing the overall company strategy.IntroductionThe elementary goal for introducing strategic management in any organization was to establish a successful plan helping the company to survive and to gain competitive advantage over its competitors in a rough business environment. Strategic management is an ongoing process that evaluates and controls the business and industries in which the company is involved; assesses its competitors and sets goals and strategies to meet all existing and potential competitors; and then reassesses each strategy annually to determine how it has been implemented and whether it has succeeded or needs replacement by a new strategy to meet changed circumstances, new technology, new competitors, and a new economic environment[!]."

Jan 1, 2013

By Saad Elias Kaskah

"The Box-Behnken Design (BBD) is used to model the sacrificial Cathodic Protection System (SCPS) to find the factors effectiveness behaviour. For protection potential assessment the BBD receives (resistivity of environment, sacrificial anode alloy, distance between anode and cathode and surface area for the structure to be protected) as input and gives the protection potential as output. By applying BBD with their analysis tools we get many results. The important results which are the factors individual effectiveness on the sacrificial cathodic protection (SCP) process are the resistivity which has the greatest effect on the potential protection (rank=l) followed by sacrificial anode alloy type (rank=2), surface area for structure protected required (rank=3) and distance between anode and cathode (rank=4). The interaction of sacrificial anode alloy and cathode area {X2X4 ) has significant effect on CP process with the limits which are used in this work while the other factors interaction (X1X2, X1X3, X1X4,X2X3, X3X4 ) has insignificant effect on the limits which used in this work.IntroductionFor carbon steel in seawater the normal corrosion potential E '°""_is in the range -550 to -600 mV vs. Ag/AgCI [1]. The most effective method to overcome the corrosion is cathodic protection {CP) which represents a control method in the steel wall corrosion. Cathodic protection has been used in several areas including marine and underground structures, storage tanks, and pipelines [2]. Sacrificial anodes system generates protective current which depends upon the inherent potential difference between the anodes and the structure to be protected. If the structure is made of iron or steel, any metal that is more active in the electromotive force series can theoretically be used as anode material [3]. There are many factors influencing on cathodic protection like resistivity (NaCl content), chemical composition of sacrificial anode alloy, distance between anode and cathode, surface area of cathode, temperature, humidity, velocity of solution, dust, impurities, bacteria and etc .. The present work studied four factors: NaCl content, resistivity), chemical composition of sacrificial anode alloy, distance between anode and cathode, surface area of cathode) with different three levels of values for each one. Then this work will find the optimum value from the factors levels that tacked to investigated there influencing on sacrificial cathodic protection system."

Jan 1, 2013

By L. Flett, S. Woods, C. Deredin

"Following a significant reduction in world Imperial Smelting Furnace (ISF) capacity from 2003 to 2008, a major optimization initiative was successfully carried out on the lead upgrading and bulk (zinclead) flotation circuits in the Brunswick Concentrator.This paper describes the process improvements that have taken place in order to reduce the quantity of bulk concentrate:•,Increase in lead upgrading rougher flotation circuit capacity•,Installation of a closed-circuit bulk regrind utilizing MillPebs and 150 mm Cavex hydrocyclones•,Installation of two additional cleaner flotation stages on the bulk circuit•,Optimization of the manipulated variables in the lead upgrading and bulk circuitsINTRODUCTIONThe Brunswick Mine (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The planned closure of the mine will take place at the end of the first quarter in 2013. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.A simplified flowsheet for the concentrator is given in Figure 1. The overall flowsheet involves SAG milling, secondary ball milling, selective flotation, and dewatering by thickening, filtering and drying. The complexity of the flowsheet evolves from the requirements for fine grinding and the production of four concentrates: zinc (sphalerite), lead (galena), copper (chalcopyrite) and bulk (sphalerite plus galena).Primary hydrocyclone overflow feeds the copper-lead aerator-roughers for flotation at pH 9.0 with soda ash. Plant xanthate (80-20 sodium isopropyl and potassium amyl) and AP407 are used as collectors in the copper-lead circuit. The rougher concentrate is directed to the copper-lead regrind circuit and the tailings are fed to the secondary grinding circuit. The secondary hydrocyclone overflow from the secondary grinding circuit feeds the copper-lead rougher-scavenger banks. Rougher concentrates are reground to a P80 of 28 µm prior to three stages of copper-lead cleaning. The first stage of cleaning is done in an open circuit with the tail reporting to the cleaner scavenger. The cleaner scavenger concentrate reports to the regrind circuit and the cleaner scavenger tail combines with the rougher/scavenger tail to feed the zinc circuit. The second and third stages of cleaning are performed in closed circuit with the cleaner tail being recycled to the copper-lead regrind circuit. The average final concentrate grades 23% Pb, 3% Cu and 704 g/t Ag, and is fed to the copper separation circuit."

Jan 1, 2013

By Hiroaki Kawamura, Takeshi Yoshikawa, Kazuki Morita, Yutaka Yanaba

"To develop an alternative metallurgical process for phosphorus removal in the production of solar-grade silicon (SOG-Si), slag treatment of metallurgical-grade silicon (MG-Si) was conducted, followed by acid leaching. Phosphorus-doped silicon alloy or MG-Si containing certain amounts of phosphorus and calcium was reacted at 1723 K and 1773 K with CaO--CaF2 of several compositions. Phosphorus removal from the molten silicon into the slag phase was confirmed by reduction to phosphide ions, P3-, and phosphate ions, P3-. These ions were separately determined using a wet chemical analysis method developed by ourselves. The highest phosphorus distribution ratio obtained was 2. 7 after reaction for 18 h with 17.5 mass% CaO--CaF2 slag. We then conducted acid leaching of the silicon and achieved removal of a large fraction (over 90 % ) of the phosphorus, which was much higher than that obtained by ordinary oxidizing slag treatment.IntroductionIn recent years, the production of solar cells has been increasing rapidly. Because of this, the demand for solar-grade silicon (SOG-Si) has also been growing rapidly. The development of lower-cost mass production processes is therefore needed to provide silicon feedstock. Phosphorus is one of the impurities in metallurgical-grade silicon (MG-Si). Because of its large segregation coefficient (kp = 0.35) [l ], it is difficult to remove phosphorus using a solidification refining process. Vacuum melting is considered to be a promising method for removing phosphorous from MG-Si [2], but the issues of high cost and large energy consumption have still to be resolved.Slag treatment is often used to remove impurity elements by oxidizing reactions during general oxidation refining processes. For example, phosphorus in molten steel is removed into a slag phase as phosphate ions, PO4 3-l-, by the following reaction:"

Jan 1, 2013

By Anthony (Sam) J. S. Spearing

Backfilling using coal waste is not a novel means for waste disposal throughout the world; yet, backfilling using a high density (paste) backfill is relatively new, except in Germany and Poland. One of the main benefits of a high density backfill, as opposed to a low density (slurry) backfill, is that, if placed at a low permeability and low moisture content, the risk of water table contamination can be relatively low. In addition, if paste backfill can be placed cost effectively, environmental benefits are huge because the surface impoundment footprint can be greatly reduced or even eliminated. This is especially true in room-and-pillar applications. In its current state, backfilling is considerably more costly than surface disposal. This is mainly because paste, as opposed to slurry, significantly increases backfill placement costs; however, this could be offset by increasing the achievable extraction rate. Overall, such a system could potentially improve the public?s image of coal mining in the US for a myriad of reasons. This paper discusses a proposed backfill system for a typical room-and-pillar coal mine in the Illinois Basin of the US and clearly shows the technical advantages, although costs are still higher with fill. The cost differential will likely reduce over time, in favor of the backfill option, as costs of traditional surface disposal increase, due mainly to ever-restrictive disposal regulations.

Jan 1, 2013

By C. D. K. Gauert

High-pressure waterjet technology is proposed as an alternative tool for selective underground mining of high-grade ore sections in stratiform orebodies showing a preferred ?bottom? or ?top? enrichment such as the Witwatersrand reefs and the Bushveld Complex platiniferous reefs. This technique, utilizing known mining technology together with more advanced machinery and additives as used in industrial and cleaning applications, may lead to an increased life-of-mine (LOM) for mining operations. A series of experiments was successfully carried out in a laboratory on Witwatersrand quartzite material, indicating acceptable cutting performance. Mining volumes by selectively cutting of reef portions are considered to be comparable to traditional drilling and blasting. Economic advantages of waterjet mining include energy savings due to the lower quantity of gangue rock to be hoisted to surface, as well as savings by a decrease in the usage of blasting materials. Capital expenditure of waterjet cutting, if applied on a broad scale, could be lower in the long term than that of conventional drilling and blasting methods. Mining by the application of high-pressure waterjet technology could become a competitive ?green technology? improving the economics and safety of labour-intensive mining operations. This paper suggests that waterjet cutting at an industrial scale can become a routine hard-rock mining technique in the future. Keywords waterjet cutting, high pressure, mechanized narrow reef mining, abrasive agents, costs, selective mining.

Jan 1, 2013

When it comes to safety in the mining and extractive industries, success is literally a matter of life and death. Anything short of perfection is not acceptable. In recent years, the mining industry in the United States has made tremendous strides in terms of health and safety for its workers. Part of that success has come with an increased focus on the issues of safety, an intense examination of procedures, liberal sharing of best practices and a focus on the synergy between safety, reliability and environment. During his closing keynote address of the Safety Management & System Reliability Conference in Minneapolis, MN on Nov. 15, Joe Driscoll, vice president of Great Basin Gold, showed a calendar from the coal fields in Pennsylvania from the early 1900s. The calendar marked the number of mine-related deaths each month. Some months, the number was as high as 50. It was an illustration of how far things have come, but there is still much more work to be done.

Jan 1, 2013

Miners really are an optimistic bunch. Even with the dark clouds hanging over the global industry, mining professionals still turn out in droves at industry conferences. In February, more than 7,200 professionals attended SME?s Annual Meeting in Denver, CO, a record. And the following week, more than 30,000 people converged on Toronto, ON, Canada for the Prospectors and Developers Association of Canada (PDAC) meeting. For many small and junior mining and exploration companies the PDAC conference is a place to find potential investors in their projects. The Investors Exchange attracts several hundred companies, each showing off their properties to the many money types who wander the hall during the four-day conference.

Jan 1, 2013

By Gaifeng Xue, Jingxuan Zhou, Shangchao Liu

"Both COD and TOC can characterize organic pollution of coking wastewater. In theory, there is a linear correlation between these two indicators. After continuous monitoring TOC and COD of coking waste water, linear regression relationship between of these to indicators was studied with the use of mathematical statistics. And conversion equation between these two indicators was established, and using t-test method for significance testing. The results showed that the linear relationship of COD and TOC was significant. Also interval estimation of equation slope and intercept were given in the condition of 95% confidence level. A linear regression equation established can be used to indirectly convert TOC to COD with high precision and accuracy.IntroductionBoth chemical oxygen demand (COD) and total organic carbon (TOC) are measure of the degree of characterization for organic pollution of water bodies. The current COD standard analytical methods is Potassium dichromate titration method [1] . there are some disadvantages in this method, such as only part of organic matter in the water bodies being oxidated, the refluxed steps, a long time needed for each measurement, high cost. It is the most important that sulfuric acid silver and mercury sulfate reagents used in the measurement may easily lead to secondary pollution. In contrast, the measurement of TOC is by the method of combustion or Photocatalytic Oxidation. The result could be easily got from the instrument. There are some advantages in this way, such as easy operation, short time and little expenses for each measurement and no secondary pollution 121• In addition, the measurement of TOC has higher degree of precision and accuracy than the measurement of COD both in the determination of calibration standards and actual samples. The meaning and contrast of TOC and COD are listed in the table 1."

Jan 1, 2013

By Ken Cross

This paper aims to demonstrate that explosives organizations and workers have a legal, moral and financial duty to be able to demonstrate their competence when required, and how that may be achieved at any level from explosives storekeeper to senior explosives engineer on a major project. The concept of competence is outlined, as are the benefits to members of staff, management and the organization, particularly in a regulatory regime that includes competence management as a key performance indicator.

Jan 1, 2013

By Matthew Baumann, Bahram Sameti, Tafazoli Zeng Hairong, Edmond Chow

An automated, centralized, image-based rock fragmentation analysis system provides blast engineers with the benefit of minimizing tedious and mundane work, and allows them to focus on their expertise of blast optimization. In typical manually-operated image-based rock fragmentation analysis, much time is spent on collecting proper images, handling and transferring data, and processing for fragmentation.

Jan 1, 2013

By L. J. Leach

Quench and tempered Cr-Mo plate steel was found not to contain a fully martensitic structure as a result of either slow slack quenching or insufficient hardenability at the cooling rates used. The resulting microstructure contains bainite in combination with martensite. It is necessary to examine the implications of bainite for the toughness of the final product. Loss of toughness arises primarily from the inter-lath carbides that typically form in upper bainite. An investigation into the effect of upper bainite in a martensitic matrix of a steel grade containing 0.17% C, 0.1% Cr, 0.54% Mo, and 20 ppm Bindicated lower toughness than in a fully martensitic structure.

Jan 1, 2013

By E. V. Redin, B. A. Dubrovsky, E. V. Knyazev, A. I. Starikov

"Ti-V magnetite is one of the most abundant composite ore resources in the world. This ore cannot be fully processed via blast furnace technology because of high content of Ti02. According to the investigations carried out in the USA and Japan ITmk3 RHF (Rotary Hearth Furnace) technology is a breakthrough in Ironmaking. Reduction, melting and slag removal can be achieved in just 10 min. The main objective of the investigation is to establish optimum operation conditions for the production of iron nuggets from Ti-V magnetite ore via the ITmk3 by means of the lab scale testing. Samples of ore from the Maly Kuybas deposit (Southern Ural), carbon reductant and fluxes were chemically analyzed. Green pellets were processed via a lab chamber furnace to simulate RHF conditions. The nuggets and slag were chemically analyzed. This preliminary test work provides valuable information which may be used for large-scale testing in a commercially sized RHF.IntroductionThe ITmk3 process upon which this paper focuses was developed by Kobe Steel in its research facilities [l]. After pilot testing at Kobe Steel's Kakogava Works in 1999-2004 the pilot demonstration plant was built and operations were successfully carried out by Mesabi Nugget joint venture in 2002-2004. Steel Dynamics put into operation the commercial plant at the Mesabi Nugget site in Hoyt Lakes (Minnesota) in 2010. Results were consistent with nugget characteristics confirming ITmk3' s flexibility with respect to raw material inputs. At the same time, no research in the field of nugget from the Ti-V magnetite bearing ore with high content of Ti02 and Alz03 has been done. It is well known, if a lot of Ti02 and Alz03 enter the blast furnace, slag becomes viscous. The viscous slag is obstacle for stable operation of the blast furnace. Besides, high content of Alz03 raises the melting temperature of gangue minerals disturbing the coalescence of reduced iron to the nuggets."

Jan 1, 2013

By Shuo Wang, Yu Wang, Bing Xie, Rui Tang, Hong-Yi Li, Kun Wen

"During present converter vanadium extraction process, phosphorus could not be removed from hot metal due to absence of CaO in slag though it is an efficient way for vanadium extraction. In order to improve the phosphorus remove and produce CaO-containing vanadium slag, which could be directly used in subsequent roasting process, during the converter vanadium extraction process, lime dissolution in FeOx-Si02-V203-Ti02 slag was investigated by using a rotating cylinder technique and the slag-lime interface was characterized by SEM/EDS. Results showed that changes in the slag chemistry and phase compositions during the lime dissolution process were similar to that in CaO-Si02-FeOx based slag during the BOF process. The V and Ti in the slag were expected to diffuse into the lattice of2CaO·Si02 solid solution, which formed a rather thinner layer in thickness at the slag-lime interface than that in BOF process, leading to improvement of lime dissolution in the slag.IntroductionVanadium is important material that widely applied in industries. The traditional technique to extract vanadium was to leach vanadium after sodium salt roasting. However, the sodium salt roasting process has several problems including lower yielding rate[!] and environmental pollution[2]. Therefore, the more environment-friendly technique of calcium roasting[3-4] was proposed. In order to increase roasting efficiency of vanadium slag, it is essential to study the dissolution/reaction mechanism between lime and vanadium slag. Many investigations about the dissolution reaction of lime in molten slag have been carried out from the standpoints of rapid slagging to De-Pin steelmaking process[5-6]. However, their studies were focused on BOF slag and the reaction mechanism between solid lime and slag containing vanadium has not been reported yet. In present work, the dissolution process was studied with rotating cylinder technique and the reaction interfaces were observed and analyzed by SEM/EDS to elucidate the dissolution mechanism of lime in vanadium slag. This work was supported by National Natural Science Foundation of China No. 51090382."

Jan 1, 2013

By Gerald Onyedika, Tochi Onwumere, Martin Ogwuegbu

"The kinetic study for the leaching of iron from cassiterite ore in KOH solution was studied. The effects of KOH concentration, particle size and reaction temperature on the leaching rate of iron were also examined. The results of leaching studies showed that the leaching of iron from cassiterite ore in KOH solution is significantly influenced by the reaction temperature, KOH concentration, and decrease in particle size. The study showed that 90.62% of iron ore was leached in 8M KOH solution at 80°C within 120 minutes. The experimental data were well evaluated using the shrinking model for surface chemical reaction and diffusion control through the product layer. The activation energies for the iron ore dissolution using the two models were calculated to be 32.06KJmor1 and 97.97 KJmor' respectively.IntroductionIn recent times, there has been increasing attention on the kinetic study of mineral dissolution. In most of these studies, the experimental results were analyzed with a suitable shrinking core model under the assumption that the ore is a homogeneous spherical solid phase [1-4]. A study of the dissolution kinetics of a Nigerian cassiterite ore by hydrochloric acid showed that increase in the hydrochloric acid concentration is accompanied with increase in the amount of cassiterite ore dissolved at various times [4]. The optimal concentration was found to be 4.0M HCl, after which there was a decline in the amount of the ore dissolved, which showed that the concentration of the reagent has a significant effect on the leaching rate of the ore. Also in studying the effect of stirring speed on the rate of cassiterite ore dissolution while keeping other conditions constant for 120 minutes, the result showed that the rate of cassiterite ore dissolution was dependent on the stirring speed over a range of 0 to 630 rpm. Above 360 rpm, the stirring speed no longer had any effect on the solid dissolution. The dissolution rates of cassiterite were analyzed using a suitable shrinking model. The results showed that the reaction was controlled by the diffusion of tin through the porous product layer, a reaction order with respect to hydrogen ion concentration of 0.92 M and activation energy of 50.05KJmor'. In another kinetic study on the leaching of a low grade niobium-tantalum ore with concentrated KOH solution the effect ofreaction temperature, KOH concentration, agitation speed, particle size and alkali-to-ore mass ratio on the dissolution rate of niobium were examined [5]. The result of niobium leaching from low grade niobium-tantalum ore with concentrated KOH, solution at different agitation speeds showed that the dissolution rate increased with increase in agitation rate. In the case of particle size effect, the results show that small particles require much shorter time for complete dissolution than the large ones."

Jan 1, 2013

By Ximeng Li

The entries that are subjected to dynamic pressure are much more difficult to maintain due to repeated disturbance. A case study of an entry stress distribution was performed using the FLAC3D program. By analyzing the distribution of stress field around the entries, this paper provides guidelines for entry support design in the lower (#16) seam subjected to the repeated disturbance from longwall mining in the immediate overlying (#17) seam, 72ft (22 m) above. The results showed that there was stress superposition inside the barrier pillar in the lower seam, 15ft (5m) to 45ft (15m) deep, during development. The influence zone of the front abutment pressure in the upper (#16) seam was about 100ft (30m) outby the faceline. The stress-relieved zone was from 0 to 100ft (30m) inby the face. The area further inby the face (i.e., 230 ft (70 m) inby the face) was within the gob compaction zone. Along the face advancing direction, the affected zones of the entries in the lower (#17) seam that were subjected to the dynamic pressure from longwall mining of the immediate overlying seam could be divided into four stages: pillar development stress stage, front abutment pressure stage, unstable gob stage, and stable gob stage. Those entries within an area from 100ft (30m) outby to 100ft (30m) to 230ft (70m) inby the faceline should be reinforced with special supports. The numerical modelling matched the monitoring results well.

Jan 1, 2013

By Duan Xin-hui, Wang Xin, Peng Jin-hui, C. Srinivasakannan, Zhang Li-bo

The work attempts to optimize the process of preparation of modified semi-coke from semi-coke using phosphoric acid (H3P04) as the activating agent using the response surface methodology (RSM). The influences of three major dependent variables, the impregnation ratio, activation time, and activation temperature were assessed on the independent variables yield and the iodine number. The empirical relationship between the dependent and the independent variables were established using the quadratic response surface models, which were utilized to optimize the process parameters. The significance of each of the parameters and interaction among the parameters on the independent variable was assessed based on analysis of variance (ANOVA). The process variables were varied within the range of impregnation ratio (IR) from 1.5 to 4, activation time from 30 to 90 min and activation temperature from 550 'C to 650 'C. The optimized process conditions were estimated to be an IR of 2.29, activation time of 32 min, and an activation temperature of 605°C respectively using the process optimization tool. The BET surface area of modified semi-coke of the optimized sample was estimated to be 915m2/g, with the pore volume of0.71cm3/g, with an average pore diameter of 3.09 nm, with micropore volume fraction being 52.36%. The scanning electron microscope (SEM) images were utilized to visualize the surface pore structure.

Jan 1, 2013