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By L. J. E. Hofer

THIS BULLETIN analyzes and summarizes research at the Bureau of Mines dealing with the preparation, properties, and reactions of iron carbides in the period 1948-60, part of which was sponsored by Wright Air Development Laboratories. The objective was to develop better catalysts for the synthesis of methane and higher hydrocarbons from hydrogen and carbon monoxide. The investigations resulted in the first adequate characterization of epsilon iron carbide, which later proved to be an important intermediate in the tempering of martensite in steel. At temperatures near 170° C, the carbon in carbon monoxide reacts nearly quantitatively with finely divided alpha iron to form an iron carbide in which the metal atoms occupy the positions of the close packed hexagonal arrangement with lattice parameters of ao=2.754 A and co=4.349 A. The carbide has a composition within 2 atomic percent of that required for the formula Fe2C, a Curie point of about 370° C, a specific magnetization of 160.4 ergs per gauss-gram Fe at 50° C, and a ferromagnetic moment of 1.70 Bohr magnetons. Epsilon iron carbide can be converted to chi iron carbide by thermal treatment at 343° C for about 70 hours. The chi iron carbide so formed has a Curie point of 247° C, a specific magnetization of 142.5 ergs per gauss-gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 5.5 Bohr rnagnetons per iron atom. Direct synthesis of this carbide from carbon monoxide at 240° C indicates a composition within 7 atomic percent of that required for Fe2C. Chi iron carbide can be converted to cementite at 550° C in about 315 minutes. The theta iron carbide so prepared has a Curie point of 210° C, a specific magnetization of 147.3 ergs per gauss gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 3.9 Bohr magnetons per iron atom. Pure chi iron carbide reacts to form theta iron carbide by the elimination of free carbon. In the presence of an excess of free iron in intimate contact with the carbide, chi iron carbide reacts with the free iron to form theta iron carbide. The second reaction proceeds at an appreciable rate at 320° C and can be used to snythesize finely divided theta iron carbide with no free-carbon impurity at low temperatures. The ease of the reaction in the presence of free iron suggests that chi iron carbide is an intermediate in the tempering of epsilon iron carbide to theta iron carbide as it proceeds in steels. Experiments on carbon steel show that the magnetic moment of the iron atoms in martensite is about 2.2 Bohr magnetons per atom, a value approximately the same as that of the iron atoms in alpha iron. The Curie points of epsilon iron carbide, chi iron carbide, and theta iron carbide were found -in various specimens of tempered steel to be 10° to 20° C lower than normal values. This shift is probably the result of manganese in solid solution. Preparations of various compositions of epsilon iron carbonitrides show many effects of extensive isomorphism between epsilon iron carbide and epsilon iron nitride. The action of carbon monoxide on finely divided alpha iron at 400° C results in free carbon deposits containing filaments about 0.1 micron in diameter and several times as long. The filaments are characterized by nuclei of dense material located midway from each end of the filament. Although carbiding to near completion at 240° C over periods of about 300 hours produces a preparation containing no appreciable percentage of epsilon iron carbide, very brief periods of carbiding of the order of a minute result in the formation of detectable epsilon iron carbide even at temperatures as high as 325° C. The data indicate that epsilon iron carbide is an intermediate in the formation of chi iron carbide during its formation from carbon monoxide in the gas phase. Attempts to convert cementite to chi iron carbide by cold work increased the Curie point but did not change the X-ray powder diffraction pattern.

Jan 1, 1966

By Emad W. Shublaq

Contractual site plans are implemented for executing pile foundations (5 x 5) at segmental concrete bridge. Project schedule demands have forced the contractor to find out the most economical procedure in achieving the goal. This paper presents a site management technique which is applied by the Contractor. This was found to be fruitful and as much as 60% saving was gained.

Jan 1, 1992

By D M. Menne

This paper is intended to give a general review of current gold extraction technology for free-milling or non-refractory auriferous ores. Fundamental process concepts and some of the differences between the current technologies is referred to. Typical flowsheets and layouts are provided and it is demonstrated that technology for extracting free-milling gold is relatively simple. For environmentally sensitive areas such as encountered in New Zealand relevant cyanide decay and destruction technology is also discussed. Brief mention is made of some likely future innovations. Finally reference is made of New Zealand's previous significant contribution to gold extraction technology. These contributions were pioneering ranging from the cyanide leaching of gold to adsorption by carbon and precipitation by zinc. New Zealand has not allowed its potential gold projects to develop at a rate commensurate with the rest of the world thereby stifling its renowned innovative approach in this technology. It is time for New Zealand mining to recognise its unique opportunities in developing gold extraction technology and again take a rightful place in leading the way.

Jan 1, 1986

By C. R. Summers, J. N. Murphy

In response to the Coal Mine Health and Safety Act of 1969, mandatory noise standards have been developed that specify time-noise limits of mine personnel exposure. Most affected by elevated noise levels is the pneumatic roof bolter operator, both in terms of levels near or in excess of 115 dbA and in terms of length of exposure. Therefore, the principal emphasis of this Bureau of Mines report is on pneumatic drill noise control. It is not the intent of this report to suggest any drill redesign; instead, methods are suggested to reduce the noise level by complementing existing machines. An integral muffler system and a separate muffler system were tested in an attempt to lower pneurnaric drill noise levels. Pneumatic drills, when new, operate at about 115 dbA when drilling in sandstone. Using the drill muffler systems, it was possible to decrease the noise level of a 115 -dbA s rope drill to approximately 100 dbA.

Jan 1, 1974

By Harry: Lobb Verakis

Mining operations have made tremendous strides in improving the safety of blasting as shown by the significant and continual decrease in fatalities and serious injuries. Advances in blasting technology and blasting practices have played a significant role in reducing fatalities and injuries. However, even with the decline of fatalities and injuries blast area security continues to be by far the leading factor in blasting accidents. Even though there continues to be an increase in the use of industrial explosives and blasting agents in the U.S.A., the decline in fatalities and injuries from blasting accidents has persisted.

Jan 1, 2010

By Y R Fu, D R. Xu, C J. Wu, G C. Hu, H Chen

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Hainan Province (Hainan Island) in South China hosts numerous Mo-polymetallic ore deposits that are genetically related to Cretaceous granitoid intrusions. Laser ablation inductively coupled mass spectrometry (LA-ICP-MS) zircon U-Pb dating and molybdenite Re-Os dating reveal three metallogenic episodes: the late Early Cretaceous (ca 112 Ma), the late Early to Late Cretaceous (ca 95–106 Ma) and the Late Cretaceous (ca 72–89 Ma). The third mineralising episode might represent the youngest Mo mineralising event in East China. Results from this study demonstrate that Mo mineralisation on Hainan Island occurred under an extensional setting that was prevailing in the late Mesozoic (ca 180–67 Ma) in South China, which was likely due to the slab rollback of the subducted palaeo-Pacific plate beneath the South China continent.CITATION:Xu, D R, Hu, G C, Wu, C J, Fu, Y R and Chen, H, 2015. Geology and geochronology of the Mo-polymetallic ore deposits in Hainan Island, South China, in Proceedings PACRIM 2015 Congress, pp 645–648 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By John C. Holtz

Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in mines is analyzed after blasting, aid in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in

Jan 1, 1940

By John C. Holtz

Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in nines is analyzed after blasting, aid in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in

Jan 1, 1940

In common with general experience in the iron-making industry overseas, Australia has in recent years suffered a deterioration in the physical quality of her iron ores in their suitability as a direct blast furnace feed. The increasing amounts of fines and the more friable nature of lump ore, especially in the ore from the Cockatoo Island deposits in Yampi Sound, Western Australia, have focused attention on problems of ore preparation and agglomeration, particularly sintering.Although very small pilot scale Dwight-Lloyd type sinter machines were operated at the steel-making centres at Newcastle and Port Kembla during World War II, no sizeable capacity was installed, so that ore was charged to the blast furnaces almost entirely unscreened, and the resultant flue dust was stockpiled.Towards the close of the war, the pilot plant at Newcastle was replaced by a small machine, adjacent to the flue dust stockpile, with a rated capacity of some 20 tons per hour. After approximately five months of part-time operation, this plant was closed down in January, 1945. Production was not resumed until December, 1950, when, due to a temporary ore shortage, it was decided to supplement available ore with sinter produced from the large flue dust stocks of about 300,000 tons. In spite of mechanical and process difficulties, inherent to the design of the plant, operation was continued on a two-shift basis, with several shutdowns for extensive overhaul and plant alterations, until September, 1954, when production was put on a three-shift basis. Addition of Yampi ore fines to the sinter machine burden was not commenced...

Jan 1, 1957

By Robert E. Schock, Eric J. Risberg

"Less than 20,000 years ago, the last of the glaciers retreated from the Chicago region. They left behind sheets of glacial clay till underlain by dense, over-consolidated till (“hardpan”) below which is the limestone bedrock, found about 100 ft (30.5 m) below street level. The most notable feature in this profile is the unusually soft clay till that has historically been called “Chicago Blue Clay.”But the founding fathers of Chicago really didn’t care about what was under the ground. They recognized the importance of the city’s location as a potential trade and transportation hub. With access to the East through the Great Lakes and access to the West through the Mississippi River system, the viability of the city was evident. Chicago’s population grew rapidly. The city continued to grow through the Civil War years, but was dealt a devastating blow in 1871 by the Great Chicago Fire, leaving the city in ruins. The Birth of the SkyscraperAfter the cleanup of the Great Fire came the first real building boom in Chicago’s history. During this era, buildings were generally founded on shallow footings bearing on sand or clay. Many multistory buildings were constructed between 1880 and 1890 on spread footings. The first tall buildings were constructed with load bearing masonry walls. These early tall buildings suffered significant settlement as the soft clay underwent consolidation.The Home Insurance Building, built in 1885, was 12-stories tall and is generally acknowledged to be the first “skyscraper” in the U.S. It was the first building constructed with an iron skeleton frame instead of load bearing masonry walls. Spread footings were used under the interior columns in an effort to better distribute the loads, but the building still experienced large settlements.Construction began for the Monadnock Building in 1891. The 17-story building was built using load bearing walls 7 ft (2.1 m) thick, supported on rail-grillage footing foundations. When completed in 1893, the Monadnock Building boasted the title “World’s Largest Office Building.” The total building settlement over the past 125 years has been measured at over 20 in (0.51 m). The engineering community in the late 19th century observed settlement, but did not yet understand the process of consolidation of the soft clay beneath the city. During this time, many of the new buildings required structural repairs during and after construction; the problem was especially acute in buildings where highrise towers joined lower podium structures."

Jan 1, 2016

By Austin Metz, Kevin Stanton, Ramin Motamed

"A recent study calibrated Load and Resistance Factor Design (LRFD) resistance factors for local soil conditions in the Las Vegas Valley. As a part of this calibration, an extensive database of drilled shaft load tests and associated subsurface soil information were collected and compiled. This database, deemed the Nevada Department of Transportation Deep Foundation Load Test Database or NDFLTD, was designed with the presentation of load test data, the subsurface soil conditions, and the spatial distribution of the data in mind. In addition, the NDFLTD was developed in a way that allows additional data to be added as it becomes available. As such, the rules of database normalization were followed to allow for additional and different types of data to be added to the database and reports. Microsoft Access was chosen to present the data because it is easily accessible to anyone with Microsoft office software, it has a quick learning curve, and it has the ability to present a relational database. The largest obstacle faced when creating the NDFLTD was normalizing the data used in the LRFD calibration, with the goal of reaching the 5th normal form.INTRODUCTIONLRFD is based on statistical performance of engineering components, as opposed to the more traditional Allowable Strength Design (ASD), which divides the strength of a component by a safety factor. Calibration of resistance factors for LRFD requires a robust statistical analysis of past performance. For drilled shafts this requires a database of full scale load tests (Abu-Hejleh et al. 2014). The FHWA developed the largest US based deep foundation load test database, deemed the DFLTD, collecting data from 1985 to 2003 when funds ran out (Abu-Hejleh et al. 2014). Recently, the DFLTD has been updated to modern standards (Petek et al. 2016). In October of 2007, the FHWA mandated state department of transportations (DOTs) to follow AAHSTO LRFD guidelines for their highway foundation designs (Abu-Hejleh et al. 2014). Since then multiple state DOTs have developed their own, region specific deep foundation load test databases. Florida has a long history of developing databases for deep foundation LRFD resistance factor calibration, with the two main databases being the FL database, and The Deep Foundations Database (Abu-Hejleh et al. 2014). Iowa developed a Microsoft Access based database in 2014 (Garder et al. 2014). Oregon developed a database compiling pertinent data from the DFLTD, Florida DOT’s Deep Foundation Database, as well as from other databases (Smith et al. 2011). Illinois developed the “International Database” for static and dynamic reliability based calibration (Long et al. 2009). Louisiana developed a database for LRFD Calibration of driven piles in 2009 (Abu-Farsakh et al. 2009). The California Department of Transportation has its own internal foundation database, which is housed within the Foundation Testing Branch archive (Smith et al. 2011). In 2016, the Nevada Department of Transportation (NDOT) presented its own LRFD calibration for the Las Vegas Valley (Stanton et al. 2017), and the NDFLTD was developed as a part of that project (Motamed et al. 2016)."

Jan 1, 2017

By G. A. Kosick, C. A. Harris

"Metallurgy at the Polaris Mine is approaching an impasse, with lead and zinc concentrate grades and recoveries approaching their theoretical maximums. In an effort to increase productivity, plant throughput and operating material costs became a major focus of milling personnel.one method of increasing plant throughput was to minimize flotation circuit upsets by; standardizing operating strategy, decreasing control action response time of operators, increasing training of operators, and providing a more available decision support system for operators.To achieve these goals, Polaris personnel decided to utilize expert system technology to develop a real-time process controller for the flotation circuit which would be capable of justifying its actions to operating personnel.This paper describes the procedures followed in constructing the first process controller in the mineral industry which is based on the principles of Artificial Intelligence.IntroductionThe Polaris Concentrator was constructed in 1980 on a barge in Trois Rivieres, Quebec and towed to its present location on Little Cornwallis Island, North West Territories, about 1450 kilometers from the North Pole. The plant presently treats about 2,800 MTPD of new feed with average feed grades of 3% Pb, 13% Zn and 5% Fe. Current production averages 36,000 tonnes of lead concentrate and 220,000 tonnes of zinc concentrate annually.In an effort to increase the efficiency of the concentrator, the decision was made to implement an innovative control system on the flotation circuit. This system would embody and utilize heuristics ""rules-of-thumb"" gained from operators to make on-line process decisions. It would also justify these decisions on a demand basis."

Jan 1, 1988

By C. Larsen, E. Goodwin, E. Konigsmann

"This paper describes the development of an innovative effluent treatment process for cyanide and heavy metal removal from tailings wastewaters at Hemlo Gold Mines Inc. Golden Giant operation.The importance of minimizing dissolution of contaminants in the gold leaching circuit is discussed, as well as using recycled water in milling circuits to the fullest extent possible. Finally, a brief description of the role of natural cyanide degradation in the tailings pond is provided.Emphasis is placed on the need for overall water quality management to ensure minimum effluent treatment process costs and complexity while producing excellent quality effluents.1.0 INTRODUCTIONHemlo Gold Mines Inc. owns and operates its Golden Giant Mine located forty kilometres east of Marathon, Ontario. The Golden Giant mine is one of three gold operations exploiting the large gold orebody located in the Hemlo area. The milling facilities include two stage secondary crushing, three stage, closed circuit ball mill grinding with no reagents, thickening, cyanide leaching and carbon in pulp gold recovery unit operations. The average throughput is 3000 tonnes per day of 10 grammes per tonne gold ore. Figure 1.1 shows a schematic flowsheet of the operation."

Jan 1, 1989

These proceedings consist of papers presented at two Bureau of Mines Technology Transfer Seminars in early 1980 for the purpose of disseminating recent advances in mining technology related to surface coal mining reclamation.

Jan 1, 1980

By Albert Musschoot

The expanding applications of vibrating feeders for controlling the flow of bulk materials, and their adaptation for processing requirements, have developed considerable interest in stockpiling and reclaim systems. The general design of these units consists of a material transporting trough, or platform, driven by a vibratory force system. Design flexibility and variety is limited only by engineering ingenuity. The basic motion of the vibratory trough, or work member, is a controlled directional linear vibration that produces a material tossing or hopping action. Material travel speeds vary from 0 to about 30 m/min, depending on the combination of frequency, amplitude, and slope vibration angle.

Jan 6, 1981

Characterisation of Manganese Ores

Sep 13, 2010

By Bruce I. Thomas

[THIS PAPER, tine of a series on placer ml n in iii Alaska, describes mining methods and gives unit costs at operations where hydraulic and mechanical excavation equipment is used with nonfloating washing plants. The mining methods described were developed during the last 30 years to copy with conditions peculiar to arctic and subarctic regions arid are now used by a large segment of the placer mining industry in Alaska. The operations described have been classified if m ii into three main categories: Those having sluices at a bedrock level, those having sluices above bedrock and those having mobile nonfloating washing plants (dryland dredges). Diesel-powered bulldozers and draglines convey or clevate gold-bearing gravel to the sluices, remove tailings, and strip waste gravel and other overburden. Diesel-powered centrifugal pumps supply water foe sluicing and hydraulic stripping. Detailed descriptions and unit cost arc presented for 14 operations to illustrate the numerous arrangements udder the first 2 categories.]

Jan 1, 1959

By L. J. Barnes

The process for bio-remediation of sulphidic slag (BROSS) operates at 45 degrees C in a neutral (pH 7), aerobic aqueous environment in which sulphide in the slag is converted to sulphate. A two-stage version has been developed that involves quantitative chemical pre-oxidation of total sulphide to thiosulphate, followed by complete biooxidation of thiosulphate to sulphate. Ferric hydroxide, also produced, acts as a flocculant in the bioreactor effluent, concentrating heavy metal precipitates in the thickener as a sludge which can be returned to the smelter. The process has a high sulphate production rate and low acid and nutrient consumptions. Microorganism growth is the rate-limiting stage, requiring a minimum liquid residence time in the bioreactor of about 7 h. Although large quantities of oxygen are needed, sufficient gas mass transfer can be attained in an air-lift reactor. Products are an aqueous stream containing sodium sulphate with only trace levels of toxic heavy metals and a benign, toxic metal-containing sludge

Jun 18, 1905

By D. Lawrence, H. Lawrence, G. Saevil

Plant operators in the mineral processing industry have been implementing expert systems for several years now, with the intent to increase production and reduce costs. Most systems have been installed on grinding circuits of some type and have proven that the technology is viable in that application. However, few applications on other processes have been attempted for various reasons, such as lack of reference sites, complexity of the process, lack of suitable measurements and lack of confidence in the technology. The successful application of an expert system on an Alumina Calcining kiln is the first such application in the West Indies Alumina Company (Windalco), and demonstrates how this technology can be successfully applied to other processes. The key objective of an expert system is to optimize the process. To achieve this the process must first be stabilized, followed by optimization of the operating parameters. The steps taken by this expert system to optimize the process are: • Check for abnormal conditions and deal with them using a prioritized set of special actions. • Use a selection of rule blocks to stabilize the process. • Once the process is stable, achieve additional benefits through further optimization of the process. The potential benefits that a user can expect to achieve through installing an expert system can be assessed on the basis that performance will improve from that of an "average operator" to that of the "best operator" performing at his optimum for 24 hours a day, every day. The quantifiable process benefits include: • Increased production • More consistent product quality • Reduced operating costs • Reduced standard deviation of key variables • Consistent plant operation The success of this project was measured in several ways: project implementation, realised economic benefits, and realised non-economic benefits. With a commitment to maintain the system over the long term, the longevity of the system is assured and will become an important part of the Alumina Calcining control strategy at Windalco. This paper discusses the various phases of implementing the ABB Expert Optimizer expert system, what the benefits were and the procedure that is in place to maintain the system to ensure continued long term success.

Jan 1, 2002

By Robert D. Perry

This report describes methods of reclaiming abandoned or inactive tailings ponds and dams. The investigated sites were selected tailings deposits adjacent to metal mines in the southwestern United States and the Pacific Northwest. The basic data developed for each site consisted of the following: a review of existing literature; a site visit that included sampling of the tailings and surrounding materials; laboratory and engineering studies; and development of reclamation plans. Laboratory tests determined the gold and silver content of each tailings deposit and the chemistry of the tailings and surrounding materials. Reclamation plans that include approximate costs were developed for five tailings deposit sites. These ranged in size from 52,000 to 103,000,000 tons. Our conclusions on the remining potential of each site are based on the tailings assay and other technical data. This study concludes that remining as a reclamation tool is feasible at certain sites. Included in this report is a remining program as part of the overall reclamation plan for two sites. Our preliminary results indicate that remining as a reclamation tool is feasible for only one of them.

Jan 1, 1981