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By Tony Lipiec, Ian Orford

"A key part of plant design is the selection of the design tonnage which is the hourly tonnage target that the equipment selection is based on. Its selection is critical for ensuring that the nominal tonnage which is critical to the financial performance of the project will be met. With deposits being developed at lower grades, higher tonnages and a higher degree of hardness variability, it is essential to ensure that the design process selects the comminution equipment which will be able to deal with the impact of this ore quality variation.Ore hardness and its variance are key factors to be taken into consideration for the selection of the design tonnage. It is well accepted that for the nominal or name plate tonnage to be consistently achieved, it is necessary to base the design tonnage on a hardness value greater than the average ore hardness of the deposit to be mined. The question is how much greater should this design value be to ensure that the nominal tonnage is met to the satisfaction of the project financial model. Standard industry practice is to set the design tonnage by:1. Select an ore hardness percentile that is greater than the average ore hardness to be the basis of the nominal tonnage. Typically either the 75th or 80th percentile value from the data set will be selected.2. Selection of a design factor to multiply by for determining the design tonnage, i.e. the design tonnage = tonnage (based on the average ore hardness) multiplied by design factor.This paper discusses the selection of the design ore hardness through the use of modelling or the use of a design factor. It further shows the impact of ore hardness variance on the capacity of the process and its ability to meet the nominal tonnage. Insight is provided as to what ore hardness percentile value should be selected balancing the shortfalls of tonnage for ores harder than the design value versus the above target production achieved for ores softer than the design ore hardness."

Jan 1, 2016

By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By Y. Vermeulen, J. Simoes, P. Guillo, A. Di Donate

New design techniques have been developed to optimize continuous casting (CC) refractory components. The overall objective is to increase CC productivity as well as steel quality by using optimized refractory from tundish-to-mold. These techniques allow the prediction of steel and refractory chemical interactions and, thus, steel chemistry evolution as well as build up and corrosion occurrence. Specific fluido-dynamic models (CFD) have also been developed to better take into account the physical parameters at the steel/refractory interface and to optimize steel flow control. The CFD model can be coupled with refractory chemical interactions to simulate steel chemical evolution. These two different approaches result in shape and material modifications. They are completed by dedicated thermal stress analysis in order to improve thermal shock resistance. The mechanical FEA evaluations take into account specific mechanical behavior of refractory components as well as high temperature evolution of their properties.

Jan 1, 2004

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

Magnetic separation of precipitated magnetite as iron resources in copper slag is one of the potential effective ways to recycle the slag. It is preferable to convert molten fayalite slag after copper smelting process to magnetite slag via oxidation. With a TTT (Time-Temperature-Transformation) diagram, the crystal composition of the slag obtained after air isothermal oxidation could be estimated through a designed cooling path. The crystallization behaviors concerned with molten oxidation was studied for better understanding of the trade-off relationship between magnetite and hematite during molten heat treatment. Moreover, a brief consideration was implemented of the reaction mechanism.

Jan 1, 2014

By W. G. Jeffery

"The mining and mineral industries have been, and remain, a major component of the Canadian economy. There are approximately 560 producing mining establishments of which there are some 130 metal mines and an equal number of non-metal mines, the balance being quarries for stone, sand and gravel. For 17 metals and minerals, Canada ranks within the top five as a world producer. There are 29 metallurgical plants. Employment in mining, smelting and refining was about 150000 in 1990. Mineral production, including coal, is about $20 billion. Exports up to the metal stage amount to $15 billion providing a positive trade balance of some $10 billion.The producing industry has a wide diversity of products. The companies range from small single mining operations to large multinationals. In terms of technology the industry has always been in the forefront of cost-effective practice, either using home-grown innovation or freely importing technology from around the world,The Mining Industry Technology Council (MITEC) makes an annual survey of the exploration and R&D expenditures of the senior mining industry that is the mining companies that are involved in mineral production from their existing mines. It does not include those companies solely involved in exploration using funds raised through equity sales.Table 1 shows the actual R&D and exploration expenditures as a per cent of sales. R&D shows a rising trend since 1988although the drop in value of output due to lower prices must be recognized as contributing to the increase. The point about this compilation is that the mining industry re-invests some 4070 of its sales in both exploration and R&D in order to sustain itself. Exploration for the renewal of metal inventories for future mining is a process unique to mining. It is not classified as R&D, and the necessity for this investment goes unrecognized by those who state that the industry does not do enough R&D."

Jan 1, 1993

By M. E. Moraes Castanho de Almeida, A. Ribeiro Cotri

Recovery of cobalt to produce high grade cobalt sulfate from cobalt concentrate by leaching and solvent extraction was investigated. The PLS typically contains Co 10g/l, Mg 2g/l, Fe < 10ppm, Mn < 200ppm, insolubles <100ppm and is extracted with 20wt% Cyanex??272. The typical strip solution contains Co 60g/l, Mg 0.03g/l, and was sent to the current process for the production of cobalt sulfate heptahydrate. The cobalt yield of the plant with two extraction steps was 92%, with three steps was 97% and with four steps 99%. The extraction stage used the concept of "scrubbing" in a countercurrent system. In the first stage of extraction pH was 4.8, and in the last stage of extraction pH 5.5 to promote the exchange of magnesium in the organic with cobalt contained in the PLS. Following the extraction, when using two scrubbing stages, Co/Mg selectivity between of 2,000-3,000 was obtained, and with three scrubbing stages, selectivity was greater than 6,000. The desired selectivity was reached when using a scrubbing configuration with O/A ratio of 10:1. The typical cobalt sulfate heptahydrate had the following composition: Co 20wt%, Mg < 0.01wt%, Fe < 5ppm, Mn < 0.01wt%, Cu < 0.01wt%, Zn < 0.01wt%.

Jan 1, 2014

By René Dufour

Jusqu?à son acquisition par MM René Dufour et Alain Robin en 1994, les claims miniers et les droits de surface de la propriété étaient détenus depuis 1953 par la société Québec Columbium, une filiale de la socité américaine Kennecott Copper qui y a réalisé d?importants travaux miniers. En 1995 la compagnie NIOCAN inc. fut incorporée; ses actions furent inscrites à la bourse de Montréal en 1997, et à la bourse de Toronto en décembre 1999. Jusqu?à maintenant, NIOCAN a investi plus de 7 millions de dollars dans le développement de sa propriété minière de niobium située à quelques 40 kilomètres au nord-ouest de Montréal. Le haut rendement économique des deux gisements principaux que compte exploiter la compagnie, le S-60 et le HWM-2, a été établie par des études de faisabilité effectuées par le consortium Met-Chem/SNC-Lavalin. La mission que s?est donnée NIOCAN inc. consiste à mettre en production ses deux gisements et à devenir ainsi productrice de ferroniobium dans les plus brefs délais. Figure 2 Le projet est présentement à un stade avancé d?obtention du certificat d?autorisation du ministère de l?Environnement. À plus long terme, la compagnie compte aussi exploiter les sous-produits de ses gisements (apatite, forsterite, magnétite, calcaire et terres rares).

May 1, 2003

By A. C. Stevenson

"The most common theory is that, since thyristors, diodes, and insulated gate bipolar transistors (IGBTs) are “solid state” they will live forever. This is not so. They have wear-out mechanisms (e.g. insulation) and other mechanical parts such as motor bearings. These wear-out phenomena can be easily calculated. In this paper we will look at some of the failures and the failure rate of thyristors in power converters to see what affects them and to see what improvements can be made. If converter failures do occur, some simple forensic engineering steps will show if this is the root cause of the problem.IntroductionLook at the general failure rate curve for thyristors, diodes, gate turn off devices (GTOs) and IGBTs shown in Figure 1. We see that there is an initial high failure rate due to manufacturing defects, application problems, and drive start-up stresses that lasts for a few weeks. This is followed by a long period of (hopefully) several years with a relatively low but very slowly rising failure rate. At the end of this period, the devices start to wear out and the failure rate suddenly starts to increase rapidly over a few months. This signals the end of life for the devices in the system. We will start by looking at this end of life area."

Jan 1, 2000

"This paper discusses the use of risk assessment and risk management techniques within the Australian underground coal mining industry, within the context of geotechnical risk. The industry works within a pro-active, “enabling” legislative framework, where companies and management apply a range of risk assessment tools as part of their everyday management processes. Different geotechnical risk factors and approaches are reviewed, together with application examples – ranging from mine planning and design, operations, and accident investigations.A particularly powerful resource in each of the above stages of geotechnical management is the RISKGATE system. RISKGATE is an assembled “body of knowledge” structured under different topics across the Australian coal industry, of which three topic areas address rock mechanics issues for both the underground and surface mining sector. This paper will provide an overview of RISKGATE in the context of risk-based rock mechanics applications in underground coal mining."

Jan 1, 2015

By G. R. Baiden

"An Automatic Haulage Truck (AHT) has been developed for manless tramming of run-of-mine material in an operating mine. The AHT has a 70-ton capacity and uses an electric trolley system in combination with a computer control system to operate the vehicle. The purpose of the AHT was to provide a high capacity, high productivity material transfer system where conveyor belt applications are not immediately practical.The AHT project was started in 1983 at Inco Limited, Ontario Division as a result of the need for rapid material transport to match increased extraction rates resulting from bulk mining methods. The original concept was to use a continuous loader with the truck. However, in order to minimize development problems the truck project was considered a stand-alone project.The AHT project consisted of concept development, preliminaryand detailed design, manufacture, surf ace testing and mine implementation.The AHT was manufactured and ready for testing in 1988. At this point the truck was first moved onto the test track for debugging. This proved successful and in 1989the decision was made to install the AHT at Little Stobie mine on 2000 level. Commissioning of the system was started in 1990and at present a fully functional automated haulage system is in place at Little Stobie mine producing 3000 tons/day.This paper describes the project presenting results achieved to date."

Jan 1, 1992

By M. M. Papic

"This paper describes the Sasol coal liquefaction process, as used in South Africa. It covers coal supply, coal gasification, gas purification, Fischer-Tropsch synthesis, the major utility systems involved and the economics of the process.IntroductionThe Sasol coal liquefaction process is based on Fischer-Tropsch synthesis of liquid fuels from carbon monoxide and hydrogen, which are in turn obtained by gasification of coal with steam and oxygen. The process is shown schematically in Figure I.The first step in the process is coal preparation, in which the coal is crushed and screened to a 3-50 mm size for gasification on one side and to -3 mm size for steam and power production on the other. Oxygen needed for coal gasificatoin is produced in the air separation plant.Coal is gasified under pressure by steam and oxygen in the Lurgi gasification plant, where raw, impure gas is produced . The raw gas is first washed in a scrubber with a circulating gas liquor, heat is then recovered from it in a waste heat recovery boiler and the gas is further cooled for purification. Water-insoluble materials (tar oils) in the gas liquor are separated from aqueous solution and sent to tar refining for the recovery of tar products. The aqueous portion of the gas liquor goes to a Phenosolvan solvent extraction process, where phenols and ammonia are recovered. Water then proceeds to the effluent treatment plant.The scrubbed and cooled raw gas goes to a Rectisol gas purification plant, where all components other than hydrogen, carbon monoxide and methane are removed as completely as possible by absorption in refrigerated methanol. The acid gases (CO2, H2S) stripped from the methanol in the Rectisol unit are processed in a Stretford plant for recovery of sulphur. Regenerated methanol is returned to the process. The purified synthesis gas is passed to the fluidized-bed Synthol reactors, where Fischer-Tropsch synthesis reactions take place.The synthesis products are recovered in a product recovery unit as separate streams of decant oil containing higher-molecular- weight hydrocarbons, light oil comprised of lower-molecular- weight species, the aqueous stream containing water solubles, a C3/C4 stream, a C2 stream , a methane stream and a hydrogen-rich stream. Most of the hydrogen is recycled to the Synthol reactors; a major portion of the methane is reformed to hydrogen and carbon monoxide for recycle; the C2 fraction goes to an ethylene plant; and liquid streams proceed to the product refinery.The product refinery is used to upgrade and purify the Synthol products to specification fuels and chemicals.Sasol l, the first coal liquefaction plant in South Africa , was built in 1955. It is still operating and has a product output of about half a million tonnes per year. The Sasol II plant is in a commissioning stage and will be in full operation in 1981. It is about five times the size of Sasoll. It uses over 12 million tonnes of coal and produces more than 2 million tonnes of saleable products annually (1,2,3). The Sasol llI plant, which is a mirror image of Sasol II, is under construction and scheduled for completion in 1983."

Jan 1, 1981

By D. Chakravarty, B. Samanta, D. Ghosh

Autonomous robots are useful for 3D underground mine mapping to avoid human exposure to hazardous spaces. To prepare a precise mine map, a self-navigating robot must navigate an arduous path, avoiding obstacles and sensing the environment. A prototype laboratory-scale robot was built and evaluated through a mock-up in a test mine gallery. It was outfitted with a 2D laser scanner, a stereo camera for obstacle avoidance, and a high-precision, laser-based imaging and digitizing system for collecting 3D point cloud data. Various algorithms were used for scan matching to facilitate simultaneous localization of the robot for mapping.

Jan 1, 2014

By Marc Lavigne

"The Lac Knife graphite deposit was estimated, as part of a feasibility study, using a geostatistical ore reserve estimation method: ordinary kriging. Based on the geology and its interpretation, the results of a variogram study, and the statistical parameters of the grade distribution of the core samples and the composites through the mineralization, the deposit was divided into three separate zones (west, centre and east), and each of these zones was then analyzed and kriged independently.The geological ore reserve estimation results of ordinary kriging are compared to the results of a conventional method (sections) used previously. The two methods gave almost similar reserve figures. The conventional method provided a +2% estimation for tonnage and + 10% for grade because it ignored the spatial relation between sections and samples, and ordinary kriging gave a more accurate longitudinal definition of the deposit.Finally, the paper concludes with the advantages of proceeding with ordinary kriging, namely: higher flexibility (change of cut-off grade), better deposit resolution and enhanced selectivity for the design of the open pit.IntroductionWithin the context of a complete feasibility study for the Société d&apos; Exploration Minière Mazarin Inc., specialists of the Mines and Geology Division of Roche Ltd., Consulting Group, defined a modelling method appropriate to the graphite deposit of the Lac Knife property near Fennont. Many patterns were considered. Based on the geology of this deposit, the planned mining method, the statistical parameters of grade distribution and the variogram study, the process of reserve estimation retained was to use the ordinary kriging in a selective way. It was required because the geometry of the deposit is such that it was unthinkable to apply ordinary kriging without restrictions.This paper gives a detailed explanation of the observations and interrogations which led to the choice of this ore reserve estimation method, and the calculation procedure itself."

Jan 1, 1991

By Eric J. Grimsey, Don C. Ibana, David E. Grimsey

The segregation process as applied to nickel laterite ores involves the formation of gaseous nickel and iron chlorides which are subsequently reduced to form ferronickel on the surface of a solid carbon reductant. A fundamental study of the process has been carried out using limonite, nontronite and garnierite ores. The study highlighted the significant impacts that ore mineralogy and carbon addition have on the amount of nickel which is segregated rather than retained within the ore due to in-situ reduction. These important aspects affecting nickel recovery and the success of the process are discussed in this paper.

Jan 1, 2017

"In 1989, improved milling and recoveries resulted in a record production of 7 722 200 Ib Nb2P5 at the Niobec Mine. At the beginning of 1990, proven and probable reserves stood at 11 952 000 tons grading 0.65% Nb205. This year, the world steel market has slowed and as a result, niobium consumption is down. Consequently, production at the mine dropped 14% for the second quarter.IntroductionThe Niobec Mine is located approximately nine miles northwest of Chicoutimi, Quebec, (Fig. I). After ten years of production, the Niobec Mine is the only operating niobium mine in North America and the second largest producer of niobium in the world after Brazil.The Niobec Mine is a joint venture held equally by Teck Corporation and Carnbior. Teck Corporation operates the mine while Cambior is responsible for marketing and selling the niobium pentoxide concentrate (Nb2P5).The deposit was discovered in 1964 following an airborne radiometric survey in search of uranium. However, mining of the deposit did not begin until 1976. The initial production capacity of 1500 tons per day was increased several times to the present capacity of 2450 tons . The deposit is considered as an ample source of pyrochlore concentrate for at least 15 years at the present production rate.Niobium, also known as columbium, is a greyish-white metal used primarily as an alloy in various steels and other metals. The use of niobium in alloys heightens tensile strength and improves corrosion resistance while at the same time reducing the weight of the alloy. Niobium is also used in the fabrication of steel for the aerospace, automobile, and oil and gas pipeline industries. Although substitutes for niobium exist, their use often results in diminished performance and net cost increases."

Jan 1, 1990

By A. G. Roach

MILLING of Nova Scotia gold ores began in 1862 with arrastras and wooden stamps and has progressed to heavier stamps followed by tables and other forms of concentration for the recovery of the sulphides. Chlorination and cyanide leaching of the concentrates has been practised, and in 1936 the combined amalgamation and all-sliming cyanidation plant of Seal Harbor Gold Mines was built. It has since been found that it is not necessary to cyanide the full tonnage and now only the concentrates are being so treated. From his experience in this enterprise, the writer presents the accompanying flow-sheet and supporting comments. While he has not the temerity to maintain that it is the best or only flow-sheet for Nova Scotia gold ores, he feels that it warrants thoughtful consideration by members of the milling fraternity of the Province. THE ORE The gold in Nova Scotia ores occurs both free and intimately associated with sulphides-chiefly arsenopyrite. Much of the free gold is quite coarse and crystalline. This is especially true when it occurs in white quartz. When in the slate, it is usually in thin plates and scales, frequently coated and discoloured. The values bound up in the sulphides are not amenable to amalgamation and must be recovered by other methods-concentration, followed by smelting or fine grinding and cyanidation. While high freight and treatment charges apply on concentrates shipped from the Province to smelters, a considerable quantity has been so disposed of in the past. However, it is hoped that a customs cyanidation plant will soon become available to producers of these auriferous concentrates in Nova Scotia.

Jan 1, 1938

By B. Coupal, F. D'Hennezel

Sorption measurements show that peat moss has much stronger affinity for oil than straw, which is currently used. Microscopic studies of peat moss show a highly porous and fibrous material, and this property, associated with the phenomenon of selective absorption, had been used to absorb oil. Laboratory experiments show that peat moss absorbs up to eight times its weight of oil. Field tests have proved that peat moss can be an effective absorbent and can be used on a large scale.

Jan 1, 1972

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By T. Negeri, M. Boisclair

"A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. Fine grinding to a d80 of <65 microns was required to obtain acceptable separation of 92% of the contained total rare earth oxide (TREO) and niobium in half the feed mass. Whereas it was possible to obtain 85% of TREO in 28% of the feed mass through staged cleaning, it was demonstrated that at least 87% and 85% recoveries of TREO and Nb respectively could be achieved in 16% of the feed if the rougher-scavenger concentrates were calcined, quenched, reground to <25 µm and then magnetically upgraded. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this progress. INTRODUCTIONOut of the approximately 250 minerals known to contain rare earth elements (REEs), only about 60 of them contain REEs in significant amounts. Over 95% of the world’s rare earth oxides (REOs) are believed to occur in the form of three minerals (Pradip & Fuerstenau, 1991) namely bastnaesite (Ce,La,Y)CO3F, monazite (Ce,La,Nd,Th)PO4 and xenotime Y(PO)4. An estimated 51.4% of global REO resources are hosted by carbonatite deposits with the same three minerals as major constituents (Weng et. al., 2015). Any one of the REEs or commonly all of them can be found in these minerals (Ravnaas, 2010). As the demand for critical REEs increases due to the ever increasing applications in advanced technologies, many deposits containing other forms of REE minerals will have to be developed. REE minerals are extensively dispersed and intergrown with several oxides, silicates, carbonates, and phosphate minerals. Consequently it is possible to liberate them only at fine grinding and is thus difficult to separate and produce high grade rare earth mineral concentrates. Most of these minerals contain other important elements such as tantalum (Ta), niobium (Nb), uranium (U), and thorium (Th) in varied quantities. REE minerals in the same ore may exist as carbonates, fluorocarbonates, niobates, silicates, phosphates etc. in association with gangue minerals belonging to different mineralogical groups."

Jan 1, 2016