Molten Oxidation of Copper Slag for Magnetite Precipitation

Magnetic separation of precipitated magnetite as iron resources in copper slag is one of the potential effective ways to recycle the slag. It is preferable to convert molten fayalite slag after copper smelting process to magnetite slag via oxidation. With a TTT (Time-Temperature-Transformation) diagram, the crystal composition of the slag obtained after air isothermal oxidation could be estimated through a designed cooling path. The crystallization behaviors concerned with molten oxidation was studied for better understanding of the trade-off relationship between magnetite and hematite during molten heat treatment. Moreover, a brief consideration was implemented of the reaction mechanism.