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By D. G. Eskin

"It is well known that it takes some time for the solid phase to completely dissolve upon melting, especially inside the defects of insoluble particles, e.g. oxides. Until then the oxides remain active solidification substrates in the case of subsequent solidification. It is also known that ultrasonic melt treatment causes grain refinement through activation and dispersion of solidification substrates (one of the mechanisms) and also accelerates the dissolution of solid metal in the melt. In this study we combine these effects and demonstrate that the introduction of an alloy rod into the matrix melt of the same composition results in significant grain refinement, this effect being increased by the ultrasonic vibration of the rod. The achieved grain size is comparable to that obtained by a standard Al–Ti–B grain refiner. All samples were cast using a standard TP-1 mould to enable correct comparison. The effect of the temperature range of the rod introduction, as well as the effect of ultrasonic vibrations are discussed.INTRODUCTION The fact that by introducing solid metal into the melt one can achieve structure refinement is rather well known. As early as in the 1930s–1950s a series of papers and patents have been published, showing the benefits for grain refinement when dissolving solid metal in the melt before solidification (Danilov and Neimark, 1938; Scheil, 1956). Later on this way of structure refinement was developed further and dubbed “suspension casting” or introduction of “internal chills” (Madyanov, 1969; Zatulovsky, 1981). The solid metal was added in a form of cut wire, cut sheet, or powder, with the resulting grain refining, elimination of columnar grain structure in ingots and castings of steel, copper and aluminium alloys. The underlying mechanisms have been suggested as (1) rapid cooling of the melt due to the latent heat consumption upon melting of the solid metal with the resultant melt undercooling and (2) introduction of many solidification substrates in the form of crystal fragments and active non-metallic inclusions (Danilov & Neimark, 1938; Balandin, 1973). A number of patents have been filed where either the same solid alloy or a master alloy with additions (e.g. Ti for Al alloy) is introduced in the amounts up to 50% (typically less than 10%) into the melt close to the liquidus temperature (Schmidt, 1966; Talbot & Soller, 1973, Krupp, 1974; Bondarev, 1979). The main reason that this technique is not widely used in industry is the possible incomplete dissolution of the solid parts introduced into the melt with ensuing inhomogeneous as-cast structure and potential defects. Also the selection of the temperature range where the technology works the best is not clear."

Jan 1, 2018

By A S. Leitch

This paper is based on the accident prevention pro-gram carried out in the coal mines of Alberta. It defines the role of the Alberta Mines Branch and of The Work-men's Compensation Board, and relates how a safety pro-gram was initiated. The formation of the Alberta Class 1 Mining Safety Council is also described. The responsibilities of both management and the individual worker are then outlined, and the main features of a successful accident prevention program are delineated. T HE purpose of this paper is not to repeat generalities and platitudes about industrial safety, but rather to relate the experience of Alberta coal mines during the past number of years in their efforts to keep accidents to a minimum. It has been learned from experience that many basic principles are as sound today as they were 20 years ago. How-ever the complexities of modern mining methods and the modern man or miner have created problems that did not exist then.

Jan 1, 1964

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By T. P. Lim, N. K. Davé

"A modified accumulator method was devised to measure surface radon flux from porous media. It consists of a collector hood type of accumulator with a homogenizer pump and a pressure balancer. The latter was used to compensate any pressure changes produced during sample withdrawal and hence eliminate additional radon transport from the media. Errors resulting from radon back diffusion due to decreasing concentration gradient with time across the interface were also eliminated by measuring radon concentrations in the accumulator for two different periods of time and calculating the true radon flux, J(o), from the solution of a time-dependent radon transport equation in the absence of any pressure and temperature gradients.Core samples from the observation site were also withdrawn for laboratory determination of porosity, moisture content, bulk and grain densities, Ra-226 source concentration and the fraction of Rn-222 produced in the void volume. The data were used to calculate the radon diffusion coefficient for the media.Using the present method, the true value of surface radon flux for an abandoned uranium tailings pile was obtained as J(o) = 2020.2 mBq/m2/sec (54.6 pCi/m2/sec) compared to the value J = 1406.0 mBq/m2/sec (38.0 pCi/m2/sec) obtained by the conventional method. The bulk diffusion coefficient of radon for the media was obtained as 1.2 x 10-7 m2/sec.IntroductionRadon-222 (hereafter called radon) released from uranium mill tailings is a continuous source of environment radioactivity in terms of its transport as an airborne gas and its decay products. The particulate daughter products readily attach to aerosols or dust particles and can further be transported by various other environmental pathways. Typical radon release rates from existing tailings piles vary between 740 and 14,800 mBq/m2/sec (20-400 pCilm2/sec), depending on the nature of the tailings material, moisture content, etc. The United States Nuclear Regulatory Commission (NRC) is proposing radon release rates of 74 mBq/m2/sec (2 pCi/m2/sec) above that of background."

Jan 1, 1982

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By C. Barlow

The White Mesa Mill (WMM) began operating in 1980 as a regional processing mill owned by Energy Fuels Nuclear, Inc. Original mill design was for 656,000 Mtpa of U ore producing 1,250 tpa of U3O8 concentrate. Sustained market downturns delayed facility upgrades during most of the 1980s and 1990s. The new owners of WMM, Denison Mines, elected to advance the regional mill concept in 2007 with the modernization of these facilities. This paper details decisions taken and lessons learned in plant redesign, choice of leading-edge instrumentation, motor controls and process automation, training and some example benefits from process control stabilization.

Aug 1, 2010

By A. Longval, Q. Jiao, T. Shannon

In 2000, Xstrata Zinc (former Falconbridge Ltd.) Brunswick Smelter commissioned a modified lead blast furnace. Since then, efforts have been made to improve its operation in order to achieve optimal operation in terms of coke consumption, lead loss to slag, and improved environmental and hygiene conditions. This paper will review the important step changes in operational philosophy, undertaken since 2004, for the control of the blast rate, oxygen enrichment in blast, slag chemistry and charge level. Furthermore, a review of the improvements made in secondary materials consumed at the blast furnace will be made. This paper will also discuss the significant reduction of the frequency of accretion removal as a result of improved furnace operation.

Jan 1, 2008

This work illustrates the potential of two welding processes for joining AA1100-16 vol.% B4C metal matrix composite: laser welding process using a 4 kW Nd:YAG laser and Friction Stir Welding. A comparison is made between these two welding techniques in terms of microstructure and mechanical properties of welded joints. A large amount of brittle needle-like phases, together with some residues of B4C particles were observed in the fusion zone of laser welded joints. The use of Ti filler can improve the microstructure and increase the joint efficiency from 63% to 75%. On the other hand, the friction stir welding process being a solid state welding technique is interesting as it avoids the formation of brittle intermetallic phases. In addition, the breakage of B4C particles and the grain refinement of the matrix were observed in the weld zone. Consequently, FSW joints show much better mechanical properties than laser welded joints. Up to 100% joint efficiency can be achieved by FSW for annealed AA1100-16 vol.% B4C materials.

Jan 1, 2011

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By J R. Barber, B. E. Rogers, R. Fukuzawa

Mercury is sometimes present in non-ferrous ores including gold, zinc, copper and lead. The selection and use of appropriate mercury abatement technology is critical for preventing its release to the environment during ore processing and to protect workers from mercury exposure. This paper presents a general decision-making process for mercury abatement technology selection for major emission sources in the gold industry. Mercury abatement can be accomplished through making process changes and/or by adding a process step to an existing system (i.e. "end-of-pipe control"). Advantages and limitations of the technologies along with waste / by-product management options are discussed through case studies of current operating mercury abatement systems.

Jan 1, 2015

By Norman A. M Macleod

FOR the past seven years, all flotation at the Britannia mill has been done in Forrester Air-Lift cells. Prior to 1931, the roughing and part of the cleaning operation had been performed in four 21-cell and two 14-cell M.S. machines. The resulting economies in reagent, power, maintenance, and general operating costs, and the increased recovery, more than justified the exclusive use of the Forrester machine. About three years ago, the possibility of still further improving the efficiency of the flotation section was the subject of considerable discussion and experiment. Arising from these experiments, tests were made of the practicability of using a cell of greater depth than that of any pneumatic or mechanically-agitated machine in common use. Cells were constructed with depths of 7 .5 feet, 10 feet, and 15 feet, and, in all cases, a very definite improvement in operation was indicated. The cell now being used in the mill treats from 5,500 to 6,200 tons of dry feed per day. It is 100 ft. long by 5 ft. wide by 8 ft. deep, and has replaced a total length of over 500 feet of standard Forrester machine. The choice of a depth of 8 feet was governed by the type of blower which was available-in this case, a Roots-Connersville blower, driven by a synchronous motor and delivering 6,000 c.f.m. of free air at 4.0 pounds per square inch. At the Chelan Division of the Howe Sound Company, where a new mill was recently built, all flotation is carried on in cells 10 feet deep, with good results.

Jan 1, 1938

By A. C. Munro

The concrete work on the new Britannia mill was started in April, 1922. The erection of steel commenced on July 10th, following. The installation of wood work and machinery , began on November 4th of the same year and was pushed to completion in January, 1923. The new mill building is an all steel structure enclosed with galvanized corrugated steel. All main floors and foundations are of reinforced concrete, which makes the building practically fireproof throughout. The mill building rises on a steep hillside to a vertical elevation of 210 feet and has seven distinct floors, for the various opera-tions. Only one elevator, with 30-foot centres, is used in the entire mill. The building is exceptionally roomy and well lighted, both by day and night. The capacity of the mill, as originally designed, was to be 2000 tons daily, but this tonnage can be readily increased to over 3000 tons daily by making slight changes in the fine grinding equipment; in fact, an average of 2700 tons per 24 hours was maintained throughout the month of September.

Jan 1, 1923

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By E. You

The concentrator at Kennecott Utah Copper currently has 4 lines with a configuration of one SAG mill feeding two ball mills. The slurry that reports to each ball mill will vary resulting in an unequal load of material. This configuration contains two separate sumps that receive material from a distribution box relying solely on natural slurry flow to feed each sump. The unequal split to each mill results in one mill receiving a greater amount of material. This will result in the equipment on one mill reaching limitations that may affect product quality and the operation of the equipment near maximum. The parallel mill in this condition will often have additional capacity that can be used but cannot be utilized due to the unequal split. The major consequences of this issue result in reduced throughputs and metal recovery. To resolve this condition an advanced control strategy was implemented to control the split in April of 2002 using equipment that was in place.

Jan 1, 2007

By A. C. de Araujo, M. G. Barbosa, R. Martino, S. Gaydardzhiev

The Iron Quadrangle district is a world-class iron ore mining district in the region of Belo Horizonte, capital of Minas Gerais state, in Brazil. Many mining companies have been mining high-grade hematite ores for decades throughout the region. The mines reserves often include itabirite ores which are available in high volumes, but have lower iron grades than hematite ores and require elaborated mineral processing to meet the requirements of downstream steelmaking. Itabirite ores have acquired importance, with the depletion of high-grade hematite reserves due to their intensive mining. The objective of this paper is to propose a geometallurgical model for the processing of itabirite ores from an Iron Quadrangle deposit, which will allow predicting the behaviour of ores throughout the deposit, according to their local variations. An initial step consists in characterizing representative samples of the different ores to acquire mineralogical and textural data. Then, itabirite ores of known characteristics are processed with different techniques, in order to extract the trends and key parameters upon which the geometallurgical model is developed. At first, the model takes into account the particle size distribution and its shift during mining and screening, as well as the chemistry and mineralogy of the material. Then, using the previously identified key parameters such as iron recovery, the model predicts the composition of the processing products. Finally, this data is used to model the mineralogy and mass recovery of the products. The geometallurgical model is of great importance, as it is able to model the processing of any sampled ore throughout the deposit. The incorporation of the results in a mining block model will assist mine planning and opens new opportunities for an optimized mining schedule.

Jan 1, 2016

By M. Turek

Cost management in the conditions of increasing competition and unforeseen market turbulence constitutes one of the key areas of the enterprise?s activity. In the last two years the demand for hard coal on the domestic and global market of non-renewable resources has increased significantly. Polish hard coal mining industry, as an industry in the stage of decline, received a chance for rejuvenation. However, one of the most significant conditions of seizing this opportunity is the rationalization of mining costs and improvement of production effectiveness. Due to the significance of this issue, the main objective of the paper is to identify the possibilities of improving the production effectiveness in the hard coal mining industry. In order to meet such an objective, in the first part of the paper we measured effectiveness in the Polish hard coal mines in years 2006- 2011. The research encompassed three out of five mining enterprises operating in the country. Then based on the received results, guidelines concerning the improvement of effectiveness of production were created, taking into consideration infrastructural, technical, economic and organizational determinants. Furthermore, opportunities and threats for improving the production effectiveness, stemming from the external conditions have also been indicated.

Aug 1, 2013

The Bluebell mine of The Consolidated Mining and Smelting Company of Canada Limited extends under Kootenay lake, in southern British Columbia, and water control underground has always been a major problem. This paper gives a brief history of the operation, and then de-scribes the methods used by Cominco to keep the combination of lake seepage, ground water and thermal spring water under control. The pumping arrangements are de-scribed in considerable detail, with illustrations to show the various stages of development, and the power supply sys-tem is outlined.

Jan 1, 1966

By Li. L.

Backfilling has become a popular solution in underground mines around the world. It reduces environmental impact of mining industry and improves ground stability. In most cases, backfill has a high water content so that it can be delivered by pipes from a backfill plant on ground surface to underground stopes. Upon deposition in the stope, the backfill tends to consolidate under its own weight, leading to a generation of excess pore-water pressure. To avoid excessive pressure and protect the backfill barricade installed at the base of the stope, the backfilling of the stopes is usually divided into two stages: plug pour and backfill body pour. The interruption of backfilling operation is undesirable as it slowdowns the mining productivity, and sometimes causes pipe clogging, leading to unexpected increase in manpower cost and further reduction in mining productivity. The backfilling interruption time may be reduced, even eliminated if the drainage of backfilled stopes is sufficiently improved. This paper presents an application of wick drains, a material commonly used in civil engineering, to mine backfilled stopes to help accelerating the drainage. A protocol is proposed for installing the wick drains in a mine stope to be backfilled. Numerical simulations were made, showing that the drainage of the backfill can significantly be improved by the introduction of wick drains. The application of wick drains in mine backfill can thus be considered as a promising technique and merits deeper and more detailed investigation.

Aug 1, 2013

SOFCs with thin electrolyte of two types: SDC (15um) single-layer and YSZ (5um) + SDC (15um) bi-layer were fabricated by screen printing and co-firing on Ni¬YSZ cermet substrates. Using in-situ sintered Sm0.5Sr0.5CoO3 cathode the SDC-cell shows high performance at low temperature, 1180mW/cm2 peak power density around 650°C, while the YSZ+SDC bi-layer cell generates about 340mW/cm2 at 650°C, and good performance at 700-800°C with almost theoretical OCV value. Many Zr-content micro-islands were found on the SDC electrolyte surface. The influence of co-firing temperature and thin film preparation methods on the Zr-islands&apos; appearance was investigated.

Jan 1, 2005