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By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By C. P. Moore, G. W. Taylor

Vertically dipping lenses of nickel-copper ore at Dumbarton Mines Limited are being mined by a modified blasthole stoping method. The principal access to the mine is provided by a 15-degree decline, which, in conjunction with the use of ramps and declines for secondary access, maximizes the accessibility and mobility of trackless mining equipment. Sublevels are driven in ore on 80-foot vertical intervals and subsequently the ore, ranging in thickness from 15 to 30 feet, is slashed to its limits by a procedure of face sampling and test holing. Two longhole drill jumbos are used to drill off 40-foot vertical slices above and below these levels. Following blasting, the ore falls by gravity to the 500-foot horizon, where it is removed from drawpoints by load-haul-dump units and transported by truck to the main orepass. The rock is crushed to minus 3-4 inches and conveyed to surface by a 30-inch-wide wire rope suspended conveyor. This is achieved in two flights, a lower one of 290 feet and a main flight of 2260 feet. All aspects of the mining operation are discussed in the paper, including ventilation, services and safety.

Jan 1, 1973

By Amir Asadi

Various damage modes that evolve with time in polymer composite laminates, such as transverse cracking, vertical cracking, delamination, and fiber fracture, as well as the interaction among them, influence the time-dependent degradation in modulus (creep) and strength (creep rupture) of polymer composite laminates. This study is focused on modeling the time-dependent evolution of transverse cracking in [90] plies of a multidirectional polymer composite laminate [0m/190n]. This model uses a two-dimensional variational analysis to determine the stress state at any given creep time. The elastic stored energy, determined using this stress state, is compared with a critical energy for fracture to determine the crack evolution with creep time. Model predictions are compared with experimental results to validate the model.

Jan 1, 2010

By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

"5.1. IntroductionThe sample preparation requirements for bulk analyses of platinum-group elements (PGE) are different from the requirements for ore microscopy and in-situ analyses. It is necessary that the initial sample collection results in as representative a sample as possible for both types of analyses. Ingamells (1980) believes, however, that sampling is always imperfect and that there is no such thing as a truly representative sample. Once collected, the usual low content and irregularly dispersed nature of the PGE require that samples for bulk analyses be made as uniform as possible, whereas in samples for ore microscopy and in-situ analyses the PGE must be concentrated. Because of the generally high specific gravity of platinum-group minerals (PGM), certain precautions must be taken, such as mixing the sample material in the bags prior to opening.5.2. Preparation forBulk Analytical MethodsThe principal factors that determine the size of the sample required for a bulk analysis are grade, heterogeneity and grainsize. Initially, the grade and sample heterogeneity can only be estimated and a sampling methodology is developed with experience. It is essential at all times, however, that the assayers have information about the source of the sample and the purpose for the analysis. Information on the grain-size, which can only be obtained through mineralogical analysis, is also very important for PGE analyses, but, unfortunately, is often ignored.5.2.1. Samples fromUnconsolidated DepositsConcentrations of PGE may occur in eluvial deposits as well as in a large variety of alluvial deposits, including those of fluvial and glaciofluvial origin. These deposits are often difficult to map and sampling is further complicated by the wide range, from sand-size to boulders, of the non-POE-bearing constituents, and by the irregular distribution and shape of the ""pay streaks"". PGE concentrations in unconsolidated deposits are largely composed of resistant Pt-Fe and Os-Ir-Ru alloys (cf. Cabri and Harris, 1975 and Raicevic and Cabri, 1976), thus making comminution to the usual-150 to -200 mesh somewhat unreliable, due to the malleability of these alloys."

Jan 1, 1979

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By G. C. Nowlan, A. Illis, H. J. Koehler

At its iron ore recovery plant at Copper Cliff, INCO produces about 17 million pounds per year of a pure, acid-soluble, dense nickel oxide from nickeliferous pyrrhotite. The process used is also applicable to a broad range of ammoniacal nickel-bearing streams. The product has been widely accepted by the chemical, ceramic and electronic industries.

Jan 1, 1970

By Jean-Luc Collins

"This new tool can be used as a quick guide f or the assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type ""go or no go"" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break even while the other measures a probable value based on the asymptotic theory of statistical extremes.Its application is briefly illustrated by means of an underground gold mine extension project, an oil sands mine project and a polymetallic open pit project.Once a favourable recommendation has been obtained then a detailed ""cash flow after taxes"" analysis can be carried out for the project.IntroductionMany tools are used in financial decision-making such as the payback period, the discounted cash flow, the internal rate of return and the wealth growth rate (Berry , 1971).These tools are useful and meaningful in evaluating normal projects closely related to regular business where the number of assumptions made is usually very small and where the cost of capita! is usually selected as a discount rate or a hurdle value. In situations where a significant number of assumptions have to be made,two problems can emerge, namely:I. the risk involved is underestimated leading to a potential financial disaster; or2. a good opportunity is lost because the approach used in evaluating the project is too conservative.Each assumption has its own degree of uncertainty and it is well known that combining uncertainties together can lead to a total uncertainty of critical proportion. The easiest way to account for risk is to increase the discount rate or the hurdle value, but this approach alone is quite subjective and can easily lead to the problems described above."

Jan 1, 1993

By C. J. Sullivan

Many metalliferous ?provinces are co-extensive with particular groups of sedimentary, volcanic, or :basic plutonic rocks. Deposits may be truly syngenetic (Rand, Rhodesia-Katanga, Mans-field, Blind River, White Pine); re-. concentrated by circulating waters (Colorado Plateau, Red Bed Coppers) ; or re-concentrated thermally during metamorphism and granitization (most uranium and lead-zinc provinces ?and some copper and gold provinces). Basalts may yield important cop-per provinces when folded and re-heated. Granitization of basalts which have not reached the chlorite-carbon-ate phase of metamorphism may produce copper provinces. If they reach ?the chlorite-carbonate stage, granitization may result in a gold province. Copper and copper-nickel provinces may result if gabbros are granitized, and a ?similar alteration of per-idotite may result in asbestos or nickel ores. Many similar associations are known. Granite is not a source of ore, but a result of heat. A classification of ?ore with respect to source rocks is of greater prospecting value than are classifications based on magmatic differentiation and hydrother-mal solution theories. Volcanic centres are important ore foci because the thermally unstable metallic sulphides may be concentrated here by a distillation process. The ores found in the hot spring deposits, viz., mercury, mercury sulphide, sulphur, and the compounds of ?antimony and arsenic, are not those which are soluble in water at low temperature (epithermal sub-division of hydrothermal class), abrut those which are unstable thermally at comparatively low temperatures . Water is one of the most common thermally unstable minerals, and generally accompanies the thermally activated ore-forming sulphides.

Jan 1, 1957

By J. O'Leary, R. Cannell, D. Honsberger

"The Scully Mine deposit lies within the group of metasediments that together comprise the rocks of the Labrador Trough. The ore itself still retains the bedding characteristics of the parent rocks and on this basis has been divided into three main members, namely: Upper, Middle and Lower. The Upper and Lower both show many of the bedding characteristics of the cherty taconites of the northern U.S.A.; the Middle member is a coarse-grained friable specularite rock. The ore minerals are hematite (normally present in the specular variety) and magnetite, although the latter rarely occurs in concentrations greater than 20 per cent. Gangue minerals are quartz and the hydrated iron oxides. Manganese oxides also occur as accessory minerals. The outcrop area of the orebody is in excess of 2 square miles, displaying a complex pattern of faulting and folding, which has been formed as a result of at least two orogenic periods."

Jan 1, 1972

By S. A. Briggs

Bioremediation has been accepted as a treatment technique for groundwater contamination in subsurface soils and shows promise for contaminated fractured rock environments. Biological growth in fractured rock is expected to occur predominantly as biofilms attach to the fracture surfaces. Biofilms in rock fractures are subject to a complex system of forces and other phenomenon due to the dynamics of the bulk fluid in which they grow. In this paper, through the applications of computational fluid dynamics (CFD) to rock fractures, where the boundaries are rough and the flow is complex, a precise analysis was conducted of the interaction of a fluid flow and the rock fracture. Specifically, hydraulic parameters and velocity profiles of an actual rock fracture were calculated and compared to a fracture of equivalent aperture. From the analysis it is clear that it is important to use more complex models such as the Lattice Boltzmann Method used is this paper to describe fracture flow.

May 1, 2009

By J. F. K. Brown

WHEN I first received the kind invitation extended to me by the Mining Society of Nova Scotia, I read over very carefully the suggested title-"The importance of long-distance planning and budgetting in modern methods of mining, and the advisability of working to some definite plan". I came to the conclusion that I might as well confess my inability to handle properly such a vast and intricate subject within the scope of any one paper. More properly, I think a round-table discussion should be indulged in-a sort' of symposium carried on in similar fashion to the World Power and Coal Conferences- you know, a committee for this, a committee for that, and, finally, a committee to see what the committees are doing. Weil, your Secretary's suggestion is just like that- much too comprehensive for any half-hour's presentation. As a paper, also, it either becomes too general and therefore uninteresting, or i.t descends into detail and describes means and methods to the end desired, which have little attraction because they were designed to meet quite different conditions than those my audience would mentally be considering. Of the two evils facing me, I have chosen the one that sticks to the generalities. Your Secretary's query almost automatically divides itself into two distinct phases: First, the importance, and second, the advisability, of planning. Let us dwell for the moment on the second, because, if we can prove advisability, that leads to desirability and, finally, to doing. Proving is the difficult part of the little problem. Here was something I, personally and as a mining engineer, had been battling for all my corporate life without being able to prove it to anybody. Then I saw the way out of that. I perceived I could put that little question of advisability on another basis altogether-:put it in the class of "coming- some day- soon" whether you or l or anybody else liked it or not; call it, if you please, mandatory, certain, necessary, enforceable planning. All of which means that the problem of advisability has rather suddenly become the very practical one of "how to do it". Why?

Jan 1, 1937

By Steve Custer, Chris Bennett, Patrick Garretson, Glenn Dobby, Jacques McMullen

"Barrick Gold is in the process of expanding one of its grinding circuits at the Goldstrike property as a response to both increasing ore hardness and increased ore sensitivity to finer grinding as it relates to gold recovery. The plant currently operates with two parallel grinding lines, each with a SAG mill, a pebble crusher, and a ball milling arrangement. As part of determining what additional equipment was to be required, a CEET evaluation program was conducted (CEET is an acronym for Comminution Economic Evaluation Tool). The work included: Development of a hardness ‘model’ for the ore body, as described by SAG Power Index and Bond Work Index;Site benchmarking surveys to fine tune the SAG and ball mill calibrations within CEET;Conducting CEET studies to examine the process options;Comparing CEET results to standard grinding circuit design techniques.The recommendation of the study, presently being implemented, is the installation of an additional ball mill on one of the two grinding lines. This paper reviews the sizing techniques applied, providing a CEET case study for circuit performance analysis and circuit design. OVERVIEW OF COMMINUTION AT GOLDSTRIKEOre feeding the autoclaves at Goldstrike are first processed through two parallel grinding lines. Both lines use SAG mills with cone crushing of pebbles followed by ball milling. A summary of the key circuit parameters is provided in Table 1. Line 1 primarily processes underground Meikle ore, although when no Meikle ore is available, it processes open pit Betze ore. Line 2 processes Betze ore exclusively. The Mill Line 1 P80 objective for Meikle ore is 74 microns. According to the recovery optimization analysis, a P80 of 90 microns was recommended for Betze ore. The potential however exists to perform co-mingling of both ore types and feed the higher grade Betze ore to Line 1, in which case the P80 of 74 microns would be retained."

Jan 1, 2001

By B. Arlyuk

On the basis of research of relations among the market participants the analytical model has been created which connects the price of industrial good at stock exchange with volume of sales and the stock of the sellers and buyers, Also a model was developed for assessment of these parameters of the market status by the actually fixed stock exchange and general market indicators. The composition of these models made it possible to create reliable system of short-term price forecasting for commodities or base metals up to one quarter ahead. Imperfectability of creation a model for reliable price forecasting by purely statistic methods (by the "black box" principle) was shown. A model of price behavior qualitative forecasting till one quarter ahead has been developed, which determines the probability of reaching in future of the given level as well as of the price maximums and minimums, Optimal values of threshold probability were determined for forecasting the future price maximums and minimums securing the maximum profit from the forecasting system application for commercial activity. The developed system of forecasting was identified for primary aluminium at the period of 1990-2003. The system was tested daily during 20 months period for speculations on 3M primary aluminium forwards at London Metal Exchange with high commercial result.

Jan 1, 2004

By R. B. Anderson, N. J. Sherren

The mining equipment at the Scully Mine, Wabush, consists of approximately twenty-five large haulage units, eight large dozer-loader applications and seventy other related pieces of service and maintenance equipment. This equipment is operating in sub-Arctic conditions. This pa-per presents a description of the tire maintenance procedures in use here and discusses the tire troubles that are being encountered and the methods of dealing with them.

Jan 1, 1969

By Therese Schneck

The presence of xenon isotopes from in-situ spontaneous fission of short-lived Pu244 has been confirmed in Hadean detrital zircons from Western Australia. Hadean and meteoritic zircons can retain secondary overgrowths developed after primary cristalization at 3.97-3.94 Gyr. On the moon, the metal grain in sample 66095,78 is mantled by troilite, schreibersite and cohenite. High chlorine content FeCl2 is deposited around metallic FeNi. The magnitude of Pollonium-210 to Radon-222 on the Aristarchus plateau spectrum indicates a past greater activity. The Earth Moon system from Nb/Ta systematics is consistent with a Moon iron core delayed to 3,9 Gyr.

Aug 1, 2010

By Janos de Warga

"After a short introduction to the history of the semi-conductor theory, the paper describes the principles of electron and hole flow in the semiconducting materials, the operation of the PN junction, and the rectification process in multi-layer devices (diodes and SCR's). The various methods of purification and zone-refining of the silicon are illustrated prior to the discussion on the most commonly used junction-forming processes (alloying, diffusing, etc.). Modern device fabrication and packaging operations are illustrated. Factory testing, evaluation, electrical parameters and guaranteed rating characteristics are listed. It is explained in this paper how the various device parameters affect the electrical performance of the finished unit and how the finished unit characteristics (turn-on, turn-off time, etc.) will influence the equipment rating. In concluding, some typical items of equipment are highlighted, and the applications of these semiconductor rectifiers in the chemical, mining, pulp and paper, and steel industries, etc., are dealt with."

Jan 1, 1967

By E. J. Marcotte

"INCO LIMITED'S Shebandowan Mine and Mill is located in a scenic tourist and cottage area near the western tip of Lower Shebandowan Lake, approximately 90 Km west of Thunder Bay, Ontario. This nicely designed complex is a positive indication that mining operations can co-exist in harmony within the natural environment.The Shebandowan complex processed nickel-copper ore from 1973 to 1985, inclusive, after which operations were shut down.In late 1988, INCO LIMITED decided to place the Shebandowan complex back into operation, under contract, to mine and mill the remainder of the ore body, according to their specifications. MaclSAAC'S EXPLORATIONS was the successful bidder for the project. Following preliminary rehabilitation, operations were re-activated in late March, 1989. The ore mined to date is of a moderately lower nickel grade than the majority of previous years. However, a higher tonnage rate, combined with improved nickel recoveries, has contributed to a viable operation.A series of mill operating and equipment modifications has enabled MaclSAAC EXPLORATIONS to achieve the quality and grade of nickel-copper concentrates specified, and at the same time, expand mill tonnage throughput while attaining increased nickel recovenes."

Jan 1, 1992

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011