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By Claudia Gasparrini

"The ore microscope and electron microprobe, two common instruments for academic research, have not been used to full advantage in the Canadian mining industry, perhaps because they are not readily available to most mining companies.The present paper gives a description of the two instruments and of the manner in which, when used together, they contribute to the identification and description of mineralogical and metallurgical samples, and reviews the applications, to . date, in the mineral industry.The metallurgical applications can assist in determining the best separation technique for a particular metal or other economically important element, can provide explanations for poor recovery and/or liberation, can be used to determine theoptimum concentrate grade and can indicate environmental problems that may arise from the extraction process.In certain cases, the use of the two instruments may assist in the evaluation of new mineral deposits and in the determination of the origin of mineralization.IntroductionThe ore microscope and electron microprobe, two widely used instruments in universities and other research institutions, have not been exploited to their full potential by the Canadian mining industry.High-magnification, high-resolution ore microscopes, owned by most Canadian universities and government mining branches, are not widely used by mining organizations. The situation is very much the same with the microprobe. The geology departments of several major Canadian universities have easy access to this instrument. Fifteen of them, to the author's knowledge, own one and a few have already acquired or are planning on acquiring a second and later model. The mining branches of the Canadian Government have similar easy access to microprobes, as at least four of these instruments are available to them in Ottawa alone. The mining companies, on the other hand, except for the few larger ones which have their own research laboratories, have not been able to take advantage of electron microprobes in the past.This failure to exploit good ore microscopes and electron microprobes has been mainly due to a lack of expertise in the use of the two instruments for the study of metallurgical problems related to ore mineralogy. Government institutions providing research and test work to the industry are few in number, and are not always equipped with these instruments or are not geologically-oriented. Information provided on a consulting basis by universities and by government mining branches is normally limited, and frequently is not oriented to the needs of the mining company."

Jan 1, 1980

By L. E. Reed, I. G. L. Sinclair

An exploration program seeking kimberlite pipes, the common primary hosts for diamonds, Was' conducted during the years 1979 through 1982 in the James Bay Lowlands of Ontario by Selco Mining Corporation (now the Mining Division of BP Resources Canada) and Esso Minerals Canada. The area to be explored was selected on the basis of its regional geological setting, and because of the known presence of kimberlite indicator minerals in the region. The primary exploration technique was low level airborne magnetic surveying, followed by detailed ground geophysics. This work located many pipe-like bodies, with diameters of a few hundred metres, as well as several dykes. Targets located by these geophysical methods were drilled, intersecting a total of45 intrusions, consisting of34 alkaline diatremes containing tuffisitic breccias, 7 carbonatites, and 4 massive alnoites. K-Ar determinations indicated ages of 152 Ma and 180 Ma for two of the massive alnoites. The texture and general mineralogy of the tuffisitic breccias are similar to those of diatreme facies kimberlites, but detailed examination of their mineralogy and chemistry demonstrated that they lie within the alnoitic rather than the kimberlitic compositional field. Although the exploration program did not lead to the discovery of true kimberlites, it did demonstrate the presence of a large, previously unknown province of alkaline volcanic activity, which has no surface expression.

Jan 1, 1991

By Royston Colbourne

Objectives Of Presentation - Identify specific risks - A fresh look at risk - Provide a moment reflection on risk - Open discussion on risk A route to solution and advanced thinking.

May 1, 2010

By J. T. Vehkala, S. S. Kerr, D. E. Robertson

"Since the late 1970s, extensive work has been carried out at Placer Dome Inc. 's Dome Mine to develop new mining methods and equipment to improve the productivity of narrow vein mining (Mining Magazine, Oct. 1986, pp. 308-317; Mar. 1988, pp. 176-/79). This work has been focused on mining veintype deposits varying from 0.9 m to 1.5 m in width using open stoping and cut-and-fill mining methods.In 1989, the Dome Mine entered into a contract with Ram Raising Ltd., a joint venture company of Angus Martin and I.S. Redpath Ltd., to develop and mine a narrow vein test stope using an Alimak Raise Climber. Early results have been favourable, indicating that Alimak methods can be used successfully to mine narrow vein are.HistoryThe Dome Mine, which has been in continuous operation since 1910, is located in South Porcupine, part of the city of Timmins, Ontario. The mine is wholly-owned and operated by Placer Dome Inc. and is part of Placer Dome Inc.'s international stable of of 19 mines."

Jan 1, 1990

By John E. Callahan

"A stream sediment geochemical survey covering an area of 13.000 sq. km near Churchill Falls. Labrador. was conducted for Brinex (British Newfoundland Explorations Ltd.) prior to partial flooding by the Churchill Falls power project. Stream sediments (minus 80-mesh) were analyzed for Cu, Pb, Zn, Ni, Ag, Mo. U and Mn, and the heavy mineral, nonmagnetic fraction (minus 60-mesh) for Cu, Pb, Zn, Ni, Ag, Mo, Ba and Mn. A binocular examination of the concentrates for sulphides and pyrope garnet was done on the heavy mineral concentrates. The concentrates were also examined for fluorescent minerals.Two distinct areas with high trace-element values indicate the need for follow-up studies. The first is in an area of gabbro erratics containing massive and disseminated sulphides (pyrrhotite, pyrite and minor chalcopyrite) on the western edge of the survey area along the Esker Road. The second, largest area (several hundred square kilometres) is anomalous in U and Mo and associated with felsic intrusives (Red Wine Complex?), syenites. granite gneiss and sedimentary rocks (Seal Lake Group?).The binocular study showed that almost 15% of the heavy mineral concentrates contained pyrite and no other sulphides. This indicates that this technique may be worthwhile in determining the presence of sulphide minerals in stream sediments from glaciated environments. The only fluorescent mineral observed in the study was zircon."

Jan 1, 1981

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By A. B. Carino

Gulf Minerals (Canada) Limited's Rabbit Lake uranium operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and /34 miles northwest of Lynn Lake, Manitoba. The paper follows the ore flow through crushing, grinding, sulphuric acid leaching, countercurrent decantation, solvent extraction, ammonium diuranate precipitation, thickening, drying and tailing neutralization.

Jan 1, 1979

By M. W. Gilmore, J. Ndlovu, T. Sepoloane, Anglo American Platinum, L. R. Nelson, R. N. Varty, L. J. Bryson, B. Peyper, J. P. Hagemann

"As part of Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) expansion, a new Nickel Electrowinning Tank House, with a nameplate capacity of 32 400 tons per annum, was constructed. Commissioning of the new electrowinning technology, which involved world first full deposit plating, commenced in 2011.The old nickel electrowinning process at the RBMR used starter sheets which, along with a divided cell configuration, was very labour intensive and exposed operators to high levels of aerosols that contained both nickel and acid. To overcome this problem two key design intents of the new technology are aerosol abatement and minimising labour in the electrowinning cell environment, with a design target to reduce the nickel occupational exposure limit (OEL) to half the legislated limit of 0.1 mg.m-3.Commissioning of the new technologies adopted to achieve mist abatement is described, together with a review of technical and operational challenges relating to the titanium blank edge strips, blank roughness and sandblasting optimisation, blank quality control, electrode spacing, polyconcrete cell dimensional stability and cell top furniture. The impact of these on process performance is presented and the development of fault checking and rectification methods, to maintain high process performance, is explained.INTRODUCTIONThe expansion of Anglo American Platinum’s Rustenburg Base Metals Refinery necessitated the construction of a new Nickel Tank House to achieve two primary objectives, namely increasing the nickel electrowinning capacity from 22 500 tons per annum (tpa) to 32 400 tpa nickel, and a design to reduce the nickel aerosols to 0.05 mg.m-3 as a time weighted average over 8 hours, which is half of the legislated occupational exposure limit (OEL) of 0.1 mg.m-3."

Jan 1, 2016

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By A. Tikhonov, D. Kipper, V. Korovin, A. Olifirenko, Yu. Shestak

The present paper deals with vanadium and molybdenum sorption from industrial wastes and intermediate processing products using Cybber macroporous strong- and weak-base anionites. Vanadium and molybdenum recovery by Cybber anion-exchange resins as well as desorption processes were studied in static and dynamic modes; their efficiency was demonstrated for that purpose. The results of the work may be used to design technologies for complex processing of both ores and industrial wastes containing vanadium and molybdenum.

Jan 1, 2011

By Randolph A. Pax, Brian Cornish

The operation of grinding mills in an ore processing circuit is supported by monitoring the input and output variables. These can include the feed ore size distributions, ore feed and water addition rates. The outputs can include the discharge undersize density, oversize tonnage rate and the P80 of the discharge. The grinding mill performance is judged by the power draw, recycle rates and discharge grind size. Conditions inside the mill are inferred from loads cells or bearing pressures and past histories. An overall noise value is sometimes used to evaluate the load as well as the occurrence of excessive impacting of steel balls onto the liners/lifters of the mill. This paper presents results of the internal behaviour of a mill using non-contact stationary microphones located close to the mill outer shell (Pax, 2012). The noise generated by a mill can be attributed to a number of events that occur inside these mills and suitably analysed can provide real-time determinations of in-mill behaviour and can provide powerful insights into the operation of the primary comminution tumbling mills. The acoustically determined signals including a specific 'steel' signal, water hold-up, integrated area together with a classification of impact events. Specific results from case studies will show information of the trajectories inside a mill, steel to rock ratio as well as rheology effects. By incorporating a self-consistent understanding methodology for the in-mill processes from an array of microphones, the information can be used to diagnose the dynamic conditions inside a mill.

Jan 1, 2016

By J. B. Sabey, V. R. Degner, D. MacGillivray

"Hydrodynamics principals are applied to the design of a natural air ingestion flotation machine for coarse solids applications. Preliminary laboratory test data and subsequent operating plant flotation kinetic performance evaluations are reviewed. INTRODUCTIONThe concentration of potash (sylvite, KCI) from halite and other salts using flotation is well understood and practice a with much success. Reagent schemes and plant circuitry for obtaining the desired product recovery and grade have been established with proven performance. These flotation circuits normally process the medium and finer size particles, less than 30 mesh (600 microns).However, often the potash market trends specifically demand a coarse product size. This emphasis, accompanied by the existing high losses of coarse (+30 mesh) potash in flotation circuits, creates the need for development of a flotation machines specifically designed for coarse potash beneficiation.This technical challenge was undertaken by the WEMCO Research and Development Group. The specific objectives of this flotation machine development program were ( l) to achieve an ""Ultra Coarse Flotation Machine"" capable of adequately suspending and transporting particles in the 4 - 30 mesh (4.75 - 0.6 mm) size range at solids concentrations of 30% or greater and (2) ascertain metallurgical performance of this machine.This paper covers the development (both theoretical and mechanical/ hydrodynamic), the field test program and results, a discussion of applicable flotation kinetics, and conclusions of this ""Coarse Potash Flotation Machine"" development project."

Jan 1, 1986

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed.The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grade, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the final cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure I."

Jan 1, 1995

By P. W. A Severin

"The Sturgeon Lake deposit, a partly eroded lens of massive sulphides with an underlying sulphide stringer zone, is one of five orebodies that occur in the Sturgeon Lake area of northwestern Ontario within volcaniclastic rocks of the Archean Wabigoon Subprovince in the Superior Province of the Canadian Shield.The Sturgeon Lake Cu-Zn-Pb-A g-Au deposit was discovered in October 1970 as a result of an I.P. survey. Production from this open-pit mine began in March 1974 and continued until the ore was exhausted in March 1980.The Sturgeon Lake property is underlain by basaltic volcanics, minor amounts of mafic lapilli tuff and rhyolite volcaniclastics. A quartz crystal-bearing rhyolite occurs at the top of the felsic volcaniclastics and is ""capped"" by the Sturgeon Lake massive sulphide deposit. The felsic volcanics have been intruded by a crudely layered sill-like, carbonatized mafic intrusion. Recent work suggests that the felsic rocks that underlie the Sturgeon Lake deposit are lateral equivalents of those in the vicinity of the Mattabi Mine and are not correlative with the dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits. Hydrothermal processes that resulted in the formation of the Sturgeon Lake orebody have resulted in a depletion of Na2O, CaO and FeO and an increase in MgO, K2O, copper and zinc. In the vicinity of the sulphide stringer zone, the rhyolites are ""bleached"" due to silicification and sericitization. The rocks lying immediately below the massive sulphides are locally strongly chloritic.The Sturgeon Lake deposit may have formed on a top ographic high which prevented mafic flows and dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits from inundating the Sturgeon Lake fumarolic vent from the west. Continued or resurgent activity from the Sturgeon Lake fumarole may have resulted in the formation of the Lyon Lake and Creek Zones as more ""distal "" deposits in topographic lows. The Sturgeon Lake, Lyon Lake and Creek Zone deposits were subsequently overlain by mafic tuffs and flows."

Jan 1, 1982

By J. W. Reynolds

"The use of approved fire-resistant hydraulic fluids in equipment operating underground was made mandatory in British Columbia by amendment to the Provincial Mines Regulation Act effective January 1, 1975. This paper covers the action taken to achieve this, in the largest underground metal mine in British Columbia. Some evaluation of costs and effects based on experience to date is included.BackgroundAn amendment to the Mines Regulation Act of the Province of British Columbia was passed in July 1974 as follow s: "" Rule 111 (b) Hydraulic Fluids. After the first day of January 1975, all hydraulic fluids used in equipment operating underground shall be of a fire-resistant type accept able to the chief inspector.""Unquestionably, its intent was justified as a safety improvement measure. The list of fires in mines involving machinery where hydraulic fluid was a factor in the fires is long and sobering. In British Columbia, in a 22-month period from 1972 to 1974, there were six fires in metal mines resulting in extensive equipment damage and injury to four workmen. Nevertheless, no provision was made for research or development of systems modifications compatible with conditions encountered in B.C. and, as late as June 1977, the Mining Association of British Columbia continued to argue that fire suppression systems should be considered sufficient until a universal suitable hydraulic fluid could be developed. The sole concession was to issue permits for continued use of mineral oil in equipment bought prior to 1975 in order to allow producing operations to continue. The burden of developing the necessary technology was laid on the industry.The Sullivan Mine at Kimberley, the largest and longest established underground mine in the province, and Cominco's most important source of ore s for its smelter at Trail, B.C., was at the outset of a conversion from conventional to trackless mechanized mining methods in pillar recovery operation s. Introduction of fire-resistant hydraulic fluid s had to be done in a period of change, in many instances on equipment for which no data existed, and called for research which had to be done while retraining the work force.The introductory phase is complete. All equipment is on FRF, the requirements of Rule 111(b) are being satisfied, and a number of research and development programs continue."

Jan 1, 1980

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By J. E. Amadi-Echendu, F. Stober, J. Ndlovu, L. R. Nelson

The Polokwane Smelter Complex (PSC) relies on a single 68MW high-intensity six-in-line furnace to smelt a planned 650 000 t/a dry concentrate to produce a platinum group metals (PGM)-bearing matte. As typical of a greenfields venture, considerable attention was paid to the project development and implementation stages of design, engineering, construction and commissioning. Somewhat unusual though, was the role of a dedicated multi-disciplinary "Operational Readiness" and support team, comprising the owners team and specialists from the furnace designer, HATCH, to effect a safe and rapid ramp-up to the design smelter capacity of 68MW. The challenges encountered in developing an effective partnership will be discussed. The modus operandi and roles of the "Operational Readiness" team during the design, procurement, construction and commissioning stages as well as that of the operational support team within the overall ramp-up objective will be presented. The "Operational Readiness" team was responsible for:

Jan 1, 2005