Search Documents

By John Wilson

"The Rietveld numerical method was used to calculate the relative abundances of phases in both synthetic binary mixtures and synthetic and natural ores, using X-ray diffraction data. The results were compared with those of image analysis and a chemical method. The ranges of the relative errors were estimated. The Rietveld method is found to be acceptable for determining the abundances of major and minor phases and the amorphous component of partially crystalline samples. In complex mixtures, where there are several trace phases (~<2 wt%) present, the technique becomes less accurate. It is most useful as an alternative technique to image analysis when sample preparation is problematic or sample particle sizes are sub-micron. It is a manual method which requires user input during the fitting process, but is both simpler and faster than image analysis due to the reduced set up time and sample preparation required. It is now implemented at CANMET as a technique for quantitative analysis.INTRODUCTIONUntil recently, the Applied Mineralogy group at CANMET used only image analysis and chemical techniques to determine phase quantities. An effort to develop quantitative X-ray diffraction (XRD) has been on-going for several years. Initially, the reference intensity ratio (RIR) method with external standards was tried with some success (Szymanski and Petruk, 1989). The main difficulty with this technique was finding adequate standard material for each phase present in the sample. This shortcoming made the method ultimately impractical, given the wide variety of materials which come to the laboratory for analysis.The Rietveld refinement method of quantitative XRD (Hill et al 1993, Mumme et al 1996), in contrast, requires no standards and requires minimal sample preparation and therefore a more rapid turnaround compared to image analysis. The Rietveld method also has advantages over image analysis in that it can identify and quantify polymorphs, ultra fine materials and many types of hydroxide products. As well, it is useful for analyzing materials such as bauxite or talc, which do not polish well enough for making mounts of the quality required for image analysis. To quantify amorphous material and phases which are present in amounts below the detection limit of XRD, the addition of a standard material is still required. However, in such cases only one standard is needed, which is alumina."

Jan 1, 2003

Some 800 analyses for Cu, Zn, Pb, Ag, Fe, S, CaO, MgO, C02, Si02 and Al203 were used to examine the elemental constitution of the Mount Isa ores, and, for comparison, those of the Northern Leases area.Lead: zinc relations show little order from sample to sample, but means of large zones (Le. individual orebodies) show a highly linear inverse relationship. Lead: silver ratios are fairly constant from sample to sample, and means show a highly linear direct relationship.Sulphide sulphur appears to be related to carbonate and alumina abundance, sulphur decreasing systematically with increase in the ratio CO2:AI203. In all graphs involving members of the group CO2-A203-S the lead-zinc and copper ores conform to the same simple trends, confirming that the two ore types and their host rocks are genetically closely related. The earlier deduction of a volcanic-sedimentary origin for the sulphides of the Black Star orebodies appears compatible with present findings.On the basis of such an origin, the pattern of sulphide occurrence and mineralogy in the Mount Isa district is possibly related to the configuration f the upper surface of the &quot;Eastern Creek Volcanics&quot;, the facies patterns of the overlying sedimentary rocks, and to the oldest faults affecting the two.INTRODUCTIONStanton (1962) described and interpreted the chemical constitution of the Black Star No. 2 lead-zinc and the 650750 copper orebodies at Mount Isa. The investigation has now been extended to the other principal orebodies of the area.The earlier study showed that the host rocks of the two adjacent Black Star orebodies were constitutionally closely related, and suggested that this was probably due to their original formation in contiguous zones of sedimentation. On this basis the silica-dolomite of the copper ore appeared to represent the slightly more shoreward, &quot;limey&quot; member, probably a fairly massive algal calcareous sediment laid...

Jan 1, 1963

This article attempts to outline essential features of the Mount Isa ore deposit, to reveal the agencies thought to be responsible for its localization, and to describe methods used for obtaining and applying geological data on a commercial basis. Structural features are emphasized because they have proved the most useful agencies to date in searching for ore. Vertical depth, horizontal width and stratigraphic thickness are used throughout the article, and quantities are quoted in long tons.THE DEPOSITA width of more than two miles of evenly bedded shale of the Mount Isa series (upper pre-Cambrian) lies sandwiched conformably between quartzites. The series strikes N.S. and dips approximately 60&#176; W. Shale is unaltered...Important geological work has been carried out by the Queensland Geological Survey, chiefly by Mr. S. R. L. Shepherd, in co-operation with the Geological Department of Mount Isa Mines Limited. Selected references are The Queensland Government Mining Journal for December, 1931, January, 1932 (Rio Grande Lode); December, 19B2 (Black Rock Lode); October, 1933 (General structure); October, 1936 (Mount Isa Lode).

Jan 1, 1939

By W. de Beer

We present aspects of one of several ongoing case studies used in the development of prediction techniques for major seismic instabilities. The current investigation centres on accelerated coseismic deformation described by the kinematics of failure and on softening, as well as the characterization of areas of interest by measures of the seismic response at such sites.

Jan 1, 1998

By B. Sivarama Sarma, Biswabikash Rout

"Seepage control has to be achieved with plastic concrete cut-off diaphragm walls in dam structures. Materials selected for construction of cut-off walls must be durable, impermeable and have stiffness comparable to the surrounding soil.Plastic concrete provides a feasible and economical solution for construction of durable and impermeable cut off walls for dam structures. Plastic concrete wall should not be understood as a concrete wall with similar mechanical properties of concrete used in buildings, piles and spillways sections. Though it consists of the same materials as those of conventional concrete it has the major differences in end product due to predominant addition of bentonite slurry in the mix with very high water cement ratio. This makes the hardened concrete with very low compressive strength less than 5MPa and high failure deformations after the peak load.This technical paper examines a case study, the typical specifications on demand for construction and the issues corresponding to misunderstanding of the material as a structural grade concrete material. Conclusions were drawn based on a few project site quality data and trial mix experimental data. The anomalies in specifications on demand for construction of curtain wall in a dam structure were removed with modifications.INTRODUCTIONDiaphragm walls which are constructed in trenches made of plastic concrete basically serve the function of seepage control under confined measures. They should have the ability to sustain and undergo large plastic strains as compared to conventional concrete. The three basic mechanical properties of plastic concrete cut-off walls are to have least permeability, minimum strength to retain its shape and ability to undergo large deformations under confined loading conditions. The constituents of plastic concrete are cement, bentonite, coarse and fine aggregates, chemical additives to improve flow of concrete and sometimes to retard the setting time and water."

Jan 1, 2017

By Siegmund Babendererde, Jan O. Babendererde

Extruded Concrete Lining combines technological and financial advantages. The tunnel lining is reliably embedded in the surrounding ground as the fluid concrete is extruded at constant pressure directly behind the TBM supporting the exposed surface. Ground deformation from the TBM passage can be compensated and the ground will be pre-stressed by the extrusion process. Developments in concrete technology permit high speed tunneling by use of a slip formwork attached to the TBM. Realised projects in Milano (Italy), Lyon (France), Frankfurt (Germany) and Akima (Japan) will be demonstrated.

Jan 1, 2001

By R Tom Watts

The blasting industry has changed more in the last five years than in any period to date. The equipment utilized to load boreholes has changed in response to more precise blasting products and programs, and the need to maintain tighter control over product formulations produced by bulk loading equipment. Tread Corporation has built over 1,300 heavy ANFO type bulk loading units currently operating in over 40 countries worldwide. These units have been designed to meet almost every possible loading scenario but there are always new situations that require special designs and configurations to meet the challenge. The focus of this presentation is to make you aware of the process that should be used to determine the equipment best suited for your application. We will discuss loading cycle times, delivery rates, multiple product mixing capability, capacities, manpower utilization, regulatory compliance, and where and when to use automation in the loading process. We will also discuss the suitability of chassis with regard to ground pressure, turning radius, terrain, weather conditions as well as highway suitability. The US Bridge Law as well as laws that cover the concept of axle loading and spacing will be covered. Through new computer aided design and modular design capabilities, you can now have almost any configuration required to meet your bulk loading objectives. We will also review the range of equipment currently available in the market place and discuss tradeoffs between price, capacity, and complexity.

Jan 1, 2000

By Hoskings R

Conceptual studies of the run of mine stockpiling and reclaiming requirements com- menced in 1975. Final selection of equipment was made in 1978 and the equipment was commissioned in June, 1979. Equipment selection was made after extensive investigation and visits to existing facilities throughout the world. The equipment selected is described and com- pared with the alternatives. Foundations were designed to minimise clean up effort and to ensure stability of equipment under design wind loading without storm bays. Program- mable logic control enables the stacking and reclaiming facility to provide a blended feed to the coal preparation plant.

Jan 1, 1980

By Winton J. Gale

Coal pillar design has been based on generalized formulas of the strength of the coal in a pillar and experience in localized situations. Stress measurements above and in coal pillars indicate that the actual strength and deformation of pillars vary much more than predicted by formulas. This variation is due to failure of strata surrounding coal. The pillar strength and deformation of the adjacent roadways is a function of failure in the coal and the strata about the coal. When the pillar is viewed as a system in which failure also occurs inthe strata rather than the coal only, the wide range of pillar strength characteristics found in the United Kingdom, United States, Republic of South Africa, Australia, People&apos;s Republic of China, Japan, and other countries are simply variations due to different strata-coal combinations, not different coal strengths. This paper presents the measured range of pillar strength characteristics and explains the reasons. Methods to design pillar layouts with regard to the potential strength variations due to the strata strength characteristics surrounding the seam are also presented.

Jan 5, 1999

By Michael D. Justason

...a global perspective... In March of 2000, the Japanese Geotechnical Society added "Rapid Load Testing" to their national standard for pile testing. In the year 2000. it is estimated that there will be more than 500 "Rapid Load Tests" on foundations around the world. ...so what is a "Rapid Load Test", and why is it gaining acceptance and popularity?

Jan 1, 2001

By E. J. Ripling, M. W. Toaz

Tensile tests were conducted on pure magnesium and on four commercial alloys over a variety of temperatures and strain rates. The high positive slope of the ductility vs testing temperature curves that is found over a short range of testing temperatures for these materaturerials was shown to result from the fact that the microstructure was not stable at these testing temperatures. Pure magnesium did not display a transition temperature, although its sub-room temperature ductility was low. This poor ductility resulted from a grain boundary weakness. The aluminum-bearing commercial magnesium alloys had a higher ductility than the pure magnesium. ness.Thealuminum-bearingcommercialThese alloys did exhibit a transition temperature and grain boundaries that were stronger than the grain material. Both pure magnesium and the commercial alloys began initiating cracks at strains equal to one half of their fracture strain. MAGNESIUM base alloys&apos; enormous potential as structural materials lies in their high strength to weight ratios. At present, the high strength magnesium base alloys such as AZ-80, which will be discussed later, have about as high a tensile strength to specific gravity ratio as the highest strength wrought aluminum alloy, 75s-T6, and, of course, a much higher strength to weight ratio than structural steel. Further, since the magnesium base alloys develop their high strength to weight ratios with moderate strengths and extremely light weights, the ratio of load carrying capacity to the weight of many structures is relatively higher for the magnesium base alloys than their strength to weight ratios would indicate. This results because judicious increases in section size, such as increasing the depth of bending members or adding reinforcing ribs, can frequently increase the weight of a structure linearly while the strength and stiffness increase as the second or third power of the added weight. Strength and rigidity must be designed into lightweight structures by those techniques which establish multiaxial stress states. Consequently, strong, lightweight structures frequently also possess a greater propensity toward brittle failures. In order to insure against these catastrophic failures, an extra premium must be placed on ductility and toughness in light alloys. Current knowledge of the ductility and toughness behaviors—notched behaviors—of magnesium base alloys is limited.* Most of the magnesium base alloys * The state of present knowledge regarding the effect of testing temperature on mechanical properties has recently been summar-ized by Pritchard.&apos; crystallize in the hexagonal system, so that they are expected to exhibit a tough and ductile to brittle transition temperature. Actually, a transition temperature behavior has been reported for commercially pure magnesium in the literature, but the characteristics of this transition temperatureh uggest that it may not be a transition in the usual meaning, but simply the onset of some thermal softening, a performance much like that which face-centered-cubic lead might exhibit slightly below room temperature. If transition temperatures do exist, such important questions as the manner in which they are affected by internal variables such as chemical composition and grain size, or the effect of external variables such as rate of straining or notch severity have never been investigated. The investigation reported upon herein was undertaken in order to define some of the mechanical behaviors of the magnesium base alloys better, to gain a better understanding of the influence of some of the above listed variables, and particularly to understand their effect on ductility and toughness better. Material and Procedure Material-—Pure magnesium and four commercial alloys were used in this investigation. The alloys were selected so that chemically they made up a series with approximately the same minor alloying

Jan 1, 1957

This chapter summarizes data on crude mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are tables that show the principal mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at &apos;any of several stages of extraction and processing, the stage of measurement used In this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the product of auxiliary processing at or near the mines.

Jan 1, 1977

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By Wilton Johnson

Native asphalt was produced by three companies in two States, Texas and Utah. Bituminous limestone, used primarily as a paving material for street and road repair, was produced by one firm, R. L. White Co., Uvalde County, TX. Gilsonite, a solidified hydrocarbon found only in Colorado and Utah, was mined by two firms, American Gilsonite Co., a division of Chevron Resources Co. (a subsidiary of Standard Oil Co. of California), and Ziegler Chemical and Mineral Corp. Hydrocarbon Mining Co. (a subsidiary of Oberon Oil Inc., a Utah corporation) closed its mining operation during the year.

Jan 1, 1988

It is possible to divide industrial minerals into four general categories: 1. fuels, 2. construction&nbsp;materials, 4. agricultural minerals, and 4. industrial minerals. It is proposed to ignore the fuels in the context of this paper and deal in general terms with the others. Mining companies have often considered getting into the industrial mineral business because they can see a resource development with good growth and consistent profits. However, many mining companies being conversant with the metallic side of the industry have spent sleepless nights determining which industrial minerals are most suited for their particular situation. Some have got into the business for the wrong reasons and wished they had never heard of it. Others have successfully adapted to the industrial minerals philosophy and now operate in both metallic and industrial mineral arenas. There is a large difference between firstly, the philosophy and secondly, the functions of being in the industrial minerals business as opposed to metallicÆs. The philosophies can be considered in parallel but it is necessary to clearly have an appreciation of the dominant influences that affect industrial minerals.

Jan 1, 1984

By John C. MacCartney

In the Pennsylvania anthracite region, the principal source of U.S. anthracite, refuse disposal problems are common since cities and towns are located over the anthracite measures. The Bureau of Mines surveyed refuse banks in the area, determining that 863 banks containing aver 910 million cubic yards of material occupy a total area of about 19 square miles. The vast bulk of the refuse is located within 2 miles of the traffic centers of incorporated c unities which have a total population of 625,000. Twenty-seven banks are burning, causing considerable distress in a number of communities.

Jan 1, 1969

By D. Dodgen, L. Larrimore

Electric utilities depend heavily on coal as a major fuel source for power generation, annually producing more than 85 million tom of ash, boiler slag and FGD (flue gas desulfurization - "scrubber") materials as by-products. Utilities and others who bum coal have traditionally disposed of these by-products in ponds or landfills. However, in the last 10-15 years there has been a greatly increased emphasis on beneficial utilization of these materials by the producers themselves as well as by customers who purchase the by-products. Regulatory, cost and technical performance issues currently impact the use of coal ash and other coal combustion by-products (CCB).

Feb 24, 1997

By Shuvranshu K. Rout, Anup K. Mandal, Biswajit Das, Manos De

"To adopt new technology advancement in Steel Plant, there is a requirement of shifting of operation process from Coke Wet Quenching (CWQ) to Coke Dry Quenching (CDQ). New CDQ chamber foundation with deep basement and underground conveyor tunnel are to be constructed in an operating plant where heavy foundations and structures are located in close proximity. Furthermore, the existing CWQ system will be in operation during new underground construction and erection. Challenges to deep excavation of tunnel and chamber foundation consist of non-uniform ground condition, prevent washing out of soil from bottom of existing foundations, stability of existing nearby structures, presence of large number of underground utilities, ensuring safe underground workplace to construction resources engaged in new construction work along with project schedule and budget constraints. A combination methods involving use of soil nailing, soil grouting, contiguous bored pile and micro pile had been adopted for protection of excavation sides as well as existing structures. Each side of excavation in different stretches were analysed during design as well as construction stages. The use of combination of all techniques in a single brown field project in context of the nature of site constraints and safety issues made this a unique project.INTRODUCTIONSteel Industry is one of the backbones of industrial growth of any developing country like India. Due to increasing land prices most of the steel plants in India are expanding within their existing plant facilities. In addition to that, there is demand of adoption of new technology for future expansion projects to set new benchmarks with global standards.The property owner had earlier installed a Coke Wet Quenching (CWQ) for their Coke Plant. Now, there is a requirement from process department to proceed with Coke Dry Quenching (CDQ). To facilitate the CDQ within the existing CWQ which will be in operation is the main challenge for the property owner. The second challenge is the limited space for underground construction and subsequent equipment erection within the stipulated time frame.From a geotechnical prospective, the project team had uncertainty and reservations in their mind about the construction methodology. Therefore, the role of three “C”: ‘Consultant’-‘Client’- ‘Contractor’ and their combining brainstorming is essential to freeze a working plan for achieving the goal. In this paper, only the excavation support systems for underground foundation structures have been highlighted in the context of solving geotechnical problems."

Jan 1, 2017

By David Smith, Bernie Martin

The Queens Bored Tunnels consist of 11,000 feet of 19&apos;-6" inside diameter tunnels mined through rock, mixed face and dense glacial till, constructed with bolted gasketed one pass reinforced concrete liner. The tunnels are to be excavated with a pressurized face TBM, either EPB or slurry. The construction of the tunnels will require ground stabilization in the mixed face area, instrumentation and monitoring of railway infrastructure, underpinning of bridges, relocation and protection of utilities, demolition of some industrial buildings, construction of open-cut approach tunnels and emergency exits and vent plants. The purpose of this paper is to describe the scope of work, the suggested methodology and the proposed construction schedule.

Jan 1, 2005

By B. Genc

"The risk of spontaneous combustion is well known in the South African coal mining industry. In the coming years it is very possible that the incidence of spontaneous combustion will increase from current levels, due to factors such as an increased rate of mining, re-working of previously mined seams, more stooping and total extraction for underground mines, and higher stripping ratios for surface mines, leading to more spoils. It is also fairly certain that coal mining will face tougher environmental emissions legislation in the near future. To determine the areas where the risks of spontaneous combustion are high, it is necessary to improve on our current laboratory procedures for testing and evaluating coal samples, combining the results with site and field data, and if necessary revising the laboratory rating system to refine our understanding of South African conditions.Currently, laboratory tests are conducted in order to determine both the Wits-EHAC index and the crossing-point temperature which, when combined, give an indication of the spontaneous combustion propensities of the coal samples. This procedure has enabled the establishment of a database of results to review and evaluate South African coal seams. Using this database, the high-risk areas in terms of spontaneous combustion are identified. Tests have been undertaken for five consecutive years, between 2008 and 2012. In total, 119 coal samples from different coal seams and production coalfields have been analysed and classified through a series of laboratory tests. A comprehensive database of these results is available, and is continually being updated as new test results are added. This database will continue to expand, and to provide the basis for an improved risk evaluation methodology for spontaneous combustion"

Jan 1, 2015