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By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

Cambior has been involved in the Guiana Shield since 1990, first in Guyana and then in Suriname starting in 1994. This paper presents the history of Omai Gold Mines Limited in Guyana, where commercial production started in 1993 after an investment of US $150 million. In 1995, the mine was expanded in order to increase the milling capacity to 21,000 tonnes per day. After ten years of production, approximately 3 million ounces of gold have been produced. Building on this experience, Cambior became involved in Suriname with the Rosebel Project. A US $95 million pre-production program started in the fourth quarter of 2002, and the mine should be in commercial production early in 2004.

May 1, 2003

By V. C. Pandolfelli, S. F. Santos, L. A. Rodrigues

Under conditions of stable crack propagation at room temperature, the elastic energy stored in ceramic materials is converted mainly to surface energy. However, at high temperatures, creep may also occur in such materials, in which case it will present a ductile behavior. This paper discusses the brittle-ductile transition of a refractory material. Stable crack propagation and creep tests were carried out under a three-point bending device. A commercial ceramic containing 63 wt-% of SiO2 and 31 wt-% of Al2O3 was used as testing material. The results revealed that the change in behavior from brittle to ductile was caused by softening of a vitreous phase present in the material's microstructure.

Jan 1, 2004

By C. L. O?Brian

Note: The figures quoted and used herein have been collected and furnished by the Dominion Bureau of Statistics. Without the help and willing co-operation of the officials of the Burreau, this study would not have been possible. Introductory and General Coal has one unique quality that distinguishes it from other minerals, one that is too, often forgotten. This is the quality of ubiquity. No other single mineral supplies such a wide and varied range of human requirements nor, up to the present, is there any indication of a rival in this regard. There is, consequently, reason for individual study of each of the major portions of the overall market for coa1. The provision of heat for our homes is a necessity of life in our Northern climate and the largest single source of this heat is coal. It is intended to present here a factual survey of the use ?of coal in home heating throughout Canada and the effect of these requirements upon the production of coal and the development of this phase of the mineral industry. The coals used for house heating in Canada fall into two more or less distinct classes, the very low volatile fuels such as anthracite and including coke, and the bituminous coals, including the sub-bituminous and lignite types. The bituminous coals are, of course, consumed in very large quantity by industry and the railways and are the most important type both in tonnage and in respect to the area supplied. Canada consumes annually for all purposes some 4,400,000 tons of anthracite, 4,300,000 tons of coke exclusive of Petroleum coke, and some 40,000,000 tons of bituminous coals. This is a fair measure of the relative importance to the overall economy although it will be seen later that the concentration of the household use of anthracite and coke into one area does create a considerable problem.

Jan 1, 1951

By Y. Kocaefe, S. Afshar, D. Kocaefe, Z. Kunt, C. Allaire

Interaction of aluminum with silica based ceramics Jose M. Soto, Jeffrey D. Smith, William G. Fahrenholtz. Department of Ceramic Engineering University of Missouri-Rolla Rolla, MO 65409-0330 USA ABSTRACT Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy. The interactions between bed media and aluminum have been studied under static and dynamic flow conditions. An experimental system was set up simulating a small filter. Desired flow field can be created around alumina particles and velocities can be adjusted. A mathematical model was developed to predict the velocities, and this was validated using data from a visualization study. The interaction zone on the surface of the particles was analyzed with optical microscopy and SEM. This paper presents the study and compares the results under static and dynamic flow conditions.

Jan 1, 2004

By J. Day, Matthew X. Yao, Lijue Xue

Hardfacing overlays are commonly applied on the shroud Z-section of turbine blades for enhanced wear resistance. Among various processes that are used to apply the hardfacing overlays, the plasma transferred arc (PTA) welding process offers several advantages including lower heat input, less base material dilution, rapid process time, and reduced operating cost associated with the capability to apply materials in the powder form. The development of a robust PTA process is crucial for overlay performance and repeatability, particularly in the aerospace industry where a quality intensive manufacturing environment prevails. For this reason, the Taguchi method of experimental design was selected to develop a test plan. A 4-factor 3-level (L9) orthogonal array (OA) was used in the experiment. The L9 OA allows for a more detailed (3 level) investigation of critical process parameters, namely plasma gas flow rate, traverse speed, powder feed rate, and arc current. Two hardfacing materials, Stellite 694 and Tribaloy T-800, both Co-based wear resistant alloys, were investigated by deposition onto a cast IN738 Ni-based superalloy substrate. Performance measurements of the hardfacing deposits included deposit hardness, substrate hardness, deposit density (porosity), degree of cracking/inclusions, and a quantified visual inspection. The procedure resulted in optimized PTA hardfacing parameters for both Stellite 694 and Tribaloy T-800 on IN738 turbine blade material.

Jan 1, 2004

By Guohong Yin

Oxidized sulfidic tailings contain significant amounts of accumulated acidity in the form of water-soluble secondary sulfate minerals and thus constitute long-term sources of acid drainage at many metal mining sites. As part of site remediation activities, alkaline amendments are often added to the oxidized tailings to increase the pH and immobilize the metals. This study assessed the advantages and limitations of using lime mud, a byproduct of Kraft pulp mills rich in calcium carbonate (> 90 wt. %), as alkaline amendment. The inorganic and organic constituents of lime mud samples were quantified. Leachable impurities were determined by the TCLP method. The performance of lime mud was compared to that of reagent grade quicklime (CaO) and calcite (CaCO3). Tailings treated with lime mud or calcite have strong buffering capacities and remain at neutral pH conditions (pH ~ 6.7) for long times. In contrast, tailings treated with quicklime have a very low buffering capacity, and their pH decreases with time. Furthermore, lime mud has finer particle sizes and thus a greater specific surface area than most forms of commercially available calcite, which results in enhanced reactivity. Dissolved metal concentrations are similar in tailings slurries treated with lime mud or calcite. This study suggests that lime mud is an environmentally and economically attractive alkaline amendment for oxidized mine tailings.

Nov 1, 2002

By A. McLean, J. Hou

Waste slag is a major environmental concern within the metallurgical industry. In the steel industry, about 100 kg of slag is produced in making one tonne of liquid steel from iron in addition to that produced during ironmaking. The amount of slag from the steelmaking converter can be significantly reduced when charging hot metal with low phosphorus and sulphur contents. In this context, hot metal pretreatment is known as an effective means of preparing high quality charge material for the converter thus limiting the generation of residual slag during the steelmaking process. In the aluminum industry, about 2-4 tonnes of slag, including red mud from alumina production and dross from aluminum electrolysis and casting, are generated during the production of one tonne of aluminum. In recent years, reuse of waste slag from the aluminum industry is a topic that is receiving increasing attention. In this paper, the possibilities of using waste slag and by-products from the aluminum industry as a refining flux in the steel industry are discussed. Several successful processes to convert waste materials from the aluminum industry to steel refining fluxes are described. Some theoretical aspects of using calcium aluminate based flux for desulphurization are outlined together with results obtained from laboratory experiments on sulphur removal from hot metal. By intelligent use of waste materials, the disposal of solid waste from the metallurgical industries can be reduced.

Jan 1, 2004

By Mario A. Morin

The last few years have seen considerable consolidation of the mining software industry and a trend towards greater planning and production control system integration, particularly for surface mines. The mining industry is starting to realize the benefits of system integration and will continue to drive the evolutions of these systems. Several trends can now be observed. The trends include application and system integration, data portability, ?intelligent? systems for support of decision-making activities, mine process-control and automation. While many planning systems are moving in this direction, there is room for considerable improvements. This paper will discuss these trends, examine the current state-of-the-art in mine design software, and identify areas where improvements should be made and why.

May 1, 2004

By E. Czech

Hydrogen generated through aluminum-assisted water split reaction is a novel, efficient and environmentally friendly method. It has been found previously that the passivation of aluminum can be prevented in neutral (pH=7) or near neutral pH conditions in water by grinding aluminum with a catalyst, such as A12O3, SiO2 or SiC. Recently, the best results have been obtained by using water-soluble inorganic salts (WIS), ground with aluminum. The massive, rapid corrosion reaction of the Al-WIS system which takes place in regular tap (or marine, or ground) water can be utilized to produce hydrogen by aluminum-assisted water split reaction, in-situ, on-demand. The reaction offers clean, low-cost, environmentally benign and entirely recyclable technology for on-board on-demand hydrogen generation. Besides pure gaseous hydrogen, only pure solid aluminum hydroxides AlOOH or Al(OH)3 are formed as the reaction products. The hydrogen yield and Al-WIS reaction efficiency are high. From 1 g of mechanically alloyed aluminum powder, up to 1.25 liters of hydrogen were generated, i.e. efficiency up to 92% was achieved. The amount of hydrogen and hydrogen generation rate depend on various reaction parameters. The effect of chemistry and concentration of additives, water temperature, powder particle size and milling conditions on the reaction kinetics will be presented and the possible process mechanism will be discussed.

Jan 1, 2005

By R. Ham-Su, J. P. Healey, S. P. Farrell, R. S. Underhill, M. A. Gharghouri, C. V. Hyatt, L. M. Cheng

Magnetic shape memory alloys (MSMA's) are a class of materials where magnetic energy can be converted into mechanical energy and vice versa. NiMnGa-based MSMA's have attained magnetic field induced strains up to approximately 10% and have a relatively wide operating temperature range, from well below 0°C to above RT, making them very attractive for a variety of applications. However, these materials also suffer from low toughness. Using these materials in a composite could mitigate this shortcoming, and also overcome limits imposed by inertia and eddy current losses. In this work, we describe the manufacture and characterization of such composites. Composites with 30% by volume MSMA were fabricated under a magnetic field resulting in anisotropic magnetic properties. Damping properties were evaluated by dynamic mechanical analysis.

Jan 1, 2004

By A. Valenzuel

Arsenic is a common impurity in copper sulfide concentrates treated pyrometallurgically, which inevitably during the smelting-converting process reports in the final copper product affecting its properties, but also it is a very toxic occupational hazard. Arsenic recovery or disposal from concentrates or arsenic-containing copper smelter dusts have been practiced in the metallurgical industry for many years. It has been recovered principally as arsenic trioxide by roasting or leaching then precipitated. On the other hand, several hydrometallurgical processes have been developed and implemented in smelters to remove it from arsenicbearing dusts and stabilize it prior to disposal in the form of a solid compound, either as calcium arsenate, arsenic sulfide or ferric arsenate. This paper reviews the methods implemented for arsenic recovery worldwide and arsenic disposal in the metallurgical industry.

May 1, 2001

By K. Shitogiden, Y. Samada, T. Miki

Steelmaking slag contains nutrition such as Si, P and Fe for acceleration of phytoplankton growth. Phytoplankton can fixate carbon dioxide more than any other species on earth. Hence, suppression of CO2 can be achieved by applying the potential of steelmaking slag as the nutrition for their propagation. When it is considered to supply nutrition from steelmaking slag to seawater, we must avoid dissolution of hazardous elements or change of pH of seawater by steelmaking slag addition into seawater. The protection against dissolution of fluorine into artificial seawater has been studied based on dissolution behavior of steelmaking slag and synthesized substances into artificial seawater in the present work. The dissolution mechanism of fluorine from steelmaking slag and buffering action of pH change are discussed by using stability diagram in seawater.

Jan 1, 2004

By S. Kawai

Natural convective flow of the electrolyte solution plays an important role in several electrochemical systems. Copper refining electrolysis is the most important industrial process to produce high purity copper on large scale. Turbulent natural convection develops along vertical plane copper electrodes installed in an unstirred electrolyte accompanying with the electrochemical deposition and dissolution of copper during the electrolysis. It introduces the electrolyte stratification phenomenon. Thus, the electrolyte is circulated in a special way depending on each electrorefining tankhouse. The theoretical discussion is indispensable to understand the coupling phenomenon between the ionic mass transfer rate and the morphological variations of electrodeposited copper. In present study, the mass transfer rate of both Cu2+ and H+ ions as well as the momentum transfer rate is numerically analyzed accompanying with the turbulent natural convection along 1 m high Cu metal electrode surface.

Jan 1, 2007

By J. L. Rodrigues Bravo

The aim of this paper is to show the results of the study that relate the variations of the bismuth content in the Caraíba Metais' electrolytic copper with the main electrolysis' process variables as electrolyte flow rate and temperature, anode's impurities content, electrolyte composition, current density, etc and their combinations and factors like cathode washing, blend of materials entering rod plant's furnace, analytical methods, shot-circuit inspection, etc. Also, the methodology considered arsenic, bismuth and antimony mass balance in the electrolysis and their electrolyte's molar ratio relations as well as bibliographic references of refineries that operate in similar conditions. The results showed the circumstances with the major probability of causing bismuth content increasing in the electrolytic copper and the main operating conditions that have to be fixed for having less bismuth variation and lower content in the electrolytic copper.

Jan 1, 2007

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By F. Golestani-Fard, A. A. Nourbakhsh

In this paper microstructural development of nitride-Bonded SIC refractories is reported in presence of Al203, Mg() and Urea additives .The samples were prepared by mixing, shaping and firing at 1400-1500°c in a controlled atmosphere furnace. Phase analysis, microscopic observation and mechanical evaluation were taken for microstructural investigations. The strength of samples doped with Al203 was first increased and then decreased at higher amount of Al2O3 additions. The addition of MgO decreased the strength while the urea showed an improving effect on strength. These phenomena could be attributed to microstructural evolution and mainly to liquid phase formation and grain morphology. It was found that the additives such as Al203, MO and urea could modify the microstructure in terms of phase formation and texture modification, which in terms influences the mechanical behavior.

Jan 1, 2004

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004