Numerical Simulation Of Turbulent Natural Convection Along Vertical Plane Electrodes

Natural convective flow of the electrolyte solution plays an important role in several electrochemical systems. Copper refining electrolysis is the most important industrial process to produce high purity copper on large scale. Turbulent natural convection develops along vertical plane copper electrodes installed in an unstirred electrolyte accompanying with the electrochemical deposition and dissolution of copper during the electrolysis. It introduces the electrolyte stratification phenomenon. Thus, the electrolyte is circulated in a special way depending on each electrorefining tankhouse. The theoretical discussion is indispensable to understand the coupling phenomenon between the ionic mass transfer rate and the morphological variations of electrodeposited copper. In present study, the mass transfer rate of both Cu2+ and H+ ions as well as the momentum transfer rate is numerically analyzed accompanying with the turbulent natural convection along 1 m high Cu metal electrode surface.