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By X. J. Guo, Q. K. Wang, S. P. Zhong

With depletion of traditional clean copper reserves and fast expansion of the global copper demand and smelting capacity in the past decade, more and more copper smelters have to treat copper concentrate with increasing content of complex arsenic-bearing minerals. Developing economically viable and environmentally reliable methods and approaches for arsenic control in copper smelting has become more critical for sustainable growth of the copper industry. This paper will report the recent effort of Zijin Mining Group Ltd. in developing processes for improving arsenic control and management in the Zijin Copper Smelter. The arsenic distribution and balance data for matte smelting, converting and refining operations in Zijin Copper Smelter is reviewed for understanding of the current challenges in arsenic control. The processes developed for treating the arsenic bearing waste acid bleed stream from the smelting-converting off-gases wet cleaning circuit and the arsenic sludge produced in the refining electrolyte purification circuit for arsenic disposal are discussed. INTRODUCTION With fast expansion of the global copper smelting capacity to meet the world copper demand and depletion of traditional clean copper reserves, more and more copper smelters have to treat copper concentrate with an increasing content of complex arsenic-bearing minerals. China is the world largest copper consumer and also has the largest copper smelting and refining capacity, but majority of its smelting capacity relies on supply of imported copper concentrate. In order to meet the increasing copper demand and ease the tight supply of clean copper concentrate, the Chinese copper industry has to look at the domestic opportunity of developing non-traditional copper resources, specifically those of lower grades, more complex mineralogy, and increasing level of deleterious elements especially arsenic and also process imported copper concentrate with increased arsenic content. Due to a significant and growing environmental issue associated with arsenic contamination, developing economically viable and environmentally reliable methods and approaches for arsenic management and control in unlocking the maximum value of such arsenic bearing copper resources has become more critical for sustainable growth of the industry.

Jan 1, 2019

By E. G. Joe

"The continuing increase in costs for power and fuel are affecting significantly the cost for milling of Canadian ores. In order to ascertain the scope and source of energy consumption in Canadian mills for further energy conservation opportunities, CANMET, in cooperation with the Canadian Mineral Processors carried out a detailed survey on the metallic mineral processing plants. Sixty-seven mills representing almost 300 million tons of annual capacity participated in the survey. The results indicated that in general, copper and iron ore mills, representing the bulk of the tonnage, consumed relatively low levels of energy per ton. Nickel-copper, zinc-copper and lead-zinc ore mills were moderate in energy consumption, while uranium and some copper-lead-zinc mills reported much higher energy consumptions due primarily to the increased heat requirements of the ore pulp. While the plant heating costs varied somewhat with the location in Canada, it was apparent that the lowest heating costs were achieved by those built with proper insulation and energy conservation design. If the cost per million British Thermal Units is taken as $2.00, the mill energy costs generally ranged from 40¢/ton up to $1.20/ton.IntroductionEnergy consumption in milling has always been of significant interest to Canadian mineral processors who traditionally calculate their milling costs down to pennies per ton. Even the measure of an ore's grindability is expressed empirically by Bond in kilowatts hours per ton milled. Some of the mills located in isolated areas were obliged to generate their own electrical energy from fossil or petroleum-based fuel at a cost substantially higher than that obtainable from captive or public hydro-electric installations. These mills practiced energy conservation long before the advent of O.P.E.C. energy cost inflation. One example of this was the use of electric boilers to produce process and heating steam during off-peak electrical load periods."

Jan 1, 1978

By Niels Verbaan, Ron Molnar, David Dreisinger

"An acidic chloride leach solution was generated from the treatment of an ore containing the following value elements: silver, gold, indium, gallium, copper, zinc and lead. Iron was also co-extracted into solution as a ferric chloride species. Iron extraction was a significant component of the overall acid consumption of the leaching process. The recovery of iron by solvent extraction and water stripping was investigated. Tri-butyl-phosphate (TBP) was very effective at recovering iron from the leachate. The water strip solution could be decomposed to produce ferric oxide (hematite) and hydrochloric acid for recycle via hydrothermal hydrolysis or pyrohydrolysis.INTRODUCTION The Malku Khota deposit is situated in the eastern part of the Bolivian Altiplano at elevations between approximately 3,800 and 4,580 meters above sea level (Figure 1). The project is located 98 km east-southeast of Oruro, and 85 km south of Cochabamba in a relatively remote area."

Jan 1, 2016

By Xian Jian Guo, Lei Li, Hua Wang

Direct smelting of copper concentrate to blister copper has the advantages of energy saving and environmental protection. There has been a lot of effort invested in process development including test work and theoretic analysis in the past half century. However, the process has only been applied commercially to a few smelters that treat chalcocite types of copper concentrate. The main limitation to treating chalcopyrite types of copper concentrate is high copper content in smelting slag and low direct copper recovery. Thus intensive slag cleaning is needed. In this paper, the thermodynamic analysis was mainly carried out for the multiphase equilibrium of direct to blister copper smelting for both chalcopyrite and chalcocite concentrates. The practical problems in direct to blister copper smelting, which are mainly in copper content in slag, are clarified. The operational window of slag composition for different temperatures and oxygen partial pressure for the treatment of chalcocite type concentrates is identified. The process operation optimization for the blending of chalcocite, pyrite and chalcopyrite concentrates was done. INTRODUCTION The extractive metallurgy of copper can be divided into two broad groups of processes, namely, pyrometallurgy and hydrometallurgy, and the former is dominant. About 80% of copper in the world is produced by pyrometallurgy (Christopher et al., 2006). The first stage of conventional copper pyrometallurgy processing is to smelt copper concentrate to copper matte composed of FeS and Cu2S with slagging to remove a proportion of the iron (Gargul, Boryczko, & Bukowska, 2017). The smelting processes include bath and flash smelting. The second stage of the process is to convert copper matte to blister copper. In most cases, the copper matte is converted in Peirce Smith (P-S) converters, which are batch operations (Kubiszewski, 2015). The P-S converting can be divided into two periods, slagging and copper blowing. During slagging period, FeS in copper matte is oxidized to FeO, which reacts with silica flux forming slag. When the iron content in matte is less than 1%, copper begins to oxidize and reduce to form blister copper (Kucharski, Sak, Madej, Wędrychowicz, & Mróz, 2013).

Jan 1, 2019

By Alan B. Morrow, William A. Poe

"Minerals processing operations are constantly challenged with improving production rates, yields, energy efficiency and process stability. Advanced Process Control has proven to be an effective tool for improving operations by capturing the full process capabilities consistently. However, the velocity of applying the technology as well as the sustainment of these significant benefits has been hampered by the usability of the software and adaptability of the applications.Some of the new technology developments that improve the usability and adaptability of advanced process control include:• modern and intuitive user interfaces,• customizable models to support unique process behavior,• fast and flexible OPC connection tools,• automated model building,• integration with first principles dynamic models and• improved performance monitoring.This paper will briefly discuss the new technology developments that have improved the usability and adaptability of advanced process control and how this can affect minerals processing operations.In today’s environment, Minerals Processing plant managers continuously face new challenges and requirements including:• higher energy efficiency,• increased run lengths,• reduced product quality variability,• reduced emissions,• higher availability, and• lower operating costsOperating a unit to meet these challenges in real time is not easy for operators and conventional process control systems. However, innovatively using existing technologies in Minerals Processing plants can improve operations on a minute by minute basis and reap significant benefits.Advanced Process Control (APC) can extract the maximum performance benefits from existing equipment while respecting plant operating constraints. Expensive capital projects to upgrade equipment are not always necessary. Advanced Process Control can deliver significant economic benefits by maintaining the plant at its most profitable point as conditions change."

Jan 1, 2016

By Karl Houseley, Dr. Robert J. Chapman

"A gravity concentration process has been applied to ores from the Clogau Mine, north Wales, the Tyndrum deposit, central Scotland and an alluvial ore from Leadhills area of Scotland. In the case of the Welsh ore and the alluvial deposit the gold grains in the concentrate and tailings streams have been characterised in terms of their three dimensions.In the case of Welsh ore, the thickness of a gold grain has been shown to be the single most important factor in determining behaviour in a gravity concentration operation. Six indices were used to quantify the overall geometry of the gold grains and those which incorporate a thickness term have proven to be effective in predicting the destination of gold particles within the concentration circuit. It is proposed that the most simple of these, the Heywoods flakiness ratio, has potential for the control of milling operations as an alternative to the established practice of characterising the size of the mill discharge.The effect of grain geometry on the recovery of fine gold has been studied using Tyndrum ore. The recovery of gold by gravity concentration increased from 20% to 70% when the criteria used to design the milling operation was the prevention of over grinding of gold grains.The destination of alluvial grains in the concentration circuit did not show such dependence on shape, and this has been attributed to the effective classification of all the gold grains in the sample by fluvial action producing a population of similar geometric characteristics."

Jan 1, 1996

By Chunlin Chen

Published data on thermodynamics of tin in liquid copper, matte and slag have been reviewed, assessed and used in development of thermodynamic solution models of melts. The developed model/database was applied in modelling the Sn deportment in primary copper smelting and e-waste melting processes. The results show that Sn can be removed from the matte through evaporation of various volatile Sn species (with SnS the most volatile) and slagging during copper smelting. The Sn removal increased with increasing matte grade due to the increased gas and slag volume. In the e-waste smelting process, fluxing strategy was developed for smelting e waste to produce a slag with reasonable liquidus and viscosity. Modelling results show that very low amounts of Sn reported to the gas phase due to low S, hence low SnS partial pressure in the system. The black copper produced could contain a few percent of Sn depending on the oxygen potential. The Sn in the black copper could be removed to the slag phase during anode refining. INTRODUCTION Tin is an impurity element commonly found in copper ores, which will be dispersed into various solid, liquid, and gaseous streams during the pyrometallurgical processing of copper. Tin alloy is widely used in electronic soldering due to its low melting point. The growth in treatment of recycled e-waste through primary and secondary copper smelting has led to an increased tin input to the smelting system. Therefore, the deportment of tin between phases is of great interest to the operators of modern smelters. Multi-Phase Equilibrium (MPE) is a thermodynamic package developed by CSIRO for simulating reactions between phases in multi-component and multi-phase systems (Zhang et al., 2002). Over the years the capability of the MPE model has been extended to cover the behavior of a large number of elements in high temperature system (Chen, Zhang, Wright, & Jahanshahi, 2006). In the present paper, the thermodynamic data on tin in liquid copper, matte and slag have been reviewed, assessed and used in the development of a database for Sn slag, alloy and matte phases. The model/database was applied in modelling the tin deportment in primary copper smelting and e-waste smelting processes. The aim of this study is to provide a better understanding of the chemical behaviours of tin in high-temperature copper processing and e-waste smelting.

Jan 1, 2019

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By Laxman M. Amaratunga, Glen G. Hein

"Most mining operations utilize the tailings coarse fraction for backfilling while the fines have been traditionally disposed on surface in tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10-30% w/w of <45 µm) in the fill (Brummer and Moss, 1991). This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMO) from these ponds has proven to be a costly environmental problem and a long term liability.One practical method to reduce the environmental impacts associated with the tailings pond is to modify the physical and chemical prope1ties of the fine tailings so that they can be utilized in an environmentally safe manner. This was accomplished by agglomerating the tailings into pellets and using theses pellets as a coarse aggregate in a total tailings paste fill. This technology does not require any supplemental sand or gravel to be added to the fill.This paper presents the ongoing research into utilizing these tailings agglomerates as a coarse aggregate fraction, in order to create a total tailings paste fill which has supe1ior strength characteristics.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. The waste rock is usually returned underground for use as rock fill in underground support with the tailings remaining to be disposed of in tailings ponds. Tailings consist of a coarse and fine fraction, and can be either reactive (acid generating) or non-reactive. In an effort to minimize tailings disposal, the coarse fraction has been used underground in backfill along with alluvial sands. This diversion of the coarse fraction, however still requires that the fine fraction be disposed of in tailings ponds. This disposal creates the potential for acid mine drainage (AMO), since in the presence of air and water, reactive sulphide tailings can generate acid. It is therefore an important goal in the mining industry to minimize the disposal of fine tailings into tailings ponds since the treatment of AMO is a costly and long-te1m environmental liability."

Jan 1, 1997

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

The scanning electron microscope (SEM) was primary developed for imaging applications. With the introduction of the Si(Li) energy dispersive spectrometer (EDS), simultaneous imaging and x-ray microanalysis became possible. However, long working distance and high current were needed because the position and small solid angle of the EDS detector. The high spatial resolution is generally obtained at short working distance with a SEM. Unfortunately x-ray microanalysis is never performed in the best imaging conditions. The annular silicon drift detector system is inserted below the objective lens which gives a higher solid angle (up to 1.3 sr). In consequence, a lower working distance and probe current can be used. An improved spatial resolution becomes possible during x-ray microanalysis. With this x-ray detector installed on a cold-field emission scanning electron microscope, quantitative x-ray microanalysis with high spatial resolution at low beam energy and low current becomes possible with the possibility of using the various different type of imaging at the same time. Also, since the count rate can be as high as 1,500 kcps, which lowers significantly the detection limit of elements as well as the minimum feature sizes of different phases that can be distinguished.

Jan 1, 2014

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By Aimee Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario, using bacterial metabolic processes are used to enhance the solubilization of the metal(s) of interest. The cost effectiveness of bio-mining in Elliot Lake depends on the bacterially-influenced dissolution metals of economic importance, as well as on the ability to suppress microbiological activity following the release to solution of the economically important elements. This poster provides an overview of elemental recovery results and release kinetics for more than 50 elements. The data is obtained using a combination of advanced spectroscopic tools (ICPAES and ICP-MS) to analyze solutions obtained from a series of environmentally controlled biologically mediated uranium ore extraction experiments. The focus will be on rare earth elements, potential environmentally toxic elements, and metals of economic importance. Furthermore, the importance of these findings will be put into an economic and geologic context for the re-development of the mining industry of the Elliot Lake Camp.

Aug 1, 2010

By John D. Carriere, Jean Leung, Daniel. Laguitton, Michael .. J. Burrows

"The objective of this expert system application in a copper-zinc concentrator, is to increase the availability of assay data through substitution for erroneous data. The assay data is used by the Operations personnel and automatic process control strategies to control flotation circuit performance. Two online X-ray fluorescence analysis systems analyze 24 streams across four divisions to provide the required data. Data availability of individual streams average 90% while the resulting circuit availabilities are 70%. The unavailability of correct data results from mechanical, X-ray or process problems. The erroneous data can be identified by process experts using knowledge relating stream interdependencies and historical process behaviour. An expert system was devised to provide real time identification of erroneous data and substitute for that data with the ultimate aim of improving metallurgical response by both the operator and automatic control systems.The paper discusses the early development work and architecture of the knowledge base designed using Neuron Data's expert shell NEXPERT.INTRODUCTIONThis paper describes the early development of an expert system (ES) prototype at the Kidd Creek concentrator. The project is a joint undertaking of the Kidd Creek Division of Falconbridge Limited and CANMET. Kidd Creek entered into the project to apply heuristic rules to the XRF assay data to improve the metallurgical control of the flotation process by increasing availability of analysis data. This project provided a problem of suitable size and future expandability while making use of a wide base of in-house expertise and experience. Another important benefit is the introduction of expert system technology to the site providing tools and experience for future system selection and technology application. CANMET has an on-going interest in assessing various aspects of ES technology (hardware, software, knowledge engineering, integration) while addressing problems in process operations that could most readily benefit from the technique. CANMET's role in the project was to provide project assistance, financial support, substitution algorithm assistance and software for data substitution. The knowledge bases (rules) have now been completed and are to be tested in the online environment."

Jan 1, 1989

By M. Nowak

Extreme high grades often exert too much influence on surrounding block estimates, leading to a smearing of high grades that can cause overestimation of mineral resources. This concern underlies the decision to cap high grades, i.e., to lower the highest grades in a drill hole data set to some level deemed to be reasonable for producing reliable resource estimates. The choice of a capping level can, by itself, have a large influence on the analysis of the economic viability of a project. Despite this, it is often a choice that is made arbitrarily, guided more by art and tradition than by sound technical analysis. This paper makes suggestions for good capping practices, using methods and procedures that have been presented elsewhere, in the technical literature and in conference papers. The authors propose to use capping only if absolutely necessary, and review examples of cases where capping may not be necessary, or where capping does not make the estimates more reliable. It addresses two particular instances where capping is recommended: (1) where there is good reason to believe that estimation with uncapped grades will overstate the true underlying average grade, and (2) where there is potential for overly optimistic assessments of local block grades in the vicinity of some very high grade assays. The proposed capping practice is based on adjustments to only a very few high grade assays. The level of this capping can be assessed by bootstrapping and through analysis of the effect of extreme values on summary statistics like the average and the coefficient of variation. The paper recommends that good practice include an examination of the potential for local overestimation in higher grade areas.

Aug 1, 2013

By B. McFadzean, J. Taguta

In order to recover minerals by flotation, the sub-processes of collector adsorption onto the valuable minerals followed by bubble-particle attachment should occur efficiently. This paper investigates both of these sub-processes for various thiol collectors and their mixtures onto base metal sulfide minerals. The aim of the work was to investigate whether there is a correlation between the strength of the collector interaction with the mineral and the subsequent bubble-particle attachment. The collector-mineral affinity was measured experimentally using an isothermal titration calorimeter in order to determine the molar enthalpy of adsorption for each collector-mineral system. The bubble-particle attachment was measured using a microflotation device which essentially determines the hydrophobicity of the mineral. Sodium ethyl xanthate (SEX) and sodium diethyl dithiocarbamate (DTC) and mixtures thereof were used as collectors with either single minerals or binary mixtures of pyrite and chalcopyrite, respectively. The adsorption enthalpies of the collectors were interpreted with reference to the chemical structure of the collector molecule and showed that the greater the positive inductive effect of the collector, which may be qualitatively related to their pKa, the greater their affinity for the mineral surface. In the microflotation studies, recoveries were strongly related to the alkyl chain length but there was no correlation between the enthalpies of adsorption and the flotation recoveries. When mixtures of collectors were used there was clear evidence of synergistic effects and in the case of DTC/xanthate mixtures it is possible that this synergism is related to a DTC promoted oxidation of xanthate to dixanthogen. When mixtures of pyrite and chalcopyrite were used the flotation recovery and enthalpy of adsorption of SEX onto the individual pyrite particles in the mixture increased substantially compared to the case of pyrite alone. Mechanisms are proposed to interpret these important observations.

Jan 1, 2016

By M. Remillard, M. Garon, M. Thérien, D. Hodouin

"Nineteen streams in the copper and zinc flotation units of the concentrator of the Matagami division of Noranda Inc. have been sampled for particle size distributions chemical assays, and gold and silver contents in each particle size interval. The data are upgraded by the mass balance package BILMAT. These results, in conjunction with microprobe analyses, are used to quantify the silver losses in the copper clean¬ing flotation stages and to determine how overall silver and three silver-bearing minerals are recovered in the plant final products.RESUME Dix-neuf produits des circuits de flottation du cuivre et du zinc de la division Matagami de Noranda Inc. ont été échantillonnés pour leur distribution granulométrique, analyses chimiques et le contenu d'argent et d'or des fractions granulométriques. Le bilan métallurgique a été obtenu à l'aide du programme BILMAT. Ces résultats couples avec une etude minéralogique à la microsonde sont utilises pour quantifier les pertes argentifères aux diverses étapes de nettoyage du circuit de cuivre et pour de¬terminer la repartition de l'argent et des trois minéraux argentifères dans les produitsfinals de l'usine.INTRODUCTION The Matagami division of NORANDA INC. produces copper and zinc concentrates from a sulphide ore which contains a small amount of gold (0.34 g/t) and silver (20 g/t). Only a small part of the silver (~-30%) is presently recovered in the copper concentrate. The objective of this study is to evaluate the metallurgical behaviour of silver, and secondarily of gold, in the flotation circuit for a possible increase of its recovery in the copper concentrate to improve its economic value. For that purpose it is worthwhile to study the minerals which bear silver and to determine the critical flotation stages where they are lost in the tails. The methodology proposed here is based on a coupling of a mineralogical study and a detailed mass balance calculation in the flotation circuit."

Jan 1, 1986

Mining Impact in Water Quality: Understanding the conflict Mining is an industrial process Metal mines that chemically process ore to concentrate metals such as copper and gold use more water than non-metal mines such as coal, salt and gravel. Tailing Ponds Water contaminated with high concentrations of metals, sulphide minerals, dissolved solids, or salts can negatively affect surface water quality, aquatic ecosystems and groundwater quality.

May 1, 2013

By Dale A. Sketchley

"Abstract - Large differences in gold content between rock fragments or small volumes of unbroken rock, commonly referred to as the nugget effect, are related to sample and subsample weights, crushing and pulverizing sizes, and density, shape and size distribution of gold grains. Gy’s sampling theory, which relates gold grain characteristics to sample weight, fragment size, and error, provides a method of estimating a sampling constant that quantifies deposit characteristics that contribute to the nugget effect.Sampling control tests provide methods for determining the sampling constant. Sampling control charts, comprising nomographs that relate sample weight, error and particle size, use the sampling constant to optimize sample weights and comminution sizes, and to minimize the variability introduced by incorrect or inadequate sampling and sub-sampling procedures. The sampling constant is useful in classifying ores into arbitrary categories according to expected sampling difficulties. Spatial variations in the sampling constant can be used to aid in defining ore types for modeling geological domains, which should have unique sampling protocols. Examples that illustrate the relationship between the sampling constant and expected sampling problems, and the spatial variation of the sampling constant, are given for various deposits. Case histories of sampling programs are presented.Quality control procedures consist of monitoring sample contamination amd accuracy and precision of analytical results. Accuracy, precision and contamination are monitored by including standards, duplicates and blanks into batches of samples being analyzed. Analytical results of standards and blanks are plotted on a batch-and-time basis with control lines at plus or minus two/three standard deviations as confidence limits of the accepted round-robin value. Examples are given that illustrate a laboratory system in statistical control and the various types of problems encountered when interpreting quality control data. These include sample transcription errors, degradation, contamination, sampling errors, detection limit problems, instrumental drift, lack of statistical control, laboratory bias, procedural problems and data tampering.Where bias is negligible, precision, as a function of concentration, can be obtained from duplicates using the Thompson-Howarth precision algorithm, which also allows calculation of the practical detection limit. Examples are given that illustrate variations in precision, with grain size, for different types of duplicates, as well as mineralogical changes and sampling errors."

Jan 1, 1998

By Jose A. Jimenez

"Mining operations generate an enormous amount of data that is difficult to organize, analyze and act on. These data require an extremely broad range of experts to investigate and manage the cross-disciplinary information. The data collects in paper files, diverse databases, historians, stand-alone applications, and excel files. This collection of sources represents everything from monthly, weekly, or daily inputs to real-time feeds or sporadic unscheduled entries. With the operational complexities ever increasing and fewer engineers per mine, an efficient operation is becoming more and more challenging. Engineers are typically burdened with data collection, clean up, and administrative efforts leaving very limited time for engineering assessment and/or optimization analysis. Often optimization becomes limited to the analysis of equipment uptime through existing field automation systems. A great portion of the field data is tucked away in historians seldom reaching those engineers who might leverage the data. Few mine operators have the time or budget to re-architect their operations data collection or management practice, so solutions must enable improvements without requiring expensive or time-consuming implementation. This presentation highlights examples where the aforementioned challenges are addressed using a solution framework designed to enable: 1) data integration and connectivity, 2) monitoring and opportunity recognition, and 3) engineering workflow automation. The initiative extends the concepts and success proven in the automation market segment to all disciplines across the mine operations. INTRODUCTIONThe mining industry by its very nature spends a great deal of its capital on equipment maintenance and replacement. In addition, periodic shutdowns due to equipment failure are typically very costly in terms of interrupted operations. Keeping mining equipment running at peak performance and avoiding costly shutdowns can make a huge difference in the overall return from mining operations. Today, information can be make available that can go a long way towards spotting equipment issues and permitting timely intervention to avoid costly unplanned shutdowns. That said, gathering all of the information from numerous points on many different pieces of equipment necessary to enhance overall equipment effectiveness presents its own daunting issues."

Jan 1, 2016