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By M. A. Boucher

The purpose of my presentation is threefold: a) to make you aware of what is available in Canada in terms of refractory minerals. b) indicate the mineral deposits that have potential for development. c) show the advantages of Canada as a supplier of electrical energy necessary for the production of electrofused minerals. Canada is a producer of natural refractory minerals, electrofused minerals, and synthetic refractory minerals. Several deposits also have good potential for development. The natural refractory minerals produced in Canada are shown in Table 1. The major minerals by decreasing order of importance in terms of tonnage and values are: dolomite, graphite and magnesite.

Jan 1, 1992

By Abb Raymond

Finely processed industrial minerals in "powdered" form have long been utilized by the plastics, paint, rubber, paper, ceramics, and adhesives industries as fillers, extenders, coatings and special additives. These minerals, primarily calcium carbonate, talc, kaolin, titanium dioxide, and the like, have provided economic, uniform and consistent base materials which have, in turn, been used by the referenced industries to manufacture quality products. The focus of this paper will be the development of equipment and systems at ABB Raymond for the dry processing of such non-metallic minerals in order to meet what have become increasingly stringent requirements of the producers of these minerals. Changes in these requirements seem to have been accelerating rapidly during the last ten years, and it is expected this process will continue into the 1990's.

Jan 1, 1990

By B. T. Darnton

Gravity concentration at the Pegasus Gold Montana Tunnels Mine was initiated in late June, 1991 with the commissioning of a coarse gold scalping circuit that processes a small portion of the ball mill circulating load. The primary objective for the circuit was to reduce the risk of gold particles advancing to flotation that are too coarse to float. The secondary objective was to enhance overall gold recovery and payable gold ounces in a cost effective manner. The gravity circuit has proven itself to be a major success. The above mentioned goals have been achieved, and they have been maintained at record throughput rates that are 30% higher than when the circuit was commissioned. A number of modifications and improvements were made over the last three years which allowed the gravity circuit to keep pace with the higher tonnage, these are discussed in detail in the body of this paper. The overall approach to gravity concentration at Montana Tunnels has always been to optimize production rather than maximize the gold ounces produced. This philosophy has now yielded a circuit expansion and relocation project which will allow for an estimated 50% increase in gravity gold production, while reducing the overall unit costs of production significantly. This paper will review historical gravity circuit performance, improvements, and the current relocation and expansion project.

Jan 1, 1995

By Dan Eyde

Low levels of thallium were detected in the mine water drainages, and process water discharges of western mining and smelting operations. This required remediation under state regulatory standards, which allow discharges of no more than .0017 ppm thallium in mine water discharges. Influent streams containing thallium can be mitigated to state discharge standards after a single pass through the series of fluidized upflow columns. Test work to determine the optimal flow rates used pilot scale systems at two separate locations treating 5 - 25 gpm of effluent. The test system at the gold mine mimics the full-scale system, which will be based on the existing upflow carbon tanks that have been converted to zeolite columns. The system installed at ASARCO's East Helena smelter has a far more complex influent stream with a high loading of competing cations. Nevertheless the columns filled with CABSORB® are successfully mitigating the thallium contamination. CABSORB® ZS500RW is a product based on the sodium analog of the zeolite mineral chabazite named herschelite.

Jan 1, 1998

By Robert A. Blake

Introduction Sulfide copper, zinc and iron concentrates are recovered in the 5000 ton per day flotation plant operated by Cities Service Company at Copperhill, Tennessee. The heavy-sulphide ore is first ground to 50 pct. minus 200 mesh and a bulk concentrate floated. The bulk concentrate, over 60 pct. of the ore weight, is reground to 72 pct. minus 200 mesh and then treated in a selective flotation circuit to recover copper and zinc concentrates. The tailing of selective float is the iron sulphide material source for the manufacture of sulfuric acid and iron sinter. The valuable minerals in the ore are chalcopyrite, marmatitic sphalerite, pyrite, and pyrrhotite. A typical mineralogical analysis will be found in table 1. A typical material flowsheet will be found in figure 1. Shown in the flowsheet are a scavenger float on the bulk rougher tailing and a copper-talc separation unit. At times a lead-copper separation circuit has been run.

Jan 1, 1971

By Henrique D. G Turrer, Desmond Edifor, Marcello R. Cruz, Josue M. de S Junior, Darius Wonyen

A geometallurgical testing program was developed to anticipate ore behavior in the beneficiation plant and support production planning. Over 100 drill core samples from a major iron ore deposit were tested using bench-scale gravity and magnetic separation methods to assess variability in process responses. Results showed significant differences in key attributes such as iron grade, gangue content, slimes generation, and specific gravity, directly impacting concentrate grade, recoveries, and tailings quality. Correlation analysis and regression models were used to link feed properties to process outcomes, and a mass recovery estimation equation (Wrec) was developed for predictive use. The study proposes the integration of geometallurgical parameters—such as Fe, SiO2, Al2O3, LOI, ore type, size fractions, and slimes content—into the block model to support blending decisions and minimize operational risks. This work establishes a solid foundation for long-term mine-to-plant integration, with future phases aiming to expand testing and build a calibrated geometallurgical model.

Feb 22, 2026

By Bruce L. Bryson

In the past decade a principal growth area in refractory technology has been the development and use of extra high alumina refractories. The refractories user is asking for, and is prepared to pay for, higher purity, more dense materials with longer life, less maintenance, and better dimensional tolerance to meet the exacting demand of high output processes. High alumina and bauxite refractories are being used more and more to keep pace with the demand for guaranteed performance. The steel industry, for example, is starting to place great reliance on these products. A unique material now available with all the requirements for extreme purity and density is tabular alumina, already proving itself in many refractory applications.

Jan 1, 1973

By Moreno Pescara, Luca Soldo, Piergiorgio Grasso

"Risk management in tunneling is more important today than it was a few years ago, considering increasing demands for safety and environmental and socio-economic sustainability, which are now required by citizens, owners, lenders, and insurers. Moreover, our current risk management philosophy should not only address risk avoidance and mitigation, but should also be used as a means of value creation, benefiting the overall project. Given the strategic implications of risk management, the authors intend to present, in this paper, a comprehensive overview of references and experiences from current practice—e.g., what is missing or weak, as well as possible or necessary developments that can have a key role in implementing effective risk management, particularly for a project’s design and construction phases. Therefore, as God has set some things in broad daylight; as he has given us some certain knowledge, though limited to a few things so, in the greatest part of our concernments, he has afforded us only the twilight, as I may so say, of probability (John Locke) PREFACE Many large-scale engineering and construction projects suffer millions of dollars in cost overruns, delays in design and construction, and operability troubles once finally completed (Edward W. Merrow, 2011). The undesired effects of these problems can become disastrous for large-scale megaprojects (those that typically cost US$1 billion or more), particularly considering that these are increasingly used as the preferred delivery model for infrastructure (Bent Flyvbjerg, 2014), often in public-private partnerships (PPPs). McKinsey G.I. (2015) has estimated that bridges and tunnels average 35% in cost overruns, and roads 20%. Some of the values published by Flyvbjerg (ibidem, 2014) for projects with relevant underground elements are the highest, with cost overruns from 60% to 300%. The analysis of 32 other case histories (from 1994 to 2010) given by Hartmut, R. (2011, IMIA Annual Conference, Amsterdam) indicates an average increase of costs around $55 million, with a 20-month average delay."

Jan 1, 2016

By Matthew Grzelak, Gulsah Erinc, David R. Chapman

"The third phase of the Bagram Drainage System project at Bagram Air Force Base in Afghanistan included construction of a shallow, 540-m long, 1.8-m inside diameter drainage tunnel. The tunnel penetrated mostly stiff to hard clayey and silty soils. The contractor’s Value Engineering Change Proposal (VECP) to use pipe-jacking with a microtunnel boring machine (MTBM) instead of the specified two-pass Earth Pressure Balance method was evaluated and supported using hand calculations. Contractor support was provided throughout the project by providing design reviews and instrumentation monitoring during construction. This paper compares the value-engineering proposal to the specified method and describes the construction conditions encountered. INTRODUCTION As part of a larger improvement project at the Bagram Air Force Base in Afghanistan, a shallow, 540-m long, 1.8-m inside diameter drainage tunnel was constructed to provide additional capacity for Coyote Creek to pass below several critical structures, including taxiways and the main runway, for mitigation of recurring flooding (see Figures 1 and 2). Overburden over the tunnel crown ranged from about 3 m to 5.5 m. An existing cast-in-place twin barrel concrete culvert runs approximately parallel to the new tunnel and is within about 8 m at its closest point. The contractor’s Value Engineering Change Proposal (VECP) to the specified two-pass Earth Pressure Balance (EPB) method (steel ribs and lagging or steel liner plate with a carrier pipe later grouted in-place) called for installation of the required drainage pipe by pipe-jacking (one-pass installation) using a slurry microtunnel boring machine (MTBM). The critical nature of the operations at the air base resulted in significant construction coordination challenges and a greater than usual need to avoid excessive settlements. Substantial restrictions were placed on drilling of investigative borings and installing instrumentation near runways and taxiways due to drill mast height. The prime contractor was SERKA TAAHHUT INSAAT A. S. (SERKA), the microtunneling subcontractor was Ludwig Pfeiffer Microtunnel GmbH & Co.KG (Pfeiffer), the jacking pipe designer was Gollwitzer Pipe and Shaft Technology GmbH (Gollwitzer), and the contractor’s tunnel engineer was Lachel & Associates, Inc. (Lachel). Lachel provided contractor support throughout the project including preparation of a VECP/Design Summary (including interpretation of existing and new geotechnical information), design reviews for jacking pipe, estimating settlement of an existing drainage structure above the new tunnel, and instrumentation planning, monitoring, and analysis during construction."

Jan 1, 2016

By Harry Perry

The Bureau of Mines is glad to have this opportunity to discuss its present Coal Research Program and its significance to the industry with a group which has for many years been representative of the coal producing community. We believe we have a dynamic program that will help our vast coal resources to find their proper place in the U. S, economy. The present coal research activities of the Bureau are conducted in three organizational subdivisions: Minerals Research, Mineral Resource Development, and Health and Safety. All investigations are carried out in Bureau research facilities located in different sections of the country, Since its creation by the Organic Act of 1910 and subsequent amendments, the Bureau has worked closely with the coal industry--first by providing assistance in mine safety for anthracite and bituminous coal mining, and since that time, in providing information on conservation, safety, mining, preparation, and utilization.

Jan 1, 1966

By D. M. Ziebarth

"During the mid to late 1960’s, the underground potash industry in Saskatchewan was born. For the next four decades the industry operated at a steady pace supporting a large part of the world demand; until 2008 when the potash market heightened. Operators were motivated to capitalize on this increased demand, new mines were proposed while existing mines were planning upgrades. Potash Corporation of Saskatchewan (PCS) was one of the major producers planning upgrades to their production facilities quickly, including modifying the existing headframe and shaft at the PCS Cory Site to accommodate a new 1500 tonne per hour hoisting plant. Upon completion of the project, the innovative operations group continuously reviewed methods to increase production and reduce operating costs, allowing PCS to continue being competitive on the world market. This paper will describe the design challenges encountered during the development of the infrastructure around an operating facility whilst minimizing down time, schedule, capital and construction costs. This paper will also explore the strategy to increase capacity of the newly commissioned hoisting plant. BACKGROUND Potash production is a major Saskatchewan industry, and has played a significant role in the economy for over 40 years. Production commenced in 1962 when water problems were overcome at the International Minerals and Chemical (IMC) mine near Esterhazy, Saskatchewan. A surge of development by other companies resulted in twelve companies opening ten mines by 1970. In 1975 Potash Corporation of Saskatchewan was created by the government of Saskatchewan and shortly thereafter purchased several mines in Saskatchewan, including the Cory Mine (Cory), near Saskatoon. Cory has been in operation since 1968 and is located 12 km (7.5 mi) west of Saskatoon in central Saskatchewan. The mine is located in the center of the world’s largest potash deposit, 1,000 m (3300 feet) below surface. PCS has embarked on sizable capital expansions of more than CDN $7 billion. The Cory CDN $1.6 billion expansion was expected to raise operational capability of the site to 2.7 million tonnes per year, an increase of 1.9 million tonnes per year (MTPY). To achieve 2.7 MTPY of finished product and considering the 22.6% average production recovery1, 12 MTPY of ore must be hoisted to surface for processing. To deliver this rate required upgrading of the hoisting plant to 1500 tonne per hour (TPH). To accomplish this ambitious challenge, creative thinking, careful planning and a cohesive team was needed to work together to ensure the schedule, budget and most importantly the work was completed safely"

Jan 1, 2017

By Steven Keim, Steven Stansfield, Kevin Andrews

Geotechnical, geological, and hydrogeological fieldwork and data collection for the mining industry is often conducted by younger, less-experienced staff members. In many cases, fieldwork personnel are recent college graduates or are otherwise relatively new to the mining industry. Due to busy schedules, staffing shortages, project budgets, and in some cases, poor management, new fieldwork hires often do not receive thorough training. In the past and the present, many workers in the mining industry learn(ed) by “doing.” While this is still considered to be the most practical approach and the easiest way for a company to determine the skill set of an employee, there is always some risk involved in the “feet to the fire” method. The reality is that field personnel are often collecting data on which major operational decisions will be made or on which regulators will base enforcement decisions. Inadequately trained or inexperienced field personnel may collect inaccurate data or fail to recognize key conditions that may influence decisions made by regulators, design engineers, mine managers, and corporate leaders. Even the best engineers may come to incorrect conclusions if they are starting with poor input data. Decisions based on inaccurate data often result in delays, budget issues, unsafe conditions, or even worse consequences. This paper provides numerous mining industry examples of incidences where inaccurately collected field information did, or could have, resulted in major adverse consequences. The paper also offers some simple approaches to minimizing the potential for such problems.

Jul 1, 2023

By Rafael C. Castro, Paul V. Savard, Kathleen M. Murtagh

Preliminary design is underway for the Massachusetts Water Resources Authority’s (MWRA) next major tunnel program, the Metropolitan Water Tunnel Program (MWTP). The MWTP is the latest part of MWRA’s ongoing efforts to achieve redundancy for its metropolitan water transmission system including its historic deep rock City Tunnel, City Tunnel Extension and Dorchester Tunnels. The MWTP comprises several deep rock tunnels that will be approximately 10-foot to 12-foot finished diameter totaling just over fourteen miles long and ten connections to existing large diameter surface piping and pumping stations. This paper will present an update on current engineering and permitting efforts, packaging schemes, and the schedule to complete the MWTP.

Jun 13, 2023

By G. W. Phelps

This discussion deals with the geology o£ the Tennessee-Kentucky ball clay deposits; their mineralogy and chemistry; methods of finding, mining and refining; and makes observations on reserves of and future prospects for these clays. Ball clays appear in ceramic formulas for manufacture of vitreous china sanitary-ware, electrical porcelains, floor and wall tile, dinnerware and artwares(l). This type of clay is used for refractory (2) and abrasive products(3), and as a suspending agent for ceramic glazes(4), engobes(5) and porcelain enamel slips(6). Although some ball clay is imported, probably 85-90 percent of ball clay used in the USA(7) is obtained from deposits in Weakley, Henry and Carroll Counties in Tennessee(8), and in adjacent Graves County, Kentucky(9). The term "ball", as applied to clay, probably derives from former mining practice in England whereby conveniently-sized blocks of clay were cut from moist clay beds by spading(10), The expression "ball" has no other technological significance. ASTM(11) defines ball clay as "a secondary clay, commonly characterized by the presence of organic matter, high plasticity, high dry strength, long vitrification range, and a light color when fired." This, and similar(12) definitions, applies to English ball clays but is not satisfactory for many American ball clays. Geology of the Tennessee-Kentucky Ball Clay Deposits Figure 1 shows that most commercial clay areas of the eastern United States lie near the edge of the Coastal Plain; a skew-shaped configuration of its landward boundary outlines the Mississippi Embayment(13), Near the apex of this basin a broad plain, with a rolling, Bullied topography(14), dips gently westward from the Tennessee River to bluffs at the edge of the Mississippi River flood plain.

Jan 1, 1972

By P. Somasundaran, S. Venkatachalam, N. K. Khosla, K. Khosla

Froth flotation of alumina particles was studied by employing and hydrogen gas bubbles. The effect of current density was studied over a range of 0.1 to1.6 kA/m2. Compared to hydrogen, the use of oxygen bubbles at any given gas evolution rate resulted in a higher flotation recovery. The existence of an optimum current density, for each given particle size was indicated. Flotation at higher current densities resulted in better flotation kinetics, while flotation at lower current densities resulted in better Spas utilization.

Jan 1, 1996

By E. A. Domínguez

La Espingarda kaolin deposit was formed by ?in situ? alteration of volcaniclastic rhyolitic rocks belonging to Jurassic Marifil Formation. Three volcanic lithofacies were identified: porphyric biotitic ignimbrites (PBI), a coarse lithic ignimbrite (ILG), a fluidal intrusive rhyolite (RFI), all kaolinized in different degrees. The alteration covers an ellipsoidal area of ~20,000 m2, with its alteration decreasing downwards and disappearing at 8-12 m from the surface. The length to thickness ratio of alteration is 60:1. An erratic silicification was found as small zones (<3 m2) of quartz stockwork. The mineralogy is kaolinite + quartz + feldspars + Fe-oxyhydroxides ± halloysite ± illite and interstratified I/S, although the relative proportions change in each rock type. Due to coarse grain size and high quartz content, natural kaolin is unsuitable for slip cast ceramics, unless beneficiated. Washed ILG kaolin has the best rheological properties and behavior in casting and drying for its mineralogy, particle size distribution, thin texture and surface activity, as well as a certain fusibility and firing kinetics. PBI and RFI kaolins, due to finer texture, smaller grain size, lower surface activity, and higher halloysite amount, have worse slip viscosity and thixotropy that are due also to soluble salts. For the same reason, they have good casting and drying properties, but their purity brings about higher softening temperatures and water absorption. Several parameters are used to discriminate between hypogene or supergene kaolinite genesis. The hydrothermal genesis is mainly sustained by fluid inclusion temperature (150-180ºC) in quartz veinlets, while weathering is supported by deposit morphology, simple mineralogy, kaolinite stable isotopes (d18O ? 18, 13; dD ? ?59; ?85) and paleoclimatic record. It is concluded that a weathering process formed the main alteration with some participation of steam-heated meteoric waters. Neither the contents of Au, Ag, As, Sb, Hg, nor drill data support the existence of any epithermal gold mineralization at the kaolinite bottom.

Jan 1, 2010

By P. Zhang

Phosphate mining in Florida generates approximately 100,000 tons/day of phosphatic clays (slime). This waste slime not only creates one of the most difficult disposal problems in the mining industry, but also causes tremendous loss of P2O5. About 20-30% of the phosphate mined end up in phosphatic clays. Recovering the phosphate from this waste is difficult for two main reasons: 1) the slime is extremely fine in size, and 2) clay minerals account for almost half of the material. A half dozen dispersants were evaluated for keeping the clay minerals suspended for subsequent separation from non-clay minerals by either settling or cycloning. The separation efficiency and economics are discussed.

Jan 1, 1998

By J. Choi

For the first time, the influence of stearyl trimethyl ammonium chloride (STAC) as a collector, on the flotation behavior of lepidolite (Uljin, South Korea) was systematically examined in Denver Sub-A cells. Flotation tests were carried out by varying amount of STAC (50?200 g/ton), feed size (-65, -100, -150, and -200 mesh), and solution pH. The impeller speed of 1000 rpm, flotation time of 10 min and AF-65 (a frother) of 250 mL/ton were invariably applied. In order to complement flotation experiments, zeta potential measurements and XRD analysis were conducted. XRD results showed that the ores were mainly composed of lepidolite, muscovite, quartz, calcite and albite. In addition, zeta potential results showed that isoelectric points were about 2.5, 2.3, and 9.7 for quartz, albite, and calcite, respectively, and lepidolite was determined to be less than 2. Overall, the results of 3-stage flotation showed that Li2O grade and recovery tended to increase with increasing STAC dosage and decreasing feed size. In addition, Li2O grade increased with decreasing pH. The results were explained by the extent of the interaction between STAC and each mineral.

Feb 23, 2014

By O. Salami, G. Xu

Fire accident is one of the most classic safety concerns in underground mines both in the USA and abroad. It may occur from pool fires due to leakages in hose or pipes, vehicle fires, or fires in tires and conveyor belts in the underground mines. It may also result from the storage of flammable materials such as gasoline, diesel, and explosives in the underground. When fire occurs in an underground mine, it releases heat, smoke, and other toxic gases such as carbon monoxide, and methane to the surrounding thereby making life unbearable to the miners. Furthermore, smoke greatly impact visibility in the underground which makes evacuation even more onerous and challenging. To this end, a thorough investigation of fire behavior and spread of toxic gases in a practical underground mine is imperative to develop a reliable emergency evacuation plan in an event of fire disaster in the underground mine. The objective of this study is to investigate temperature variation and CO spread along mine airways by conducting full-scale fire experiment in the underground mine. The results presented from this study are crucial to developing evacuation plans in underground mines. In addition, the findings from this study could be used to validate existing evacuation models.

Mar 2, 2022

By Neely H. Bostick

The primary and secondary organic matter in sedimentary rocks changes markedly when it becomes heated as a consequence of thick sediment accumulation and normal geothermal gradients, high geothermal gradients, hydrothermal fluids, or igneous events. Contact zones adjacent to small igneous dikes allow sampling of a single sedimentary bed that has been exposed to temperatures in a range as great as 30-500°C. Dike-heated rocks are, therefore, good sites for research on thermal effects because variation of the original organic matter is minimal, the range of heating is great, and the history of rock heating in a dike zone is relatively well established. In rare cases, such as at the dike near Wolcott, Colorado, described in this paper, the rock samples are sufficiently unweathered to allow analysis of secondary bitumens generated by the heating. We show by optical microscopy, scanning and transmission electron microscopy, and geochemistry the kinds of solid organic constituents in sedimen¬tary rocks and in ore deposits and the effects of heating. The primary phytoclasts that make up kerogen In sedimentary rock and in some ore deposits (pollen, resin, charcoal, humified woody remains, etc.) change in ways that are familiar to coal specialists. Progressive loss of moisture and other volatile matter yields residual kerogen that Is relatively higher in carbon and lower In oxygen and hydrogen, and has greater molecular or polymer ordering. In our contact zone examples, atomic H/C ratios of kerogen decrease from 0.8 (one case from 1.4) to 0.4, the hydrogen index from Rock-Eval pyrolysis decreases from 70 to 5, and the transformation ratio from Rock-Eval pyrolysis increases from 0.06 to 0.5 with increased heating. The visible effects of heating seen by scanning electron microscopy and light microscopy include formation of vesicles and flow structure, the development of optical anisotropy and mesophase, change of color, and increase in the refractive index, absorption, and reflectance. Some of these changes In primary organic matter are observed also in secondary organic matter, for example, in solid bitumens in sedimentary gold ores or In lead-zinc deposits. Quantification of color or absorption changes is difficult because it Is hard to make thin sections of organic matter with uniform thickness. However, natural objects with uniform thickness can be used. We show the colors of pollen In rocks from the Salton geothermal field at temperatures ranging from 100 to 300°C, and of pollen heated in laboratory bombs from 150 to 400°C. Measurement of vitrinite reflectance is a practical way to quantify thermal changes of kerogen and minerals of most sedimentary rocks because vitrinite is fairly widespread In sedimentary rocks of Devonian age and younger. For example, the reflectance of vitrinite rises from the regional level, as low as 0.4 % Ro, to more than 5% Ro adjacent to dikes that cut sedimentary rock. This is equivalent to the rank change from subbituminous coal to extreme meta-anthracite. The rise is most abrupt near thin dikes, but when the distance from the igneous contact is expressed as a ratio of dike thickness the reflectance rise is similar for all dikes. Controlled heating of vitrinite-bearing rocks In the laboratory provides a means to assign known temperatures to vitrinite-reflectance values. The derived plots of temperature In dike contact zones have the same shape and level as those predicted by heat theory, and the temperature lines extend toward dike contact temperatures that are about half those of most magmas, as expected if the intrusions did not flow past the sedimentary rock for a long time. The globular submicroscopic structure of vitrinite and Its heterogeneity, which we show by means of transmission electron microscopy, pose some problems In selecting a uniform type of vitrinite for measurement of thermal changes. At present, routine reflectance values of vitrinite dispersed in rocks have a relative uncertainty as great as 10%. Thermally caused chemical changes in the primary kerogen, especially decrease in the oxygen and hydrogen contents, lead to formation of secondary products in the contact zone. The measured changes of secondary organic products in these rocks include formation of peaks In concentration of total extractable organic matter and in hydrocarbons, and in the saturated/aromatic hydrocarbon ratio over the interval where primary organic hydrogen decreases most rapidly--then destruction or expulsion of these products at high temperatures. The odd carbon-number predominance of the C25-C31 n-alkanes In samples far from the dike disappears by about 1.3% Ro whereas the 13C: 12C ratios of the saturated and aromatic hydrocarbons increase over most of the thermal range. The saturated aromatic hydrocarbon ratio at first increases, corresponding to thermal generation of saturated hydrocarbons, then decreases in the most altered samples. One use of organic petrography, in addition to identifying organic fades or thermal alteration, is recognition of sample contamination such as the solid organic additives used in some drilling muds which may contaminate geochemical samples.

Jan 1, 2013