Search Documents

By Narasimha Mangadoddy, Balraju Vadlakonda

"Bubble size distribution, bubble rise velocity and gas and solids hold-up are the key major hydrodynamic parameters that are extensively used for column flotation design and performance evaluation. The distribution characteristics of mean gas hold-up is studied using electrical resistance tomography (ERT) coupled with pressure transducers (PT) in column flotation. The ERT technique facilitates non-invasive and nonintrusive visualization of different flow regimes even in the presence of particles in a column flotation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas hold-up and its radial distribution has been analysed for both two-phase and three phase flows. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the three-phase flow hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, are employed to explore the influence of parameters in two phase flow in column flotation. Mean gas and solids hold-up values extracted from ERT have been critically analysed for the column operating in various flow regimes. Gas hold-ups and solid hold-ups results using ERT are in very good agreement with conventional estimation and correlations obtained using pressure transmitter methods. Meanwhile, the results show that the gas hold-ups in the centre region increase constantly with an increase in the superficial gas velocity, whereas solid hold-ups distribution is very heterogeneous for high gas velocity. Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the 'inside' flow behaviour of gas –liquid–solid three phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is perhaps the most significant technological innovation in flotation machinery and its successful introduction in mineral processing plants. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker & Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena, Biswal, Das, & Reddy, 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on performance of column flotation (Finch, J.A.;Dobby, 1991). Many techniques have been developed that could be used to experimentally analyse the hydrodynamics of column flotation. Tomography techniques are well sound to investigate the hydrodynamics for process equipment. Among that, Electrical resistance tomography (ERT) has been used in various industrial investigations for visualization of the concentration profiles and characteristics of the fluid dynamics in gas–liquid two-phase systems (Wang, Dickin, & Mann, 1999; Williams, R.A; Wang, 2000). ERT is an imaging technique to analyse the internal flow behavior non-intrusively. ERT provide very useful tools for measuring and monitoring of column flotation process on line. Due to its high speed capability, low cost measurement, robust sensors, ERT is considered to be the most powerful tool among other tomography techniques such as positron emission tomography (PET), magnetic resonance imaging (MRI), optical and infrared tomography. Application of ERT has extended in process systems due to its improved speed of data acquisition, sensitivity, flexibility and noise immunity. In multiphase flow of bubble columns, gas hold-up and solid hold-up are explored by using the coupling of ERT and difference pressure method (Jin, Han, Yang, & He, 2010)."

Jan 1, 2016

By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By A. S. H. Kabir

Due to the high specific strength and excellent corrosion resistance, Ti-6A1-4V has been widely applied in aerospace industries. In this study, the welding performance of 3.2-mm and 5.1-mm thick Ti¬6A1-4V sheets was studied using a 4 kW continuous wave Nd: YAG laser. It is found that the use of filler wire, matching the parent metal composition, can bridge the joint gap and produce full penetrated welds up to a width of 0.6 mm without cracking. The laser welds were characterized in terms of the bead geometry, defects, microstructures, and hardness. With increasing joint gap, the percent porosity area increased, reaching just over 1% of the fusion zone area at a gap width of 0.6 mm for the 3.2 mm and 5.1 mm thick sheets. The maximum underfill depth in the Ti-6A1-4V laser welds was about 5% or 7% of the sheet thickness for the 3.2-mm and 5.2-mm thick materials, respectively, meeting the AWS D17-1 specification. The microindentation hardness was maximum in the fusion zone and sharply decreased through the heat affected zone until reaching the base metal value.

Jan 1, 2011

By A. W. Jacob

THE shatter cut, or burn cut as it is often called, is one in which the centre of the round is almost reamed out by drilling holes so close together that the blasting of a few holes shatters the rock embraced by all of them. The idea of shattering the centre of a face by shooting holes drilled parallel to one another is not new. Some miners have used this method for years past, when drilling quartz or a face near timber. But, they followed the age-old practice of first blasting the cut, then the square-up. It was not thought possible to shoot both together. In the case of machine men, the two largest contributors to silicosis are dust from drilling and dust from blasting. It follows, then, that material reduction of exposure to either constitutes an important step in lessening the incidence o silicosis. It was? the hope of being able to do away with the necessity of the men having to return early to a face, through dust concentrations of 60,000 to 80,000 particles per cubic centimeter, that aroused interest "in the shatter cut at McIntyre. Efforts to this end were successful. Now, with this kind of cut, all holes of a round are shot simultaneously.

Jan 1, 1942

By S. M. Grillo, Fiori. M., R. Bornioli, C. Marini, S. Fadda

Abstract - The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temper- ature, the composition of the albitizing fluids was modified by an influx of meteoric or other waters.

Jan 1, 1996

By E. M. Stiles

Introduction The papers that follow deal with recently completed major improvements in practices at the Sullivan operations in Kimberley. The papers have been prepared by members of the Consolidated Engineering Staff and outline the construction programme which has been in progress for the past three years, entailing an expenditure of some millions of dollars. Four major operational changes have been brought about in the mine and concentrator. They are: (1) A change in backfill procedure for filling stopes below the 3900 level. (2) A 12,000-ton,per-day sink-float plant at the concentrator. (3) A new haulage system from the mine to the concentrator. (4) A completely new crushing plant and ore storage facilities located underground. A brief outline of the background and history leading up to this overall project will be given to show how each started as an independent betterment and how they were finally co-ordinated into one major programme. The first of these, namely, the necessity for backfilling stopes below the 3900 level, was the most pressing problem. All filling to date bad been done above the 3900 level, where mining was carried on in an irregular pattern of open stoping. Stopes below the 3900 level were first opened in 1940 and are being worked on a regular pattern of panel sub-level open diamond drill stopes. The two areas are separated by a sill pillar traversing the entire length of the vein at the 3900 level elevation.

Jan 1, 1950

By S. M. Grillo, M. Fiori, R. Bornioli, C. Marini, S. Fadda

The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temperature, the composition of the albitizing fuids was modified by an influx of meteoric or other waters. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1997

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968

By P. Langlois, G. Labonté, J. J. Barrett, J. Holmes

"The Voisey’s Bay mill processes a high-grade pentlandite and chalcopyrite ore in a largely pyrrhotite/troilite matrix. From 1994 to 1997, circuit development focused on making a 14% nickel concentrate. When flowsheet development resumed in 2001, the target grade was raised to 20% ni. initially triethylene tetramine and sulfite pyrrhotite depressants were used in a lime circuit, but by recycling process water and the contained thiosalts, the required nickel grade was made without depressants. construction of the mill was fast-tracked, with start-up in september 2005. ramp-up was faster than other recent nickel installations, with tonnage being limited by concentrate dewatering due to higher-thanexpected ore grades.RÉSUMÉ l’usine de traitement de Voisey’s Bay traite un minerai à teneur élevée en pentlandite et chalcopyrite dans une matrice formée surtout de pyrrhotite/troïlite. De 1994 à 1997, le développement du circuit ciblait la production d’un concentré à 14 % de nickel. lorsque le développement du schéma de traitement a été repris en 2001, la teneur cible a été élevée à 20 % de ni. initialement les déprimants triéthylènetétramine et sulfite de la pyrrhotite étaient utilisés dans un circuit à la chaux; cependant, en recyclant l’eau du procédé et les sulfosels qui y sont contenus, la teneur en nickel a été atteinte sans utilisation de déprimants. la construction de l’usine de traitement a été accélérée et elle a démarré en septembre 2005. la mise en opération a été plus rapide que pour d’autres installations récentes de nickel; le tonnage traité étant limité par le séchage du concentré en raison des teneurs de minerai plus élevées que prévu."

Jan 1, 2017

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By Edward (Ted) R. Lord

The application of thickened/paste tailings for surface disposal has been practiced for many years but has recently started to gain wider international acceptance. With tailings ponds coming under increasing environmental scrutiny, there is growing momentum towards mine/tailings plans that greatly reduce the size or even eliminate tailings ponds completely. This paper provides examples from the author&apos;s own experiences of the application of thickened/paste tailings for surface disposal in different countries, under different climatic conditions and in different industries. The paper will also comment on current research initiatives and future trends.

May 1, 2001

By A. Haldar

This study focuses on the flow characteristics of hypereutectic Al-Si alloys in thin sections. The pattern assembly consisted of spiral horizontal patterns, 6.25 mm (0.25 inch) and 12.50 mm (0.50 inch) in thickness with a common sprue. Al-Si alloys with silicon levels of 14%, 18% and 22% were poured with superheats of 60°C, 115°C and 170°C. It was observed that metal fluidity (in terms of flow length and metal velocity) increased with increase in silicon levels and superheat for both section thicknesses. It was also observed that, for a section thickness of 6.25 mm (0.25 inch), silicon level had more pronounced effect on the metal fluidity. For 12.50 mm (0.50 inch) thickness, both silicon level and superheat affected the metal fluidity. The surface hardness of the castings increased with an increase in silicon level of the alloys at the gate and the flow tip. Detailed study of the flow tip was also carried out with a view to understanding the effect of silicon level and superheat on undulated flow length, surface hardness and microstructure.

Jan 1, 2007

By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By P. Coursol

The Noranda Reactor Process (NRP) has been in operation now for more than 30 years and this mature process has attained a high level of performance. The NRP at the Home Smelter of Xstrata Copper treats a wide range of feed materials and a thorough knowledge of both process control and smelting physico-chemistry has been beneficial to help meet the required plant flexibility. In this regard, some level of predictive knowledge related to slag chemistry, in particular, the liquid and solid phases such as spinels or olivines, has been found to be beneficial. In the last decade or so, the availability of commercial thermodynamic modeling packages, such as Factsage1m have been utilized with advantage to help the plant optimize slag chemistry and minimize problems from difficult slags, for example, those the could arise from undue feed variability. This paper illustrates the application of this software in examining a range of operating parameters such as: %Fe in product matte, the %Fe/%Si02 ratio in the slag, the levels of minor slag components including CaO, Ah03, ZnO, and MgO, and the level of oxygen enrichment on the operating conditions of the NRP. The slag composition boundaries at the conditions affecting magnetite control and solid magnetite/other precipitated solid phases, as well the conditions influencing the slag liquidus ranges of NRP slags are also discussed with respect to the overall process chemistry.

Jan 1, 2007

By I. Demers

The abandoned Manitou mine site covers an area of approximately 190 ha near Val d?Or, Quebec. This old site has been generating acid mine drainage for several decades. In 2006, a partnership was established between the Quebec Ministry of Ressources Naturelles (MRN) and Agnico-Eagle Mines to reclaim the Manitou site using tailings from the nearby Goldex mine. These neutral tailings were to be deposited on top of the Manitou site. An extensive study was performed to evaluate specific reclamation scenarios to control acid mine drainage using Goldex tailings as cover material. The article first describes the global approach used for this evaluation, which includes in-situ hydrogeological monitoring, tailings characterization, laboratory column tests, and numerical modelling. Of the thirteen column tests, three were conducted to evaluate the parameters affecting the performance of covers made of Goldex tailings placed over the spillage area of the Manitou site. Geochemical and hydrogeological parameters were assessed during the leaching column tests for almost two years. The tests aimed at evaluating the effect of water table level and monolayer cover thickness on the overall performance. The testing procedure involved monthly leaching and measurement of geochemical parameters. Results indicate that water table position is the most important factor affecting the monolayer cover performance to control AMD. Based on these results, it was established that the water table must be located near the interface between the Goldex and Manitou tailings to effectively reduce AMD generation. Cover thickness also has an impact on cover performance, which is however less significant than the water table position. The testing scenario with a water table located at the interface with a one-meter Goldex tailings cover showed progressive improvement in effluent quality.

Aug 1, 2013

By T. Wajima

"A novel carbonaceous adsorbent for recovery of nickel from nickel plating waste solution was prepared from rice straw using sulfur impregnation. The rice straws were cut to 1 cm pieces, and then immersed in 0.01 - 3 M K2S solution to prepare sulfur-immersed materials. The immersed-materials were heated at 100-700 ºC in nitrogen gas to produce the sulfur-impregnated carbonaceous adsorbent by pyrolysis. The contents of carbon and sulfur in the adsorbent and abilities of adsorbent to recovery nickel from aqueous solution were examined. The contents of carbon and sulfur in sulfur-immersed materials are almost same as those in raw material. In pyrolysis, with increasing the heating temperature to 200 ºC, the contents of carbon and sulfur are almost constant, and then above 300 ºC those increase. The recovery for nickel using raw material, sulfur-immersed material and the product pyrolyzed at 100 - 200 ºC are almost same, and with increasing the heating temperature to 400 ºC, that of the product increases, and above 500 ºC that of the product decreases. In immerse step, with increasing K2S concentration, the carbon content of the product at 400 ºC gradually decreases, the sulfur content of the product increases, and the recovery for nickel using the product gradually increases and then above 1 M K2S decrease. The product prepared from material immersed in 1 M K2S solution at 400 ºC indicates a maximum recovery for nickel ion. The product can adsorb nickel ion in nickel plating waste solution coexisting with phosphate ion, and adsorbed nickel ion in the product was deposited as nickel metal after heating at 1000 ºC under N2 atmosphere.INTRODUCTIONRice is the second world’s largest cereal crop after wheat, but produces large amount of straw residues, of about 330 million metric tonnes. Rice is a widely grown crop in Asia, and rice straw is produced as a by-product of rice production. In most parts of rice fields, open-field burning of rice straw is commonly practiced in the region when there is limited time to prepare a field for the next crop. However, open-field burning of crop residues is an uncontrolled combustion process during which air pollutants are emitted into atmosphere. These air pollutants have significant toxicological properties and are potential carcinogens (Gadede et al., 2009). Although wildfires are prohibited in cultivation fields of most countries, farmers usually keep on burning their crop by-products. Biomass burning is an important source of aerosol particles which may affect local and regional air quality (Gao et al., 2011), and also contribute to global climate changes."

Jan 1, 2016

By E. Talebi, P. Roghanchi

"This study aims to discuss personal and behavioral parameters contributing to heat-related accidents. To study the prevention approaches, it is essential to look at the various factors at the individual, management, and industrial levels. Qualitative risk analysis methods are used based on the public data in the USA to find the impact of the environmental and behavioral parameters on the heat stress and heat strain of mine workers. The effects of individual factors such as worker experience, age, fitness, lifestyle, acclimation, and more are illustrated. The significance of factors such as the roles of the mine management and regulatory agencies are addressed.INTRODUCTIONOccupational hazards in mining industry endanger the health and safety of the workers and productivity loss for mining companies. Among those hazards is the exposure to excessive heat that has adverse effects on the health of mine workers. The intensity of heat load is a significant factor in fatal and non-fatal heat-related accidents. Severe environmental conditions combined with a high level of activity in the mining industry increases the vulnerability of individuals to health and safety hazards (Ngwenya, Oosthuizen, Cross, Frimpong, & Chaibva, 2018). Lack of regulations and legislation addressing the heat issue in the mining industry (i.e., underground and open pit mines, processing plants) also raises widespread concerns.Along the climate change, various sources contribute to the overall heat load at a mine site (Hanna, Kjellstrom, Bennett, & Dear, 2011; Kjellstrom, Lemke, Hyatt, & Otto, 2014). In underground mines, the majority of heat comes from different sources such as geothermal gradient, equipment, auto compression, groundwater, and blasting (Maurya, Karena, Vardhan, Aruna, & Raj, 2015). On the surface, however, the majority of heat load can be sourced to solar energy. The exposure to excessive heat might result in heat-related illnesses, fatigue and fainting, loss of concentration, performance reduction, and production loss (Kocsis & Sunkpal, 2017; Roghanchi, 2017). The severity of the effects depends on duration and level of exposure and the response of an individual to heat stress. The response of an individual is influenced by different factors including age, gender, fitness, lifestyle, experiences, and past medical history."

Jan 1, 2019

By R. R. Song, Q. Li, H. Xing, X. C. Wei

Geomechanical modelling of fault stability is an important part of CO2 capture and storage (CCS) research program to ensure its viability and long-term safety. Storage of CO2 in deep subsurface reservoirs requires estimates of sustainable fluid pressures that will not induce fracturing or fault reactivation which could cause fault slip. More importantly, fault slip gives rise to seismic waves, which inflict severe damage to the cap rock of the reservoirs and may result in leakage pathways for the buoyant plume and thus compromise the integrity of seal formations. In this study, we generated a numerical model tuned towards conditions usually encountered in the Shenhua CCS demonstration project in Ordos basin. In particular, with the purpose of evaluating the sensitivity of the parameters as well as their relationships with the moment magnitude of the seismicity, a variance-based sensitivity analysis was adopted for importance ranking of the uncertain input parameters of the given model. However, such flow models could involve one or several spatial inputs, for instance, fault dip, distance between fault and the injection well, friction angle of fault, permeability of fault, Young's Modulus of fault, injecting pore pressure and the stress field. Studying the sensitivity to each of these spatial inputs motivated the present work. The results led to the following conclusions: fault depth and fault dip significantly affect the behavior of the fault and the fault slip becomes violent with the fault depth increasing and fault dip decreasing. Furthermore, the results indicate that slip time increases with the fault dip decreasing and decreases with permeability of fault increasing. In addition, the calculation of seismic moment and moment magnitude of an earthquake demonstrates that it rises significantly with the decrease of fault dip and the increase of fault depth, and it decreases with the rising stress field. The results show that variations of the only controllable parameter injection pressure do not show great influence to the fault behavior compared with other geological factors, which imply site selection is extremely important for the CCS projects.

Jan 1, 2015

By J. Duby

"A description is given of a series of tests performed to determine the comparative effects which dynamic and static straining, in compression, have on the physical strength properties of mild steel and an aluminum alloy. The dynamic deformation was imposed during the passage of single stress pulses of about 100 micro-second duration. These pulses were recorded with strain gauges mounted near both ends of the specimen. The resulting records were analysed using a simple wave theory; there from the dynamic stress-strain curves for the respective metals were deter-mined and were then compared with the static stress-strain relation. The respective hardnesses of the metals after deformation are evaluates by means of static stress-strain curves in compression. The micro-structures of the metals before and after deformation are also shown. It is observed that dynamic de-formation considerably modifies the rate of strain hardening. This modified hardening appears to be persistent. The observed differences in physical strength properties and micro-structures are discussed in the light of the accepted dislocation theory for metals."

Jan 1, 1960

By S. Uddin

Microsegregation manifests its effect on microstructural evolution of cast or welded alloys which in turn influences their important mechanical and electro-chemical properties. In the above context, mathematical models of microsegregation have proven to play an important role in estimating the nature and predicting the effects of this phenomenon in wide varieties of solidification processes. Microsegregation models are useful in designing new commercial alloys, in estimating the homogenization time for the post-process heat treatments and in many other practical applications. In this study, two semi-analytical models of microsegregation were developed to predict the concentration field of solute in the liquid and solid regions for dendritic solidification of binary metallic alloys. Both models assume that the growing dendrites are cylindrical in shape. This assumption is more realistic compared to the common assumptions of plate like dendrites that most of the earlier researchers employed in their microsegregation modeling study. The solute redistribution profile, in the developing solid layer, necessary to determine the back diffusion parameter was derived from Fick&apos;s second law for the model without coarsening. The application of this parameter in a wide range of conditions and the use of its basic form in the model with coarsening has been verified. The concept of coordinate transformation and enhancement of back-diffusion Fourier number were used in deriving the model which took into account the coarsening of dendrites. The models are then extended to deal with rapid solidification and peritectic transformations and the results were compared with relevant experimental data for Aluminum and other alloys. A good agreement between model predictions and experimental results was found.

Jan 1, 2007