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By C. O’Donova, E. Adam, L. A. Torres-Cruz

High-profile failures of tailings dams illustrate the significant safety challenge they pose. The decant pond of such facilities plays an important role in their mechanical stability. This study investigates the feasibility of using public multispectral data collected by the Sentinel-2 satellite mission to monitor the area of the decant pond. The Sentinel-2 mission has a revisit time of 5 days and the data used herein has a spatial resolution of 10 m/pixel. We considered two water-detection metrics: the normalized difference water index (NDWI) and the near-infrared (NIR) reflectance. Implementation of the method at a South African platinum tailings dam illustrates the capabilities and limitations. Public, sub-metre resolution true-colour imagery served as validation data. There is good agreement between pond area measurements based on Sentinel-2 and the validation imagery. These results suggest the feasibility of using Sentinel-2 data to supplement the monitoring of the decant pond.

Apr 2, 2022

By P. Stefanek, N. Duda, B. Jachni, P. Stefaniak, B. Bursa

The Zelazny Most Tailings Storage Facility (TSF) is the largest reservoir of post–flotation tailings in Europe. The total amount of tailings from the mines in Lubin, Rudna, and Polkowice are stored each year at the disposal facility, which reaches approximately 30 million tons. It is crucial to accurately monitor and maintain such a huge storage facility, for the safety and economics of the entire region. In general, the monitoring network installed at the Zelazny Most TSF includes four groups of components: (a) geotechnical network (VW pore pressure transducers and inclinometers), (b) hydrological network (open piezometers, water level gauges, drainage discharge measurements, (c) geodetic survey network (e.g. surface and in-depth benchmarks, laser measurements, GPS measurements within GEOMOS network and (d) seismic network (e.g. accelerometer stations, cone penetration tests.) Apart from the above, chemical water analyses, tests of soil samples, monitoring of spigotting processes, and monitoring of relief wells’ discharge are also conducted. In total, approximately 2900 monitoring instruments are installed within the area of the Zelazny Most TSF. Such large amounts of data from the various information sources makes manual data analysis by the engineers almost impossible. In this paper we discuss a machine learning driven approach to improve the quality of the monitoring and maintenance of such facilities. We focus on the seismic cone penetration test (SCPT) data analysis. First, we carefully describe the collected data, its quality and availability. Then we discuss possible events that can occur in the TSF that need to be predicted using SCPT. Based on the information obtained in these two steps, the applicability of several machine learning methods is estimated. Some of them are then tested on available historical data. The algorithms described in this article will be further developed in the IlluMINEation project (H2020).

Sep 1, 2021

By J. P. T. Kapusta

"The copper smelting industry faces increasingly stringent environmental regulations and must continue driving innovation to reduce energy usage in its production chain. With the coming of age of ‘bottom-blowing’ copper technologies in China over the last decade, much renewed attention has been brought to tuyere bath smelting for clean copper-making. Since bottom-blowing sonic injection was originally developed and implemented in steelmaking in the 1970s and lead smelting in the 1990s, the time seems appropriate to revisit the sonic injection concepts and dispel some myths. After reviewing the trends in the copper industry and providing a brief historical context of research and development related to sonic injection, the author presents a comparison of the main submerged tuyere bath smelting technologies, namely the Noranda Reactor (NR), the Teniente Converter (TC), and the Chinese Bottom-Blowing Smelting Furnace (SKS/BBS) for copper, and the Queneau-Schuhmann-Lurgi Reactor (QSL) for lead. The core of this article, however, consists of a brief description of the fundamental theories for sonic injection (jetting regime) and ‘sonic flow mapping’ to illustrate the relationship between the minimum tuyere back-pressure required to achieve sonic flow and the tuyere internal diameter. The article also offers a comparison between side- and bottom-blowing in jetting regime before concluding with the author’s vision of the new trend in submerged tuyere bath smelting. IntroductionIn the last decade, developments in the copper smelting industry have been driven by two key concepts: (1) increasing cleaner smelting capacity to meet the world’s growing copper demand, as illustrated in Figure 1, and (2) increasing process off-gas capture to comply with more stringent environmental regulations and abide by a corporate social responsibility ethic of a clean work environment (for smelter employees) and clean air (for families living around smelters). The copper smelting industry has also faced some major challenges in the last few decades, including (1) low treatment and refining charges (TC/RC or processing fees) impacting custom smelters, (2) lower concentrate quality and grades with higher levels of impurities (e.g. As and Hg), (3) higher processing and transportation costs due to the rising cost of energy, (4) restrictions in process intensification (tonnage oxygen usage) due to furnace integrity limits, and (5) scarcity of educated and trained personnel due to fewer metallurgists graduating from pyrometallurgical school programmes combined with a high retirement rate of skilled workers."

Nov 1, 2018

It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidizing pulp potentials, reduced levels of grinding media corrosion products, and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proved difficult. This paper provides details of the protocol developed and used during a high-chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry as well as concentrate grades and recoveries to produce a statistically meaningful result. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial. To demonstrate the protocol, data gathered during a plant trail in a PGM concentrate will be presented describing the changes in pulp chemistry and metallurgical response observed.

Jan 1, 2012

By J. van der Walt, W. Spiteri

Flyrock remains a significant threat to the health and safety of mine employees and integrity of infrastructure, as well as to the safety of the neighbouring communities and their property. This investigation was motivated by the general lack of fundamental research and mathematically quantifiable data in the literature regarding the relationship between blast design parameters and their impact on flyrock. The focus was to develop a concept that can be used to mathematically quantify the trajectory of flyrock resulting from a blast, which can be used for future research. The ultimate goal for this technique, once it has been fully developed, is to: ➤ Enable mining operations to generate a database with accurate historical flyrock measurements resulting from their blasting operations ➤ Allow research teams to conduct scientific investigations into flyrock and the impact of various blast design parameters ➤ Generate point-cloud data to visualize blasts and flyrock in a virtual reality environment for training and education purposes. This paper summarizes a conceptual technique and preliminary fieldwork that was carried out to determine the technique’s feasibility and motivate further development. The results show conclusively that a modified photogrammetric technique is capable of capturing flyrock data for further processing and analysis. The data acquisition procedure can, at this point, be used to meet the first aim of the project, namely to gather a field database of historical flyrock generation. Further development of the technique is ongoing and it is envisioned that the scientific-based technique will provide a method whereby future flyrock studies will be comparable and that assumptions will be limited.

Apr 5, 2023

The March General Meeting of the Institute was held in Kelvin House, Johannesburg on 18th March, 1970, at 4.30 p.m. Mr J. K. E. Douglas (President) was in the Chair. There were also present fifteen Fellows, Messrs H. Britten, R. C. J. Goode, Prof D. D. Howat, Mr T. C. A. Meyer, Dr R. E. Robinson, Messrs V. C. Robinson and P. W. J. van Rensburg (Council Members), S. K. de Kok, Dr N. P. Finkelstein, Messrs K. W. Findlay, H. N. Hepker, J. Levin, Dr K. A. Murray and Mr A. H. Mokken. Four Members including Mr D. Ayres, Dr M. I. Britten and Dr A. Granville. One Associate: Mr G. S. Stander. One Student, Mr R. N. Guest. Four Visitors, Messrs S. A. Allison, C. N. Leibb, C. J. Kooij and A. Mavrogordato. Secretary: Mr D. C. Visser. Total present: Twenty-seven. OBITUARY The President: "It is my sad duty to announce the death of Henrik Johannes Van Eck, Honorary Life Member, who joined the Institute in 1929 and passed away on 18th February, 1970. Dr van Eck started life as a chemist and chemical engineer and, as we all know, he rose to become one of our most distinguished leaders of industry in the country. On many important occasions we, in this Institute, have been privileged to have him address us on subjects which were always of great importance and relevance to the developments in this country. He was a man of great vision and imagination and could put across his ideas in a most eloquent and convincing manner. In his important position as chairman of the Industrial Development Corporation and of Iscor, whatever he said carried great weight. Busy as he was he always found time to participate not only in the affairs of this Institute but in many other technical and public bodies. His passing is a great loss to South Africa and we in this Institute wish to associate ourselves with the many other tributes which have been paid to this great man. We extend our sympathy to his wife and family and as a mark of respect I would ask you to rise and observe a few moments silence." MEMBERSHIP The President: "I have much pleasure in announcing that the names of the undermentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Fellow: Ian Douglas Bruce Corner, Joachim Bernhard Rolfes. Member: Michael Vernon Nolan. Associate: Karl Franz Wilhelm Eick. MEMBERS TRANSFERRED TO A HIGHER GRADE From Member to Fellow: Nilo Zolezzi. From Graduate to Member: Roger Billingham. I welcome the newly elected members to the Institute and congratulate the members who have been transferred to a higher grade." PAPERS FOR PRESENTATION The President: (i) "Mr Lee, may I call on you to deliver your paper entitled 'A new bubble pick-up technique as a rapid flotation test method'." After the presentation of the paper the President said: "The paper which Mr Lee introduced this afternoon was a short one but was nonetheless important in that it described a new tool for use in flotation test work. Those of us who have experienced the frustration of trying to solve flotation problems by trial and error methods know what this means. I well remember 25 years ago at T.G.M.E. trying to improve the recovery from the flotation plant there by trying various combinations of reagents and then having to wait a couple of days for the assay office to give results. Even then, on the small scale laboratory tests which had to precede full scale tests one could never be sure that the results obtained were reproducible on the full scale. Here it seems we have a relatively simple apparatus which can measure instantly the effectiveness of various reagents under different concentrations and pH values, etc. It is most important, I believe, that developments of this kind be reported in our journal for the benefit of all involved in such work, not only so that we know about it but also in order to provoke constructive discussion which might lead to further developments. I would like to invite members, therefore, to submit papers or notes on important

By G. Poropat, A. R. Guest, H. P. Grobler

At the De Beers Consolidates Mines operations it is common practices to perform Geotechnical mapping of the newly exposed faces in the waste and ore rock. The purpose of Geotechnical mapping is to quantify the in-situ fracturing of a rockmass that in turn is required during the planning and application of a mining method. Whether it is to determine slope angles, caveability, impact of blasting or support requirements. This mapping involved a cumbersome and time consuming procedure that requires individual examination and description of the natural inherent fractures exposed by mining. During highwall mapping in an open pit this can be a safety concern due to the duration of time spent below a highwall. The advantages gained through the recent introduction and application of SiroVision® allows safer mapping, an increase in statistical fracture population, archiving of rock faces and the more accurate reflection of the true mapping. This paper aims to describe in detail the application of the recently developed SiroVision®, photogrammetry software, to replace conventional face mapping. A De Beers Consolidated Mines, il est pratique courante de faire une cartographie géotechnique des tailles récemment exposées dans le rocher stérile ou minerai. Le but de la cartographie géotechnique est de quantifier la fracturation in-situ d’une masse rocheuse, qui sera nécessaire lors de la planification et application d’une méthode minière, que ce soit pour déterminer les angles des galeries inclinées, les possibilités de foudroyage, l’impact du dynamitage, ou les besoins en supports. Cette cartographie nécessitait une procédure longue et compliquée qui demande l’examen individuel et la description des fractures naturelles propres exposées par l’opération de mine. Pendant la cartographie de parois dans une exploitation à ciel ouvert, cette opération peut être dangereuse à cause du temps passé sous la paroi. Récemment, le lancement et application de Siro Vision apportent l’avantage d’une cartographie plus sûre, une augmentation des statistiques de population de fracture, l’archivage des tailles de roches, et le reflet plus précis de la cartographie. Le but de l’étude présente est de décrire en détail l’application du développement récent de Siro Vision, logiciel de photogrammétrie, pour remplacer la cartographie de taille conventionnelle. Bei den De Beers Consolidates Mines Operationen ist es gängige Praxis geotechnische Aufzeichungen des Taub- und Erzgesteins neu geöffneter Abbaustellen zu erstellen. Zweck dieser geotechnischen Aufzeichnungen ist die vor-Ort-Quantifizierung des Bruches der Gesteinsmasse, welche im Gegenzug während der Planung und der Anwendung einer Abbaumethode erforderlich ist, sei es um einen Neigungswinkel festzustellen, Abbaubarkeit, Auswirkung von Sprengungen oder Anforderungen an Unterstützungen. Die Aufzeichnungen waren mit umständlichen und zeitaufwendigen Prozeduren verbunden, die eine individuelle Prüfung und Beschreibung der durch den Abbau freigelegten natürlichen inhärenten Brüche, verlangten. Dies kann auf Grund des Zeitraumes der unterhalb einer Flözoberschicht verbringt wird zu einer Frage der Sicherheit werden wenn die Aufzeichnung einer Flözoberschicht im Tagbau erfolgt. Die Vorteile auf Grund der jüngst erfolgten Einführung und Anwendung der SiroVision® gestatten sichereres Aufzeichen, eine Zunahme in der statistischen Menge an Gesteinsbrüchen und eine akkuratere Reflektion der tatsächlichen Aufzeichnungen. Diese Arbeit hat zum Ziel im Detail die Anwendung der kürzlich entwickelten SiroVision®, eine photogrammetrische Software, die die konventionelle Abbauortaufzeichnung ersetzen soll zu beschreiben.

Jan 1, 2003

By V. Oberholzer

The presence of fines (particles smaller than 6 mm in diameter) causes hydrodynamic problems in gasifiers and therefore it is of great importance to minimize the amount of fine coal in the feed. This serves as motivation for understanding coal?s breakage mechanisms, which could lead to the ability to predict the generation of fines. The aim of this project was to simulate the pulsating effect of the conveyor belt in order to investigate factors influencing the breakage. Results indicated that an increased initial particle size had an increasing effect in the amount of fines generated. Weathering had an insignificant effect on the breakage of coal. To conclude, a breakage model was developed to describe the rate of breakage out of the top size when a combination of two breakage modes is present.

Jan 1, 2009

By T.R. Stacey

Physical testing of rock support for rockbursting conditions has been carried out for over 40 years. A review of this testing shows that it has been mostly component based, rather than actually testing support systems. Further, it is concluded that none of the testing is truly representative of rockburst loading in a similitude sense. Similitude conditions are not achievable, mainly because the real conditions in a rockburst event, such as seismic source location and magnitude, wave frequencies, amplitudes, and interactions, are not all known. Because such information is not available, and because the results of all testing carried out to date have not been able to define, for support design purposes, the capacity of support systems, ongoing physical testing of rockburst support systems is essential. It is essential that the test should simulate, or actually take place in, a supported rock excavation. A rock support system is a combination of individual support components that work together to retain and contain the rock. In doing this, the components are subjected to loading by the rock and to interactive loading between one component and another. It is necessary to prove the capacity of such rockburst support systems by subjecting them to severe loading, as in direct blasting. The direct blasting approach, pioneered more than 40 years ago, probably still provides the greatest validity as a significant test of rockburst support capabilities, even though it does not simulate a rockburst. Direct blast testing of rockburst support systems in a surface environment, such as in a quarry or on exposed rock cutting surfaces, could represent a practical development of the approach, facilitating the execution and monitoring of tests.

Jan 1, 2012

By Y. H. Suh, H. C. Lee, D. S. Kim

A progressive karst formation and its influence upon engineered structures in the ‘phil-karst’ rock mass draw a tunnel engineer’s special attention to a long-term stability and the maintenance issues. Karst sinkholes of any size beneath the railway bed cause train wrecks or long interruptions in train traffic during rehabilitation work. The collapse of cave roof, called a ‘doline’, is in general connected to the cave by the gradual dissolving of the rock, developing into subsidence and sink-holes. The principal conclusions obtained from the field experiments are as follows: It is found that the development of karst cavity shows a relationship with a structural geological line and it is necessary to define the dominant directions of joint and geological layer (formation). The relation-ship between the water flow and joint direction can be used as an indicator of cavity presence in their direction. In addition the direction of in-situ stress can play a role in the development of karst cavities. A risk map of karst scenario is produced for the tunnel supporting systems with rock type classifications in water-soluble karstic rock mass. Eine fortschrittliche Karst-Formung und sein Einfluß auf angelegten Strukturen in der Phil-Karst-Felsenmasse wecken einem Tunnelingenieur eine besondere Aufmerksamkeit zu einer langfristigen Stabilität und der Wartungsausgaben auf. Karstensinkhöhlen in irgendeinen Größen unter dem Eisenbahnbett sind die Ursache der Zugeszerstörung oder der langen Unterbrechungen in Zugverkehr während Rehabilitationsarbeit. Der Zusammenbruch von Höhlendach, d.h. ein “doline”, ist im allgemeinen an die Höhle, die durch das allmähliche Auflösen des Felsen zu entstehen ist und sich in die Subsidence und Sinkhöhlen entwickeln, angeschlossen. Die Hauptschlüsse, die von Feldenprüfungen erhalten wurden, sind folgendermaßen: es wird gefunden, daß die Entwicklung von Karstenhöhlung eine Beziehung mit einer strukturellen geologischen Linie zeigt und es notwendig ist, die vorherrschenden Richtungen von Gelenk und geologischer Schicht (die Formung) zu definieren. Die Beziehung zwischen dem Wasserablauf und der gemeinschaftlichen Richtung kann als ein Anzeiger von Höhlungsanwesenheit in ihrer Richtung benutzt werden. Zusätzlich kann die Richtung von In-Situ-Spannung eine Rolle in der Entwicklung der Karstenhöhlungen spielen. Für das Tunnelunterstützungssystem, welches mit Felsentypenklassifizierungen in wasserlöslicher Karstic-Felsenmasse, ist eine Risikokarte von Karstenszenar hergestellt. Une formation progressive de karst et son influence sur les structures tracées dans la masse de roche "phil-karst" retiennent l'attention particulière des ingénieurs de tunnel aux problèmes de la stabilité à long terme et du maintien. Les creux de karst de toute la taille sous le chemin de fer causent les accidents de trains ou de longues interruptions pendant le travail de réhabilitaion. L'effondrement du plafond de caverne qui s'appelle "doline" s'est, en général, connecté à la caverne par dissolution progressive de la roche, en devenant l'affaissement et les creux. Les conclusions importantes venant des experimentations sur le terrain sont suivants: d'abord, le développement de la cavité de karst montre le rapport avec la ligne géologique de la structure et il est nécessaire de définir les directions dominantes du joint et la couche(formation) géologique. La relation entre l'écoulement de l'eau et la direction du joint peut être utilisé comme un indicateur de la présence de la cavité dans leur direction. De plus, la direction sur place peut contribuer au développement des cavités de karst. Le plan risqué de karst s'est produit pour le système d'appui du tunnel avec les classifications du type de roche dans la masse de roche karstique qui est soluble dans l'eau.

Jan 1, 2003

By C. Steyn, J. D. le Roux

A dynamic model is used to represent the single-stage closed grinding mill circuit at Mogalakwena North Concentrator. The circuit consists of a ball mill closed by a hydrocyclone. The circuit is modelled according to a semi-mechanistic non-linear dynamic model available in literature. An algebraic routine is used to fit model parameters to steady-state process data. Preliminary validation results against dynamic data indicate that the model is capable of capturing the main dynamic trends of the plant. Since classical system identification techniques proved insufficient to produce accurate models; the non-linear model can be used as a reliable source for model-predictive controller design. Keywords: Grinding, modelling, process control, parameter estimation

Jan 1, 2020

By J. A. L. Napier

One of the most important characteristics of tabular mine stress analysis is the need to represent the complex evolution of mining face positions and the accompanying induced stress changes in the rock mass. Integration of seismic activity with numerical modelling requires flexible and efficient solution schemes in which both off-reef damage and large-scale fault slip can be effectively represented. A new approach is investigated in which the stope closure and ride variables can be found using a moving least squares estimator. Some advantages of this approach over traditional element-based tessellation schemes are identified. At the same time, shortcomings of this method are noted when the displacement discontinuity variable is approximated by a polynomial shape function. Difficulties and possible solutions to the shape function formulation near excavation edges are discussed. Une des caractéristiques les plus importantes de l’analyse des contraintes minières tabulaires est la nécessité de représenter la complexe évolution des positions du front de taille et des changements concomitants des contraintes occasionnées dans la masse rocheuse. L’intégration de l’activité sismique avec la modélisation numérique requiert des projets souples et efficaces qui permettent la représentation des dommages hors-filon et des glissements de faille à grande échelle. Une approche nouvelle est étudiée qui permet de trouver la fermeture de la taille et les variables de montage en utilisant un estimateur par les moindres carrés mobile. Certains des avantages de cette approche sur les traditionnels projets basés sur une structure en mosaïque sont identifiés. En même temps, les défauts de cette méthode sont notés lorsqu’on calcule la variable de discontinuité du déplacement approximativement par une fonction de forme polynomiale. Les difficultés et solutions possibles à la formulation de la fonction forme près des bords d’excavation sont discutés. Eine der wichtigsten Charaketeristika der taublaren Grubenspannungsanalayse ist die Notwendigkeit, die komplexe Entwicklung der Abbaupositionen und der damit verbundenen induzierten Spannungsänderungen der Gesteinsmasse neu vorzulegen. Die Integration der seismischen Tätigkeit mit einem numerischen Modell erfordert flexible und effiziente Lösungsschemata, in denen sowohl Schäden ausserhalb des Riffs als auch Verwerfungen großen Ausmaßes effektiv dargestellt werden. Ein neuer Vorstoß wird untersucht in welchem die Strossenschliessung und Schneisenvariablen unter Verwendung des Schätzwertes der kleinsten quadratischen Abweichungen (Gaussscher Schätzwert) gefunden werden. Einige Vorteile dieser Annäherung im Vergleich zu der traditionellen Element-basierenden Tessellation sind identifiziert. Gleichzeitig werden Unzulänglichkeiten dieser Methode vermerkt, wenn die Verschiebungsdiskoniuitätsvariable durch eine polynomische Formfunktion angepaßt wird. Schwierigkeiten und mögliche Lösungen zur Formfunktionsformulierung nahe Exkavationsrändern werden besprochen.

Jan 1, 2003

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By P. K. Hofmeyr

Traditional fire assay dates back over 3000 years and has changed very little over that time. The only improvement is to replace the gravimetric finish with dissolution of the Precious Metal bead followed by AA or ICP analysis of the solution. The newly developed FIP A (Fast In-line Fire Assay) method allows full automation of the fire assay process from sample preparation to spark analysis of the Pb button. This results in fully quantitative analyses for Pt, Pd, Rh, Ru, lr, Au and Ag in typically less than an hour after a sample is entered into the system. Detection limits are theoretically Pt 0.08 ppm, Pd 0.002 ppm, Rh 0.002 ppm, Au 0.08 ppm and Ag 0.002 ppm but in practice the lower measurable limits are about double these figures. Few opportunities have been available to present data obtained using the FIFA system as all FIFA laboratories have been in the domain of a Pt mining company which prefers to keep all Pt analytical matters confidential. However, IMP has recently participated in the round robin exercise to establish recommended values for a new series of Merensky Reef and UO-2 Layer reference materials produced by African Mineral Standards. The precision of the results was excellent being on average Pt 2.05%, Pd 1.25%, Rh 4.08% and Ru 4.94% being expressed as Relative Standard Deviation. The excellent precision is a reflection of the efficient collection of POEs in the Pb buttons and the homogeneity of the Pb buttons. However, the accuracy was not as good. The poorer accuracy is interpreted as the calibration of the spectrometer not being as good as desired due to the difficulty in acquiring a suitable range of standards with reliable recommended values for the PGEs. The most recent spectrometer was calibrated with the greatest care and produced slightly better results for Pt, Pd and Rh and slightly worse for Ru.

Jan 1, 2014

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By T. Bhambhani, E. Arinaitwe

Solvay has developed several novel reagent innovations to improve separations in sulfide ore flotation and address major industry challenges. These innovations include: a) carbon management strategies to reduce the deleterious impact of organic carbon on flotation circuits; b) new collectors for heavily tarnished or oxidized Cu-Au ores; and c) a functionalized depressant for minimizing penalty elements in metal concentrates. Owing to their unique chemistries, these innovations exhibit a wide spectrum of rather unique properties that are quite in contrast to the traditionally used reagents. The chemistry, attributes, application, and advantages of these innovations are discussed in this paper based on laboratory, pilot, and plant results and observations for various ores

Jan 1, 2023

By F. L. D. Cloete

he above article by E. Barnea, which appeared in the January 1978 issue of the Journal (vol. 78, no. 6, pp. 143-145), calls for comment in view of the author's claims for the novelty of his proof. He states in his article that its main purpose is to give a mathematically acceptable proof by induction of the 'recently proposed' equation

Jan 1, 1978

By B. Amankwaa-Kyeremeh, W. Skinner, R. K. Asamoah, C. Greet

With the continuous increase in ore mineralogical complexity coupled with decreasing head grades, there is a need for mining industries to process large tonnages of material to meet global metal demands. Smarter, cheaper techniques are required to better map ore mineralogical variations proceeding to pre-concentration (flotation) stages for higher performance and metal recoveries. This paper is aimed at briefly reviewing previous studies on different selected ore mineralogy, with the focus on their pulp chemistry, to identify relationships which aid quicker flotation feed variation monitoring. Very little published work exists linking pulp chemistry parameters to flotation feed mineralogical variation. A successful application implies maximising grades at higher metal recoveries and reducing the cost of reagent for a better performing flotation circuit. Keywords: Mineralogical variation, flotation, pulp chemistry

Jan 1, 2020

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

"Chairman: Professor J. C. Griffiths Rapporteur: Mr J. P. G. PRETORIUSPapers:Mine-mill production scheduling by dynamic programming by R. J. Roman Optimization of a large mining venture by J. C. Paynter, B. K. Loveday and C. G. Robinson Economic surface mining of multiple seams by T. V. Falkie and W. E. PorterIn introducing his paper, Mr Roman said that whereas in manufacturing plants the yearly production levels were usually chosen to produce the largest annual cash flow, in a mining operation, the raw materials (ore) were exhaustible so that the production had to be scheduled to maximize the total net present worth of the operation. This optimum production schedule could be determined by using dynamic programming. The required information was readily available to management at most mines. The 'possible operating range' of production rates lay between the rate with the highest profit per ton. and that with the highest profit per year. The optimum production rate started typically at the top of this range and decreased slowly as the deposit was depleted.Dynamic programming was used to determine several production schedules for a hypothetical mine-mill complex. The effects of changes in the ore grade estimates, size of deposit and acceptable rate of interest on the production schedule were taken into account. Apart from the fact that the net present worth of the overall profits was larger than that obtained by conventional methods, it appeared from the cases studied that the amount of metal recovered was also greater.Dr it P. King commented that this was a very interesting application of dynamic programming. He pointed out, however, that the market price of the metal was likely to vary significantly and randomly during the life of the mine, and he suggested that the problem should, therefore, be reformulated as a stochastic dynamic programming problem.If the price of the metal rose to abnormally high levels, a much higher than normal production rate could be expected. The results of analyses given in Table 5 showed that the production rate was a function of market price. In his view the stochastic problem could be solved just as easily as the deterministic problem.In reply to a question by Dr King as to whether the function relating recovery to production rate (Table I) was based on real data, the author replied that it was based on the results of an analysis conducted at the Union Carbide Corporation's Pine Creek tungsten mine in California.Dr D. M. Hawkins stated that costs were incurred when the production rate was altered, for example, in appointing or laying off staff, and that in practice it may be necessary to take these costs into account in finding the optimum production rate. Mr Roman replied that, while normal administrative costs were accounted for, the additional costs incurred in appointing and laying off staff were not taken into account."

Jan 1, 2014