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By Yafei Xiong, Yue Wang, Guotao Xu, Shuzhong Li, Huaiyuan Li

"The composition, properties and structure of taphole clay with high strength and friendly surrounding used in a new blast furnace with 3800 M3 volume was studied. The developed taphole clay had been applied in the blast furnace for four months, pouring times were 11-13 every day, flowing rate of hot iron was 7.5 t/min and the consumption of taphole clay was 0.49Kg per ton iron, which can make the new blast furnace attach the designed production quickly and decrease the cost of hot iron. The taphole clay is easy to be opened in the channel of hot iron which can be remained in stable shape under the corrosion of slag or hot iron, and it dose not produce poisonous smoke in yellow or dark color in the use process. The development of new taphole clay is useful to improve the work surrounding of the blast furnace.IntroductionIn the iron-making process, the taphole clay's function is filling up the taphole and protecting the formation as well as the growth of the clay in the blast furnace, maintaining the enough taphole depth; simultaneously it is easily to open a hole and knock out the clay. The taphole clay has a good performance of molten slag and hot iron resistance. The traditional taphole clay uses coal tar or carbolineum as a binder, and the performance of taphole clay is good, but it has the black and yellow poisonous smoke, which is harmful for work condition. Through the investigation on the binder's composition and poisonous performance of taphole clay, the environmental taphole clay is developed by some foreign companies, which is named the third generation product with benzene is less than 300ppm, and it has been used in European steel companies. This application of the taphole clay with high strength and environment-friendly using in 3800m3 blast furnace is introduced and the performance is discussed and analyzed in this paper."

Jan 1, 2012

By George A. Calboreanu

In order to overcome drilling and tapping of high hardness wear resistent material in slurry pumps, most of time mild steel inserts are mounted in the mold and after pouring they become an integrated part of the casting. This process is limiting the size and design possibilities of slurry pumps and efforts were made to drill and tap the hard iron itself. The paper will present practical results obtained in drilling and tapping Cr-Mo wear resistent material with hardness in excess of 700 HBN. The life time of the slurry pump parts used in hazardous waste fuel transportation with high slurry velocity and 15% solid loading some of it being quartz, increased 2.5 to 6 times.

Jan 1, 1996

By B. J. Jody

Each year, about 11 million tons of metals (ferrous and nonferrous) are recovered in the U.S. from about 10 million discarded automobiles. The recovered metals account for about 75% of the total weight of the discarded vehicles. The balance of the material or shredder residue, which amounts to about 3 million tons annually, is currently landfilled. The residue contains a diversity of potentially recyclable materials, including polyurethane foams, iron oxides, and certain thermoplastics. This paper discusses a process under development at Argonne National Laboratory to separate and recover the recyclable materials from this waste stream. The process consists essentially of two- stages. First, a physical separation is used to recover the foams and the metal oxides, followed by a chemical process to extract certain thermoplastics. The status of the technology is discussed, and the process economics are reviewed.

Jan 1, 1994

By A. Buzaianu, P. Motoiu, G. Popescu, C. A. Popescu, I. Rusu, A. F. Olteanu

"In recent years, the recycling magnesium metallurgy has developed new types of alloys, some of which exhibiting special electrochemical characteristics. Their application has found a fertile field in the energy conversion technologies. The paper introduces some technologic data on the recycling of aeronautical parts and scrap materials generated from the disassembling of magnesium alloy components, attempting to also solve the recycling of magnesium painted parts. The approach is meant to establish a superior quality method for recycling discarded parts or the excess of re-melting material in order to reduce environmental impact and costs. Magnesium-base alloys used as anodic materials are characterized by a high uniformity of the structural properties as well as by superior electrochemical performances, as compared to the ""classically"" used materials: Zn, Pb, etc. In nonconventional applications of magnesium alloys used as sacrificial anodes working in seawater, special alloying elements contribute to improving anodic processes. The influence of these alloying elements on magnesium sacrificial anodes was studied. It was found that the use of recycled materials in anode manufacture could reduce the Mg alloy cost by as much as up to 75% of the cost for virgin material, including the costs for the entire sequence of collection and transportation from a molding factory to a refinery, re-melting and composition adjustment.1. IntroductionMagnesium alloys are valuable materials because they exhibit low density, good forming and machining qualities, particular electrochemical properties and have a high recycling potential. There exists a false idea about the high costs of the use of magnesium alloys, partly justified by the lack of secondary materials suppliers and the insufficient knowhow in the diverse user industries to provide for an efficient substitution of conventional magnesium alloys for multipurpose applications. These circumstances have lately spurred the magnesium industry to develop new alloys and coatings and to improve processing techniques [1]. As a result, magnesium supply has greatly expanded and so have the research and development efforts to achieve complete recycling of Mg alloys.In consumer markets, magnesium is frequently selected because it helps reduce enery consumption. For example, an equal volume part made of magnesium is 23% the weight of a steel part and 64% the weight of an aluminium part."

Jan 1, 2008

By Vladimir I. Skorohodov

The technology for copper utilization from circuit boards etching is proposed. The technology is based on combination of electrochemical and sorption methods. The conditions of copper electroextraction from ammonia-chloride solutions with obtaining of cathode copper are defined. The stage of electrolysis is destined for copper recuperation from etching process. Due to the electrochemical processes are unacceptable for cathode precipitation of the copper from diluted solutions such as rinse waters, the concentration on the strong-based cationites are used. After filtration throw the sorption columns solution is directed to the stage of circuit boards washing. It allows organizing close loop water recirculation. After saturation. resin is 'regenerated by chloride ammonium solutions. Obtained eluate directed to the etching stage, Generally. the technology provides copper recuperation and minimize wastes amount.

Jan 1, 2001

By Takafumi Kondo, Satoshi Yamashita, Noboru Masuko

"Aqueous oxidation of phosphite ions to phosphate ions with dissolved oxygen was examined at 80° C and pH 4.5 mainly from the stichiometric point of view. Dissolved oxygen alone can not oxidize sodilim phosphite in aqueous solution, but when sulfur dioxide is coexistent, cooperative oxidation for both sulfite and phosphite can occur in aqueous solution. Sulfur dioxide itself is well known as a reducing agent, but it also reacts as an oxidation-promoting agent for other species under a certain condition. So sulfur dioxide is· a promising cheap reagent for waste phosphite processing.IntroductionIn a liquid-phase oxidation reaction using the dissolved oxygen gas, the eoexistence of a copper salt is required generally. Recently, it was reported that the oxidation reaction progressed by using mixed gas of sulfur dioxide and oxygen without the copper catalysis, and the attention has been collected1·3). The present authors also noticed the phenomenon since the early time and have been studying on the reaction mechanism of sulfur dioxide in liquid phase oxidation 4l. It was found that; by using the SO2-O2 mixed gas, the oxidation of phosphite ions to phosphate ions proceeded efficiently in sulfuric acid solutions. In the present report, the applicability of SO2-O2 mixed gas as a cheap oxidizing agent to the industrial processing of the waste solution of electroless nickel· plating is investigated. It is well known that the sulfur oxide dissolved in aqueous solution is oxidized ·by the oxygen in the air to sulfuric acid according to the following equation"

Jan 1, 2000

By W. -S. Hwang, R. A. Stoehr, P. Ingerslev

"The flow of molten metal entering complex two-dimensional foundry molds has been modeled using the Simplified Marker and Cell (SMAC) and Solution Algorithm (SOLA) techniques. The molds were for a series of four and three-spoke wheel designs. The computer calculations were compared to physical experiments in which molten cast iron was poured into C02-bonded sand molds. The metal was photographed with a high speed motion picture camera focused through a Pyrex glass window on one face of the mold. To get good agreement between the calculations and the experiments, it was necessary to accurately represent the velocity through the ingate. This was calculated by application of the Bernoulli equation to flow through the feed system. Some difficulties were experienced with mathematical instability, expecially in the three-spoke design with a narrow ingate. This was overcome by using 100% upwind differencing, and over relaxation parameter near 1.0 (i.e. no over relaxation), and variable mesh spacing.IntroductionModeling the flow of molten metal entering molds has the potential for making significant contributions to the design of feed systems. It will supply information to the computer-aided-design systems of the future that will enable the designer to optimize the placement of gates, dimensioning of passages, and designation of casting speeds. Such design criteria have generally been based on application of energy balance (Bernoulli equation) principles to flow in the sprues, runners, and gates. Indeed, this is the easiest way to determine the proper dimensions to give a suitable filling time for a casting of a given size. A number of computer programs, including one by some of the present authors, have integrated such calculations into CAD systems. l Modeling the flow of metal inside the mold cavity requires other techniques that will handle free-surface transient flow. Stoehr and Hwang reported on the application of the Marker-and-Cell (MAC) technique to mold filling problems at the previous conference in this series at Hennicker, N.H. in 1983. 2 Although considerable progress has been made since that time in improving the accuracy, stability, and convenience of these techniques, the shapes to which they were applied remained limited. Also, physical verification of the results of the calculations was limited to water models.The work to be reported in this paper was undertaken with two objectives: (1) to apply these techniques to more complex and realistic shapes, and (2) to verify the results by comparison with flow patterns observed in molten metal poured into actual sand molds."

Jan 1, 1986

By Fathi Habashi

In the past five years Cuba has been attempting to more than double its nickel production by constructing two new ammonia leaching plants. No metals are yet produced on commercial scale but a variety of oxides and sulfides. This report updates the Cuban nickel industry as a result of two visits : one at the invitation of the Cuban Ministry of Basic Industries in 1987 and the other as a consultant to the United Nations for the Cuban Laterite Project in 1989.

Jan 1, 1993

By John W. Graydon

Incineration is an attractive alternative to the disposal of MSW in landfill sites. However, the process of incineration generates fly ash which contains significant levels of leachable heavy metals - particularly cadmium, lead, and zinc - and it is essential to manage this fly ash in an environmentally sound manner. The compositions, phases, textures, morphologies and size of fly ash particles have been studied by light microscopy, scanning electron microscopy, X-ray microanalysis, and X-ray diffraction. The detailed spatial relationships and speciation of the environmentally significant constituents have received particular emphasis. The information obtained is useful in understanding how fly ash is formed during incineration, in understanding the leaching behavior of untreated fly ash if it is disposed of in a landfill and, most importantly, in guiding the development of the best treatment strategies for fly asti to mitigate its environmental impact.

Jan 1, 1992

By Shadia J. Ikhmayies

"Tin oxide (SnU2) thin films of thicknesses in the range 100-600 nm were prepared on glass substrates by vacuum evaporation at ambient temperature. The films were characterized by transmittance measurements, X-ray diffraction (XRD), scanning electron microscope (SEM) observations and energy dispersion X-ray analysis (EDAX). It is found that the films have high transmittance and non sharp absorption edges. XRD diffractograms showed that the films are amorphous and the SEM micrographs showed that the surfaces are smooth, uniform and well covered with the material. The EDAX analysis showed that the films are deficient in oxygen. Indirect optical bandgap energy and Urbach tailing in the bandgap was observed, and the width of the tail, which is related with disorder and localized states, was estimated.IntroductionTin oxide is an n-type wide bandgap semiconducting material with a direct bandgap energy of 4 eV and an indirect bandgap of 2.6 eV [1], where inherent oxygen vacancies act as an n-type dopant [2], Tin oxide thin films have been used for transparent electrodes in photoelectric conversion devices namely amorphous silicon solar cells, liquid crystal displays, gas discharge displays, etc. [3]. Perfectly amorphous thin SnO2 films show good electrical response to reducing gases in air and could, hence, be applied to construct semiconductor gas sensors where the metal oxide films function as a monograin-eqivalent active layer [4]. Amorphous SnU2 can also be used in extended gate field-effect transistors (EGFET) as a pH sensor, where the sensitive part is made of the SnO2/Al structure. This device can be used to detect and to quantify any kind of substance that can produce or consume protons, like an enzymatic reaction, therefore showing a large range of applications as biosensors [5].There are different methods to prepare SnO2 films, such as atomic layer deposition (ALD) [6], reactive magnetron sputtering [7], chemical vapor deposition [8, 9], dip coating [10], spray pyrolysis (SP) [3, 11-14], and evaporation [8], The thermal evaporation method was chosen to produce SnO2 thin films in this work because deposition by this technique does not present any compositional problems. In addition, it is a low temperature technique, which increases the probability of producing amorphous films. To increase this probability, the films were deposited at ambient temperature."

Jan 1, 2012

By Nickolas J. Themelis

The role of copper in the economy will not diminish in the 21st century. Following the tenets of industrial ecology, production and use of copper must take into account both human needs and also how to minimize "collateral" effects on the environment. Dispersive uses will be phased out and post-use recovery of copper will increase. This will result into an advantage for smelting processes that can accommodate mixed metal scrap and waste streams. The bath smelting processes of Noranda and Mitsubishi will continue to make progress but the dominance of the Outokumpu flash smelting will not be challenged until the Noranda reactor overcomes the obstacles to the direct production of copper, thus eliminating the need for a converter.

Jan 1, 1999

By Jianhang Hu, Li Yang, Yonggang Wei, Kongzhai Li

"In this paper, the pyrolysis of biomasses including bamboo, sawdust and walnut shell were performed in a tube furnace under temperatures between 400? and 600? to obtain biomass carbon, gas, and tar. Textural parameters analysis revealed the caloric value of biomass carbons between 32 MJ/kg and 34 MJ/kg. It also indicated that the surface of biomass carbon consists of mesopore and macropore structures. By using GC analysis, it was determined the main ingredients of pyrolysis gas are CO, H2, CO2, CH4, C2H4 and C2H6. Calculation states that the density of pyrolysis gas is roughly between 1.0 kg/m3 and 1.7 kg/m3, while the calorific value of pyrolysis gas is between 12000 kJ/m3 and 16500 kJ/m3, illustrating that pyrolysis gas is a median gas. The calorific value of biomass tar was found to be between 32 MJ/kg and 34 MJ/kg, with more than 80 compounds in the biomass tar identified by GC-MS method.IntroductionBiomass as a renewable source is the world's largest and most sustainable energy resource [1].The conversion of biomass has the potential to be a renewable and carbon neutral method of producing fuels and chemicals [2-4]. Pyrolysis is a thermo-chemical process defined as applying heat to degrade biomass in an inert atmosphere. It transforms unstable biomass and other organic materials into biomass carbon, gas, and tar [5]. Biomass carbon can be stored or transported much easier as compared to parent biomass or be converted to value added products such as activated carbons[6]; gas is a relatively low-energy-density fuel; tar can be considered as a source of useful chemicals[7].The characterization of biomass pyrolysis will lead to its increased understanding and utilization as a source of solid, liquid and gaseous products which can be used as fuels and petrochemical feedstock[8,9].In recent years, many researchers studied the effect of temperature on biomass pyrolysis product distribution characteristics in a variety of pyrolysis reactor[10]. Ramin Azargohar's paper [11] presents the results of characterization for biomass and investigates the effects of pyrolysis temperature on the pyrolysis products obtained by fast pyrolysis of four different types of biomass."

Jan 1, 2014

By Rivera Jose Antonio Ore

Top Submerged Lance (TSL) smelting technology is currently used in a wide range of applications in the non ferrous and waste product treatment industries. The use of TSL technology for tin concentrates smelting has been successfully applied at the Minsur Tin Smelter and Refinery at Pisco, Perú. The process is based on the air-cooled top entry submerged Sirosmelt lance, developed by Dr. John Floyd at the CSIRO division of Mineral and Process Engineering in the 1970?s. Advantages of the process include flexibility to operate the lance, main burner of the Sirosmelt furnace, with different levels of combustion stoichiometry which allows us to get from highly reducing to highly oxydising atmospheres in the smelting reactor according to the type of feed we are processing, ability to utilize cheap energy sources such as natural gas, low capital cost and an environmentally friendly operation. This presentation summarises the application of the Submerged Sirosmelt technology for smelting tin concentrates and a variety of tin containing materials like iron dross, copper dross, tin residues, low tin/antimony slags by applying recent metallurgical developments at the Minsur smelter. The impact of new feed conditions and level of impurities on reactor performance with features of process and operation control are described. As a result of these recent advances in tin smelting using TSL technology, the Minsur Tin Smelter and Refinery improved its overall tin recovery, substantially reduced tin inventories and became the second largest tin smelter in the world, currently producing more than 40,000 metric tones of refined tin per year.

Jan 1, 2006

By Fumitaka Tsukihashi

Increasing amounts of steel scrap are being used as resources for steelmaking. Therefore, there has been a growing interest in the removal of harmful tramp elements such as antimony, zinc, tin, arsenic, bismuth, lead and copper from the molten steel. The problem that should be solved is the economic removal treatment of residual tramp elements in the steelmaking processes and the production of high quality steel by reducing the effect of the contaminated tramp elements and satisfying the environmental regulations. In this paper, the available thermodynamic data of the residual tramp elements in the molten steel arc summarized and the possibility of the removal of residual tramp elements from the molten steel is thermodynamically estimated.

Jan 1, 2003

By J. Huisman

With the introduction of ever-stricter environmental operating guidelines, capital expenditure restrictions and operational budget cutbacks, the biological method of SO2 removal becomes more and more attractive. Biological treatment of dilute flue gases is a more cost effective technology in comparison to conventional sodium hydroxide scrubbing. Although the investment costs for sodium hydroxide scrubbing is lower, the operational costs are significantly higher. In addition, the end product of the biological installation is sulfur instead of sodium sulfate; and no further wastewater treatment of the bleed from the biological installation is required since heavy metals are removed simultaneously. Another option for the treatment of SO2 containing gas at a sulfuric acid plant is the production of extra sulfuric acid of the discharged SO2 by applying an additional converter. Comparing biological treatment with this option shows much lower investment costs for the biological installation. Sulfur is produced which can be converted to sulfuric acid, so the bio-route will be more cost-effective than an additional converter. In principle, the biotechnological gas cleaning system is an integration of an absorber with a wastewater treatment facility. In the absorber, the SO2 containing gas is brought into contact with the washing water. The effluent absorber liquid contains a mixture of sulfite and sulfate that is converted into elemental sulfur. This conversion takes place in an integrated system; first, the sulfite/sulfate mixture is converted anaerobically into sulfide; secondly, the sulfide is converted aerobically into elemental sulfur. Subsequently the sulfur is separated and the water is returned to the absorber. Due to the buffer capacity of the washing water, removal efficiencies over 98% are possible. In addition to SO2 removal, it is possible to convert for example other bleeds streams such as scrubber acid or weak acid to sulfur in the same SO2 installation. Recent evaluations concluded that biological desulphurization of flue gases is not only economically attractive in comparison to convention sodium hydroxide scrubbing but also in comparison to gypsum producing systems and even seawater scrubbers. This paper describes the technological and economical viability of biological flue gas desulphurization.

Jan 1, 2005

By V. I. Lakshmanan

Crown ethers are gaining importance in separation technology specifically for rare earth elements (REE, La to Lu plus Y) and precious metals (Au, Ag, Pt, Pd, Rh and Ir) due to their specific binding ability, metal complex stability and high extraction efficiency. The selectivity of crown ethers in extraction of these metals depends on different factors, including the cavity diameter and nature of a donor atom of the crown ether, size and charge of the metal ion, diluents and counter ion. Demand for strategic REE and precious metals are consistently increasing in the world while the separation of these metals is most challenging tasks. In this paper, the use of crown ethers in separation of REE and precious metals, reaction mechanisms and simplified process flowsheets will be elucidated. New reagents with high selectivity for the separation of these metals are further expected to produce high purity metals.

By Jan A. Aune

The paper describes a number of electric furnace equipment modules especially developed or modified for slag furnace applications. Both the resulting design concept for a modern electric sulfide smelter and some of the changes in traditional process-concepts made possible are outlined.

Jan 1, 1983

By Peter Kong

This paper provides a general discussion of atmospheric-pressure plasma generation, processes, and applications. There are two distinct categories of atmospheric-pressure plasmas: thermal and nonthermal. Thermal atmospheric-pressure plasmas include those produced in high intensity arcs, plasma torches, or in high intensity, high frequency discharges. Although nonthermal plasmas are at room temperatures, they are extremely effective in producing activated species, e.g., free radicals and excited state atoms. Thus, both thermal and nonthermal atmospheric-pressure plasmas are finding applications in a wide variety of industrial processes, e.g. waste destruction, material recovery, extractive metallurgy, powder synthesis, and energy conversion. A brief discussion of recent plasma technology research and development activities at the Idaho National Laboratory is included.

Jan 1, 2006

By Sheng-hai Yang

The ultrafine, monodispersed, spherical cobalt powder has been fabricated by reducing cobalt hydroxide with glycol. It were investigated that the effect of NaOH concentration on the reaction rate and the effects of the concentration of cobalt hydroxide and surfactant on the morphology and particle size. The particles were characterized by the X-ray diffraction(XRD), scanning electron microscope(SEM), laser diffraction particle size analyzer and BET specific surface analyzer respectively. The XRD shows that the cobalt powders exist mostly in face centered cubic (fcc) structure, a little in simple hexagonal. The cobalt powders prepared at Co(OH)2150g/L, NaOH 40 g/L and surfactant 30g/L, its average particle size, specific surface area and cobalt content, were 0.88µm, 2.705m2/g. and more than 99.5% respectively.

Jan 1, 2006

By John J. Mortvedt

Application of some by-products of the metals industry which contain plant nutrients to agricultural lands could constitute resource recovery instead of costly disposal. Some industrial by-products contain appreciable concentrations of heavy metal contaminants, such as Cd, Cr, Ni, and Pb. After land application, these metals may be absorbed by plants and enter the human food chain or be leached to groundwaters. Plant uptake of these heavy metals varies with plant species:, soil pH, soil texture, and the particular metal. Certain leafy vegetables can absorb significant amounts of heavy metals, while absorbed metals are usually poorly translocated to cereal grains. Allowable heavy metal concentrations in fertilizers now are not regulated, but EPA is considering such regulations. Heavy metal impurities in animal feed supplements are regulated by the states; so some by-products may not be permitted for this use.

Jan 1, 1992