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By Hans-Åke Häggblad, Bertil I. Pålsson, Jan Stener, Kent Tano, Andreas Berggren, Pär Jonsén

Numerical modelling of grinding in tumbling mills is traditionally done with the discrete element method (DEM). The grinding balls are then represented by DEM particles and the mill structure is considered rigid. To include more physical phenomena several numerical methods can be combined. One important improvement is to include the mill structure response, using the finite element method (FEM). The interaction between charge and lining can then be studied in detail. The pulp can also be included using a particle-based continuum method e.g. smoothed particle method (SPH). The strength of SPH lies in modelling of free surface flows and very large deformations and it is suited to model simultaneous fluid and granular flow. Still, the coarse particles (grinding balls) in the charge are suitable to be model using DEM. Each of these methods has their strength and weaknesses, but combined they can successfully mimic the main features of the charge movement. With these numerical tools the complex interaction between the different components of the grinding process; pulp, charge, lining and the mechanical behaviour of the mill, can be studied together. This work will present novel numerical approaches to model, simulate and validate charge behaviour in tumbling mills. These numerical models give possibilities to better understand the physical and mechanical behaviour of particulate material systems during grinding in a tumbling mill. This is important in order to develop and optimise future high-capacity grinding circuits and save energy.

Jan 1, 2014

By Robinson Irarrazabal, Edison Collinao, Rodrigo de Carvalho, Patricio Davila, Marcelo Tavares

"In recent years, DEM (discrete element method) softwares, along with 3D laser measuring equipment, have become powerful tools to describe mill charge behavior, as well as forces acting on the liners of SAG mills. With the aim of contributing to streamline this application of the advanced technologies ME Elecmetal and Universidade Federal do Rio de Janeiro, UFRJ, proposed a new approach to improve the design of mill liners using elements from mechanistic modeling of grinding. The paper presents a methodology for continuous improvement of liner design, which uses information from the DEM collision energy spectra in the mill discriminated for the different components (ore and steel balls), as well as information on the breakage properties of the ore being ground. From these it proposes the concept of "effective collisions", which corresponds to the collisions that are of sufficient magnitude to cause breakage, thus allowing to discriminate from impacts that do not cause breakage either in a first impact or after repeated loading. It also tracks the collision of steel balls against the shell in order to assess their potential damage to the liners. An industrial case study is presented of a 38’ diameter SAG mill, which was experiencing challenges associated to liner breakage and low efficiency with the old liner design. Through a modification of the liner design, simulations demonstrated the potential benefit associated to reduction in ultraprojection and improvement in mill capacity. Implementation of the new design in the SAG mill was carried out, resulting in increase in daily throughput from 6 to 12%. Further, the time spent in liner change was reduced by 47% given the reduction in the numbers of parts. This operation also benefited from having no stops due to unplanned shutdowns to replace broken tiles. These demonstrate the benefit of coupling advanced computational tools to sound engineering principles in continuous improvement of liners."

Jan 1, 2014

By Genrich A. Denisov

Principles of ecologically friendly geo-technologies construction are formulated on the basis of the works of the leading scientists in the field of rational processing of mineral resources of the Russian Academy of Sciences. One of these concepts is a new direction in rotational disintegration of mineral and technogenic raw material with the purpose of effective subsequent enrichment. A large amount of practical experience has been accumulated in the industry on selective destruction by application of vibrational method on initial material with consideration of its physical-mechanical properties and mineral structure. This method is successfully realised in a conic inertial pulverisation devices constructed by Mekhanobr Institute (St. Petersburg). A new construction of conical-inertial pulverisation with a modification of disintegration force has been developed recently at Mekhanobr Institute. It allows, in some cases, to increase selectivity of subdivision and to avoid over-disintegration. Advantages of “wet” subdivision methods in conic inertial disintegration devices are proved. The efficiency of such subdivision can be increased due to rational use of the phenomenon of a dislocation-dynamic diffusion. Its advantage is proved by the effect on disintegrated material by frequency-modulated variable electrical fields of low power. It was shown in industrial conditions, that the productivity of the spherical mill can be increased by 10 %, and that it also prevents ecologically harmful surface active substances (SAS) in milling zone and it reduces the dust content in the air. The techniques of tentative estimation of efficiency of various proceedings technogenic materials and their classification are created. The scientific fundaments of rational, ecologically friendly technology of processing and regeneration of various kinds of technogenic raw material are developed. A number of effective technologies on processing of wastes is developed and inculcated in concentration factories and metallurgical factories.

Jan 1, 2003

By Douglas Fuerstenau

"Comminution not only is the major energy cost in mineral processing but it also can limit the grade of ores that can economically be processed. Rittinger first postulated that the energy for comminution is proportional to the new surface produced. Because most of the strain energy needed to initiate and propagate cracks in particles cannot be recovered, researchers reported woefully low comminution efficiencies. Recognizing this, Schoenert proposed that the baseline for assessing comminution efficiency should be the mechanical energy needed to break single particles. After extensive single-particle studies, Schoenert turned to comminuting beds of particle in piston dies. Finding particle-bed comminution to be energy efficient, he had the brilliant conception of making the process continuous, namely his invention of the choke-fed high-pressure roll mill (HPGR). Practical comminution involves masses of particles, which can lead to energy efficiencies far less than that of single-particle breakage. A three-way classification of grinding modes in terms of the mobility of the particle mass provides the necessary insight into the low efficiency of different comminution machines: namely, single-particle breakage, confined particle-bed grinding (HPGR), and loose-bed grinding (ball mill). Examples are given for determining and comparing comminution efficiencies. The size distribution of comminuted products become self-similar, and a single parameter, the median size, can be used to quantify the extent of comminution. The reduction ratio, expressed in terms of the mean size of the feed and product, varies linearly with expended energy and the slope of such plots is a measure of the grindability of the mineral. This approach clearly gives the order of energy efficiency as single-particle > particle-bed > loose-bed comminution. HPGRs are more efficient at low reduction ratios but lose that advantage at higher reduction ratios. Extensive hybrid grinding experiments carried out with our instrumented ball mill and HPGR showed significant energy savings by first comminuting the material in the HPGR and followed by the ball mill. At Cerro Verde an industrial-scale hybrid HPGR/ball mill system is reported to have a 13 percent energy savings over a SAG mill/ball mill system."

Jan 1, 2014

By Thomas Mütze, Petya Atanasova, Kai Bachmann, Urs A. Peuker, Thomas Leißner

"A method is presented for the evaluation of mineral processing by liberation and upgrading. The method bases on the plot of recovery of valuables versus the recovery of gangue (Fuerstenau upgrading curve). The locking curve of a feed material was plotted together with the upgrading curve in a Fuerstenau diagram. The assessment of liberation and upgrading is done by a comparison of surfaces formed by the curves and some characteristic lines of the diagram. This plot allows the calculation of two new quantitative measures for liberation and upgrading. Both parameters can be combined to a third parameter describing the quality of the whole technical setup for mineral processing by subtracting the upgrading parameter from the liberation parameter. The third parameter shows a positive value in cases of upgrading determined processes, a negative value in cases of liberation affected processes and about zero for processes affected equally by liberation and upgrading. Thus it is easily possible to distinguish between poor results in the mineral processing caused by insufficient liberation or poor results caused by insufficient upgrading. Preliminary results from two case studies, performed on two different ore types, are very promising illustrating the practical use of such an approach."

Jan 1, 2014

By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, T. Gurkova, T. Chumakova, Sylvinit Co.

"INTRODUCTIONFlotation of mineral particles by cationic surfactants – namely alkyl amines and their derivatives – is finding ever growing application in processing of various ores and in quality refinement of the benefication end products, iron concentrates for example. In the recent years application of cationic collectors - alkylmorpholines - enabled the development of new highly efficient procedure of water-soluble mineral processing, being also the one with low energy consumption. This procedure is a reverse flotation of carnallite from bay salts of salt-pans and from carnallite ores.The efficiency of cationic SAS influence depends upon colloid-chemical state of the collector in flotation liquid phase, especially if the latter comprises mineral salts. Availability of clayey impurities or slime particles of iron oxide in cation flotation feed, which actively sorb the cationic collector, deteriorate considerably the cation flotation performances. In Halurgy Institute the investigations of cation flotation under potash and carnallite ore processing have been carried out, and new reagent modes, enhancing cationic surfactants sorption at mineral particles, have been developed. Application of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles."

Jan 1, 2003

By A. T. Sutaone

"Battery grade Mn ore is not found in India except in Dongri-Buzurg Mine, Dist. Bhandara, Maharashtra. The mine located in central India is operated by a premier company viz. Manganese Ore India Ltd., under Central Government Public Sector Undertaking. The company is not selling the product as battery grade material but instead primarily catering to the needs of the iron and steel industry in the country. However, a part of the ore is being used in-house for the production of electrolytic manganese-dioxide in their EMD plant, which is located near the mine.The production of lumpy ore for steel industries generated through multi-stage crushing and screening has resulted in accumulation of about 50,000 tonnes of low grade fines over the year, which contain low of Mn values. Further, the generation of fines is still on going process due to the production of lumpy ores. These fines are stacked in the form of unconsolidated dumps, which create environmental problems like air and water pollution and siltation in the adjoining fields. Besides they are occupying large space, which is scarce in this mining area. The Indian Bureau of Mines under one of its statutory functions has suggested the company to explore the possibility of recovery of additional values under conservation and environmental aspects. Hence the company has sponsored a bulk sample for beneficiation studies in the Modern Mineral Processing Laboratory and Pilot Plant of Indian Bureau of Mines at Nagpur, India. The main manganese minerals present in these mine rejects have been identified as pyrolusite and psilomelane. The purpose of this study was to explore the possibility of evolving a suitable beneficiation flowsheet to obtain manganese concentrates assaying over 72% MnO2 to be used as raw material for the manufacturing of dry cell batteries."

Jan 1, 2003

By Yimin Zhu, Dezhou Wei, Haijun Liang, Zhifu Zhou

Pyrite is one of sulfide minerals most widely distributed in the earth. During the flotating separation of metal sulfide and the floating desulfation of coal, it is often requaired to restrain pyrite. However, the result is not very satisfactory because of the little difference of floatability of minerals to be separated. The problem is extremely outstanding for the floating desulfation of coal. Researchers carried out a number of experiments with T. ferrooxidans (Yang et al, 2001; Zhou et al, 2000; Zhou et al, 2001; Wei et al, 2001) for an enhanced restraint to pyrite. The results showed that the T. ferrooxidans after being cultured works the best in restraining pyrite. After 10 min pretreatment, the removal rate of pyrite from coal is up to 80%~90%. The research results by Yuan Xin et al (Yuan et al, 2000) show that T. ferrooxidans can restrain effectively the floatability of pyrite and can reduce the recovery of pyrite from 95% to 8%. Though the restraining properties of T. ferrooxidans to pyrite have been proved by many tests and experiments, there are very limited reports on its restraining mechanism. Thus, a systematic experimental research is carried out in this paper.

Jan 1, 2003

By M. Schneider, J. Regler, Th. Neesse, AKW A. + V GmbH & Co., J. Dueck, F. Donhauser

"In practice the advantages of high-quality hydrocyclone separation are often reduced due to varying feed suspension properties, solids concentrations and particle size distributions. Therefore, a new control system for a battery of hydrocyclones with a nominal diameter of 150 mm was developed for bentonite slurry regeneration associated with tunnel excavation using bentonite slurry as a transport aid and lubricant.As can be seen from Fig. 1, the hydrocyclone battery has been modified for regulation purpose. The battery was manufactured with an overflow collector as a closed pressure chamber (1) with a discharge pipe (2) where the throttling valve (3) was installed.With increased stepwise throttling of the overflow, the volume split is changed with the effect that the solids discharge in the underflow is increased. To stabilize the total throughput, the feed pump speed is simultaneously increased so that the pressure drop ?p across the hydrocyclones (9) remains approximately constant. However, this causes the increasing pressure inside the hydrocyclones, which results in a further intensification of the underflow discharge. After the detection of the break through of the air core (transition state) by the capacitive sensor (4), the throttle valve is shortly opened, and a new regulation interval can start again. The control concept is focused on maintaining the optimum operating state, characterized by the underflow discharge shape at the transition state between rope and umbrella discharge."

Jan 1, 2003

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By M. H. Moys, H. Dong

"Discrete Element Method (DEM) has become a standard tool to simulate grinding mills in order to gain information about load behaviour, power drawn, etc. However, parameters necessary to run a simulation are not always readily available. For example, the coefficient of restitution used in DEM simulation from the literature ranges from 0.1 to 0.9 due to lack of accurate values. The lack of correct input parameters results in the fact that some simulation parameters are adjusted to match the simulation prediction with the experimental results. It is inappropriate to tune one single parameter arbitrarily in order to fit the prediction with experimental results. The correct value of parameters for DEM simulation should be established, and rigorous validation on simulation results by DEM needs to be done.The objectives of the ongoing project are to measure the coefficient of restitution at conditions analogous to grinding practice. Equipment has been built to measure the coefficient of restitution. A typical case of impact test showing the vertical position of a ball as a function of time is presented in Figure 1. The coefficient of restitution between steel ball of different sizes and the targets including steel liner (e = 0.91), mild steel block (e = 0.57) and rubber liner (e = 0.7) have been measured. The coefficient of restitution reduces to 0.38-0.52 when there is a layer of coal particles (1-2 mm) on the steel liner. The effects of ball size, drop height on coefficient of restitution are investigated. Then a DEM code is developed of several contact models to simulate the impact process. This code can reveal details on velocities (translational and rotational) and forces (normal and tangential) during the brief impact interval. Figure 2 is a comparison of the rebound rotational velocity between experiment and prediction by different models. The results can be used as DEM input and to assess contact models."

Jan 1, 2003

By Rod Hocking, Nenad Djordjevic, Randolph A. Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures from standard operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill. Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulate the assemblage of a physical mill.By modelling the assemblage of steel balls in a 1 m pilot mill and duplicating the experimental arrangement exactly with the PFC3D model, it was possible to replicate the pattern of falling balls in the experimental mill. Furthermore, the key features of the acoustic emission spectrum that was calculated compared favourably to the measured spectrum at low frequencies. The experimental spectrum is shown in Figure 1."

Jan 1, 2003

By Pamela Castillo, Marcia Muñoz, Rodrigo Luca, Brian Townley, Fernando López

In the present study we discuss the value of multi-element geochemistry as a tool for semi-quantitative to quantitative bulk mineral characterization in geological and geo-metallurgical modeling of porphyry copper type deposits, with an emphasis on hydrothermal alteration associations, types and intensities. In mine production of porphyry copper deposits much effort is placed on ore grade and geological modeling, applied for predictive mineral processing behavior, from blasting, grinding, leaching or flotation, down to waste disposal and environmental management. High confidence geological models are commonly based on geological mapping of drill core and surface/ underground exposures, combined with discrete mineral characterization (e.g., petrography, QEMSCAN®, spectroscopy, etc.). Unfortunately these are expensive and applied to limited numbers of samples, thus lacking sufficient representation and not suitable for geo-statistical modeling. In addition, geological mapping always presents uncertainty, based mostly on qualitative estimates. The combination of information usually provides geological models that are hard to combine with geo-metallurgical data, much less with mineral processing predictive behavior models. The advent of multi-element geochemistry, at low cost, has allowed employment of such tools massively, yet little use is given to the data, usually focused on elements of economic interest (main ore and credits) and elements of negative impact to concentrates and/or process. Geochemistry reflects the mineral composition of rocks, thus allowing characterization of lithology, alteration types and intensities, and mineralization. As examples of such applications we present generic classification techniques which were developed on various porphyry copper deposits of northern Chile, these based on multi-element geochemistry, allowing for semi-quantitative to quantitative high resolution modeling of key aspects of lithology, hydrothermal alteration and mineralization, and which may be cross-referenced to metallurgical test samples and by that, to geo-metallurgical properties of rocks and modeling. In addition, as data is quantitative and continuous, modelling of gangue can benefit from geo-statistical modeling.

Jan 1, 2018

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.Sluices are the simplest forms of the flowing film concentrators and have been used in the mineral industry since at least the 15th century (Agricola, 1556). Flowing film concentrators, in general, still have widespread applications in the mineral industry and their designs vary according to the specific need.Particle separation in a sluice appears deceptively simple, but the separation mechanism has proven complex and difficult to quantify. Separation in the sluice takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in socalled hindered settling mode. The difficulty arises because the presence of the particles influences the flow pattern and when the particles are fully transported by the flow, the flowing slurry may not have the same viscosity as water and does not have the same density. For this reason a universal theory which can explain the behaviour of a suspension in a sluice or any other gravity equipment has still not been developed. Few attempts have been made to analyse the mechanisms involved in the concentrating processes of pinched sluices and Reichert cones.Fluid flow behaviour and slurry transportation characteristics in open channels have, however, been active research topics in the disciplines of fluid mechanics, chemical engineering and civil engineering for many years. As a result, an extensive literature is available, which has led to the development of the model described in this paper.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates, and the actual particle separation taking place compared to predictions from modelling.The modelling strategy was divided into two parts; the first was to predict the horizontal slurry flow velocity profile and the second to predict the solid particle concentration over the depth of the flow at different flow conditions. The predictions were then validated with measured data sets. This can easily be done if the slurry flow is split at different fractional flow depths so that the mass flow of solids over different flow heights is measured accurately over a fixed period. Mass flow splits can then be calculated by integrating the product of the predicted slurry velocity profile and the predicted solids concentration profiles from the base of the sluice bed to the slurry free surface."

Jan 1, 2003

By Heribert F. Broicher, Arne Volland

"The analysis of laser-induced fluorescence (LIF) combines remote sensing techniques with laser spectroscopy. Over variable distances different rock types are identified or changes in the quality of one rock type are recognised. LIF Analysers operate non-destructive, non-contact, on-line and in real-time. Installed over conveyors or over driveways the analysers ""look"" at the moving bulk solids 20 times per second and provide in real-time information for downstream sorting, blending or optimisation of processing. LIF Analysers recognise rock types (hardness information or dilution control), degrees of alteration, degrees of oxidation and –semi-quantitative- content of certain minerals in an ore. Only under favourable conditions quantitative assay information can be obtained, as e.g. the phosphorus content of Kiruna type iron ore.The main application of LIF Analysers is seen in big open pit operations, where the muck is trucked to an in-pit crusher and the crushed rock conveyed out of the pit to its respective destination: e.g. the primary high grade ore to the mill, the low grade or oxidised ore to the leach pads and the internal waste to the dumps.In underground mining and especially in block caving operations dilution control is of utmost importance. Here a LIF Analyser mounted on the back of a pick-up truck can be moved from drawpoint to drawpoint and quickly assess the degree of dilution.Closer to the mill the stockpile management based on LIF analysis will lead to stockpiles sorted according to rock type (hardness), degrees of alteration and oxidation. In case of direct feeding rom ore to the mill the knowledge of the type and quality of all the material between the in-pit crusher and the mill facilitates optimisation of e.g. reagent dosage."

Jan 1, 2003

By N. T. Beukes, W. Banda

Recovery of Co from slag is a recent advancement in the extractive metallurgy of nonferrous metals. In this study a DC arc technology at laboratory scale has been applied to investigate the selective recovery of Co from slag, under three different flux types with an emphasis on influencing the activity of FeOx, SiO2 and CoO in the slag. It is known that reduction of slag by carbon is only up to a certain level after which, the recovery will depend on the chemistry of the slag, hence the need to modify the slag chemistry. Two power settings were employed to induce higher temperatures and aggressive agitation. The results were interpreted by comparing how much Co and Fe was in the slag and alloy. TiO2 reduced the amount of Fe in the product alloy compared to when CaO and CaF2 were used. The change in power did not seem to have had a major effect on the recovery although the amount of material lost to flue dust was more at a higher power rate.

Jan 1, 2003

By A. Collings, A. Farmer

"Power ultrasound may be used in the processing of mineral suspensions to clean the particle surfaces of oxidation products and fine coatings, mainly through the large, but very localised forces, produced by cavitation, which is the formation and sudden collapse of bubbles in a fluid. Cavitation occurs preferentially at solid surfaces in a liquid: at container walls, inserted objects or suspended particles. When the cavitational bubbles collapse near a solid they do so by forming a very high energy jet directed from the point on the bubble furthest from, and directed towards, the surface of the solid, in effect micro jet blasting.This paper highlights some of the major mineral processes where ultrasonics is beneficial namely: Surface cleaning of detrital mineral particles, where container quality glass sand was upgraded to tableware quality and up to 20% improvements in the sharpness of high tension separation of mineral sands was achieved"

Jan 1, 2003

By E. V. Manlapig, M. C. Harris

"The complexity of the flotation process has made the identification of an appropriate model structure for the predictive simulation of flotation circuits far from obvious. Work performed under the auspices of the AMIRA P9 flotation program has indicated that the metallurgical performance achieved from a flotation cell arises from the interaction of two essentially independent property classes, namely the cell operating conditions and the properties of the cell feed stream. These observations have led to the development of a model structure that associates a constant set of flotation parameters to the streams of the circuit, which are transformed into a flotation response depending on the operating conditions within the flotation cell.A variety of alternative model structures exist within the literature which do not make this distinction between cell and stream flotation properties, and many of these models are in widespread use for flotation optimisation and design studies, both in industry and academia.In this paper, circuit survey and laboratory batch flotation data collected from an industrial flotation circuit are analysed. The data demonstrate that streams in an industrial flotation circuit exhibit varying particle floatability – concentrate streams typically float faster than tailing streams (Figure 1(a)). This floatability, however, is generally conserved around the various units within the flotation process (i.e. the effective floatability of the combined feed and product streams of a unit is equivalent (Figure 1(b)))."

Jan 1, 2003

By Markus A. Reuter, Yongxiang Yang, Jim R. Post

In the upper part of an iron making blast furnace, sinter, coke and pellets are charged. While descending, the burden is heated and the iron oxides are reduced by the rising gases. The iron oxides start to soften and eventually melt. The melt and the remaining coke collect in the lower part of the blast furnace: the hearth. The remaining coke forms a porous bed: the dead man (see Figure 2). The melt flow through the dead man can affect substantially the hearth lining life, the furnace productivity and product (i.e. hot metal) quality. Physical characteristics like porosity and particle size distribution of the porous coke bed play a critical role. Because of the distributed nature of the coke properties, the bed packing structure and porosity will not be constant.

Jan 1, 2003

By Valentin V. Shatalov, Irina V. Pastukhova, Alexander V. Kurkov

"We have developed a technology to improve the quality of low-grade concentrates containing minerals of tantalum, niobium and tin on the basis of given conception by the way of improving selectivity and using certain reagents composition. The basic collector presents a traditional or complex-forming collector used together with organic diphilic reagents – the secondary reagents regarding the basic flotation regiment, capable of forming associates with the main collector on the surface of the mineral, thus altering the interaction energy. In the given process the main collector is the fraction of hydroxamic acids C7-C9, the reagent of the secondary action – sulphosuccinamate, which added in moderate concentrations range provides for a synergistic effect.We have determined the parameters of the process stability and necessary modifying reagents for a selective recovery of tantalum, niobium and tin minerals from refractory products. Variants have been studied where the main collector and the secondary action reagent were substituted with some more efficient flotation reagents. A possibility of a more flexible reagent compounding for the process has been shown. The flotation process is highly stable regards the saline composition of the liquid phase in the pulp. It can operate under conditions of the complete water recycling with the total salt content up to 12 kg/m3, iron up to 1.2 kg/m3.The given results consider the efficiency testing of the suggested technology for the gravitation products, which were obtained from ores of various genesis and contain large quantity of the most refractory minerals, such as topaz (80%), gamet (55%), tourmaline (30%). High selectivity of the process has been registered with the metal recovery about 92-98%, which appears to be similar to hydrometallurgical operations under certain conditions."

Jan 1, 2003