Flotation Technology for Concentration of Tantalum, Niobium and Tin Minerals from Refractory Low-Grade Products

"We have developed a technology to improve the quality of low-grade concentrates containing minerals of tantalum, niobium and tin on the basis of given conception by the way of improving selectivity and using certain reagents composition. The basic collector presents a traditional or complex-forming collector used together with organic diphilic reagents – the secondary reagents regarding the basic flotation regiment, capable of forming associates with the main collector on the surface of the mineral, thus altering the interaction energy. In the given process the main collector is the fraction of hydroxamic acids C7-C9, the reagent of the secondary action – sulphosuccinamate, which added in moderate concentrations range provides for a synergistic effect.We have determined the parameters of the process stability and necessary modifying reagents for a selective recovery of tantalum, niobium and tin minerals from refractory products. Variants have been studied where the main collector and the secondary action reagent were substituted with some more efficient flotation reagents. A possibility of a more flexible reagent compounding for the process has been shown. The flotation process is highly stable regards the saline composition of the liquid phase in the pulp. It can operate under conditions of the complete water recycling with the total salt content up to 12 kg/m3, iron up to 1.2 kg/m3.The given results consider the efficiency testing of the suggested technology for the gravitation products, which were obtained from ores of various genesis and contain large quantity of the most refractory minerals, such as topaz (80%), gamet (55%), tourmaline (30%). High selectivity of the process has been registered with the metal recovery about 92-98%, which appears to be similar to hydrometallurgical operations under certain conditions."