Search Documents

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By Xiao Huang, Jean-Francois Thibault, Ali Merati, Prakash C. Patnaik

Single-crystal nickel-based superalloys are the current state-of-the-art technology for the manufacture of turbine blades. This technological improvement of the turbine blade has brought a considerable increase in its cost. Repair and overhaul of service stressed single crystal turbine components is an economic necessity for life cycle cost reduction of engines since the cost associated with replacement is significantly higher than its counterpart polycrystalline component. This paper will first review the recently reported research in developing repair technologies used for DS and SX components. These techniques repair the crack or defect while at the same time ensuring that the mechanical properties do not deteriorate and, more importantly, that the single-crystal microstructure is not jeopardized. It will then be followed by a brief overview of the research conducted and initiated by the authors with regards to the repair of single crystal alloys.

Jan 1, 2004

By Alfred W. G. Wilson

MR. F. E. LATHE: In studying any subject whatever, one should at least occasionally stand back from the canvas, as it were, and take a broad view of the picture. It is such a view of the subject of industrial minerals that Dr. Wilson has given us today, and, in consideration of our efforts to utilize Canada's resources to the utmost in the present emergency, it seems most timely. I shall confine my remarks on the subject to the resources of the atmosphere and hydrosphere. We seldom stop to realize our dependence upon the atmosphere, not merely as a source of the oxygen we breathe but also of other indispensable elements. As recently as the beginning of the present century, grave concern was felt lest the rapidly increasing population of the world should ultimately starve for lack of the nitrogen required for crop growth. I recently noticed a reference to the Scientific American for March, 1890-just fifty years ago-in which an account is given of work on the fixation of nitrogen, which, said the article, "leads to the conclusion that while cyanides and ammonia may be thus produced experimentally, there are as yet insuperable difficulties in the way of adapting those methods to industrial purposes". Y et, in the early part of the present century, the development of the arc, cyanamide, and synthetic ammonia processes of nitrogen fixation was such as to remove, for all time to come the possibility of a shortage of nitrogen. Today, the atmosphere is by far our greatest source of nitrogen, and the capacity of the nitrogen fixation plants of the world is at least 4,000,000 tons annually-much more than can at present be utilized. Pure oxygen or oxygen-enriched air offers great possibilities in metallurgy and industrial chemistry, but, so far, little application has been made. In a paper presented to the Institute in 1926, 1 pointed out the theoretical savings which could be effected by the use of oxygen in burning carbon-when the gases pass off at 2,460°F., the fuel saving is no less than 50 percent. The use of oxygen on a commercial scale is intimately tied up with the question of refractories, but we should not forget that the possible changes in metallurgical practice by the use of oxygen are truly of revolutionary character.

Jan 1, 1940

By Fathi Habashi

This Historical Metallurgy Note is the final part of a three-part series, the first two of which appeared in the November- December, 1997 and January, 1998 issues of the Bulletin. This series of articles is dedicated to the memory of Nikolai Maximovitch Pereskuryakov (1940- 1994), Rector of Saint Petersburg Mining Institute from 1992 to 1994 who passed away unexpectedly at the age of 54, shortly after celebrating the 275th Anniversary of the Institute.

Feb 1, 1998

By Roger Reed

It is well known that the performance and carbon emissions associated with the modern gas turbine engine depend critically upon the properties of the nickel-based superalloys, particularly those used in single crystal form. However, the design of all alloys in current use has been essentially empirical, or at best heavily reliant upon regression/neural network analysis of experimental datasets. In this paper, alloy design approaches [1] are described which are able to identify new alloy composition spaces which are worthy of experimental study. It is shown that a large amount of design data can be generated, which can be interpreted in different ways. Of course, the success of the approach depends heavily upon the accuracy of the underlying sub-models. Estimates of the creep resistance, cost, castability, density and oxidation resistance are made. It is demonstrated that these methods allow quantitative trade-offs to be made between the properties of interest.

Jan 1, 2010

By J. W. Reynolds

This paper describes the function of the research and development department of a large mining organization and the benefits which can be derived over the years. Examples are given of work done in rock drilling, ventilation, noise control and the development of backfill stowing machinery.

Jan 1, 1970

By D. A. MacLeod

DURING the past fourteen months, dust surveys have been made at thirty-six mines in the Province. These surveys are made to determine the concentration of dust in the mine atmosphere, the flow of air through the mine, the methods adopted to prevent the generation of dust, and the measures taken for its elimination. When high concentrations of dust are encountered, suggestions are given for its prevention ?and elimination wherever possible. Dust sampling is absolutely necessary to determine the effectiveness of any measure taken in the prevention and elimination of dust in the mine workings. Consequently, more time has been spent on this phase of the work than on any other. The apparatus used is the Devers circular konimeter and Zeiss microscope. At various mines, the Zeiss konimeter is used, and the dust counts taken by the two instruments have given results that are closely comparable; so much so that either instrument can be used with confidence and the results obtained will compare in accuracy with those obtained by the methods used in Ontario and South Africa. Before the Workmen's Compensation Act Amendment Act was passed in November, 1936, most of the mine operators were already keenly interested in the prevention of silicosis. This interest has been intensified at all the mines, and measures have been adopted to decrease the amount of dust in the mine atmosphere. Several operators have spent a large amount of time and money in bettering these conditions, and have met with decided success. Practically all others are adopting the known methods of prevention, suppression, and elimination of dust, that apply to their ?particular mines. To prevent the production of dust in underground workings should be the first, as it is the most important, aim, especially during the time the men are underground. An atmosphere free of dust cannot be obtained, but measures can be adopted to lower the concentration that is found? in the average mine.

Jan 1, 1939

By R. W. Lawrence

Sulphide is an effective reagent in the precipitation of base metals for both metal winning and environmental control. BioteQ Environmental Technologies Inc. has successfully demonstrated in industrial plants that biogenic sulphide reagent can be generated cost effectively and used to win metals such as copper, zinc and nickel from low-grade leach solutions and wastewater. Commercial plants in which sulphide reagent is used to produce high quality treated effluents for discharge directly to the environment are also in operation. Operations utilizing biogenic sulphide reagent for copper recovery from acid drainage and low grade leach solutions are discussed, including those at Bisbee, Arizona, commissioned in 2004 and at the Dexing mine in China, scheduled for commissioning in 2007. In addition, a new application of BioteQ's technology for the recovery of copper from gold-cyanide solutions, and the regeneration of cyanide, utilizing biogenic sulphide in place of chemical sulphide reagents in the SART process is described.

Jan 1, 2007

By Pierre Bénard

To achieve penetration on the energy market, hydrogen must overcome obstacles in the areas of storage, safety and infrastructure. One of the most important is the onboard storage of hydrogen for transportation applications, where large performance gaps exist between the current state of the technology and user expectations. In order to develop and demonstrate viable hydrogen storage technologies for cars, a set of gravimetric and volumetric system targets have been proposed by the US Department of Energy, based on achieving a driving range of 500 km for a hydrogen powered vehicle. A factor of 2 to 3 improvement in both hydrogen storage capacity and energy density is needed along with several other performance goals. Another key issue is safety. Although some of the safety issues can be arguably assigned to misperceptions, hydrogen has specific properties that have to be addressed, particularly in confined geometries where the risk of hydrogen detonations becomes an issue.

May 1, 2007

By M. L. Free

Laboratory scale extraction of metals from heterogeneous materials such as copper ores is often performed using fine material to increase kinetics and reduce sample size requirements and costs. In contrast, commercial extraction is usually accomplished using much larger material sizes than are used in laboratory settings. The large size difference between laboratory testing and commercial application materials makes it difficult to use laboratory test data to accurately predict performance for commercial material. One solution adopted widely in industry is the use of large test columns. Large test columns cost considerably more to set up and run and take much longer periods of time to evaluate than laboratory scale tests with small particles. Consequently, from a cost and data collection efficiency perspective, the development of accurate scale up methods offers significant potential for saving both time and money. This paper provides details for a new approach to correct for scale-up phenomena in heterogeneous material processing.

Jan 1, 2007

By B. T. Lu, J. L. Luo, J. F. Lu

The present paper investigates the chemo-mechanical effect in slurry-erosion corrosion process of carbon steel to understand the synergistic mechanism due to interaction of chemical and mechanical factors. The erosion-corrosion tests were conducted with A1045 steel in slurries comprising tap water and silica sand. Various heat treatments were adopted to achieve different hardness in the test material. The chemo-mechanical effect is evaluated in line with the correlation between the degradation of hardness in the surface layer and anodic current density. During the erosion-corrosion tests, various anodic currents were applied to find the relation between the anodic dissolution rate and erosion rate. The experimental results indicate that the hardness decreased with increasing anodic dissolution. Based on the fact that pure mechanical erosion rate increased with decreasing hardness, this result suggests that the corrosion-induced degradation of mechanical property is a mechanism of corrosion-enhanced erosion. This theoretical prediction is verified by erosion-corrosion experimental results.

Jan 1, 2004

By J. Beddoes

The various microstructural factors that influence the creep resistance of y-titanium aluminides are presented and discussed. Titanium aluminides have potential for a variety of intermediate temperature applications in both gas turbine and reciprocating engines. While it is well established that the 'fully lamellar' titanium aluminide microstructure offers superior creep properties, the particular influence of lamellar morphology, third phase precipitation, and grain boundary structure in controlling both the primary and tertiary creep behaviour is presented. The results are primarily based on tensile creep experiments undertaken using several titanium aluminide intermetallic compositions processed via powder metallurgical techniques, investment casting and Bridgman directional solidification. The results indicate that lamellar structure and precipitate formation have a major impact on primary creep, while microstructural degradation through both lamellar and precipitate coarsening influence on the onset of tertiary creep leading to fracture. The results are used to design a creep resistant microstructure produced by directional solidification and the effectiveness of this designed microstructure is demonstrated through 10,000 hour creep tests.

Jan 1, 2004

By A. Siegmund, F. Mucciardi, Z. Yuan, B. Bulnes

With conventional heat pipe science as the starting point, a new heat transfer technology --- termed Thermopump technology, has been developed at McGill University and is now being tested at a number of industrial operations. This technology is of particular importance for transferring energy in high temperature / high heat flux environments where solutions based on current techniques are not available. One important application for this technology is in the metals recycling area wherein this technology has been used to make a waterless, non-consumable, high efficiency Thermopump oxygen lance. The viability and efficiency of this oxygen lance have been demonstrated by preliminary plant trials in a reverb furnace for the recycling of lead-acid batteries at the RSR Corporation. Full-scale commercial trials of the Thermopump (TP) oxygen lance have been carried out at the RSR Corporation. The results from these tests will be presented. In addition, some applications of the Thermopump technology for other metal recycling processes will also be discussed in this paper.

Jan 1, 2004

By Fathi Habashi

This Historical Metallurgy Note is the second part of a three-part series, the first of which appeared in the November- December issue of the Bulletin. Part III will be published in February, 1998. This series of articles is dedicated to the memory of Nikolai Maximovitch Pereskuryakov (1940-1994), Rector of Saint Petersburg Mining Institute from 1992 to 1994 who passed away unexpectedly at the age of 54, shortly after celebrating the 275th Anniversary of his Institute.

Jan 1, 1998

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By G. Couture

In the introduction to this presentation, we will cover the market of motorized recreational products. We will introduce the public to what is produced and sold worldwide, what is the nature and general behaviour of the customers for such products. We will cover the evolution of this market and put in evidence how drastic must be the changes in the manufacturers organizations in order to, in one hand, constantly adjust to the customer demand, and in the other hand, react to the competitors' offensives on the market.

Jan 1, 2006

By T. A. Postolski, A. J. Sinclair

"Abstract- Two examples are used to describe how geological features impact on the development of semi-variogram models to be used for geostatistical resource/reserve estimation of porphyry-type deposits. In the Main zone of the Huckleberry porphyry copper deposit, mineralization is concentrated in fracture zones localized in volcanic rocks, along the eastern and southern margins of a granitic stock. Mineralized volcanic rocks can be subdivided into three separate domains, each with its own preferred direction of mineralization that is reflected in contoured Cu diagrams and semivariograms.The East zone at Huckleberry deposit, spatially distinct from the Main zone, is controlled by a fracture zone elongate roughly east-westerly and bounded on the south by a major fault (easterly striking and steeply dipping) across which there is a dramatic drop in grades. The eastern part of the East zone appears to be coaxial with a large intrusive body; the western part contains a small, elongate dike-like intrusion. Contoured Cu values for many levels suggest that the principal direction of geological elongation of the east and west domains of the East zone differs significantly. Independently derived semi-variogram models for each domain are different and reflect this difference in trend.In both Main and East zones of the Huckleberry deposit, block estimates by ordinary kriging are significantly different using a domain-specific semi-variogram model than using a deposit-general semi-variogram model. The domain-specific estimates are deemed better because they are based on local controls of mineralization and have less conditional bias than those generated by the depositgeneral semi-variogram model."

Jan 1, 1998

By K. Pienimäki

Boliden Harjavalta Oy has produced copper since 1945. The essential idea has always been continuous development of process efficiency and environmental friendliness by using the Best Available Techniques (BAT). The ongoing development step is to increase the production capacity up to 210 000 tpy of anode copper and 155 000 tpy of copper cathode. One of the focal issues in this action is modernization of the copper refinery to utilize permanent cathode technology. This paper describes the refinery project and the technology used in it.

Jan 1, 2007

By Lyall J. Lichty

THE property of New Calumet Mines, Limited, is on Calumet island, in the Ottawa river, about sixty-six miles northwest of Ottawa. Lead and zinc orebodies were discovered here in 1893. A gravity concentration plant was built in 1912 but was not a success metallurgically, and the plant was later destroyed by fire. A programme of diamond drilling on the property, started in 1937 and continuing to 1942, indicated ore reserves amounting to 1,300,000 tons averaging 2.75 per cent lead, 8.82 per cent zinc, and 0.041 oz. gold and 6.24 oz. silver per ton( l ). These orebodies have been developed underground by cross-cutting and drifting from a three-compartment vertical shaft, sunk to a depth of 745 feet. 'The ore is a contact metamorphic deposit occurring in rocks of the Grenville series, on or near the contact between biotite gneiss and an overlying calcareous amphibolite(2,3). It consists chiefly of iron-bearing sphalerite, galena, pyrrhotite, pyrite, and minor amounts of chalcopyriteand argentite. The gangue minerals closely associated with the ore are calcite, quartz, and various lime-silicate minerals.

Jan 1, 1945

By MKS Vel, S. Mukhopadhyay, R. Mishra

Off late, the criteria of selecting the refractory have acquired a trend line aiming to a cleaner environment and the utmost importance is given to the eco-friendly approach. The stainless steel making furnaces normally use mag-chrome refractories for the obvious reasons of changing slag basicity from acidic to basic. Such refractories generate toxic fumes and compounds with hexavalent chrome, which is unhygienic if inhaled. The present paper describes the development of a chrome free alumina magnesia carbon refractory, it's different test properties, simulative testing and microstructures. The optimum quantity and distribution of carbon in the brick restricts the carbon pick-up by the steel. Bricks with the same composition were manufactured in the commercial scale and used in a stainless steel making furnaces in USA. The performance of same refractory in this furnace was quite encouraging and at present the same quality brick has become a normal practice in this furnace. Since no chromite is used in making this brick, so no toxic compounds are generated environment remains pollution free.

Jan 1, 2004