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By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By J. N. Cram

"The comments given are to help allay generally accepted ideas that the handling of arsenic as arsenic-trioxide (As2o3J in and from off gas pyrometallurgical operation fumes is difficult, hazardous and expensive. It need not be any of these things if the basic and rather unique chemic3l and physical properties are understood and taken care and advantage of through present day technologies. These particular characteristics are:-(1) As2o3 sublimes and re-condenses, at a relatively low temperature;(2) As2o3 is, for practical in-plant purposes, insoluble in water at ambient temperatures and quite soluble in water just below the boiling point;(3) residual suspended and dissolved As 2o3 can be removed from water by complete dissolution with very little sulfuric acid, followed by the addition of small amounts of ferrous sulfate and calcium chlorate, with oxidation to the ferric and arsenite state and precipitation of an insoluble ferric calcium arsenate, thereby lowering the As2o3 content of solutions to acceptable levels. Even lower levels of non-toxic forms of arsenic solids and residual As2o3 in the water solutions can be attained by also using phosphate, and lime, along with the above.A background re past arsenic processing methods, present day operations, plus predictions re future trends, and hazards, are outlined."

Jan 1, 1979

By W. D. Mulholland

"I ASSUME that any effort on my part to deal with the question of the importance of the mining industry is going to be largely an exercise in preaching to the converted, but there are one or two aspects that I'd like to particularly mention.The first is that, in terms of almost all factors, the mining industry is a very important industry in Canada. It is important in terms of employment in relation to the gross national product of Canada and it is particularly important in the international trade of Canada. So far from being insignificant domestically, it is also an extremely important factor in the international picture. That's an important point to bear in mind, because as we talk about all the other matters we never can lose sight of the fact that mining management always has to be conscious of its international competitive position. It is something that one forgets at one's peril, and to a somewhat greater extent than is true of many other industries, those managements have to compete in an international context for their markets, to some extent for their people for specialized skills and of course for finance. In the evolution of domestic policies it is a very, very perilous step to take to impair that competitive ability of the domestic mining industry."

Jan 1, 1972

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By Kenneth L. Graham

Horizontal directional drilling from existing underground workings will greatly reduce, if not replace, surface exploration drilling. Diminishing ore reserves along with increasing difficulty in acquiring access and permitting of drilling surface holes requires a change in procedure. The length and direction of the required long holes is site specific, but once determined could be quickly mobilized. Data would be available for a much more timely evaluation without any surface disturbance and required reclamation issues. Preplanned directional drilling from underground will also provide an evaluation of already inconsistent uranium deposits located under surface terrain that is inaccessible to surface drilling.

Aug 1, 2010

By Sadough vanini Ali

Hot deformation behavior of functionally graded steel (FGS) was investigated via conducting hot compression tests at different temperatures and strain rates. Functionally graded steels consist of ferrite, austenite, bainite and martensite layers that are made by diffusion of alloy elements during the melting process. The zenerhollomon parameter has been used to describe the flow stress variations as a function of temperatures and strain rates. The parameter values for all the layers via using the boundary conditions was determined based on composite graded behaviors. Furthermore by applying the rule of phase mixtures, the whole strain rate applied on composite would be the sum of layers strain rates considering the layers volume fraction, while the layers have the same stress. Consequently the composite flow stress for each strain rate and temperature was determined.

Oct 1, 2011

"These guidelines set out information on timely disclosure of news releases which are intended to provide, existing shareholders and potential investors, factual information on which a reasoned investment decision can be made.Consider the problems and concerns raised by the following hypothetical news releases:Natural Resource Company""The Company has recently optioned a large and exciting gold property near the ""XXX"" gold discovery area. In describing the property, the Company's independent consultant has said: ""The favourable location of, and some of the results of prior work done on the property give the Company a worthwhile mineral exploration opportunity .... "". The Company proposes to expeditiously conduct a sizeable exploration program on the property as soon as the appropriate financing has been arranged.""Non-Resource Company""Based on discussions with several European countries, the Company anticipates that it will have orders to ship over 200,000 crates of widgets to those European countries over the next two years. These orders, which considerably exceed the Company's forecasts for the first year, represent a projected profit to the Company in excess of $1,000,000 over the next five year period.""GuidelinesTimely disclosure news releases are intended to provide, to both existing shareholders and potential investors, factual information on which a reasoned investment decision can be made. National Instrument 43-101 Standards of Disclosure for Mineral Projects provides requirements for disclosure of a scientific or technical nature for a mineral resource company.The examples do not provide sufficient detail and are misleading because material information is omitted. The following guidelines should be observed when preparing a news release:"

Jan 1, 2003

By S. Rash Ahmadi

One of the most important elements in power plants is rotors and repairing the damaged rotors is very important in view point of economics. One of the most complicated problems in power plants is increasing of stiffness of the turbine rotors. This problem which occurs mainly due to thermal shock or rubbing makes to exit damaged rotor from service. These elements can be repaired effectively by heat treatment methods. Tempering heat treatment is the most common solution for straightening of damaged rotors but it requires having good knowledge about heat treatment parameters (temperature and time) and their affects on fundamental properties of rotors. In this article, a suitable method is introduced in order to modify the increased stiffness in journal part of rotors due to martensite transformation, using heat treatment tempering process.

Oct 1, 2011

By A Sadough Vanini

In this paper large deformation of smart functionally graded beams with initial imperfection and under thermal loadings is considered. Smart beam consist of two types of layers. One layer is made from functionally graded materials and a layer or a set of layers from active materials that usually is made from piezoelectric materials that are bounded on the surfaces of beam. An active controller is used for controlling the deformation and stress in functionally graded layer of beam. A simple Euler- Bernoulli beam theory is used for analyzing of beam. In functionally graded layer the material property vary continuously through the thickness direction and power law model is used for the variation of elastic modulus, heat expansion and heat conduction coefficients. Poisson ratio is assumed to be constant in functionally graded layer. The effects of varying the power law constants and the Gain of controller is considered here. The results are reduced and compared with smart functionally graded beam without initial imperfections.

Oct 1, 2011

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

By S. A. Sadough vanini

In this paper the influence of temperature on the flow behavior and rheological characteristics of an A356 alloy in the semi-solid state using backward extrusion process are studied experimentally and numerically. Simulation process is done by dynamic explicit in ABAQUS software for each forming condition. A cooling slope treatment was employed in order to obtain a non-dendritic microstructure. Experiments were performed in 5 temperatures and 4 different wall thicknesses. In the low forming speeds, liquid fraction had time to escape from solid phase forward the samples? wall. This condition was the main reason for the segregation phenomenon seen in the base and walls. Viscosities were determined using the force-displacement graphs obtained form back-extrusion tests. As observed experimentally, in a constant temperature, increase of shear rate resulted in decrease of alloy viscosity exponentially. Raising the temperature increases the liquid fraction hence reduces the semi-solid alloy viscosity. The results of experimental and simulation are compared and there is a good adaptation.

Oct 1, 2011

By Peter Clevenstine

Minnesota Iron Ore Trifecta 1. World Demand 2. Industry Consolidation 3. Competitive Advantages

May 1, 2011

By Sadough vanini Ali

Charpy impact energy of functionally graded steels produced by electroslag remelting in crack divider configuration has been modeled in various strain rates. It has been well known that majority of materials indicate different behaviors under different strain rates and temperatures. Therefore, modifying the elastic-plastic model considering the effects of strain rates and temperature gives us an acceptable prediction of these composites behaviors in impact test. In this investigation, graded steel was divided in to several layers in which the layers have the same strains under the impact. Constitutive equation describing the flow stress variations as a function of strain rates and temperatures, have been used to express the stressstrain behavior of layers. The parameter values of constitutive equation determined for all the layers via using the boundary conditions based on composite graded behaviors which were the characterized ferrite, austenite, bainite and martensitte phases. Consequently by applying the rule of phase mixtures and ascribing the impact energy of each layer to the area of stress-strain curve of the same layer, the whole impact energy of composite is the sum of layers impact energy with considering the layers volume fraction.

Oct 1, 2011

"The standards set out requirements of the Toronto Stock Exchange for company’s providing information to investors, regulators and/or the media regarding their mineral properties. In addition, information contained in new releases, continuous disclosure documents [annual report], or other forms of communication [printed investor relations materials and electronic publications] are also subject to these standards.1.0 INTRODUCTIONThe disclosure of the results of exploration and development activity on mineral properties mustcomply with the requirements of the Toronto Stock Exchange Policy Statement on Timely Disclosure, theOntario Securities Act and all applicable policies and rules of the Ontario Securities Commission and anyother securities regulatory body having jurisdiction over an issuer listed on the Exchange. In particular,the requirements of National Instrument 43-101 must be followed.The purpose of the standards is to set out the requirements of the Toronto Stock Exchange when acompany provides information to investors, regulators and/or the media regarding its properties, whethersuch information is contained in a news release, a continuous disclosure document such as an annualreport, or other form of communication, including, but not limited to, printed investor relations material andelectronic publications such as Internet Web sites. These standards do not apply to prospectuses orlisting applications, the standards for which are contained in the policies and rules of the securitiescommissions and the Exchange. These standards are also not intended to establish requirements for thecontent of technical reports.Any information published by or on behalf of a company must comply with these standards. If acompany becomes aware of information published by others regarding its mineral properties which ismaterially misleading to investors, it should take appropriate action to correct such information orotherwise make it known that it is not responsible for publishing such information and does notnecessarily agree with such statements.Disclosure concerning mineral properties should identify the ""qualified person"" as defined in NI 43-101 who is responsible for the work conducted on the property and such person shall have read andapproved of the technical disclosure."

Jan 1, 2003

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By S. Rash Ahmadi

Welding is highly reliable and efficient metal joining process. In welding the metal adjacent to the weld joint is subjected to severe thermal conditions. As a result, complex changes in metallurgical structure occur in this region. These changes in structure depend on the material and the temperature history experienced. Friction stir welding (FSW) is relatively a new welding process in which, heat is generated by friction between the tool and the workpiece. The amount of heat conducted into the workpiece determines the quality of weld, residual stress and distortion of the workpiece. The objective of the current work is to study the transient temperature in a friction stir welding. So, a three dimensional transient analytical model is used to study the thermal distribution during the welding. Heat input from the tool shoulder alone is considered in the model. The process parameters like axial load, welding speed and tool rotational speed, used in actual FSW process are taken to build the model. This analytical model is very useful for select the optimized affected parameters in friction stir welding. The model illustrates the comprehensive equation including actual affected parameters in FSW and it can be used for different materials. In addition to the above the thermal history finds application in design of welding tools.

Oct 1, 2011

By J. B. Yianatos, F. A. Contreras

Mineral carrying rates across the pulp-froth interface in the range of 1.4-3.2 tph/m2 and bubble surface coverages between 7 and 22 %, have been determined in large rougher flotation cells operated under normal conditions. To evaluate these variables, measurements of bubble size distribution, bubble load and size distribution of particles collected by true flotation, were performed at different concentrators. A model for estimating the bubble surface coverage at the pulp-froth interface level as a function of bubble load, Sauter mean bubble diameter and particle size distribution of the mineral collected by true flotation, was developed. Bubble loadings in the range 24-70 kg/m3, bubble sizes between 1.5 and 3.2 mm and superficial gas rates between 1.2 and 2.0 emfs, were measured in copper rougher flotation cells under normal operating conditions. Estimated bubble surface area fluxes were in the range 31 to 62 cm2/s/cm2- Results of carrying rates and bubble surface coverage, at the pulp-froth interface, were significantly lower than the maximum carrying rate for the collection zone, indicating that in this case is difficult to achieve maximum carrying rate at the pulp-froth interface level. The main constraints regarding carrying capacity limitations are then related to the froth transport characteristics (i.e. cell design, froth residence time, froth stability, froth recovery). Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By S. A. Sadough vanini

In this paper, Stress-Strain-Temperature relations for Shape Memory Alloys are studied. Temperature effects on Shape Memory Alloys are different from those related to ordinary materials. In ordinary materials, elastic characteristics can be assumed to be constant in low temperature ranges, and only the deflection arising from temperature changes could be added to the elastic defection. As long as two phases of austenite and martensite could be present in Shape Memory Alloys simultaneously, elastic modulus follows temperature and temperature gradient. In continue a smart actuator is investigated considering a homogeneous cantilever beam. Beam bending is established by using shape memory wires. An initial strain is imposed to shape memory wires in a low temperature, and then, they are installed in the outer surface of the beam. Therefore, since the temperature is imposed in these wires and they cannot have free recovery strain, the compressive recovery stress will be produced in the outer surface. This will result in a deflection in axial direction of the beam. At first, beam deflection is calculated on the basis of theoretical relations and solving the relevant differential equations. Afterwards, experimental tests are performed on an elastomeric beam equipped with shape memory wires. When a voltage is applied, a temperature rise will occur in the wires; then, this temperature rise causes a deflection in the beam. Finally, the theoretical and experimental results? comparison indicates a good conformity. One capability of this actuator is its high flexibility, and by controlling the inlet current, the end-beam deflection can be controlled.

Oct 1, 2011