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By L. Vu, V. Popov, J. Beland, R. Darling

"The Ferderber gold deposit is of Archean age. It consists of a series of gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz dioritic Bourlamaque batholith. On average, this zone strikes N70E and dips 65SE. The Ferderber shear zone, which hosts the ore lenses, has been affected by a succession of tectonic events. A possible early period of brittle shear, accompanied by the formation of quartz lenses, resulted from strike slip movement along the zone. These early quartz veins were subsequently folded and boudinaged during reverse movement that accompanied a prolonged period of ductile shear. More quartz veins were emplaced in the shear zone at this time; these were also deformed by the thrusting. The latest tectonic event to affect the shear zone was a period of brittle fracture.Early dextral strike-slip movement on the shear zone is suggested by the local occurrence of Riedel shears, the preferred association of ore with east-northeast oriented segments of the zone, and by the apparent en echelon arrangement of some ore lenses. The most important event, a reverse movement, is indicatedby the attitudesoffoliation, folds, boudins, COS tectonites and slip planes. The late brittle fracturing formed narrow gouge filled faults, locally flanked by brecciazones, whichrun generally within and parallel to the shear zone, and also conjugate fractures that crosscut the zone.The Ferderber and six other adjacent gold deposits were formed in a structural regime dominated by a generally horizontal north-south regional compression. The Y axis of the strain ellipsoid is east-west and varies from horizontal to a plunge of 25 0 w."

Jan 1, 1987

By Pingyang Zhang, Caichu Xia, Shuwei Zhou, Yu Zhou, Yongsheng Hu

A lined rock cavern (LRC) is an alternative container for compressed air energy storage (CAES) to store high-pressure air that is later used to produce electricity. A critical requirement of CAES in LRCs is that the inner seal should provide adequate sealing capacity to prevent air leakage from LRCs. In many studies, rubber sheets are applied to build the inner seal. However, air leakage through rubber seals has not been given much attention and rubber seals are usually assumed to be absolutely airtight. Given that rubber is permeable especially under high air pressure, such as in CAES, air therefore leaks through rubber seals during CAES operations. In this study, a numerical analysis was conducted based on the permeation equation of polymers and the governing equations of thermodynamics of CAES caverns to analyze the characteristics of air leakage from CAES caverns through rubber seals. A planned CAES plant in China was considered as a case study. Results show that air leakage rate increases with increasing cavern temperature and pressure during air injection and decreases as cavern temperature and pressure decline during air withdrawal. However, in total, the daily air leakage percentage is in the order of magnitude of 10-3% in a typical operation cycle, which is much smaller than the critical value of 1%. Under a common range of realistic operations conditions, the daily air leakage percentage is still of the order of 10-3%. Therefore, rubber seals can be used to prevent air leakage in LRCs for CAES. However, the experience of Japanese pilot cavern indicates that the specifications for the on-site vulcanization jointing and installation methods of rubber seals still need improvement.

Jan 1, 2015

By M. E. Bilir

In this paper, we review cases in which dramatic and visual swelling problems are experienced in underground structures. Swelling rocks have caused many problems in underground engineering projects. They pose severe problems to the design, construction and maintenance of underground openings. If an appropriate integrated design procedure, which proceeds from exploration, tests, analyses and realistic assumptions of swelling behavior, is used during the design stage, the execution of the project can be completed without any serious delays or dramatic design changes. The case histories were subdivided into three classes that include tunnels, underground coal mines and others. For the evaluation of cases, the surrounding rocks, swelling minerals, water inflow, swelling test results and swelling problems were considered. The main purpose of this review is to inform the reader about potential problems with swelling phenomenon and to emphasize the rehabilitation and extensive cost which are encountered due to the lack of necessary integrated design approaches.

Aug 1, 2013

By Yvon T. Maurice

Under the auspices of the Federal-Provincial Uranium Reconnaissance Program, a geochemical orientation survey was undertaken in an area of uraniferous Lower Proterozoic (Aphebian) rocks near Cape Dorset in southwest Baffin Island. The main objective of this study was to establish a methodology for a future reconnaissance geochemical program using lake samples over a 300-mile Lower Proterozoic rock belt that occurs along the southern coast of Baffin Island. Mineralogical and chemical studies of known radioactive occurrences, combined with detailed sampling of secondary environment media in the vicinity of the showings. indicate that uranium is the most significant pathfinder, despite considerable enrichment of other metals in the uraniferous rocks, Significant geochemical patterns produced by uranium in lake waters and uranium in lake sediments have been obtained, but their relative usefulness depends on the distribution of carbonate bedrock, which in turn affect the bicarbonate content of lake waters. In southern Baffin Island, because of erratic variation in lake-water alkalinity, it is recommended that both water s and sediments be sampled on a routine basis. The need for lake-water acidification to prevent depletion of soluble metal ions in samples resulting from adsorption on the walls of the containers and/or suspended solid matter is discussed briefly. The base metal potential of the area was examined in some detail and found to be significant, particularly for a Lower Proterozoic gossanous formation that occurs throughout southern Baffin Island.

Jan 1, 1977

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By J. A. C. Ross

Introduction To enlighten those who may be wondering where anyone could find sufficient data to write a paper on underground concrete work, the author would like to explain that, at Copper Mountain, we have found it necessary to line numerous headings with a layer of concrete in order to keep them in a safe and serviceable condition. The majority of these headings are scram drifts and ore-pass raises. This paper will therefore deal, in the main, with the methods of and reasons for placing concrete in these headings. During recent years, radical changes have been made in the methods of mining ore at the Copper Mountain mine. After considerable experimenting, a mining system has been developed making use of diamond drills for primary breaking and transfering such broken ore through scram drifts with slusher hoists. With the advent of scram drifts, it soon became apparent that some substantial means of reinforcement and protection for the scram drifts themselves would be necessary. Since the orebodies in this mine are cut by numerous dykes or faults, and often both, it was anticipated that some means of support would be required where headings necessarily passed through these incompetent zones. Further, as experience was gained, scram drifts were driven into pillars and in close proximity to old workings so as to recover the maximum amount of ore. In such places, the ground is often severely fractured, either as a result of previous mining or from the effect of excessive rock pressures.

Jan 1, 1950

By A. J. Naldrett

"Sulphurization of peridotite, that is 'to say reaction between sulphur from an external source and iron and nickel in the silicate minerals of the peridotite or in partially consolidated magma, is believed to be the me-chanism by which the small iron-nickel sulphide deposits associated with the ultrabasic rocks of the Porcupine district have formed.The pyrrhotite-pentlandite ore at the Alexo mine, Dundonald township, is localized by a shear that closely follows the lower contact of a peridotite lens. In the past, to account for this orebody, the magmatic segregation hypothesis has been advanced on the basis of textural evidence and the presence of the sulphides at the base of the lens. The nickel sulphide de-posits of the Porcupine, however, are not characteristically found along the basal contacts of bodies of peridotite. Furthermore, this study has shown that textures formerly thought indicative of magmatic segregation have been formed in certain deposits by the selective replacement of silicates by sulphides.At the Alexo mine, very minor amounts of pentlandite and heazle-woodite (Ni3S2) occur in the peridot-ite hanging wall adjacent to the ore. These sulphides are interpreted as having formed by sulphurization, the sulphur involved coming from the pyrrhotite-pentla.ndite ore emplaced along the shear. This reaction aureole raises the question of the role of sulphurization in the formation of the main mass of the sulphide ore. The very localized equilibrium that has been found to exist between sulphides and silicates in deposits throughout the area, the results of nineteen sulphur isotope determinations, and the abundance of pyrite and pyrrhotite in the volcanic country rocks of the Porcupine indicate that these deposits were formed by sulphurization rather than magmatic segregation."

Jan 1, 1966

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By Rolf Andreas Lauten, Yanhong Wang, Yongjun Peng

"In mineral flotation, bentonite as a kind of clay mineral imposes deleterious effects on the flotation of valuable minerals, possibly through its ability to increase the pulp viscosity. A higher viscosity lowers the amount of froth and affects the bubble-particle collision frequency. A previous study found that adding gypsum to a bentonite-ore mixture lowered the viscosity, possibly by inhibiting the formation of interconnected network structures. In this study, sulfate as an anion with different types of cations, Na+, K+, Mg2+ and Ca2+ were used to reduce bentonite viscosity and to improve flotation performance. It was found that at the same concentration, MgSO4 was the most effective salt in reducing bentonite suspension viscosity, while CaSO4 was not as effective likely due to the lower solubility of CaSO4. Na2SO4 and K2SO4 reduced bentonite suspension viscosity at high concentration. Flotation kinetics of ore blended with bentonite was increased with increasing the electrolytes concentration, which generally correlated with the reduction of bentonite viscosity. Meanwhile, significant discrepancies were found between flotation results and rheological measurements in the presence of monovalent ions. It is indicated that the morphology of bentonite aggregates in electrolytes solution is likely to influence the hydrodynamics in the froth zone.INTRODUCTIONClay is present in many ore bodies as a gangue mineral. Presence of clay presents several challenges in the processing of valuable minerals. They are soft compared to valuable minerals, which means that during grinding of the ore, clay particles are likely to obtain a smaller particle size than the valuable mineral. Often clay particles may be within the colloidal size domain (<20 µm). The smaller size increases the probability of entrainment in the concentrate. Another challenge is their anisotropic charge distribution, where depending upon the pH, edges (E) and faces (F) carry charges of opposite sign. This facilitates formation of aggregation structures that may impede percolation of bubbles through a froth, but also increase the viscosity more than expected from the mere change in volume fraction. In addition to lowering the froth mobility, a high slurry viscosity will have implications for the gas dispersion in the flotation column as it affects the dispersion of the suspended particles, and it modifies the bubble-particle collision rate and attachment efficiency (Bakker, Meyer, & Deglon, 2009; Shabalala, Harris, Leal Filho, & Deglon, 2011). A pragmatic approach to this problem is to blend high clay ore with ore of lower clay content, reducing the overall clay concentration. Alternatively, one may lower the solids content of the flotation slurry to counteract the viscosity-building properties of clay. While feasible, this approach has the disadvantage of increasing required flotation volume, and it also affects the properties of the froth. Thus, there are currently limited options in lowering the impact of clays and their tendencies to increase viscosity in flotation slurries."

Jan 1, 2016

By Jesus Garcia Iglesias, Jorge Loredo

"Abstract -The Asturian fluorspar district consists of vein and stratiform deposits where mineralization is controlled by a combination of lithological and tectonic factors.It is postulated that these fluorspar deposits have been formed under disequilibrium conditions created during circulation of ascending hydrothermal solutions along faults and other high permeability conduits. Mixing of solutions is inferred from fluid inclusion studies. Cavity filling and replacement processes are very important in localizing the ore deposits and in determining their morphology.Permian volcanic rocks in the area yield a regional positive geochemical anomaly in fluorine implying that Permian vulcanism may be a possible primary source of fluorine.On a regional scale a relationship can be established between some of the ore deposits and important tectonic lineaments. The stratiform deposits preferentially occur within a calcareous-detrital facies located at the margins of basins. These basin margins are related to important synsedimentary faults.Fluorite is the only economic mineral in these deposits. Quartz, carbonates, barite and pyrite are common minerals accompanying fluorite. Other minerals that may occasionally be present as minor components are: marcasite, chalcopyrite, fahlore, sphalerite, galena and related supergene minerals."

Jan 1, 1994

By A. del Campo A.

The roast segregation process, which was patented in 1974, makes use of a set of chemical reactions that are different from the traditional sequential oxidation of iron and copper sulfides used by all modem pyrometallurgical processes to treat copper concentrates. It allows metallic copper to be obtained via sublimation of copper chloride at temperatures in the range of 700-800 OC. In addition it avoids melting the concentrate, doesn&apos;t require transferring molten materials, doesn&apos;t need flux addition and allows nearly all of the sulphur to be removed in one stage as a high-S02 gas stream. Most importantly, it allows a decrease in the use of energy to approximately 6 million BTU/ton of anodes. This represents a saving of approximately 40%, compared to the potential of the most advanced processes presently used. Such a promising process has been waiting for its first industrial application for more than 30 years. This article examines the technical difficulties that have delayed application of the roast segregation process to beneficiate copper concentrates. Special emphasis is made on material handling aspects, discussing the possibility of using a well designed mass flow silo as the main processing vessel to carry out the segregation stage. Cu2007

Jan 1, 2007

By Wang Xianzheng

For a long period of time, the Chinese Government has been attaching great importance to and supporting the rapid development of the coal industry. Particularly since more than 30 years ago, when China introduced the Reform and Opening-up policy, the reform and development of the Chinese coal industry has witnessed world-recognized achievements. National coal production increased from 618 million tonnes in 1978 to 3.52 billion tonnes in 2011. While China?s coal production accounts for 49.5% of the world?s total, its annual production growth contributes to over 80% of global production growth. China is a country utilizing coal as its main source of energy. As the Chinese Government gives support to the rapid development of new and renewable energy sources, as well as to increased coal utilization efficiency, the ratio of coal in the primary energy consumption mix will gradually decline. However, for a long period of time to come, the total volume of coal demand will keep rising modestly. The Chinese Government has been highly committed to and actively promoting the overall, coordinated and sustainable development model, which puts people first. It has put forward a strategic task to build an ecological civilization, and highlighted its resolve to uphold the basic national policy of resource conservation and environmental protection, with a view to the pursuit of sustainable development. China will incorporate its response to climate change into the national economic and social development program, and take effective measures to lower CO2 emissions 40?45% per unit of GDP in 2020 compared to 2005. At the same time, China will increase the ratio of non-fossil fuels to 15% in the primary energy consumption mix. All of the above factors have raised requirements for the Chinese coal industry, with implications for clear directions, plans and goals for the development of the coal industry.

Aug 1, 2013

By M. W. Bartley

DURING the field season of 1938, the Ontario Department of Mines assigned a combined geological and geophysical survey patty to the investigation of the location, genesis, structural relationships, and economic possibilities of the hematite deposits at Steeprock lake. The investigation was carried out by detailed mapping of the rock exposures and a magneto-metric survey of the drift-covered portions of the area. This was supplemented during the winter of 1938-39 by further geophysical work conducted on the ice. Dr. A. A. Brant, of the Department of Physics, University of Toronto, was in charge of the geophysical work for the Department of Mines in the summer and for the Sterola Exploration Company in the winter. The writer supervised the geological examination. Scope of the Paper The present paper is an attempt to acquaint the members of the Institute with the structure and mode of occurrence of the deposits, since many people are of the erroneous opinion that they are analogous to the Mesaba and Michigan deposits. It is hoped that, from this discussion, they may be able to draw some conclusions of their own regarding the nature of the deposits, and the importance and future possibilities of the region.

Jan 1, 1939

By A. A. Holland

Introduction The world&apos;s largest known deposits of natural sodium sulphate (Glauber salt), generally termed &apos;alkali &apos; throughout western Canada, are located in the Province of Saskatchewan: reserves are estimated to exceed 200,000,000 tons. These are surface deposits resulting from the recent or present-day natural evaporation of brines, in which respect they are similar to those occurring in certain other parts of the world, as in semi-arid sections of the United States, Russia, Germany and Austria. In some areas, underground deposits formed hundreds of thousands of years ago have been _encountered in drilling, and indications are that they also were formed under arid or semi-arid conditions. The master key to the formation of deposits of natural sodium sulphate, wherever they occur, is a climate, either past or present, under which evaporation exceeds precipitation over a considerable period of time. Commercial development of the Saskatchewan deposits began about thirty years ago. Previously, the demand for sodium sulphate had largely been met by salt cake produced as a by-product in the manufacture of hydrochloric acid from common salt. The rapid increase in the production of Kraft paper and, more recently, the development of synthetic detergent materials, have caused a marked increase in the market for sodium sulphate. This chemical gives the extra toughness to Kraft paper and is used in detergent compositions in proportions as high as 75 per cent. Saskatchewan now has six commercial plants producing natural sodium sulphate. Production from each in the fiscal years 1947 and 1948 is shown in Table I. The newest and latest plant is that of Saskatchewan Minerals, at Chaplin, which 1s designed to produce up to 150,000 tons of salt cake, 98.5 to 99.5 per cent pure, yearly. This is equivalent to about 24 percent of the total United States production of crude commercial salt cake for 1947.

Jan 1, 1949

By J. R. Giegerich

Purpose It is the purpose of this paper to describe the application of underground conveyor systems to the transportation of ore in the Sullivan mine of The Consolidated Mining and Smelting Company of "Canada, Limited, at Kimberley, British Columbia. General Applications Conveying has been recognized as a means of underground transportation for a great number of years but only during the past fifteen to twenty years has there been any extended application of the method to underground metal-mine operations. Coal miners became conveyor conscious before metal miners. Probably one reason for this is the fact that there are more flat coal seams than flat orebodies. A second reason is that coal is light and is a less abrasive material than most metallic ores. The vast improvements made in belt construction during the past few years, together with improvements in mechanical conveyor equipment, have gone a long way in making this form of transportation attractive to the metal miner. In new mines being opened today, or in major extensions to older mines, the possibilities of conveyor transportation should receive serious consideration. There may not be any widespread application of the belt conveyor as a replacement for the conventional hoisting and locomotive haulage. Where there is an application, tl1e saving in cost can be appreciable and many operating ad-vantages gained because of ease in operation.

Jan 1, 1951

By M. S. Badollet

"DURING the past five years, production of asbestos fibers has increased in all countries that list asbestos as one of their mineral resources. Despite the many small mines that have been opened in Canada, United States, Mexico, South America, Italy, South Africa, Australia, Yugoslavia, and Rhodesia, the supply still does not meet the demand. It is estimated that total 1952 world production of asbestos fibers of all varieties approximated 1,600,000 tons, with Canada supplying 966,382 tons (I), or 60 per cent of all fiber mined.Asbestos fiber brokers continually are offering odd-lot samples of chrysotile, amosite, crocidolite, tremolite, and anthophyllite fibers to manufacturers, •quoting fantastic prices for tonnages •varying from just a few to 50 or more in a month. In many cases, the samples are not properly graded and contain quantities of rock impurities and finely ground dust.When vendors submit samples of asbestos fibers, the manufacturer should consider• them in terms of price, quality, quantity, and as possible substitutes for fibers currently used in his products.Grading of these odd-lot fibers in most cases has been poorly done, with resultant non-uniform fiber lengths. In some instances, a number of miscellaneous lots of fibers have been .blended for sale. This blending produces a fiber that is difficult for the manufacturer to accept as a substitute for the well-standardized Canadian fibers."

Jan 1, 1953

By O. W. Borgeson, D. K. Honsberger, R. T. Bell

The Scully Mine, situated in the Labrador Trough near the Quebec-Labrador boundary, is one of the world's largest continuous ore deposits. This paper outlines the sequence of the mining operations from the planning stages to the delivery of the ore to the crusher at an average rate of 50,000 tons per day, 7 days per week. The principal equipment required to maintain this production rate includes four 12.\1.1-inch rotary drills, seven 8-cu.-yd electric shovels and a fleet of large haulage trucks. Particular attention is given to grade control, programmed by computer, drilling and blasting techniques and operational aspects inherent with open-pit mining in Canada's North.

Jan 1, 1969

By B. Damjanac, S. Maxwell, D. Chorney, M. Grob, F. Zhang, J. Hazzard

"A hybrid discrete-continuum numerical scheme is developed to study the behavior of hydraulic fractures crossing natural fractures. The fully coupled hybrid scheme utilizes a discrete element model for a core domain, within which the hydraulic fracture propagates and interacts with natural fractures, and a surrounding continuum domain to better approximate boundary effects. The results show that the behavior of hydraulic fractures crossing natural fractures is affected by a combination of factors. Nevertheless, three fundamental crossing scenarios can be identified from all of the simulations: no crossing, partial crossing, and direct crossing. Each crossing scenario has a distinct injection pressure history which may suggest guidelines for interpreting field hydraulic fracture injection data. Additionally, the capability for these models to generate synthetic microseismicity makes them appealing for the integration of microseismic field data with the reservoir geomechanics for ultimately providing a practical engineering tool for improvement of well completion and stimulation. The model is capable of examining and verifying four different shear deformation mechanisms associated with a propagating hydraulic fracture. The natural fracture can fail solely due to the stress perturbation of the passing hydraulic fracture or it can fail due to a combination of stress and pore pressure changes across different types of interaction scenarios. The simulations also illustrate that the level of fracturing complexity increases as the number and extent of the natural fractures increase. INTRODUCTIONAlthough hydraulic fracturing technique has been applied extensively as a reservoir stimulation technique in the oil and gas industry for over 60 years (Economides & Nolte, 2000), it is one of the key factors promoting the shale gas boom in the past decade (King, 2010; International Energy Agency, 2014). The hydraulic fracturing of shales can be differentiated from hydraulic fracturing of conventional reservoirs by the fact that shale formations often have a pre-existing discrete fracture networks which greatly impact the hydraulic fracture propagation. Based upon field production data as well as microseismic observations, it is believed that so called “fracture complexity” may result from interactions between a created hydraulic fracture and pre-existing natural fractures and planes of weakness (Warpinski, 2009; Maxwell & Cipolla, 2011)."

Jan 1, 2015

By C. Moctezuma

Since the start up of the IMMSA electrolytic zinc refinery in 1982, the dissolved iron coming from the acid attack of the ferrites has been precipitated by the jarosite process. At the beginning of operations, sodium jarosite was produced; however, the plant was converted to ammonium jarosite in 1990. The final storage of the residue is on the company&apos;s property adjacent to the plant, over the natural surface of the land. Before the construction of the refinery, several studies were done in order to evaluate the characteristics of the ground, such as, permeability, underground water localization, etc. The results showed that the site was adequate for the storage of this kind of material. For several years, the jarosite residue was filtered on rotary drum filters and was sent as a pulp to the storage area for settling. The water from the storage pond was recycled to the re-pulp tank for the jarosite residue. These filters were replaced in 1999 by an automated filter press. Since then, the jarosite residue has had a lower water content, and the zinc recovery improved. At present, a second filter press for the jarosite circuit is in the acquisition process to diminish the soluble zinc content in the residue from the present value of 2% to < 1% Zn.

Jan 1, 2006

By M. Rafieazad, P. Fathi, M. Mohammadi, A. M. Nasiri

This study examines the impact of low-temperature heat-treatment cycles on microstructure and corrosion performance of Direct Metal Laser Sintered (DMLS) AlSi10Mg_200C alloy. It is known that the morphology and the size of eutectic silicon are the two most critical factors affecting mechanical properties of the AlSi10Mg alloy. Although high-temperature heat-treatment cycles are common practice for the strengthening of the cast Al-Si-Mg alloys, in the case of DMLS fabricated AlSi10Mg alloy, high-temperature solutionizing and low temperature annealing cycles result in mechanical properties degradation primarily due to a dramatic decrease in the solubility of Si in the super-saturated a-Al matrix of the as-printed alloy. In this study, low-temperature heat-treatment cycles that only promote precipitation of Mg2Si accompanied by the interruption of the silicon network were investigated. SEM and XRD analysis were utilized to observe the evolution of microstructure after different annealing heat-treatments at 200, 250, 300, and 350°C for 3 h. Increasing the heat-treatment temperature contributed to the Si networks interruption and an increased precipitation of Mg2Si phase. Low-temperature annealing from 200 to 350°C was found to promote the homogeneity of the microstructure characterized by a uniform distribution of eutectic Si in ??-Al matrix. Additionally, in order to investigate the impact of different heat-treatment cycles on corrosion resistivity of DMLS-AlSi10Mg_200C, the potentiodynamic polarization testing and electrochemical impedance spectroscopy were performed in a 3.5 wt.% NaCl solution. The results revealed more uniformly distributed pitting attack on the corroded surface by further increase in the annealing temperature, which was attributed to the uniformity of Si dispersion. In comparison, low temperature annealing at 200°C led to a penetrating selective corrosion attack along the melt pool boundaries, resulting in a higher corrosion rate associated with the lower absolute value of impedance of the protective passive film on the surface.

Jan 1, 2018