Leaching Behavior of the Roasted Nickel Calcine

"Sulfation roasting of nickel concentrate to generate water-soluble metal sulfates was investigated as an alternative process to smelting for the recovery of valuable metals. The kinetics of dissolution of various species of the calcine in three leachants was studied; hot water, dilute HCl, and concentrated HCl. The results indicated that dissolution of sulfates by hot water at 90 ºC is achieved within 30 minutes. In order to increase the recovery of the valuable metals, acid leaching is necessary due to the existence of ferrite in the calcine.INTRODUCTIONInvestigations on the sulfation roasting of nickeliferous sulfide ores or concentrates were mainly carried out in 1950’s to 1990’s to generate water soluble non-ferrous metal sulfates followed by metal recovery by leaching (Stephens, 1953; Thornhill, 1954, 1961; Fletcher and Shelef, 1964a, 1964b; Fletcher and Hester, 1964; Frankiewicz, 1977; Norrgran, 1983). Commercialization of the sulfation roasting process was only performed by Falconbridge Ltd. (Thornhill, 1961; Boldt, 1967), which employed a sulfation roast process on nickeliferous pyrrhotite at 680 oC where Ni, Cu, and Co were leached and Fe2O3 was produced for the iron industry. In 1965, 118,342 tons of pyrrhotite was processed, however because of the huge SO2 emissions (no acid plant) relative to the nickel production and the poor economics, this plant was shut down.Nickel production from sulfide ores via pyrometallurgical means, especially the electric furnace smelting process, is a major emitter of SO2 to the environment and a big energy consumer (Warner, Diaz, Dalvi, Mackey, Tarasov and Jones, 2007). Nowadays, due to the more stringent environmental regulations as well as the need to reduce energy consumption, metal production by sulfation roasting is gaining more attention as an alternative process to smelting. The main focus of this paper is to investigate the extent and rate of leaching of valuable metals from the sulfation roasted nickel calcine, aiming to maximize the metal recovery and minimize the dissolution of iron species."