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By M. Peshko, J. C. Gingerich, L. W. Matthews

"Noranda has successfully developed and implemented two leading-edge mineral exploration technologies — hyperspectral remote sensing and 3-D seismic surveying. Airborne hyperspectral imaging provides detailed geological and mineralogical mapping capability at both a regional and project scale that facilitates improved selection of prospective terrain and an accelerated exploration cycle. Noranda, in partnership with Falconbridge, has licensed the exclusive use of the Earth Search Sciences Inc. (ESSI) Probe-1 hyperspectral scanners (128- channel, 0.43 µm to 2.5 µm spectral range) that are capable of mapping in excess of 3500 km2 per day at 10 m pixel resolution. The technology has been successfully deployed on four continents over a broad range of terrain from desert to boreal forest and the high Arctic.To augment the company’s deep search initiatives, Noranda has successfully modified and implemented existing 3-D seismic technology to help targeting massive sulphides located at depths ranging from 500 m to 2000 m. In the fall of 1998 and early 1999, Noranda completed an 18 km2, 3-D seismic program in eastern Canada by successfully drill testing acoustic impedance anomalies locating massive sulphides at depths in excess of 1100 m."

Jan 1, 2002

By C. E. Baltzer

This is the fourth in a series of coal technology reviews being prepared. in accordance with a recommendation voted by the Coal Division C.I.M. in session at the Jubilee Meeting, Vancouver, 1948, that the Department of Mines and Resources be requested to arrange for publication by the proper Government authority of a Quarterly Review of Coal Technology for distribution among those concerned in the production and use of coal in Canada. Copies of the first review, which appeared in the November, 1948, BULLETIN, pp. 612-614, of the second review in the June, 1949, BULLETIN, pp. 272-275, and of the third review in April, 1950, BUL-LETIN, pp. 1,9?3-196 (also, respectively, in Transactions, Vol. LI, 1948, pp. 262-264 Vol. LU, 1949, pp. 117-120, and Vol: LIU, 1950, pp. 133-136), were distributed by the Dominion Coal Board and are still available on request. In this review, the first in the series in the field of combustion, development and trends during the period approximately from World War II to the present time are described and therefore the presentation is general. Later reviews will particularize developments in relation to the range of coals available in Canada.-ED. INTRODUCTION THE utilization of coal in heat and power producing equipment has become of paramount importance to the coal industry in maintaining stable and profitable markets. In the past, the chief concern was with mining, transportation, and overall supply problems, but modern conditions demand interest in and knowledge of all phases of the product, from coal in situ to its ultimate disappearance in the form of products of combustion. Even the last mentoined factor has caused complications, as is shown by current widespread activity in the field of smoke abatement

Jan 1, 1951

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By C. S. Lord

"AbstractThe slow progress of conventional geological reconnaissance of the northern Canadian Shield during the past twenty years clearly indicates the need for a radically new field technique. Operation Keewatin, involving the use of helicopters as the traversing vehicles, was planned and executed by the Geological Survey of Canada in response to this requirement.About 57,000 square miles of District of Keewatin, N.W.T., were mapped during the 1952 field season in appropriate detail for publication at 1 inch to 8 miles. The Operation disclosed about 14,100 square miles of Precambrian sedimentary and volcanic rocks ranging in •age from Archaean to Late Proterozoic. About 7,700 square miles of this area are underlain by greenstone. This work was accomplished in a field season of 113 days, including the spring break-up. Routine aerial geological observations were made from two helicopters flying about 300 feet above the ground; these observations were checked by more than 1,700 landings and about an equal number of aerial observations from heights of less than 50 feet. Logistical support was •provided by a Norseman aircraft on skiis or floats. Combined helicopter and Norseman flying time was about 990 hours. More than 1-00 square miles were mapped per helicopter-hour, and about 815 square miles were examined each day that both helicopters operated. The reconnaissance cost about $207,000, or $3.63 per square mile mapped.As a result of this trial use of helicopters there is now available a reasonably proven method whereby an acceptable geological reconnaissance of the barren grounds of the Canadian .Shield within the Districts of Keewatin and Mackenzie might be completed within a decade. Thus, within a few years, it could place at the disposal of the prospecting and mining fraternity data which, by conventional methods, might not be made available to this generation. Due weight must be accorded this time factor when evaluating the aerial technique."

Jan 1, 1953

By Daniel J. Corkery

Mines in Canada and the United States are subject to regulations limiting ammonia, nitrate and nitrite levels in mine effluents released into the environment. The primary source of these nitrogen compounds is typically explosive used in blasting operations, as ammonium nitrate (AN) remains a significant component of most explosives used in the mining industry. The amount of AN entering a local water drainage system is related to site conditions, explosives used, explosive handling and blast efficiency. Mining operators acknowledge AN loss to mine water from blasting operations. However, the mechanisms by which ammonia, nitrite and nitrate are entering the water drainage system, or the relative contribution of specific mechanisms, may not necessarily be assessed or monitored adequately. Characterization of these mechanisms, through systematic investigations, allows a mining operation to focus its efforts on reducing AN loss. This paper outlines a strategy for investigating the mechanisms through which AN enters the mine water drainage system and methods to mitigate this loss. This strategy includes collection and analysis of data to identify and quantify the AN loss mechanisms, design and implementation of tests to mitigate this loss, and assessment of the results. Such investigations are not intended to be a separate one-time project, but part of a long-term process of continual feedback and optimization that is related to the collection and reporting of AN levels for regulatory purposes. The implementation of the strategy must be tailored to each mine?s requirements and existing conditions.

Oct 1, 2010

By J. F. J. Thomas

"AbstractBoth the quantity and quality of waters available as raw materials are important to Canadian industry and to the national economy. The huge demands of many Canadian industries is illustrated by tabulated figures, based on the 1950 Canadian production of certain products, and on United States figures for the gallons of water required to produce a unit quantity of each product. It is suggested from comparison with American survey results and figures that Canadian industrial water consumption is 1 to 11/2 billion Imperial gallons per day. Since present information on Canadian usage is meagre and it is not certain that American survey results can be directly applied to Canadian industry, this estimate must await confirmation in future studies.The hydrologic cycle and the principal factors affecting the quantity and quality of water, namely, climate and season, topography, geology, vegetation, and human activities, are discussed and the principal salts dissolved in water which affect industrial use are enumerated.The present survey studies by the Mines Branch on water quality are outlined. Besides chemical analyses of municipal water supplies within a watershed, periodic sampling and analyses of major surface waters for a one-year period is being carried out. The importance of studies on seasonal variation in quality is stressed by comparing the dissolved salts in various river waters with river flow. Figures showing such relationships in the Rideau river and Ottawa river at Ottawa, the Columbia river at Trail, B.C., and the Battle river at Unwin, Sask., are presented. Different rivers show different quality changes with changing flow, and possibly only after long-term studies can the relationships be predicted.Quality studies on water may be as important as studies on many other raw materials. The quantity of the raw material, water, is not inexhaustible nor is the quality indestructible, and more realization of its importance, followed by conservation and intelligent use, is desirable."

Jan 1, 1952

By P. M. Solozhenkin, O. I. Ibragimova, I. P. Solozhenkin

Molecular models of complexes of poorly studied bismuth, gold, and arsenic mineral clusters and reagents were created for use in collector activity forecasting using Chem Bio 3D and ChemOffice2005, with optimization by MM2. The density functional theory approach was used to determine HOMO, LUMO, SOMO, and total energies, atomic charges, and s, p, d- populations for various compounds. The structure-based virtual screening (SBVS) and docking technique was proposed to reduce the vast number of compounds to a more manageable number for selection of potential flotation candidates. The prognosis of collector activity evaluation (PCAE) strategy was proposed as a consistent approach to estimate the interaction between a collector and a mineral cluster as the difference between the total energy and sum of cluster energy and collector energy to search the analogue of butyl xanthate. The negative relationship between PCAE and flotability was shown. The combinations of dialkylamino sulfhydryl collectors can be considered as prospective reagents for gold-bearing sulfide ore flotation. These results were confirmed by experimental data in ore flotation. The increase in recovery of gold and bismuth with the aid of a combination of reagents has been established and additional cyanidation of tailings has been avoided.

Jan 1, 2016

By Stewart A. Ferguson

Location.-The property consists of eight claims (P-12339 to 12343, 12403 to 12405) in Robb township, adjoining Jamieson township on the west. A mocor road extends twenty-two miles northwest from Timmins to the mine. Acknowledgments.- The field work was done in 1940 and 1943, while the writer was employed by the Ontario Department of Mines. The Metals Reserve Company has made available information regarding the property through Messrs. W. R, Dunbar, of Hollinger Consolidated Gold Mines, and W. C. Ringsleben, of the Metals Control Board, Department of Munitions and Supply.

Jan 1, 1945

By G. Danha, S. Wabula, D. Glasser, D. Hildebrandt, N. Hlabangana

"Impact tests on single particles or a bed of particles are used to determine the fracture characteristics of particles. Many different techniques have been adopted in comminution in order to find ways of optimizing energy consumption in the size reduction process. In this paper, we apply one such method called the Attainable Region (AR) analysis technique to optimize the impact energy on a bed of silica particles. The attainable region is a fundamental approach that is equipment-independent and can be used to analyze breakage processes. The AR is defined as a set of all possible outcomes, for the system under consideration that can be achieved using fundamental processes operating within the system.INTRODUCTIONThe energy crisis in Southern African has reached such critical levels, that most cities in countries like Zambia, Zimbabwe, Lesotho, Swaziland and even South Africa are experiencing load shedding challenges lasting sometimes up to 18 hrs a day. Southern Africa is well known for its riches in mineral resources, and the economies of most states in this region are driven by the mining & mineral processing sector. With the emergence of small scale miners due to government empowerment policies, national energy providers have had to resort to power cuts mainly to domestic users in a bid to cope up with the huge industrial electricity demands.It has been estimated that about 4% of the total energy used in the world is consumed by the mineral processing sector (Fuerstenau & Lutch, 1999). Tomanec and Milovanovic (1994) estimated that milling alone accounts for more than 50% of the total power used in mineral processing, but this can rise to as high as 70% for hard or finely dispersed and inter-grown ores. Today, the greatest challenge in mineral processing is how to optimize energy input to the size reduction process (Dey & Das, 2013; Nomura & Tanaka, 2011), where it has been observed that only a small percentage (1.5%) of the total energy input really does the breaking (Khumalo et al., 2008) while the rest is consumed by the equipment concerned and lost to contacts that do not result in breakage. The immediate benefits of focusing research on the optimization of energy in size reduction operations in the mineral processing sector lies in potential savings on industrial electricity usage that may then be directed towards domestic users."

Jan 1, 2016

By J. G. Martin, J. C. Campbell

THE VICTORIA JUNCTION 31,4-million-ton coal preparation complex went into operation in October 1976."' It is designed to produce a metallurgical coking coal by lowering the sulphur and ash content of the raw coal using a heavy-media cycloning process to treat deslimed crushed coal, with scavenging of fine coal by flotation from the primary minus-28-mesh screen product. A secondary H-M cyclone scavenges a thermal-grade coal from the primary H-M cyclone tailing.

Jan 1, 1985

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By Y. Miyabayashi, K. Nishikawa, H. Nagai

JX Nippon Mining & Metals Group recovers valuable metals from end-of-life electronic products in an economical and environmentally-benign way, based on technologies that have been acquired in mining, smelting, and refining operations over time. End-of-life electronic products contain halogens and hydrocarbons. When such materials are treated in the copper smelting process, corrosion of equipment and discoloration of sulfuric acid occur. As a countermeasure to these problems, we have developed pretreatment processes that include an incinerator, exhaust gas washing towers, and a defluorination facility. By implementing these improvements, we have been able to treat a large volume of end-of-life electronic products efficiently in the copper smelting process.

Jan 1, 2014

By Troy Boisjoli, Sean Hillacre, Matt Batty

Discovered in 2014, the Arrow Uranium Deposit has undergone rapid development through successive drilling programs informed by geostatistical drill hole spacing studies. An independent third-party geostatistical drill hole spacing study was completed by Clayton V. Deutsch Consultants Inc. in 2017, evaluating the uncertainty of thickness, grade, density, and areal limit of the Arrow Deposit to determine a drill hole spacing suitable for Indicated Mineral Resources. Indicated spacing was defined to be 24 to 32 metres (“m”) to be within 15% of predicted for a nominal quarterly production volume with a probabilistic tolerance between 75 and 90%. The study not only defined the Indicated Mineral Resource resultant from the 2016 drill program, but also provided drill hole targeting criteria for subsequent drill programs aiming to convert Inferred to Indicated Mineral Resources. A subsequent geostatistical drill hole spacing study on the Arrow Deposit was completed by Clayton V. Deutsch with Resource Modeling Solutions in December 2018 to define Measured Mineral Resource spacing in support of the 2019 drill campaign. The study resulted in a drill hole spacing of 9 to 17 m to be within 15% of predicted for monthly and quarterly production volumes using an accepted industry probabilistic tolerance of 90%.

Jan 1, 2020

By Gordon W. Parsons, Ross E. Sampson

"THIS PAPER will trace the work done in bringing the Munro underground ""A"" •Orebody into production to replace the open pit, which was scheduled to be completed early in 1959. Included will be an outline of the exploration work and early planning, and of the final decisions on mining methods. Some of the more detailed work will be described and reasons will be given for the decisions made regarding development work, mine ventilation, ground support, and equipment. Brief mention will be made of open pit operations, as these have had some influence on underground development. Also, some of the main geological features of the ore occurrence will be de-scri0bed, as these had to be taken into consideration when making decisions on ore development and mining methods.LOCATION AND HISTORYhe Munro mine of Canadian Johns-Manville is in Ontario, approximately 50 miles east of Timmins and 40 miles west of the Que-bec-Ontari-0 boundary. The producing orebody is in the southwestern part of Munro township. Property controlled by the Company extends nortl1westerly about 2¥2 miles into Beatty township, on which two other interesting asbestos-bearing zones have been partially expl-0red. Active exploration work on the property was started in March, 194.9, and continued until the summer of 1950."

Jan 1, 1960

By G. Merle, David L. McKay, Elmar Randveer

"THE ENGINEERING AND TECHNICAL SERVICES department is responsible for supplying the following services:1. Administration and co-ordination of the work required for capital projects.2. Engineering, design and drafting services for inplant changes or improvements as requested by the operating• and maintenance departments.3. Rock mechanics.4. Preparation of plans and layouts required for efficient extraction of the ore as mutually agreed with the mine operating departments.5. Mine planning and long-term schedules in co-operation with the mine operating departments.6. Grade control (long term and short term) and the preparation of ore and waste removal schedules to maintain a uniform grade of mill feed. This also includes the calculation of metal reserves and metal production forecasts.7. Surveying, underground and surface.8. Operations research at the mine site.9. Industrial engineering.10. Chemical analyses and assays.11. Instrumentation.12. Environmental control.A staff of approximately 35 supervisors, engineers and scientists, and 80 technicians, supply the foregoing services. Consulting engineering and drafting firms are used to supply specialized services and technical personnel in-house at Timmins to handle overloads on capital projects under the direction of Ecstall engineers.The operating and maintenance departments depend on the engineering department to supply engineering, design and drafting services for any new facilities or for any planned alteration to existing facilities. To do this efficiently requires a high level of communication and co-operation with these departments. This has been a major factor in developing the present organization of the department shown in Figure 63.The organization is predicated on a strong central technical and engineering resource from which personnel can be assigned responsibilities for different projects, and in different areas, as the work load demands. Job satisfaction is very high because of the variety and challenge in the tasks. Additionally, participation in projects with production and maintenance personnel broadens each technical employee's knowledge of operating and maintenance problems."

Jan 1, 1974

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

By N. Hosking, M. Nichols

Aluminum alloys are increasingly used for automotive body construction but are susceptible to filiform corrosion or paint blistering in service. Filiform corrosion resistance of two 6000-series aluminum alloys was investigated in this work. Test panels were produced with full automotive coating layers and scribed parallel and perpendicular to the rolling direction. The corrosion exposure comprised an inoculation step with acidified salt solution followed by a 6-week exposure period at 95% relative humidity and either 25°C or 70°C. Greatest corrosion activity was measured on the alloy with higher copper content, AA6111. Higher temperature exposure led to greatly enhanced corrosion activity for AA6111 compared to the lower temperature exposure. The 70°C exposure also led to greater mean corrosion-affected area measurements for the low copper aluminum alloy, AA6022, but the effect was not as stark as that observed for AA6111. Rolling direction affected the propagation direction, and possibly mechanism, of the corrosion effects. Cross-sectional analysis revealed dense corrosion products within the filament, comprising mostly aluminum and oxygen but with traces of chloride and sulphate. Development of varying filament and blister types on a single test panel and the progression of corrosion underneath a filament into the substrate indicate that several corrosion mechanisms can develop on the test panel, testament to the complexity of the corroding surface developed on an aluminum automotive body panel.

Jan 1, 2015

By Fathi Habashi

New technology first introduced by Nippon Steel Corporation at Kitakyushu in Japan in 1976 now used at a number of plants in other countries, known as dry quenching of coke, uses nitrogen in a closed circuit to avoid environmental emissions. In addition, heat is recovered in the form of steam, from the red-hot coke. In steel plants oxygen is used extensively and therefore by-product nitrogen from air liquefaction can be effectively utilized in this way.

Jan 1, 2014