Strategy for Reducing Ammonium Nitrate Loss to Mine Discharge Water

Mines in Canada and the United States are subject to regulations limiting ammonia, nitrate and nitrite levels in mine effluents released into the environment. The primary source of these nitrogen compounds is typically explosive used in blasting operations, as ammonium nitrate (AN) remains a significant component of most explosives used in the mining industry. The amount of AN entering a local water drainage system is related to site conditions, explosives used, explosive handling and blast efficiency. Mining operators acknowledge AN loss to mine water from blasting operations. However, the mechanisms by which ammonia, nitrite and nitrate are entering the water drainage system, or the relative contribution of specific mechanisms, may not necessarily be assessed or monitored adequately. Characterization of these mechanisms, through systematic investigations, allows a mining operation to focus its efforts on reducing AN loss. This paper outlines a strategy for investigating the mechanisms through which AN enters the mine water drainage system and methods to mitigate this loss. This strategy includes collection and analysis of data to identify and quantify the AN loss mechanisms, design and implementation of tests to mitigate this loss, and assessment of the results. Such investigations are not intended to be a separate one-time project, but part of a long-term process of continual feedback and optimization that is related to the collection and reporting of AN levels for regulatory purposes. The implementation of the strategy must be tailored to each mine?s requirements and existing conditions.