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By J Demchak, L M. McDonald

The duration of acid mine drainage flowing out of underground mines is important in the design of watershed restoration and abandoned mine land reclamation projects. People conducting land reclamation projects usually employ remediation strategies once (reshaping land, revegetating soils, and installing water treatment) with the hope that these methods will adequately improve water quality for a long time, with little planning for future changes. An understanding of changing acid water conditions from underground mines over time will help in designing efficient and cost-effective treatment methods. Past studies have reported that acid water flows from underground mines for hundreds of years with little change, while others state that poor drainage quality may last only 20 to 40 years. Several factors are important in making a prediction of drainage quality over time, such as inundation or flooding history, coal seam characteristics (primarily sulfur content), residence time of water in the mine, time since mine closure, mining method and amount of coal remaining, collapse of roof and other disturbances within the mine, and subsequent nearby surface mining. More than 150 above-drainage (those not flooded after abandonment) underground mine discharges were located and sampled during 1968 in northern West Virginia, and we revisited 44 of those sites in 2000 and measured water flow, pH, acidity, alkalinity, Fe, Al, and sulfate. All 44 discharges were from mines in the Pittsburgh and Upper Freeport coal seams, and both seams have been extensively mined in this area during the past 70 years. We sampled during the same months (June to October) as were sampled in 1968, and we found no significant difference in flows between 1968 and 2000. Therefore, we felt that the water quality data could be compared and that the data represented real changes in pollutant concentrations. There were significant water quality differences between year and coal seam, but no differences between disturbed and undisturbed mines. Average acidity declined 79 per cent between 1968 and 2000 in Pittsburgh mines (from 3342 to 702 mg/L), and 56 per cent in Upper Freeport mines (from 1189 to 519 mg/L). Iron decreased an average of about 80 per cent across all sites (from an average of 345 to 69 mg/L), while sulfate decreased between 50 to 75 per cent. Pittsburgh seam discharge water was much worse in 1968 than Upper Freeport seam water. Twenty of our 44 sites had water quality information during 1980, which served as a midpoint to assess the slope of the decline in acidity and metal concentrations. Almost all parameters showed an exponential rate of decline in acidity, iron, and sulfate.

Jan 1, 2003

For effective backfilling, a system with the 13 features covered under the section: effective backfill systems, is required. Effective backfilling cannot be done with systems that are badly designed, outdated or overextended. But in cases where the requirements for effective backfilling are overlooked, the shortcomings of such systems may wrongly come to be regarded as limitations to the capabilities of backfilling per se. Mining is currently done to depths of 3500 m, and is to go deeper since the gold-bearing reef extends down to 4000 m and 5000 m below surface. Effective backfilling systems will be required at such depths, and with suitable design this can be achieved. Mining the narrow tabular orebody of a typical South African gold mine is described at the start of this paper, then cycloned backfilling is discussed in general, and its effectiveness (most of the fill placed in South Africa is cycloned backfill or ædeslimed tailingsÆ).

Jan 1, 1998

By M Zengerer

The Basil Cu/Co deposit comprises a 26.5 Mt Inferred Resource of copper and cobalt, grading 0.57?per cent Cu and 0.05 per cent Co. It lies in the Harts Range, Central Australia, within the Riddock Amphibolite of the Irindina Province. Analysis of drilling within the mineralised zone of the deposit determined a spatial association between pyrrhotite with high magnetic susceptibility and chalcopyrite, following a strong magnetic trend as determined from airborne geophysics. A study was commissioned to examine if geophysical inversion could predict the distribution of sulfide mineralisation based on pyrrhotite from drill hole intersections, as well as predicting further mineralisation at depth or in the vicinity of the deposit. Petrophysical and geostatistical analysis of drilling susceptibility and mineralisation provided a basis of property distribution inside the model. This was followed by 3D geological modelling of mineralisation based on domain kriging of drill hole susceptibility sensitivity testing of signal to source depth, and distribution was performed using 3D forward modelling. Stochastic inversion generated alternative 3D geological models, which were tested for behaviour and adherence to observed drilling data and geostatistical limitations using GeoModeller software. Predicted mineralisation distribution was compared with conventional geostatistical modelling and found to be in agreement in planar behaviour but exhibiting possibly isoclinally folded trends, with reliability increasing closer to the surface. Predictions of mineralisation at greater depth and beneath weaker anomalies were more diffuse due to small model cell size having limited influence on the signal at depth.The Blackbush uranium deposit comprises a 64.5 Mt Inferred Resource, grading 230 ppm U in the Pirie Basin south of Whyalla, South Australia. It directly overlies the radiogenic Samphire Granite and is considered a tertiary unconformity deposit. Sensitivity modelling was performed using high-resolution ground gravity to see if a deposit signature could be detected using gravity. This required 3D implicit modelling of the geology and mineralisation from drill hole data and characterisation of an associated physical property model using domain kriging in GeoModeller. Density models relied on exploiting an observed relationship between logged density and measured uranium oxide percentage. The residual gravity response of the background geology model identified the location of the uranium deposit. Stochastic inversion of the litho/property 3D model has refined the known distribution of uranium from drilling and provided structural insights into the deposit.These projects have become excellent case studies for exploiting the relationship between mineralisation and potential fields and for testing the applicability of using domain kriging of properties determined from drilling to build robust 3D geological models for stochastic geophysical inversion, leading to robust methods for exploration targeting and mineral deposit prediction.CITATION:Zengerer, M, 2014. Use of geostatistically-constrained potential field inversion and downhole drilling to predict distribution of sulfide and uranium mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By J T. Carswell, K Sutton

Quality control (QC) of reverse circulation drill sampling commonly involves regular duplicate subsampling to monitor the extent of imprecision or random error in the subsampling system. In gold mining in Australia, the subsampling tool is usually a cone splitter.Other sources of error, including delimitation error and bias (systematic error) in the subsampler are often assumed to be negligible or ignored for being too difficult to QC.This paper describes actual sampling errors and error mitigation based on quality assurance and quality control (QA/QC) of surface and underground reverse circulation drill sampling at a high-nugget gold mine at Sunrise Dam, Western Australia.CITATION:Carswell, J T and Sutton, K, 2014. Sources of sampling error and implications for quality assurance and quality control in surface and underground reverse circulation drilling, in Proceedings Sampling 2014 , pp 65–70 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Hannington MD

On the southern flank of Lihir Island, a group of three volcanic cones were discovered at water depths from 1000-1500 m. The volcanoes are located in a narrow zone of recent seismic activity and elevated heat flow (up to 100 mW/m2). The recovered rocks consist of fresh alkali-olivine basalts, clinopyroxene-rich basalts, and porphyritic phlogopite basalts. One of the volcanoes has a recently erupted ejecta blanket (recovery of warm ash!), containing a suite of abundant mafic to ultramafic xenoliths. These xenoliths appear to represent a unique cross-section of subduction- modified mantle material sampled by volatile-rich primary fore-arc magma during its ascent to the seafloor. The most spectacular finding was the discovery of an active hydrothermal system with associated vent fauna and mineralization at Edison Seamount, and the recovery of unusually gold-rich (up to 43 ppm Au) hydrothermal precipitates in 1050 m water depth at the top of Conical Seamount, only 25 km south of the world-class epithermal Ladolam gold deposit on Lihir. The discovery of submarine hydrothermal vents associated with highly alkaline, quartz-undersaturated fore-arc volcanics represents a significant departure from similar hydrothermal systems on the mid-ocean ridges and in back-arc basins. The high gold grades in hydrothermal precipitates at Conical Seamount may indicate the first documented example of a shallow-marine epithermal system analogous to those known on land, and has important implications for the gold potential of submarine arc environments.

Jan 1, 1995

By Dean J. A, Taube A, White A. H, Messenger P. R, Jones I. W O, Huston D. L

The 50 million tonne Mount Morgan gold-copper deposit (4.99 g/t Au, 0.72 per cent Cu) was an irregular pipe-like body of quartz and pyrite, with subordinate chalcopyrite, magnetite and gold. Mineralisation was hosted by the Middle Devonian Mine Corridor Volcanics which occur as a roof pendant within the Late Devonian Mount Morgan Tonalite. On three sides, the deposit was enclosed by a series of normal, concave, listric faults and surrounded by outward-dipping Mine Corridor Volcanics. The tonalite which bounded the western side of the deposit transgresses the domal structure with no apparent interference. A pipe of intense, texturally-destructive, quartz-sericite-chlorite ¦ pyrite underlay and partly surrounded the deposit.The volcanic setting of the deposit, its shape, metal content and associated footwall alteration are consistent with a subsea-floor replacement origin for the gold-copper mineralisation. Mineralogical studies have confirmed the deposit has been recrystallised and annealed by a thermal metamorphic event, most likely the intrusion of the Mount Morgan Tonalite. Pyrrhotite Pipe mineralisation replaces annealed massive pyrite, suggesting that it formed during retrogressive metasomatism associated with tonalite emplacement. Telluride minerals have a close association with chalcopyrite, and no evidence for a late telluride paragenetic stage was observed. Telluride mineralisation is inferred to be genetically related to the massive sulphide mineralisation, and a separate magmatogenic origin for this mineralisation is discounted.

Jan 1, 1993

By R C. Morris

Secondary microplaty haematite in its variety of styles and generations is the defining component of the high-grade banded iron-formation (BIF)-hosted iron ores of the world that are dominated by martite (M; - haematite pseudomorphs after magnetite). The term microplaty haematite (mplH) was introduced during the CSIRO-AMIRA 1976-1994 iron ore program, and was used to differentiate the then main export martite-microplaty haematite (M-mpl H) ore types of Tom Price-Whaleback and Paraburdoo (Paleoproterozoic), from the newly exploited, more prolific supergene martite-goethite (M-G) ores (Mesozoic-Paleocene) of the Hamersley Province that are now the major Hamersley iron ore exports.Morris (1980, 1985) suggested that the most important genetic factor that distinguishes the two main ore types was regional metamorphism of Paleoproterozoic M-G ores at temperatures normally related to diagenesis (ca 80 - 100°C). As temperatures increased, mplH grew in goethite both spontaneously as well as by nucleating on martite and other pre-existing haematite. Because the conversion of goethite to haematite involves a ~27 per cent reduction in volume, the crystals probably grew within microvoids of their own creation, with iron transfer through water resulting from the process itself, a local hydrothermal process requiring no introduced hypogene fluids.Barley et al (1999) and Taylor et al (2001) concluded instead that oxidation of introduced siderite in hydrothermally metasomatised BIF ‘protore’ resulted in mplH + ankerite by reaction with heated meteoric fl uids. This postulated ‘protore’, still preserved locally at Mt Tom Price, was described during the CSIRO-AMIRA program as local post-ore BIF metasomatic residuals. These new hypogene-meteoric concepts for M-mpl H genesis have formed the basis for a range of varying local and international models that currently dominate the literature of iron ore.No valid petrographic data supporting the hypogene-supergene modelling was found but petrographic images of goethite-related mplH growth in a range of different environments are shown.

Jul 11, 2011

By Heath E, van Calsteren P, Turner S, McDermott F

U-Th isotope studies of recent volcanic rocks may be used to evaluate the depths and rates of melt generation beneath mid- ocean ridges and ocean islands. Island arc rocks exhibit a similar range in Th isotopes to that seen in both MORB and OIB, but while those with high (230Th/232Th) tend to have excess 238U, many of those with low (230Th/232Th) are in isotope equilibrium. The excess 238U is attributed to the preferential mobilisation of U in hydrous fluids from the subducted slab within the last 100,000 years, whereas the low Th isotope ratios in the higher-K arcs are primarily due to the introduction of subducted sediment. Preliminary results from mineral separates from lavas on Soufriere on the island of St. Vincent indicate that some of the minerals crystallised up to 50,000 years prior to eruption.

Jan 1, 1995

By D Hunter, N Cusworth, J Miller

"Recent project failures have called into question the use and relevance of benchmarking and independent reviews, forcing a rethink of traditional processes and procedures.With cost estimates and schedules dramatically varying from lows seen around the global financial crisis to peaks experienced in the recent mining boom, benchmarking has ranged between essential and misleading.Profound shifts are now underway in future project delivery strategies as the market moves away from cost-plus engineering, procurement and construction management. The current trends in project implementation are to utilise more lump-sum design and construct or fixed-price supply and construct contracts. This trend will remove transparency in detailed cost information by reducing the sources and clarity of cost data.Independent peer reviews (IPRs) of studies and investment recommendations performed over the last decade have both failed to prevent flawed or deficient projects from proceeding to approval and funding, and been successful in ensuring that owners did not proceed with doomed investments.In recent times, it has been recognised by some owners, contractors and engineers that traditional benchmarking checks or IPRs, or a combination of both, will not necessarily produce reliable assessments of study conclusions and of the forecasts of project outcomes. To be of value, the benchmarking process now also needs to recognise the highly volatile responses from the engineering and construction industry to the current and future markets for their services.Similarly, reviewers who draw upon benchmarks of past project experiences on an understanding of the things that shaped and influenced their outcomes need to be more aware of how a future dynamic market may impact the outcome of the projects and raise warning flags accordingly.With the commodity cycle currently approaching what is hoped is its bottom, ensuring that benchmarking and independent reviews evolve into reliable, transparent and worthwhile processes becomes even more important. This can only be achieved with more transparent and analytical benchmarking and business-orientated reviews that both recognise and calculate the impacts of dynamic markets on project implementation.CITATION:Cusworth, N, Hunter, D and Miller, J, 2016. The role of benchmarking and independent reviews, in Proceedings Project Evaluation 2016, pp 249–259 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By Smith G. A

The scope and complexity of the Melbourne Underground Rail Loop Project and the budget restraints on the planning, design and construction of the works necessitated sound manage- ment procedures for control and co-ordination. Project Management Procedures formulated by the Principal Consultant to the Authority, John Connell - Mott, Hay 9 Anderson, Hatch, Jacobs, ensured that the Authority retained overall control of the project at all times.

Jan 1, 1981

Sublevel open stoping (S.L.O.S.) was introduced at Rosebery in 1972 in the wider ore blocks below 14 level, largely replacing cut and fill methods which had been in use up till that time. During 1973/74 the method produced 10% of primary stoping tonnes, and by 1981/82 it increased to 65%. Because of the increasing reliance placed on sublevel open stoping for primary stoping production, every effort was made in both planning and operating to: - maximise ore recovery and reduce dilution - increase productivity - reduce costs.

Jan 1, 1982

This paper will review some of the work conducted in the past at the Dynamic Effects Laboratory to examine the use of stress waves and fracture mechanics in understanding dynamic fracture and fragmentation in blasting applications. Along the way, we will use photoelasticity and high-speed photography to better understand the mechanisms of fracture and fragmentation.CITATION:Fourney, W L, 2015. The role of stress waves and fracture mechanics in fragmentation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 27–40 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A Turner, P Hills, D Johnson

Underground mining for gold began in Beaconsfield in 1877 and development of the Tasmania Mine saw the sinking of multiple shafts, including the Hart Shaft over the ensuing 35 years. The mine closed in 1914 at a depth of 455 m due to prevailing economics, eventually reopening in 1999. The modern mine closed in 2012 after extending the mine from a historical depth of 455 m to the exhaustion of the modern Ore Reserve at a depth of 1210 m. West Tamar Council took over the lease for the immediate area around the Hart Shaft as an extension of the adjacent museum. The Hart Shaft and above ground structures became a significant drawcard for visitors. Tasmania was affected by sustained wet weather during May, June and July of 2016 which caused severe flooding and significant Statewide damage. This uncharacteristically intense wet weather caused saturation of the ground surrounding the Hart Shaft. Eventual shaft failure was first identified in August 2016. The failure of the shaft occurred at approximately 50 m below surface and resulted in a plug of material completely blocking the shaft. Significant surface subsidence affecting the surface infrastructure ensued. Due to the unstable nature of the surrounding material, it was determined that addressing the failure above the blockage would not provide a permanent solution to prevent the continued flow of material into the shaft. Many options to stabilise the shaft were considered, however it was assessed that a concrete plug in the shaft in competent ground at a depth of 100 m below surface and well below the blockage, would provide the only long-term solution. Man-entry was considered unsafe. The solution to access ultimately entailed filling the entire shaft with granular fill up to 100 m depth to act as formwork for a concrete plug. The rising mains at 400 mm and 250 mm diameter, which remained in place in the shaft, provided the avenue for placing the fill and ultimately, the concrete plug. Once the plug was in place the remainder of the shaft up to the underside of the blockage and over the top of the blockage to the surface was successfully filled with a combination of more granular fill and flowable cement stabilised sand. The Hart Shaft and surrounding above ground infrastructure was successfully stabilised and re-opened to tourist access. CITATION:Johnson, D, Turner, A and Hills, P, 2018. Stabilising and filling the Beaconsfield Hart Shaft, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 42–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

We outline a first version of an ambitious goal: The world's first horizontal (matrix-independent) generic sampling standard. The specific needs and requirements are overwhelming, as all the world's analytical standards follow strict matrix or material type classification pigeonholes, leading to a plethora of analytical standards. One could rightly expect a similar multiplication regarding sampling standards, yet the singular HORIZONTAL is aimed at being truly generic. Also the existing style of standards writing is cumbersome and partly contradictory. The current work is presently being pursued in CEN and European Union standardisation regimens, for which reason full disclosure and publication is not allowed. Respecting this constraint, we unofficially present selected key issues involved in developing HORIZONTAL: The objective and scope of a horizontal sampling standard is to delineate the minimum set of principles and procedures needed to guarantee documented representative sampling for all types of materials. The horizontal standard is designed for two types of use: 1. auditing/assessing/ improving the reliability of an existing sampling procedure, and 2. design and implementation of a new sampling procedure (new lot type). The principles in this standard are all derived from the Theory of Sampling (TOS), but the standard is far from a mere collection of TOS principles. Representativeness is a characteristic of the sampling process, not of samples themselves. For practical purposes, the horizontal standard follows the fundamental distinction between 'stationary lots' (0-D, 2-D, 3-D lots) and 'dynamic lots' (within TOS aka process sampling - including extended, non-moving 1-D lots). TOS' principles of 'correctness' must never be broken at any stage, lest representativeness is irretrievably lost. The horizontal standard is not written in the mandatory fashion for legally binding matrix-specific standards, eg ISO - for the present overarching purpose a different style had to be developed. The standard must be immediately understandable in full, which merits special demands, eg extensive use of didactic illustrations. HORIZONTAL introduces an all-inclusive sampling variability measure, Relative Sampling Variance (RSV) which is for sampling of stationary lots as variographics is for process sampling - RSV is to be used as a quality criterion for any stationary sampling procedure as applied to a specific heterogeneity (lot/material). The target for this standard is all individuals, companies, organisations and regulatory bodies who are responsible for sampling: technicians, process engineers, laboratory personal, academic and industrial scientists as well as project leaders, technical managers/directors and top managers. Based on current R&D we illustrate the principles promulgated by HORIZONTAL with cases from exploration and mining of minerals commodities, a Finnsh 'Autosampler' at work in the mining context (RSV) as well as sampling equipment for use in the cement and mineral commodities industries. This is an ABSTRACT ONLY. No paper was prepared for this presentation.

Mar 1, 2010

By Y-B Kang, W-Y Cha, Y-M Cho

Molten slag used in the secondary refining process (RH process) for the production of Ultra-Low C (ULC) steel is typically composed of CaO-Al2O3-MgOsat.-FetO with minor constituents. FetO in the RH slag is the main source of reoxidation of the molten ULC steel in the ladle by 2Al + 3(FetO) = (Al2O3) + 3Fe, thereby serving as the source of the alumina inclusions. On the other hand, FetO also enhances the fluidity of the slag, thereby increasing inclusion absorption capacity. Optimum slag chemistry design is therefore required to produce clear ULC steel. The reoxidation kinetics was investigated in the present study by employing high-temperature experiments and developing the reaction rate model. Initial compositions of slag ((% CaO)0/(% Al2O3)0 and (% FetO)0)) and reaction temperature were varied and change of [% Al] in the molten steel was measured. The rate-controlling step was analysed. It was found that the rate-controlling step in some cases changed during the reoxidation: from a mass transport of Al in the molten steel to a mixed transport including Al2O3 in the molten slag. The experimental data validated the reaction rate model based on the elucidated reaction mechanism and FactSage thermodynamic database. The model suggested that high (% CaO)0/(% Al2O3)0 suppresses the reoxidation only when (% FetO)0 is low (5 or lower in the present study).

Jun 19, 2024

By S P, F Villanueva, R Palomo, D Meadows

During 2002, design and development of the worldÆs largest flotation cell was completed. The cell is the mineral industryÆs first 257 m3 flotation cell, and represents a major development in the design of larger flotation cells, with a 50 per cent increase in cell volume over the widely installed 160 m3 WEMCO« SmartCellTM flotation machine. It is anticipated, in the next few years, world-class copper sulfide concentrators will incorporate 257 m3 flotation cells in their rougher-scavenger flotation circuits. The prototype 257 m3 cell, No 250 SmartCellTM flotation machine is installed in Minera Los PelambresÆ existing rougher flotation circuit. The machine is located in front of the first cell in Row 1 and is followed by nine No 130 SmartCellTM flotation cells. The unit has been in operation since April 2004, and has proven itself in this duty. A key to the successful development of the equipment has been the emphasis placed on fundamental hydrodynamic scale-up criteria. Hydrodynamic factors include superficial gas velocity, water (pulp) circulation through the draft tube, and pulp mixing (distribution) characteristics. This paper will review the scale-up criteria of the No 250 flotation cell, and a case study will be presented on the in-plant testing of the equipment. The case study will document the metallurgical and hydrodynamic performance of the machine. It will also illustrate the economic benefits derived by incorporating larger flotation cells in a modern copper sulfide concentrator.

Jan 1, 2005

By H Indirawati, R Ayres, A Nur Kasnanto, S Konopa

As a project moves through the mine life cycle, the quantity of data available increases and the understanding of the orebody matures. Incorporating new information quickly and efficiently in current 3D models, is essential for adding value across the life-of-mine value chain. At the Martabe Gold Mine, the resource development group manages 14 drill rigs on six resource projects, including three operating mines. The Martabe deposits are geologically complex and the volume of new information that becomes available each day is substantial. It is imperative that new geological and assay information is integrated into the 3D models as soon as possible, so that drill planning and targeting can be modified accordingly. Martabe uses Leapfrog<sup>®</sup> 3D software to update and interrogate the 3D models on a dynamic basis as data becomes available. This results in faster and more effective changes to drill planning and schedules. The impact of this is better drill productivity and cost savings due to optimal drill targeting, and availability of up-to-date models incorporating the most current data. CITATION: Konopa, S, Ayres, R, Nur Kasnanto, A and Indirawati, H, 2018. Optimised drill targeting using dynamic 3D modelling, Martabe Gold Mine, Indonesia, in Proceedings Complex Orebodies Conference 2018, pp 99–101 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

Australia is presently the world's principal producer of rutile and zircon, and also provides a major share of the world's ilmenite. Since 1980, Australia's share of the world's output of these minerals has fallen. Exhaustion of known resources, together with the changing composition of new deposits, is expected to result in Australia's share of the rutile and zircon output continuing to decline. Its role as a major supplier of upgraded ilmenite, that is synthetic rutile, is expected to increase. In 1994, the Bureau of Resource Sciences assessed Australia's demonstrated resources of mineral sands as follows: rutile 14.4 Mt, ilmenite 132.5 Mt, and zircon 21.0 Mt. These resources are located along the coast of Queensland and New South Wales, in the Murray Basin of New South Wales and Victoria, in the southwest corner of Western Australia, and in the Eneabba region, north of Perth. However, some 45 per cent of rutile and zircon resources along the coast of Queensland and New South Wales are not available for mining because of environmental concerns. World demonstrated resources are estimated at 40 Mt (contained TiO2) for rutile, 50 Mt for zircon and approximately 312 Mt (contained T1O2) for ilmenite. Outside of Australia, the most important resources of rutile, ilmenite and zircon are in South Africa (rutile, zircon , and ilmenite in the form of titania slag), Sierra Leone (rutile), India (ilmenite, zircon and rutile), and Canada (hard rock ilmenite). Significant resources of ilmenite occur in Madagascar and Mozambique.

Jan 1, 1996

By J Thoma, W Skinner, W Stewart, R Smart

The acid neutralisation capacity (ANC) of rock sample containing significant iron carbonates and/or reactive framboidal pyrite can be a difficult parameter to determine. Results indicated that negative ANC results can occur if reactive sulfide minerals are present; and an over-estimation of ANC will result if significant Fe rich carbonate minerals are present during industry standard ANC tests. In this paper we investigate these problems. Results showed that a significant lag period may be needed (up to 432 hours) after standard Sobek ANC type tests of siderite for the complete hydrolysis of iron released from this mineral. This even occurred with standard industry modifications that included the addition of two drops of hydrogen peroxide. In this work we use a modified Sobek test that included filtering, and thence continued hydrogen peroxide addition until there was no subsequent pH drop, followed by back titration to pH 7.0. Results indicated that the ANC for the siderite (after zero hours) was immediately comparable to the ANC determined after 432 hours lag by standard Sobek type tests; and a calculated theoretical carbonate ANC. Investigations of coal waste samples containing significant framboidal pyrite indicated that standard Sobek ANC type tests can result in negative ANC values due to the oxidation of this reactive pyrite. Because sulfide acidity is already addressed by the MPA calculation, the inclusion of sulfide acidity as part of the ANC determination is effectively biased towards acid generation and thus positive NAPP values. Negative ANC values cannot be ignored or assumed to be zero as this masks any actual ANC available within the sample, which may possibly affect AMD categorisation. This sulfide acidity can be factored out using the quantity of S in the ANC digestion liquor and knowing the non-acid generating sulfate content of the sample prior to ANC testing. Results indicated that incomplete iron hydrolysis at the completion of the Modified Sobek ANC test is not only a function of iron carbonate dissolution, but is also related to the dissolution of Fe-sulfate salts, and the oxidation of reactive sulfides such as framboidal pyrite.

Jan 1, 2003

By Blaskett K. S

The physical properties of monazite and the minerals with which it is associated in east coast beach sands are studied and discussed. Possible means for improving recovery are examined. In particular, it is suggested that the practice of splitting the heavy mineral concentrate into two parts as a preliminary to treatment in separate "rutile" and "zircon" mills can be modified in a simple fashion by the addition of an extra magnetic separation stage so as to aid monazite recovery.INTRODUCTIONBeach sand deposits on the east coast of Australia are a major source of rutile and zircon, and supply 80 per cent or more of world requirements. The deposits also contain a small amount of monazite, averaging about 0.5 per cent of the total heavy minerals. Yet despite a steady price in recent years of £150-160 per ton, monazite production has remained relatively small.On the basis of rutiIe production, potential monazite production on the east coast was about 1,500 tons in 1956, but only 102 tons of high-grade concentrate was produced. The main deterrent to increased production has probably been the capital cost of the necessary equipment. Separate electrostatic and magnetic equipment and separate table concentration and drying constitute a considerable outlay for a by-product contributing 4 to 5 per cent of the revenue from rutiIe.It is the purpose of this paper to discuss monazite concentration generally and to suggest modifications to flowsheets, which may facilitate monazite production while maintaining the main objective, simple and cheap means for maximum rutile production.

Jan 1, 1958