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By A. Russell, M. N. Hughes, Jack Barrett

The bacterial oxidation of arsenopyrite has been shown to be an efficient, economic and environmentally acceptable method for the liberation of any gold content . The mechanism of the process is not certain but is usually considered to involve direct and indirect reactions with respect to bacterial involvement. The direct reactions are those in which the bacteria attached to the mineral surface cause its dissolution, with dioxygen being the oxidant. The iron(III) produced in solution is the chemical oxidant in the so-called indirect reactions. Barrett et al 2 showed that a synthetic bio-oxidation solution (with no cells present) could dissolve up to 15% of an arsenopyrite sample, the products of the chemical oxidation being iron(II) and arsenic(III). This paper describes an extension of the investigation of the chemical process and its imp! ication for the mechanism of the bio-oxidation of arsenopyrite.

Jan 1, 1990

By Gary Beerkircher

WaterFlush Technology and WaterFlush crushing offers significant operational ben­efits in gold milling operations. WaterFlush crushing is the technology that Nordberg Inc. has developed, tested and proven in an actual operation during the 1980's. Patents have been obtained for both the process and the apparatus of implementa­tion. WaterFlush involves volumetric process controlled water flow into the ore feed cav­ity of a WF cone crusher. While the addition of water in itself is not new, the con­trolled amount of water coupled with the WF crusher operating parameters are revolution­ary. The WF crusher is a specially designed version of Nordberg's Omnicone crusher oper­ating at higher speeds, with a reduced ec­centric throw and higher horsepower capabil­ity. The results are increased capacity, higher crushing energy input and a finer crusher product. The WF crusher product is a slurry containing 40-60% solids by weight.

Jan 1, 1990

By Paul F. Ziemkiewicz, John J. Renton, Thomas Rymer

Any viable model or deterministic formula used to make predictions must follow certain criteria. The standard models and procedures used to project acid load from mining activities operate from a number of assumptions, some of which, although logical, are scientifically oversimplified and, hence, invalid. Highly variable field parameters have lead to highly variable acid projections. Kinetic tests are in themselves misnomers in that no parameters associated with chemical reaction kinetics are ever determined. Sampling error coupled with assumptions made as to the distribution mode of pyritic materials in rock units can lead to highly inaccurate conclusions explaining why acid generation often occurs where none is predicted. The fact that probability theory and paradigms governing luck and chance have not been incorporated into the science of acid prediction undermines any credence placed on such projections. To date, with few exceptions, the acid prediction is logically closer to a game of chance than practical science.

Jan 1, 1991

By M. Misra, J. Nanor

The removal and stability of arsenic over a wide pH range (3.0-10.0) from synthetic solutions and industrial waste effluents (including mining waste tailing slurry) can be accomplished with addition of impure lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these correspond­ing precipitated compounds is critical from the disposal stand­point. In this paper test results of this new process for arsenic removal and stabilization from the above mentioned systems are presented. Also, precipitated arsenic compounds (lanthanum arsenate, lanthanum-ferric arsenate, ferric-lanthanum arsenate and ferric arsenate) from synthetic solutions have been charac­terized. The characterization technique used was XRD. XRD patterns which shows that the lanthanum arsenate and lan­thanum-ferric arsenate formed in acidic and alkaline pH at room temperature are crystalline. On the contrary, ferric arsenate and ferric-lanthanum arsenate compounds formed under the same conditions as lanthanum arsenate were amorphous.

Jan 1, 1998

By F. W. DeVries, J. Brent Hiskey

The search for noncyanide lixiviants for treating gold and silver ores and concentrates is not a new endeavor. However, in recent years, the overall activity to seek a less environmentally controversial reagent than cyanide has occasioned considerable developmental work. While the elegant economy and simplicity of cyanide, because of its selectivity and the ease of recovering gold and silver from the cyanide complexes, is well recognized, two failings have justified the search for alternates: increasing concerns and costs to assure avoidance of environmental damage from cyaniferous liquids and solids, and the need to simplify recovery of gold and silver from refractory ores. Generally, process development work to date on the alternate reagents has lacl<::ed environmental focus ( Hiskey and Devries, 1992). This paper covers briefly the chemistry of various alternates to cyanide and reviews their environmental implications. In each case, environmental overtones are reviewed following the chemistry. For ease of follow-up, the authors have listed sources of information in detail. Alternates examined include:

Jan 1, 1992

By J. A. Meech, C. A. Harris

Expert Systems are being used in the Mineral Industry with ever­increasing frequency. A major advantage of these systems over conventional computer programs is that the knowledge and intelligence of human experts can be captured directly onto a computer for transfer to novices or other lesser experts. These programs allow rapid construction of process models that are not well-understood in fundamental terms, but for which good operational reasoning exists. In addition, user-friendly access to "high-tech" knowledge can be provided to unsophisticated personnel who otherwise might be turned off by unintelligible jargon. As such, these systems can be important training tools for new operators. This paper describes the features of Expert Systems that relate to gold processing plants. Applications include grinding circuit control, supervisory control of reagent addition and pulp density, monitoring and control of CIP/CIL carbon inventories and the operation of carbon stripping and regeneration facilities. A consultative Expert System is described that provides advice on laboratory cyanidation testwork

Jan 1, 1992

By S. Vukcevic, R. Winby, P. C. Miller

There is considerable interest in the bioleaching of chalcopyrite concentrate for the production of copper. The residue of bioleached chalcopyrite often contains gold that needs to be recovered. Despite the high efficiency of copper bioleaching, the residue may contain appreciable quantities of copper, and the difficulties of cyanidation of gold from copper bearing materials are well recognised. This paper reports the results of using different methods to recover the gold values from bioleached chalcopyrite concentrate. In particular, the behaviour of cyanide and cyanide in the presence of ammonium ions as gold lixiviants were studied. The ammonia was employed to reduce the impact of the copper on cyanide consumption. Thiosulphate as a gold lixiviant was also employed with the aim of achieveing rapid leaching rates and to reduce the impact of residual sulphur species on lixiviant consumption. Bromine solution was used to research acidic gold leaching. The paper describes the advantages and disadvantages of using different reagents with respect to reagent consumption, selectivity and kinetic efficiency.

Jan 1, 1997

By David Martin Menne, Chris Campbell-Hicks

Optimisation of many oxide gold processing facilities, in most cases, either does not really take place or if it does take place it happens too late or takes too long. This is unf01tunate as extra profits and early cash flows are lost, in new projects, and/or may not be realised at all in others. The situation is easily avoid­ed by ensuring that the plant optimisation happens immediately following commissioning or for an established operation simply 'biting the bullet' and making it happen immediately as a 'better late than never' decision. This type of optimisation requires intense undiluted focus on each and every problem or restriction that contributes to reduced plant performance or bottlenecks, without letting go, until the predetermined outcome is produced. Thus a dedicated person with specific quantative goals is required for these tasks. Methodology and strategies for optimi­sation are discussed and numerous examples presented. The secret of successful heap leaching is discussed.

Jan 1, 1998

By M. J. Virnig, J. M. W. Mackenzie, M. W. Johns

The properties of Henkel's Aurix® resin which uses a guanidine functionality to recover gold by ion exchange have been described in publications of the International Mineral Processing Congress and Randol International (1)(2). The purpose of this paper is to provide an update on the results of further testwork using Aurix®. Specifically, this paper presents the first results of resin in pulp testing, all the results previously reported were for testwork carried out using synthetic gold leach solutions.

Jan 1, 1995

By L. B. Paterson

Mining Engineers throughout the world have an appreciation for the importance of the role of the Blasthole Drill in one of the primary elements of the mining process. This paper highlights areas that could influence the overall cost effectiveness of that process of breaking rock and how equipment is designed and configured to meet that challenge. Factors influencing drill productivity and overall cost effectiveness are addressed, both in the Mine Environment and on the Blasthole Drill.

Jan 1, 1999

By Ethan B. Eilertsen

Titanium solves corrosion, maintenance and environmental problems in many reactor and autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the autoclave to accommodate local environmental conditions. Resistance to general corrosion, crevice corrosion, abrasion, and ignition conditions can be accomplished selectively and economically. Explosion clad pressure vessel fabrication and performance have been proven through three decades of experience.

Jan 1, 1997

By Bruno Sceresini

Prospectors and small scale mmmg companies have long expressed the wish for a highly mobile mineral processing plant. This is especially so in the case of gold mining as relatively small deposits can be highly profitable due to the relative ease of producing a marketable product when compared with the refming and marketing costs incurred with base metals. This paper will concentrate on gold ore treatment in fitting with the theme of the 1996 Randol Gold Forum but the principles may also be applied to base metal ores. The development and application of the Atomaer Filblast Gas Shear Reactor as a cyanidation tool has removed the con­straints of plant size in pulp cyanidation applications. KC Dodd and Associates, Consulting Engineers and Australian Mining Advisers, Pty Ltd, have designed a 1,000,000 and a 250,000 tpa fully modularised ore treatment plant. Various module configu­rations can be arranged to treat a wide variety of ores ranging from simple gold ores to gold-copper and base metal ores. This paper will limit the discussion to comparing the capital and operating costs of a conventional and a modularised 1 million tpa gold treatment employing a number ofnovel concepts which complement the compact, high capacity Filblast Cyanidation Process and the AARL pump Cell Adsorbers. The design described in the paper not only reduces equip­ment sizes and allows for rapid deployment of a sizeable capac­ity plant but also offers significant capital and operating cost benefits.

Jan 1, 1996

By Stephen Hoffman

The Environmental Protection Agency (EPA) is investigating approaches to control non-coal mining wastes. In May 1988, the EPA&apos;s Office of Solid Waste (OSW) released a document that outlined an approach to manage non-coal mining wastes and materials. This document was called Strawman I. It was a staff-level approach designed to aid the continued participation of interested parties and to enhance EPA&apos;s understanding of mining waste issues. EPA has been working with states, public interest groups and the mining industry to gather information and to solicit input on waste management approaches. The involvement of the states in the Strawman process has been coordinated by the Mine Waste Task Force of the Western Governors&apos; Association and the Interstate Mining Compact Commission. Involvement of public interest groups has been coordinated through Colorado Trout Unlimited. And the participation of the mining industry has been managed principally by the American Mining Congress. In May 1990, EPA released Strawman II. It was based on comments submitted to the EPA on Strawman I and on information given to the EPA by interested parties since 1988. Strawman II is again a staff-level approach to protect human health and the environment from wastes and other materials associated with non-coal mining. In September 1990, meetings were held with public interest groups and the mining industry to discuss their comments on Strawman II. By early 1991, the EPA expects to make a decision on how to proceed with program development.

Jan 1, 1990

By Ken Deter

My recent experience has been with wet tropical environments, which address a different set of concerns than Nevada, for example. Spraying rather than drips are required in most cases just to assist the water balance requirement, and my comments address those situations. Most tropical operations are faced with both extremely wet and very dry seasons, with some having multiple cycles during the year. A heap leach operation must address the rate of solution building up within the ponds and how long the volume must last until the next rainy season. It may be easier to construct sufficient pond volume to permit yearlong operation than by discharging excess solution now, and searching for water later. Pond capacity requirements can help with the following: Consider using the solution that could be locked up in the pads during leaching to assist water balance problems. Spray excess solution continuously onto spent ore that would not be normally be sprayed again to "soak up" the excess solution, and stop spraying when the water balance is low, allowing the solution in the spent ore to return back into the system-with or without cyanide added. In a multiple lift system, if intermediate HDPE liners are planned for solution grade control, have drips placed before the HPDE liner is in place. The drips can distribute excess precipitation throughout the lower lifts to control the water balance, while the most current lifts are being leached and sent directly for the preg pond. With only 2 million tonnes (2.2 million tons) of spent ore involved, up to 200,000 cubic meters (53 million gallons) of solution could be moved into or out of the water balance system, if proper methods are designed and installed. That is equivalent to one meter (40 inches) precipitation falling on a 200,000 square meter (2.2 million square feet) pad area. You may even get a little bit more gold recovered as the solution drains from the earlier pads, as well.

Jan 1, 1999

By Nancy L. Jackson, Leslie C. Thompson

Acid rock drainage is one of the most complex issues facing regulators and mining companies for management and remediation of mining wastes. All mining waste units, including open pits, underground workings, tailings, waste rock and leached spent ore have the potential to generate acidic leachate based on the acid generation or neutralization potential of the material. This paper uses a case study of the Walker Mine in northern California to give an overview of the available control and mitigation methods. Wetland design is emphasized as a low-cost alternative treatment option for wastewater remediation. The Walker Mine is located on the eastern flank of the Sierra Nevada, 20 miles north of Portola in Plumas County, California. The Walker Mine was an active copper mine between 1915 and 1941. During active mining, tailings were discharged into an area 1 mile west of the site at the confluence of Dolly Creek and Grizzly Creek. In addition, there were two main sources of metal-rich, acid waters impacting Dolly Creek: discharge from the mine tunnel portal, and seepage and surface runoff from waters contacting mine waste downslope from the portal area. A mine portal seal was installed in 1987 which prevented the majority of mine water drainage from further contaminating the area. Minor drainage from the portal and seeps discharge into a holding pond which overflows into Dolly Creek when elevation exceeds 6,200 feet. A site characterization study was performed to evaluate the potential water quality threat to Dolly Creek from mine tunnel discharge and waste rock seeps. Based on the results of this study several remedial options were investigated, both on a design and cost basis, to determine which abatement alternatives could be realistically implemented. The remedial options considered include both in situ containment (landfill, waste pile) or removal (backfilling into underground workings and/or sinkholes) of solid wastes. Waste water remedial options include long-term, seasonal treatment of the portal mine water, or long-term, passive treatment of portal discharge and waste pile leachate.

Jan 1, 1993

By John G. Banker, Arthur L. Forrest

Titanium solves corrosion, maintenance and environmental problems in many reactor and autoclave applications. Titanium clad construction permits autoclave designers a great deal of flexibility combined with significant cost reduction. Titanium alloys can be selectively applied in specific regions of the auto­clave to accommodate local environmental conditions. Resistance to general corrosion, crevice corrosion, abrasion, and ignition conditions can be accomplished selectively and eco­nomically. Explosion clad pressure vessel fabrication and perfor­mance have been proven through three decades of experience.

Jan 1, 1996

By Kurt Bryan, O&apos

The crushing and milling of mineral bearing ores can now be accomplished more efficiently through the application of WaterFlush technology. WaterFlush crushing has reduced capital and operating costs for the processing of a lead/zinc ore in South America. Similar benefits can be expected in the processing of other ores. WF cone crushers offer improved performance over conventional cone crushers. Performance improvements include the ability to crush wet and sticky ores, increased reduction ratios and greater production of flakier and finer products.

Jan 1, 1989

By Dennis R. Rice

The Kettle River Joint Venture is 70 percent owned by Echo Bay Minerals Company, a wholly-owned subsidiary of Echo Bay Mines Limited, and 30 percent owned by Crown Resources. Initial announced ore reserves were 700,000 troy ounces of gold contained in three deposits located east and north of Republic, WA., U.S.A. Additional reserves are being proven. Processing of finely ground ore by preaeration-carbon in leach (CIL) circuit was selected followed by cyanide destruction by the INCO Air/SO2 process.

Jan 1, 1992

By Donald R. East

In the planning and design of mill tailing disposal facilities, the chemical and physical nature of the fine­grained material to be disposed of has to be fully understood in order to create an efficient and safe long­term storage facility. Disposal of tailing has become the single most important source of environmental impact for mining projects and the development of many promising ore bodies has been delayed or even stopped due to problems of facility siting and design under pressure of increasingly stringent regulatory require­ments.

Jan 1, 1992

By James L. Hendrix, Michael R. Straka, Emil B. Milosavljevic, Ljiljana Solujic, Neil P. Gallagher

Analysts that utilize the classical distillation procedures for cyanide analysis are often frustrated by the poor reproducibility and repeatability of these techniques. Capital intensive business decisions and environmental management regulations are exas­perated by the fact that the EPA/ASTM approved cyanide deter­mination methods produce data of questionable quality. Reliable cyanide values are important in monitoring the effec­tiveness of the cyanide detoxification procedures. Efficiency and cost of gold and silver cyanidation recovery can also be improved by precise cyanide monitoring in the process itself.

Jan 1, 1996