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By Nigel J. Cook

"Detailed mineralogical examination of gold-bearing rocks, ores, concentrates and other samples should be considered an integral part of any study of a deposit for which exploitation is being planned. Adequate mineralogical study, although time consuming and often costly, can significantly improve understanding of the mineralization, can help to optimize the results of any metallurgical testing and can be of great value in case of potential trouble-shooting. The advantages and disadvantages of various examination techniques are discussed with reference to a number oj mineralogical studies oj Canadian gold-bearing samples.IntroductionVarious authors, notably Gasparrini (1983), Harris (1989) and Henley (1990), have stressed that mineralogical study of gold ores is critical to successful and efficient beneficiation. Only in cases where diagnostic cyanide leach testing is successful can detailed mineralogical examination be disregarded. Such examination of gold-bearing rocks and metallurgical products is all too often neglected because the methods involved are believed to be time-consuming, costly, and may carry a considerable degree of inaccuracy. Commonly, bulk metallurgical testing is, carried out without prior or concurrent mineralogical examination, causing the results of the testwork to be difficult to interpret, or in some cases, misleading. This, in turn, may lead to> significant delays to the project at the feasibility stage or mean that understanding of the sample is limited, preventing the introduction of prudent modifications at a later stage if problems arise. Mineralogical studies may guide the successful implementation of a metallurgical test program."

Jan 1, 1990

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By S. Joshi, E. Asselin

An electrochemical quartz crystal microbalance (EQCM) was used to study the leaching of pure gold in deaerated 1 M Na2S solution. Multiple cyclic voltammograms were measured between -0.76 and 1.242 V (SHE) at 20 mV/sec and 2 mV/sec and the frequency shift of the quartz crystal was simultaneously measured. Both the forward and reverse scans showed oxidation occurred between -0.40 to 0.20V. The frequency shift increased during both the forward and reverse scans in the potential range of -0.40 to -0.06 V indicating electrode mass decreased. Since at -0.40 to 0.20 V oxidation peaks were also observed, part of the oxidation was due to oxidation of gold. Eh-pH diagrams were constructed and showed soluble Au(I)-S(IV) species formed between -0.30 and 0.10 V (SHE). Atomic absorption spectroscopy of the test solutions and the mass change recorded by EQCM both showed about 0.015 mg of gold leached. Since the majority of the frequency shift increase corresponding to gold oxidation occurred at -0.40 to -0.06 V during multiple cyclic voltammogram measurement, the total leaching of gold could be approximated to occur at this potential interval to give a leaching rate of ca. 6.4x10-5 mg/s-cm2.

Jan 1, 2011

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract -A test survey using the MEGATEMII airborne electromagnetic system was flown over the Iso and New Insco massive sulfide orebodies in the Rouyn-Noranda mining camp, Canada. The results were compared with data from historical systems (INPUT, DIGHEM) used to discover the deposits. The historical data show that the two deposits have comparable conductances. However, the modern MEGATEMII system reveals that the New Insco deposit has a much slower decay than the Iso deposit, and it is, therefore, interpreted to be more conductive. The MEGATEMII anomaly maps provide estimates of the location, depth, dip, and strike of the two deposits, information that was not available from the historical anomaly maps. The signal-to-noise ratio of the MEGATEMII data is greater than the historical data, yielding more sharply defined anomalies. The investigations also included a comparison between 90 Hz and 30 Hz MEGATEMII data. The 90 Hz data were found to be useful for mapping the less conductive parts of the Iso body, whereas the 30 Hz data demonstrated that the New Insco body is more conductive. Analysis of height attenuation data over the Iso body indicates that the body could be seen by the MEGATEMII system if it were buried an additional 230 m deeper (in highly resistive material). On the other hand, the INPUT system would detect the Iso body only if it were buried no deeper than an additional 60 m. Tests with the transmitter turned off showed that, for this flight, the MEGATEMII system noise levels on the processed data are about 300 pT/s. Sommaire - Dans le cadre d’un projet de recherche, un ensemble de levés d’essais électromagnétiques aéroportés employant le système de MEGATEMII a été effectué au dessus des dépôts d’Iso et de New Insco, Rouyn-Noranda, Canada. Les données ont été comparées avec les réponses des systèmes qui ont découvert ces deux dépôts (INPUT et DIGHEM). Les données antérieures montrent que le dépôt d’Iso a une conductance comparable à celle de New Insco. Cependant, les données de MEGATEMII démontrent que le dépôt de New Insco a une haute valeur de la constante de décroissance, ce qui reflète une plus forte conductivité. La carte d’anomalies de MEGATEMII indique la localisation, la profondeur, le pendage et l’orientation des deux dépôts, ce que la carte d’anomalies antérieure ne montrait pas. Le rapport de signal à bruit de MEGATEMII est plus grand que celui des données de INPUT et de DIGHEM; de plus, les pics sont mieux définis. Les tests ont également permis une comparaison entre les fréquences de base de 90 Hz et de 30 Hz. Les données de 90 Hz se sont montrées utiles pour cartographier la partie du dépôt Iso dont la conductivité est la plus faible, tandis que les données de 30 Hz montrent clairement que le dépôt de New Insco est plus conducteur. Les analyses de l’atténuation du signal avec la hauteur ont indiqué que le dépôt d’Iso pourrait être détecté par le système MEGATEMII s’il était enfoui à 230 m sous la surface (dans un milieu hautement résistant). D’autre part, le système INPUT pourrait seulement détecter le dépôt d’Iso s’l était situé à 60 m de profondeur. Les tests avec l’émetteur fermé démontrent que le niveau de bruit est des l’ordre de ±300 pT/s."

Jan 1, 2006

By J. -P. Lempainen, K. Haavanlammi, K. Valkama

The Outotec nickel matte chloride leaching process is especially suitable for small capacity standalone nickel refineries. The matte is leached with hydrochloric acid and oxygen in multiple steps in atmospheric OKTOP® reactors. Oxygen feed prevents reductive conditions and hydrogen formation in the leaching process. A sufficiently high acid concentration keeps the iron dissolved in the solution. The iron is removed after leaching by precipitation and the pregnant leach solution continues to metals recovery. The metals recovery from the chloride solution is done by solvent extractions, where ammonia is used for pH control. Copper and nickel are stripped from the organic phases into sulphate solutions. Metals can be recovered from the purified solution by conventional electrowinning. Other alternatives are precipitation or hydrogen reduction processes. The ammonium chloride in the solvent extraction raffinate is regenerated into ammonia. The calcium chloride solution from ammonia regeneration is routed to acid regeneration where sulphuric acid is added and ultra-pure gypsum is precipitated. The hydrochloric acid solution from this step is recycled back to leaching. The process yields good overall metal recoveries and expensive

Jan 1, 2014

By R. D. Brown

"AbstractIn order to raise the enormous amounts of capital which will be essential for the development of Canada's mineral and petroleum resources, this country's resource industry must be permitted to earn an acceptable rate of return. The existing tax regime, with its high rates, complexities and misdirected incentives, presents a serious obstacle to our resource industries in their development of Canada's immense , but increasingly lean, resources. Government tax and other policies are not the only cause of the crisis now facing the resource sector in Canada, but a reformed tax system, with stable and reasonable tax burdens, is required if Canada's resources of minerals, oil and natural gas are to continue to contribute in the future, as in the past, to our national well-being.An independent task force, organized under the auspices of the Canada West Foundation, has recently completed a wide -ranging report: on the future development of Canada's mineral, oil and gas resources. This five-volume report, completed after almost two years of research and study, concludes that Canada •is facing a major crisis •in the development of our resources, It states that unless corrective action is taken now, mineral production and exports could decline drastically after 1985, at the same time that Canada would face massive bills for imported oil because of inadequate and declining production.The task force, chaired by the author of this article, has put forward recommendations for a fundamental shift in both federal and provincial policies in order that Canada's mineral reserves can be developed in the national interest. This article consists of excerpts from the summary of the task force's report."

Jan 1, 1977

By Steve Forgeron, Brendan MacKenzie, Kevin MacPherson

"The geological composition of strata immediately adjacent to coal seams has a significant effect on the safe and efficient extraction of coal from underground mines of the Sydney coalfield. Geological features such as paleo-sandstone river channels, seam splits, floor rolls, paleo-soils and stone-filled rupture features can rapidly alter the competency of immediate roof and floor strata, significantly reduce the height of the coal seam, cause rapid variations in seam gradient and influence the in situ and run-of-mine quality of the coal.The impact of these features on the over-all mining operation can be significantly reduced if mine management can be for-warned of their impending occurrence. Using the information acquired from boreholes, geological mapping, x-ray diffraction analyses, microscopic studies, geophysical logs and seismic surveys, sedimentary models have been constructed which enable the mine geologist to predict, with increasing accuracy, the future occurrence of deleterious geological features ahead of the working face."

Jan 1, 1986

By Brian Penney

"The Iron Ore Company of Canada (IOCC} has mined and processed an iron deposit in Western Labrador along the Labrador-Quebec border since the early 1960' s. Current capacity is approximately 19 million tonnes of concentrate, 70% of which is converted to pellets at these facilities.The ore deposits are located in hills rising 150 to 300 meters above the adjacent lakes, and most of them are covered by very little overburden. The iron minerals are mainly specular hematite and magnetite hosted in a quartz formation. Crude ore averages 40% Fe that is concentrated to 65.5% Fe. IOCC is an extensive operation extending from Labrador City NF to Sept-Iles Quebec. It consists of open pit mining, concentrating, pelletizing, railway, and dock loading facilities.The Concentrator liberates iron from the silica by crushing and grinding the ore to -14 mesh (-1190 microns}. Ground ore is concentrated in spirals and filtered for transportation. Spiral tailings are treated in a Magnetic Recovery Plant (Mag Plant} that recovers lost magnetite. Mag Plant tailings are treated in a Hematite Spiral Plant (Hem Plant} that scavenges fine iron remaining in this stream.This report deals with ongoing iron recovery initiatives within the ConcentratorIron Losses in the ConcentratorIron recovery at IOCC is approximately 70.5%. This compares with recoveries that range from 65% to 86% for other iron mines in our area. Other world large iron ore producers dig and ship concentrate quality ore directly out of the ground and have an effective recovery of 100%. With increasing costs for labour, equipment, and supplies an increase in iron recovery is required to keep the operation viable.More than 90% of our iron concentrate is produced by gravity separation using spirals. The physical characteristics of the iron minerals that most effect recovery are mineral grain size and degree of liberation. We divide ground ore into three size categories -coarse, intermediate, and fines. A brief description of each size fraction follows:"

Jan 1, 1996

By Hung-wei Liu, Kevin Plucknett

Early attempts to manufacture titanium aluminides using blended elemental powders, through powder metallurgical processes, have been obstructed due to serious swelling during sintering. Although the use of pre-alloyed powder can avoid this undesired expansion problem, there are limited commercial powder sources available. Therefore, in the present research, fundamental studies on the synthesis of dual-phase (? plus a2) Ti48Al intermetallic materials is undertaken, in particular assessing powder manufacture. In order to produce pre-alloyed powders, highly porous Ti48Al pieces are initially sintered from elemental Ti and Al powder blends, and subsequently pulverised into powders. The powder size is then further reduced by use of either dry or wet milling processes (i.e. shatterbox grinding, attrition, or ball milling). Among these methods, shatterbox grinding has shown the highest efficiency, with a slight mechanical alloying effect observed. The manufactured powder morphologies and phases, as well the sintered material, will be discussed.

Jan 1, 2015

By T. D. Brown

"A review of the current status of gasification technology shows that many engineering systems are immediately available for use in the gasification of coal. Widespread international experience can be brought to bear on the atmospheric pressure gasification of all Canadian coals.Unless a high ash content dictates the use of a fluid-bed gasifier, it appears that bituminous coals can be used in gravitating (fixed] bed systems and that the strongly caking coals are most suited to the high-pressure entrained-bed systems . Existing and developing technologies in fluid-bed gasification are attractive for reactive lignites and subbituminous coals.The Fischer-Tropsch based process is the only commercial embodiment of coal liquefaction; the use of Canadian coals in this process depends only on their gasification characteristics. Current developments in hydroliquefaction are directed toward carboniferous coals of medium or high rank. It is not clear that cretaceous coals of the same rank will give similar process yields and economics.IntroductionThe twin coal conversion processes of gasification and liquefaction have a history which dates back beyond the current energy shortages of the western world. Indeed, liquids and gas from coal were produced before this century.Coal gas produced from a coal carbonization process was originated before 1800, and the development of gasification of non-coking coals was patented by Siemens in 1860.This patent represented the first use of air and steam together in the gasmaking process. The pioneering development of coal gasification Using oxygen and steam was demonstrated by Lurgi in the late 1920s. This historical sequence was all carried out at atmospheric pressure, and it was not until the immediate pre-war (1939/45) years that operation of the coal gasification process at elevated pressure became a reality."

Jan 1, 1981

By H. Utsunomiya, Mehdi Sanjari, Abu Kabir, Steve Yue, Jing Su, L. Kestens, In-ho Jung

The microstructure and texture evolution of low temperature rolled AZ31 magnesium alloy during annealing were investigated. The specimens were rolled at the temperature of 100? at a high rolling speed of 1000m/min with a reduction of 30% in one pass. Annealing was conducted at various temperatures ranging from 200? to 500? for different time. To study the effect of fast speed rolling, the same annealing procedures have been applied for the specimens rolled at a significantly lower speed of 15m/min. The microstructure was characterized by optical microscopy and scanning electron microscopy, while the texture was analyzed by X-ray diffraction analysis and electron backscattered diffraction analysis. Texture weakening occurred during annealing at both fast and slow rolling speeds. However, at the same annealing condition, fast rolled specimens always had weaker intensity of basal texture than slow rolled ones.

Jan 1, 2014

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

By H. M. Lizama, R. L. Stephens

Secondary leaching of previously leached supergene copper ore has been developed and implemented at Teck’s Quebrada Blanca operations. This consists of using in-situ leaching techniques aided by geophysics to recover the residual metal value from dormant copper leaching heaps. These heaps of crushed and agglomerated ore had been leached 20 years previously but still contained significant copper values. The concept was first tested on a 3,200 m² sector, where injection wells introduced leaching solution into a production zone and electro-resistivity tomography was used to track solution movement within. Operating parameters such as well spacing and injection flow rates were determined. Copper recovery and leaching performance were evaluated based on solution and metallurgical balances. Both ferric leaching and bacterial leaching were enhanced through strategies to pull air into the heap. Positive results from the initial test prompted a larger, industrial pilot test on a 60,000 m² area and 97 injection wells. This larger test obtained a copper recovery of 30% in 457 days. Secondary recovery is now being implemented to all of the abandoned heaps at Quebrada Blanca and has become a production stream. This technology has the potential of wide application to mature copper heap leach operations, and Teck has patented the process and associated methodologies. INTRODUCTION Heap leaching of copper secondary sulphides has been carried out at Quebrada Blanca (QB) since 1994. Ore from the supergene deposit was crushed and agglomerated prior to leaching. Originally, the ore was leached in 6 m lifts stacked one on top of another, known as a static pad configuration. However, in 1998, after the second lift, the operation changed to a dynamic pad configuration; the ore was leached in a single lift and the resulting residues were removed to make way for fresh ore (Yáñez, Ahlborn, & Ramos, 2007). The first two static lifts were left in place and served as a foundation for the dynamic lifts above. Those two buried lifts of leached residues, some 16.8 million tonnes and covering an area of approximately 0.71 million m², remained buried under the dynamic pad.

Jan 1, 2019

By W. M. G. Heeley

In the province of Alberta the coal measures dip at so many different angles, between the horizontal and the vertical, that many different systems of haulage are in use. I will, however, only touch briefly upon the general -systems in use, and devote the major portion of this paper to a discussion of endless-rope haulage and its adaptibility to various conditions in coal mines; dealing in particular with the endless-rope haulage that was installed at Brule during the month of August 1923. In coal seams that are approximately level, and newly opened, hand-putting or tramming from the face is the cheapest, but when the mine is further developed tramming is out of the question, and the use of ponies is the next consideration. The time arrives, however, when mining reaches a point where the economical haulage of coal by horses cannot be done profitably, and then some system of mechanical haulage must be installed. The installation of any system should be carefully considered before any particular type of haulage is adopted, because a great deal depends upon the grade or dip of the seam. Motor haulage is impossible to operate profitably on a grade of over 6 per cent and, while it is possible to use ponies, on short runs, up to 9 per cent, some other means of main and secondary haulage must be installed when a 9 per cent grade, is exceeded. I will, therefore, deal first with secondary haulage, because even though a main haulage is established, secondary haulage can be used to feed the main haulage.

Jan 1, 1925

By R. C. Carne, R. J. Cathro

"Most of the recent large discoveries of zinc, lead and silver in Western Canada are Paleozoic-aged stratiform deposits that occur within the limits of the tectonic sub-province of the Canadian Cordillera known as Selwyn Basin. Bounded on either side by coeval carbonate platforms. Selwyn Basin trends northwest for 1300 km from northeast British Columbia to Alaska. Paleozoic rocks of Selwyn Basin consist primarily of chert, shale and coarser-grained clastic sedimentary rocks with minor volcanic rocks.The Selwyn Basin deposits have few counterparts elsewhere in Canada, but have a close similarity in geological setting, mineralogy and morphology to well-known deposits such as McArthur (HYC) in Australia, Meggen and Rammelsberg in West Germany, and Sullivan in British Columbia. Recent studies of these deposits have led to an emerging, but now generally accepted, model of ore deposition in which stratabound zinc-lead-silver shale-hosted or ""sedimentary-exhalative"" (sedex) deposits are precipitated in active tectonic environments from metalliferous geothermal brines that rise to the sea floor along deep-seated fault zones. Although their mineralogy and ore metal zoning can be similar to that of volcanogenic massive sulphide deposits, most sedex deposits have only a weak genetic link with volcanism.Sedex mineralization in Selwyn Basin has been identified within three separate ages of shale or its metamorphosed equivalent. The lower Cambrian-age Anvil Camp in central Yukon Territory contains the only producing mine (Faro). Important lower Silurian-age zinc-lead mineralization is at Howards Pass along the Yukon - Northwest Territories border. Barite and zinc-lead-barite mineralization of upper Devonian age occurs across Selwyn Basin. Potentially economic deposits have been found at Macmillan Pass, along the Yukon - Northwest Territories border and in the Gataga District of northeastern British Columbia."

Jan 1, 1982

By R. I. Kraydenko, A. N. Dyachenko

"The possibility of SiO2 5N production by staged purification of ammonium hexafluosilicate (NH4)2SiF6 is discussed. High-purity silicon dioxide can be obtained with fluoridation of quartz concentrate by solid NH4F at 100 °C, with further sublimation of the product at 320 °C, its dissolution, ammonia hydrolysis, filtration and drying of SiO2•nH2O. This is accompanied by regeneration of the processing reagent - NH4F.INTRODUCTIONProduction of high-purity silica-5N (SiO2 content over 99.999%) is an important and urgent task of the modern chemical industry. This material is used in the manufacture of optical glass, optical fibers for internet cables, silicon for solar power and electronics.Quartz concentrate is raw material for the production of silicon dioxide. The existing technologies of synthetic silicon dioxide were introduced in the mid-twentieth century. These methods are energy-consuming, multi-step and do not meet stringent environmental requirements. In fact, as some conventional technologies became obsolete; it became necessary to develop new methods for the production of synthetic silica. We believe that the fluoride technology of processing of quartz materials by ammonium fluoride is the most promising direction.In industry, silicon dioxide marked ""Silica White"" is obtained by liquid-phase method. The method consists of the precipitation of amorphous silica from sodium silicate solutions with acids. The resulting product is filtered, washed and dried. Depending on the deposition conditions and nature of the coagulant the ""Silica White"" is acidic, neutral or alkaline. The dry product is subjected to grinding. The degree of dispersion and porosity of the particles of Silica White depends on the nature of decomposition agent (a substance that decomposes the silicate) and coagulant, conditions of sedimentation, filtration and drying. During the drying process the silica particles are sintered into aggregates of a few millimeters."

Jan 1, 2012

By Mohammad Mehdi Salarirad

Fouling of activated carbon by different organic species is a great concern in carbon in pulp and carbon in leach circuits. The rate of gold adsorption onto activated carbon from synthetic gold solutions which contained different amounts of potassium ethyl xanthate (PEX), potassium isobutyl xanthate (PIBX), and methyl isobutyl carbinol (MIBC) were evaluated through batch adsorption tests. The results of these experiments showed that the gold sorption rate rapidly decreases by increasing the concentration of collectors including PIBX and PEX up to 20 mg/L and at higher concentrations, the kinetic rate constant (i.e., k value) gradually leveled off to 53 h-1 for PIBX, which is 46% lower than the 99 h-1 for PEX. At low concentrations of up to 15 mg/L of MIBC, a gradual decrease of the rate constant was observed, while at higher concentrations, the decrease was found to be more pronounced. The gold loading capacity and the rate of gold adsorption onto activated carbon from a gold cyanidation pulp in the presence of flotation reagents were also evaluated. The results of these experiments showed that the flotation reagents have no significant effect on the gold loading capacity of activated carbon at prolong adsorption period, meanwhile the rate of gold adsorption continuously decreases by increasing the concentration of flotation reagents in the leaching solution.

Oct 1, 2011

By M. K. Mishra, U. M. R. Karanam

Relative to slender pillars, larger size pillars exhibit improved strata control. Fly ash, though traditionally treated as a waste product, is emerging as an alternate engineering material. This paper deals with the development of a strong fly ash composite material with additives. The geotechnical properties of this fly ash composite were determined and used to trap model core pillars, which resemble squat pillars. The trapped samples were tested under uni-axial loading in the laboratory and the results showed higher load-bearing capacity of the model core pillars. The reinforced fly ash composites provide lateral confinement and exhibit improved post- failure behaviour of the model cores.

Jan 1, 2008

By I. B. Schalamuk, R. E. de Barrio, M. J. Pons, M. B. Franchini, L. Meinert

"Several Fe, Fe-Cu, and Cu-Ag prospects hosted by Mesozoic carbonate-rich sedimentary rocks that were intruded by diorite stocks define an approximately 20 × 200 km belt along the Andes Cordillera of southwest Mendoza province, Argentina (34°-36°S). This belt includes the Hierro Indio and Vegas Peladas Fe skarns, Las Choicas, and several other Cu-(Ag) prospects.The main features of the Fe skarns include: association with mantle-derived middle Miocene (~15-11 Ma) diorite stocks and sills; widespread alteration including epidote ± amphibole ± magnetite endoskarns, and zoned garnet (Grs0-66 Adr32.5-100) ± magnetite ± pyroxene (Di24-50 Jo2-9 Hd74-41) exoskarns formed from oxidized, saline, high-temperature brines (530º-660ºC; 60-70 wt.% NaCl equiv.); and magnetite-hematite orebodies associated with quartz ± epidote ± calcite ± actinolite formed at lower temperatures (290º-436ºC) from saline fluids (32-50 wt.% NaCl equiv.) of magmatic origin.West of the Fe skarn belt, the Valle Hermoso district covers more than 300 km2 and hosts several poorly known Cu-(Ag) prospects (estimated 30 Mt with 1.5% Cu and 20 g/t Ag). These prospects share many characteristics with the iron oxide copper-gold-type systems and manto-type Cu deposits of northern and central Chile. One of the prospects (Las Choicas) is located at the apex of a regional 015°-trending anticline, along the contact of stratified calcareous sandstone and limestone (Neocallovian-Oxfordian) with a diorite pluton. This pluton has positive Ta and Nb anomalies (on normalized diagrams) and a high Ti content, features uncommon in Miocene diorites associated with Fe skarns and of magmas derived from sub-arc mantle sources. Alteration at Las Choicas includes early widespread chlorite + calcite ± albite ± scapolite ± ilmenite or titanite ± apatite, and local actinolite ± hematite ± biotite alteration of diorite and sedimentary rocks along contacts. Later Cu mineralization (1%-10% Cu) is associated with calcite ± albite ± quartz alteration in fractures, vein networks, and crackle breccias. Mineralization is zoned from bornite ± chalcopyrite ± millerite with Zn, As, Mo, Ag, and U anomalies in the main orebody, through chalcopyrite-rich breccias with Zn anomalies, and chalcopyrite ± tetrahedrite vein networks with Sb, As, Ag, and Zn anomalies in the uppermost zone, to a Cu-depleted pyrite-rich envelope with Co anomalies, and finally to late, barren calcite veins in distal zones."

Jan 1, 2007

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015