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By Robert B. Parsons

"Finance Minister Paul Martin's first budget disappointed almost everyone. The business sector was disappointed at the some what feeble attempt to grapple with the country's deficit. The mining industry was disappointed by tax proposals regarding mine reclamation that fall short of the industry's needs. Has anybody been happy with a federal budget? Federal Budget DisappointsThe federal government's budget papers that were tabled on February 22, 1994, contained a rather bizarre mixture of unrelated tax proposals. The budget signals an unexpected attack on the tax treatment of debt settlements, on certain types of corporate reorgani2ations, and on income earned by foreign affiliates. This is an old style budget, which proposes a pot pourri of technical changes and policy initiatives. Mine ReclamationEffective February 23, 1994, a taxpayer's contributions to a prescribed mine reclamation trust fund will be deductible as a current expense. The budget papers do not provide a definition of what will constitute a ""prescribed"" trust: this definition will surface in due course. However, the budget papers indicate that:• income earned in such trusts will be subject to tax each year;• all withdrawals from the trust (including income already taxed) will be included in computing the income for tax purposes of the recipient;• reclamation costs will continue to be fully deductible at the time incurred; and • contributions, trust earnings, and withdrawals will not be taken into account for the purposes of determining a taxpayer's resource allowance."

Jan 1, 1994

By A. Fischersworring-Bunk

The new inline six spark-ignition engine is the realization of BMW's concept of efficient dynamics at high technological level to achieve the attributes of low weight and high efficiency, The paper presents different aspects of the development and manufacturing of BMW's inline six-cylinder engine magnesium-aluminium composite crankcase, Reference will be made on the AJ magnesium alloy optimization approach to balance between mechanical properties and the high pressure die cast ability requirements, Next to this aspect some mechanical design issues will be covered, with CAE methods playing an instrumental role in the early project stage for the assessment of the compound concept, Due to the compound design chosen, the interface posed challenges to both design and productions, A set of novel techniques has been used to cope with these tasks.

Jan 1, 2006

By T. Velea

The most widespread methods for producing metallic copper are smelting of copper sulphide concentrates (which generates various types of polluting substances) and the hydrometallurgical route which consists of leaching in sulphate and chloride media (usually employing high temperature, high-pressure and special equipments). This paper presents a process, called VEPE, which consists of oxidizing copper sulphide concentrates in weak alkaline media (Na2C03 orland NaOH solutions), under low pressure and with air sparging. The oxidized concentrate contains less than 0.4% S. Copper is recovered from the oxidized concentrate by the standard leaching-solvent extraction-electrowinning route, with a total efficiency of 98% extraction. The proposed technology could represent a good opportunity to recover copper from sulphide concentrates in a clean, simple and profitable way.

Jan 1, 2007

By Edward R. T. Tiekink

Metal complexes continue to find therapeutic applications for the treatment of a wide variety of human ailments. Amongst these, gold(I) thiolates are used to treat rheutmatoid arthritis but, usually in combination with other treatment or as a last resort. New therapeutic uses of gold, both as gold(I) and gold(III), are being sought, including against cancer, the focus of the present contribution. It will be demonstrated that certain gold(I) complexes show exciting cytotoxicity profiles, rivalling those of cisplatin and standard chemotherapeutic agents. More importantly, anti-tumour activity is demonstrated in vivo, albeit in a mouse model. The presentation will give a brief overview of ?metals in medicine? with a focus on gold and will summarise some recent advances in the development of goldbased anti-tumour agents.

Oct 1, 2003

Over the years, efficient on-line monitoring of performance and status of an electrolytic copper refining process has been challenging due to the need for complex electrical measurement systems and the management of the enormous volume of data. Recent innovative developments by Kennecott Utah Copper Corporation and Outokumpu Technology in wireless cell voltage and individual cell temperature sensing opens new possibilities to improve and modernize tank house management. This paper describes the powerful Outokumpu CellSenseTM refinery monitoring system for efficient interpretation of data produced by wireless CellSensorTM system with traditional refinery measurements. Examples from commercial tank house installations demonstrate the benefits of the system to improved process control and operation. The Outokumpu CellSenseTM monitoring system is simple to operate and accessible to all the plant operation teams.

Jan 1, 2007

By S. Theobald

Semi-finished copper and copper-alloy products are typically produced by casting, subsequent hot rolling or extruding and further cold working by rolling and drawing. The technological properties of the products depend not only on the chemical composition of the alloys but also on process parameters such as annealing conditions and degree of deformation. In each production step, measuring and control technology is an important tool for optimizing processes and ensuring constant high quality. This paper follows the product all the way from testing incoming scrap packages, chemical analysis of melts, mould level control in casting, non-destructive testing technologies in cold forming processes, controlling geometrical properties in the production process, to the final tests of technological properties. All test methods are focused on the applications and requirements of our customers, as the examples show.

Jan 1, 2007

By G. Plascencia, A. Warczok, M. Zamalloa, T. Utigard, N. Behnood

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.

Jan 1, 2004

By Joseph J. Poveromo

The blast furnace today continues as the primary production method of hot metal in large-scale steel production. The blast furnace process has been the target of repeated attempts to replace it with various process options, including direct reduction and coke-free smelting reduction. While these new technologies are being adopted in appropriate niches, the blast furnace has responded to the challenge by being amenable to continuous improvement. I will review the role of the blast furnace, major developmental and improvement trends, and then list the current important issues in ironmaking. I will outline the challenges to be faced by the blast furnace to maintain its position as the primary hot metal production process. The material presented here is an update of earlier presentations made in Stockholm, Sweden, 1996, Duluth, 1998 and Chicago, 2000.

May 1, 2003

By K. Shitogiden, Y. Samada, T. Miki

Steelmaking slag contains nutrition such as Si, P and Fe for acceleration of phytoplankton growth. Phytoplankton can fixate carbon dioxide more than any other species on earth. Hence, suppression of CO2 can be achieved by applying the potential of steelmaking slag as the nutrition for their propagation. When it is considered to supply nutrition from steelmaking slag to seawater, we must avoid dissolution of hazardous elements or change of pH of seawater by steelmaking slag addition into seawater. The protection against dissolution of fluorine into artificial seawater has been studied based on dissolution behavior of steelmaking slag and synthesized substances into artificial seawater in the present work. The dissolution mechanism of fluorine from steelmaking slag and buffering action of pH change are discussed by using stability diagram in seawater.

Jan 1, 2004

By A. Rahimi

The smelting plant at Sarcheshmeh Copper complex commenced working with two reverbatory furnaces, four pierce smith converters, two anode furnace and one holding furnace having a known capacity of 420 metric tons of anodic copper according to the initial design in 1982 (1361 Iranian calendar). During the period from the commencement date up until now, the smelting plant has undergone changes for improvement and enhanced production by substituting holding furnace with another anode furnace, installing the fifth converter and utilizing oxyfuel burners on the ceiling of the reverberatory furnaces. According to the different operational processes in reverberatory, converter and anode furnaces different types of corrosion mechanisms and degradation can be observed in the refractories of copper smelting furnaces. In the case of reverberatory furnaces, the corrosion and degradation of refractories may be factors such as hot corrosion by melt, corrosion attack by the constituents of burning fuel, degradation of sidewalk exposed to mechanical stresses of the feed charge and the hydrostatic pressure exerted by the melt inside the furnace, all of which are due to the unique operational condition governing the reverberatory furnaces environment, i.e. burning fuel atmosphere, charge concentration and combination, furnace temperature, calm melt condition, etc. In the case of converter furnaces, the most likely corrosion and degradation of refractories may be due to the chemical reaction between the melt and degradation of tuyere zones due to sever movement of the melt and mechanical strikes of the punch rod. Also the most essential corrosion reaction occurs around the mouth of the converter because of the mechanical strikes by the cleaning device and thermal heat shock. Other parts inside the furnace are corroded due to the reactions between the fayalite slag and the furnace refractory. In anode furnaces the degradation mechanism is mostly related to the gaseous corrosion (penetration of natural gas or liquid gas inside the refractory structure due to the long period of reduction processes and refining stages. Finally another important factor responsible for destruction of refractories in these furnaces is the copper oxide slag together with the fume constituents of burning fuels.

Jan 1, 2004

By Hong Zhong, Shuai Wang, Gang Zhao, Lanqing Deng, Guangyi Liu

In this paper, three novel surfactants containing double reactive centers(-CONHOH and –CONH-), double hydrophobic groups were designed and synthesized as collector for separation of diaspore and aluminosilicate minerals, such as N-(4-(hydroxyamino)-4-oxobutyl)octanamide (HA-8), N-(4-(hydroxyamino)-4-oxobutyl)decanamide (HA-10) and N-(4-(hydroxyamino)- 4-oxobutyl) -dodecanamide (HA-12). The adsorption mechanism of N-(4-(hydroxyamino) -4-oxobutyl)alkylamides (HA) onto diaspore was also investigated by FTIR spectra, zeta potential measurement and DFT. The flotation results demonstrated that three collectors all exhibited superior collecting power to diaspore and selectivity against kaolinite and illite, and could effectively realize flotation recovery of diaspore from bauxite ores contained aluminosilicate minerals under neutral conditions. Moreover, HA-12 was a superior collector than other two collectors for bauxite separation. The results of XPS, FTIR spectra and zeta potential illustrated that at around pH 6.0, HA might chemisorb on diaspore surfaces through Al-O coordination bonds formed by binding its –C(=O)NHOH or –C(=O)NH– chelate groups with aluminum atoms on diaspore surfaces. HA’s unique properties, such as characteristic bond patterns onto diaspore surfaces, double hydrophobic groups, and intermolecular hydrogen bonds between neighboring HA molecules coated on diaspore surfaces, rendered it to be a superior flotation collector for diaspore.

Jan 1, 2016

By J. L. Rodrigues Bravo

The aim of this paper is to show the results of the study that relate the variations of the bismuth content in the Caraíba Metais' electrolytic copper with the main electrolysis' process variables as electrolyte flow rate and temperature, anode's impurities content, electrolyte composition, current density, etc and their combinations and factors like cathode washing, blend of materials entering rod plant's furnace, analytical methods, shot-circuit inspection, etc. Also, the methodology considered arsenic, bismuth and antimony mass balance in the electrolysis and their electrolyte's molar ratio relations as well as bibliographic references of refineries that operate in similar conditions. The results showed the circumstances with the major probability of causing bismuth content increasing in the electrolytic copper and the main operating conditions that have to be fixed for having less bismuth variation and lower content in the electrolytic copper.

Jan 1, 2007

By S. K. Sadrnezhaad, B. Hashemi, Z. A. Nemati, Z. Moghimi

Based on the kinetics relationships of a solid - gas model, a software was developed for the prediction of oxidation. Preliminary prediction of oxidation by the software and experimental results of MgO-C refractories were studied and compared. By using the obtained data from this approach, the effective diffusion coefficient, intermolecular diffusion coefficient and diffusion activation energy in the MgO-C refractories, containing various amount of graphite were obtained at different temperatures. First of all, the prediction by the software was very compatible with experimental results, for different oxidation mechanisms in the MgO-C refractories. The results showed that pore diffusion is the predominant oxidation mechanism in this system. The results indicated that when graphite content was above 10wt%, the intermolecular diffusion coefficient was independent from graphite content, and it was closed to a constant value at each temperature.

Jan 1, 2004

By T. H. Etsell, P. C. Holloway

The fly ash produced by oil sands operations in northern Alberta represents a large, high-grade, potential resource for vanadium production in Canada. After extensive batch testing at the University of Alberta, a conceptual process flowsheet for the recovery of vanadium from oil sands fly ash has been developed. The various unit operations for this process, including decarbonization, roasting, leaching, desilication, precipitation, salt recovery and byproduct recovery, are described. Processes for the recovery of molybdenum and ammonium chloride from waste streams from this process, are proposed, as are potential uses for the ash residue; these byproducts represent significant potential sources of secondary revenue while reducing the environmental impact from the process. A preliminary economic analysis for vanadium recovery from oil sands fly ash using this process is also included and several major economic factors influencing its commercialization are discussed.

Jan 1, 2004

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By Z. Mubarok

An overview of the problems encountered the electrorefining of copper anodes containing high levels of nickel and antimony is presented. Our investigations have been focusing on the passivation behaviour of the anodes with high contents of Ni, Sb, Sn, and Pb, the formations of kupferglimmer and floating slimes. The results of linear voltammetry, chronopotentiometry and electrolysis test revealed a noticeable lower resistance of the anodes to passivation in comparison to those with lower contents of Ni, Sb, Sn, and Pb. Anode containing kupferglimmer exhibited oxygen gas evolution during the passivation state. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) indicated that tin can replace and/or join antimony in the kupferglimmer structure. Under specified experimental conditions, floating slimes precipitations took place with high Ni, Sb, Sn, and Pb anodes prior to the end of one anode period.

Jan 1, 2007

By F. Golestani-Fard, A. A. Nourbakhsh

In this paper microstructural development of nitride-Bonded SIC refractories is reported in presence of Al203, Mg() and Urea additives .The samples were prepared by mixing, shaping and firing at 1400-1500°c in a controlled atmosphere furnace. Phase analysis, microscopic observation and mechanical evaluation were taken for microstructural investigations. The strength of samples doped with Al203 was first increased and then decreased at higher amount of Al2O3 additions. The addition of MgO decreased the strength while the urea showed an improving effect on strength. These phenomena could be attributed to microstructural evolution and mainly to liquid phase formation and grain morphology. It was found that the additives such as Al203, MO and urea could modify the microstructure in terms of phase formation and texture modification, which in terms influences the mechanical behavior.

Jan 1, 2004

By G. Ladouceur

"LOCATIONThe mine and mill are located in Lemoine township which is 20 miles directly south-east of the town of Chibougamau Quebec. Personnel live in Chibougamau and commute to the property over 33 miles of paved and gravel roads. Concentrates are trucked 13 miles to a railway siding on the line connecting Chibougamau and Quebec city.HISTORY Several companies explored the property before acquisition by Patino Mines (Quebec) Limited in 1973. Further exploration led to the discovery of a high grade copper-zinc orebody and the property was brought into production by the above company in 1976.ORE The ore contains 85% - 95% sulphides consisting of chalcopyrite, sphalerite, pyrite, pyrrhotite and minor gold and silver. Argenti tetrahedrite, antimonial silver, native bismuth and galena are also pre sent in very minor quantities. Associated gangue minerals are quartz, carbonates and occasionally chlorite."

Jan 1, 1979

By Lee W. T. Weitzel

This paper reviews the Falconbridge- SMRQ?s Raglan project in northern Quebec and the process that was used in developing its current long-term mine plan. Challenges were many and not only limited to the longevity of the project, numerous ore deposits (both underground and open pit), and a 40km property strike length. As a result of its remote northern location other factors such as progressive reclamation, leachable mine waste, water treatment, and waste management were also part of the plan. A combination of modern planning tools were used to formulate the plan including DataMine, Mine 2-4D, AutoMod Simulation, and an Excel based financial spreadsheet to bring the total plan together. The focus of this paper is to show the complexity of modern mine planning and associated economic modeling of mine processes.

May 1, 2002

By Dale Coffin

Definition Of A Crisis Crisis \kri-ses:\ An unstable or crucial time or state of affairs whose outcome will make a decisive difference for better or worse (Webster's New Collegiate dictionary) An event or set of circumstances that could significantly affect a company?s ability to carry out its business, damage a company?s reputation and/or threatens the health, safety and well-being of employees, the community or the public at large You?re Having A Crisis When... . The emergency poses a significant threat to the public or employees . The emergency situation provokes government scrutiny . The company no longer has full control of the situation . The situation has created significant regional, national or international media interest . The corporation?s reputation may be damaged or there is a threat to the bottom line or share value

May 1, 2004