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By Gabriel Zarate

"Los Bronces had two ROM dump leach operations designated Leach I and Leach II. Leach I was commissioned in 1998 and stopped in 2014 due to the mine requirements. Leach II plant, commissioned in early 2002, was built to treat around 700 million tons of marginal ROM ore averaging 0.45 % total copper. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides.The original electrowinning plant design capacity for copper production was nominal 19,500 tonnes per year at a current density of 276 A/m2 and a current efficiency of 92%. Presently, Los Bronces San Francisco plant typically operates at current densities between 390 and 440 A/m2, much higher than the average in the industry, with current efficiencies around 93% and a maximum copper cathodes production of 37,200 tonnes per year.In order to accomplish these achievements, a number of modifications in the process conditions, in the cell hardware and in the operational procedures have been implemented. In the first case, the specific flowrate, copper concentration and temperature of the electrolyte were modified to accommodate the operational requirements facilitating the increased current density. Associated with the cell hardware, a six cells expansion was added, upgraded equipotential inner cell busbars were installed and the cross section of the cathode hanger bars was enlarged for increased current carrying capacity. Documented operational procedures like short circuit detection and cathode weight control were improved.The modifications implemented and the results obtained are discussed in this paper.INTRODUCTIONLos Bronces Division of Anglo American Chile is located up in the Andes Mountains, northeast of Santiago. It had two cathode plants, Los Bronces at an altitude of 3500 meters above sea level (m.a.s.l.) commissioned in 1998 and closed in 2014 and San Francisco at an altitude of 2800 m.a.s.l. and in operation since 2002.The process is leaching run off mine (ROM) low grade copper sulphide ore in dumps. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides. The average grade is 0.45% total copper (Cut).At Los Bronces dump, Leach I plant, the pregnant leach solution (PLS) was collected and stored in an underground reservoir. From there, it was fed to a solvent extraction plant with a series-parallel configuration in two extraction stages and one stripping stage. The electrolyte produced was fed to the electrowinning plant having 30 cells and 60 cathodes per cell. Maximum capacity of this plant was 12,000 tonnes per year (tpy)."

Jan 1, 2016

Flotation of a mineral bearing particle is the result of successful completion of a chain of events, such as, producing particles with sufficient exposure of the valuable mineral on the surface, reagent adsorption, suspension of the particle in the pulp, collision of particle with air bubbles and subsequent attachment, ascending to the froth column and transport to the concentrate stream, among others. These sub-processes in turn are affected by the feed properties such as size and density, and process variables such as size of air bubbles, degree of turbulence in the cell, particle/particle interactions etc.. Thus, inefficiencies occurring in any one or more of the above processes will result in inefficient flotation performance. In spite of its dependency on a wide variety of sub-processes, flotation performance is commonly modelled based on first order kinetics using two or three parameter models. As the model parameters may be affected by several of the sub-processes mentioned above, interpretation of their variations and identifying the specific causes is extremely difficult. Of the many factors that influence the flotation performance, liberation information of the particles such as the grade distribution and surface exposure are considered vitally important. In this paper, it has been demonstrated a) how a predictive liberation model may be derived and used in quantifying the liberation information of the particles produced at various grind sizes and b) how the flotation process may be modelled by explicitly incorporating the liberation information, thereby improving the accuracy of the model. Comparisons of the observed data with the proposed model and those of published liberation/flotation models have also been made.

Jan 1, 2016

By S. C. Cohen, A. F. Mikkelsen

"This paper describes the improvements made to the operation of a liquid phase, 300°C, heat transfer system in the paste plant of an aluminum smelter. These improvements were achieved by replacing the original heat transfer fluid, a synthetic aromatic, with a new technology, petroleum-based product. This new fluid, Calflo HTF, provided better thermal stability, with lower toxicity, and improved plant working conditions.The procedures for fluid selection, changeout and performance monitoring are described along with a summary of control analysis over the last three years."

Jan 1, 1993

By Simon Pelletier, Jose Delgadillo, Dave Page, Pramod Kumar, Raj Rajamani, Dilek Alkac, Martin Fillion

"In general, many past works examine mill load, mill power, shell lifter design etc with a view to improving the mill capacity. On the contrary, only a handful of papers have addressed the transport of fine slurry through the pulp lifters. We present the flow dynamics of pulp lifters via laboratory scale experiments, high speed photography and modeling with computational fluid dynamics. Next, the flow behaviour in ArcelorMittal’s Mont-Wright autogenous mill discharge flow is examined. In an effort to improve mill throughput, a comprehensive simulation and plant scale study of the mill was taken up with a focus on the shell and pulp lifter design. The shell lifter was found to be at its optimum limit for breakage of ore particles given the constraints of wear life and occupied volume. Next, the pulp lifter study was taken up with computational fluid flow code and discrete element code. The simulations directly showed that there was considerable carry-over of slurry. This effect was traced to the area restriction in the pulp lifter channels. Further, crash-stop studies confirmed slurry pooling within the mill. Thus it was readily apparent that mill throughput can be increased if the pulp-lifter could be redesigned. Consequently, the discharger section of the pulp-lifter was redesigned.First, this paper outlines the modeling in laboratory scale studies and plant scale studies leading up to the discharger design. Next, the discharge flow in seven different published mill surveys is predicted with computational fluid dynamics (CFD) methodology shown here. Finally, Mont-Wright mill circuit performance before and after the discharger redesign is described. The usefulness of fluid flow simulations in the design of pulp-lifters is emphasized."

Jan 1, 2012

By Hans Lundberg

During the last few years, geophysical methods have been introduced to aid mining geologists and mining engineers in locating mineral deposits. These methods have been developed as the result of investigations of various physical characters of minerals and rocks. In prospecting for ore-bodies, electrical methods have proved most successful. These methods are based on the great differences in electrical properties, and especially in conductivity, between ore minerals and rock minerals. The electrical resistance of the common minerals, rocks, and ores in ohms per cubic céntimeter is given in the following table: [ ] The first attempts at electrical prospecting were based on observing currents of polarization around certain ore bodies, which currents it was possible to measure. This method has been developed by Prof. Schlumberger and has been utilized by him successfully. He is represented on this continent by Mr. Sherwin Kelly, who has successfully operated the method here.

Jan 1, 1926

By Yue hua Hu, Wei Sun, Pan Chen, Li Wang, Runqing Liu, Central South University

"The flotation separation of muscovite from quartz was investigated using mixed sodium oleate/dodecylamine (NaOL/DDA) collectors. The flotation experiments were conducted on single minerals and their collecting performances were studied by means of adsorption amounts and molecular dynamics simulation. Flotation results show that muscovite presents good floatability while quartz exhibits poor floatability in alkaline condition. Adsorption amounts show that both NaOL and DDA can absorb onto surfaces of muscovite and quartz in presence of mixed surfactants. Molecular dynamics simulation indicates that DDA plays an important role in the adsorption of mixed surfactants on these two mineral surfaces. The molecules of mixed NaOL/DDA are arranged in a rigid and well-ordered packing on muscovite (001) surface. Only a few DDA adsorb on quartz directly, and rest DDA and NaOL molecule exist near by the quartz surface, forming a hydrophilic cylinder-like structure. This study may provide guidance for the flotation mechanism and application of mixed anionic/cationic collectors.INTRODUCTIONIn the past decades, there has been an ever-increasing demand for muscovite (KAl2(Si3Al)O10(OH)2) because of its potential applications in cosmetics, construction and metallurgy industries (Barlow & Manning, 1999). Besides, muscovite is an important carrier for some rare metals, including vanadium, titanium and lithium (SsuerrN, 1979). Quartz (SiO2) occurs as the main gangue mineral in muscovite ores, which results in a low purity of muscovite and limits its wide applications. Therefore, there is an urgent need for the beneficiation of low grade muscovite ores. Many studies remove quartz by screening and gravity separation in virtue of their differences in shape, hardness and density. However, these methods undergo poor efficiency in case of small particle size (below 50µm) of muscovite and quartz (Liubakka, Sullivan, Lamphere, Corradi, & Dykhuis, 2011; Santos, Franca, & Ogasawara, 2011)."

Jan 1, 2016

By F. Osmond, R. Kelly

"Malcolm Knowles, the famous adult educator once wrote: ""What a challenge we in human resources development face if we are to avoid the obsolescence of our workforce. I can foresee this challenge requiring that we reconceptualize (...) and redefine the role of HRD, away from that of managing the logistics of conducting training activities to that of managing a system of learning resources"".The context in which this was written surrounds the subject of adult education and the need for business and industry to change its approach to the treatment of adults as learners. In explaining what 'managing a system of learning resources' means, Knowles refers to line supervisors and managers as the most ubiquitous resources for day-in and day-out employee development. In many organizations training has been largely a staff rather than line responsibility. Even where trainers reported to line management, it was still seen as a staff function performed by a few specialists.This change referred to by Knowles places a much heavier responsibility on line supervisors and managers for the development of their personnel than has traditionally been the case. Managing that change - handing over the responsibility to the line organization - is the supreme challenge for the HRD function.Just why is this change necessary? Because too often, the learner does not effectively use on the job what he or she learned in the classroom. In fact, learners often discard new methods and revert to the older ways. The reason training does not stick is that the systems for training and work management are most often separate entities and while one may support the other, they need to be a single integrated system in order to ensure the transfer to the job effectiveness of training and some real value for the training dollars.Because much training can be wasted, steps have to be taken to ensure that it fulfills its intended purpose. The effective and continuing application of knowledge and skills that learners acquire can only be realized when line supervisors and managers are at the centre of the training system.This paper describes how such a systemis being developed at the Iron Ore Company of Canada (IOC) as a functional training program is introduced. The following text provides background information on the IOC - who they are and where they are located, a definition of functional training, an evaluation of the suitability of this approach for adults in industry, a description of how the program is being implemented at IOC and some observations that have been made as this change is experienced."

Jan 1, 1995

By J. C. Botham, T. D. Brown

"Coke is the most costly item in steelmaking via blast furnaces . Recent innovations in cokemaking have been directed toward reducing this cost while simultaneously improving coke quality and expanding the range of coals used in the process. It is also important to meet increasingly stringent environmental legislation.Improvements in coke quality have been achieved by novel blend selection procedures, by charge density control using both selective pulverization and partial briquetting, and by the use of modifying additives.The Canadian Carbonization Research Association provides a focus for Canadian cokemakin g research which has demonstrated these technologies in a series of pilot-scale experiments."

Jan 1, 1980

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount 'net proceeds' shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By L. Xia, B. Hart, K. Douglas1, S. C. Chelgani

Development work to optimize a flotation flowsheet for rare earth element (REE) recovery is underway. The original approach used alkyl phosphates and phosphoric acid ester as collectors to concentrate REE minerals. To improve REE recovery, hydroxamates as alternative collectors were investigated. In this paper, micro flotation of REE minerals using salicylic, benzoyl and naphthoyl hydroxamates is reported. Unlike phosphonic collectors, slime removal does not show a significant effect on REE recovery when using hydroxamates as collectors. Among the three hydoxamates, the grade of La, Ce, and Nd for concentrates produced by salicylic hydroxamate is the highest. The recovery response with naphthoyl hydroxamate is similar to that of salicylic hydroxamate; good grades for La, Ce, and Nd, less effective for Nb, Y, and Zr. The data indicated an affinity by salicylic and naphthoyl hydroxamtes for LREE over the HREE minerals. In comparison, benzoyl hydroxamate indicated an affinity for Nb, Y, and Zr. Temperature effects on REE recovery were also studied. The grade and recovery of REEs generated by flotation using a mix of salicylic and benzoyl hydroxamates at room temperature was almost identical or even better relative to the recovery using naphthoyl hydroxamates at elevated temperature.

Jan 1, 2014

By Maria Skyllas-Kazacos

The All-Vanadium Redox Flow Battery that was pioneered and has been developed at the University of New South Wales (UNSW) in Sydney since the mid-1980s is currently regarded as one of the most attractive energy storage systems for large-scale implementation in a wide range of grid-connected and offgrid applications. Several companies are now manufacturing and installing MW-scale VFBs in applications ranging from renewable energy storage, load-levelling, emergency back-up power and power arbitrage. The full-scale uptake of the VRB in commercial energy storage systems however, is heavily dependent on the availability and cost of vanadium used in the VRB electrolyte. Cost is also a function of purity requirements and although there is little scientific evidence on the effect of impurities on the VRB life and performance, VRB developers continue to demand high purity vanadium at considerable cost. This paper will provide a brief overview of the current understanding of electrolyte impurities on VRB performance together with an economic analysis of the impact of vanadium prices on overall VRB capital and levelised costs for a range of applications.

Jan 1, 2014

By Nadarajah Nanthananthan

Mine backfill has been widely used as a means of ground support. While proper design of backfill is important to ensure ground stability, understanding the failure mechanism and the various influencing factors in a filled block is essential. This paper presents a modified sliding failure model of a confined backfill block. The model considers both the gravity load of the backfill itself and the overlying load from fragmented ore or backfill on the top. A series of new equations were derived and the relationships between factors such as factor of safety, friction angle, cohesion and the exposed stope height were developed. This modified model will be a very useful tool in backfill design, for example, to optimize the design of backfill for a given stope geometry or to determine the maximum backfill height for a particular type of backfill.

May 1, 2007

By Stephen B. Hearn

The SLon Vertical Ring and Pulsating High Gradient Magnetic Separator was developed to overcome multiple disadvantages associated with traditional horizontal type Wet High Intensity Magnetic Separators (WHIMS) which have been in service for many decades for recovering iron ore and other minerals. Proven successful, with hundreds of units now upgrading low-grade iron ores and maximizing recovery of fines throughout China, the technology is now being tested in the Western world. This paper will discuss the drawbacks of traditional WHIMS, explain the operation of the SLon, and illustrate its practical use in processing hematite ores.

May 1, 2007

By G. Zeng

Although the solubility of oxygen in zinc electrolyte is less than 9 mg/L, the effect on deposit stability and zinc-dust consumption can be significant. Sodium sulfite is used to deoxygenate the electrolyte. The effect of the sodium-sulfite concentration on cobalt removal is investigated. The results show the reduction of sulfite to elemental sulfur that adhered to the zinc dust surface forming a passivating layer, and small amounts of sodium sulfite have no effect on cobalt removal. The optimum amount of sodium sulfite is 100 mg/L. It is an important consideration in purification circuits to use sodium sulfite as an additive to cobalt cementation.

Jan 1, 2005

By Matthew Violot

Vale Canada?s Birchtree Mine, located in Thompson Manitoba, has been experiencing problems with hanging wall / footwall dilution, as well as sloughing off of adjacent stopes and temporary stope block backs. Birchtree Mine is interested in determining how time affects the stability of their open stope blocks. Many factors simultaneously influence open stope stability (rock mass quality, joint condition, stress condition). This makes it challenging to determine the influence of a single parameter such as exposure time or stand-up time. This study focuses on determining the effect of exposure time on open stope dilution and combines stress analysis and empirical based approaches.

Jun 1, 2012

By Jonathan Peck, Jim Gray

"With the implementation of more advanced monitoring, control and locating systems in surface mines, there is an ever increasing need for their mine-wide integration toward achieving over-all optimization. AQUILA Mining Systems Ltd. is developing the basis for a comprehensive real-time monitoring, control and information system called the Total Mining System or TMS. This system is being designed to address both current and future needs of open pit mines toward improving productivity and minimizing costs, through better two-way information flow between each component in the operation. At a basic level, feedback from equipment and process monitoring will enable decision making to be based on quantitative, on-demand information, thus permitting proactive rather than reactive planning. Dynamic planning would be a valuable tool as market conditions fluctuate, equipment fleets age and variations in the grade, quality, geometry and hardness of the mined material all contribute to either changing production targets or levels of achievable performance. Such a capability could be implemented within the next two years.At a higher level, and within five years, autonomous operation and/or real-time supervisory control of mobile and stationary equipment in open pit mines will be achieved. A discussion is provided in regard to the development and implementation of an autonomous haultruck and blasthole drill, to demonstrate the need for such a system.This paper outlines a preliminary program for the design, development and implementation of this system, primarily in relation to high-level communications and its role in the future automation of open pit mobile equipment."

Jan 1, 1995

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By K. Tsuchihashi, A. Kishimoto, T. Uda, Y. Kado, S. Maruyama

We recently proposed a continuous production process for titanium metal with some experimental results. In the process, titanium tetrachloride is reduced by Mg in the presences of Bi to form a Bi-Ti alloy at 900ºC. At this temperature, the obtained alloy is liquid and allows for the continuous removal of product and heat from the reaction vessel. The obtained Bi-Ti alloy was vacuum-distilled at 1000ºC for 24 hr, and 98 at % (92 wt %) titanium, which was easily crashed to powder, was obtained. Bi solvent was selected because of the highest titanium solubility at 900ºC and the moderate vapor pressure among the candidate metals (Bi, Sn, Pb, Zn, and Sb).

Jan 1, 2014

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016