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By D. K. DeForest

The olfactory system (sense of smell) is crucial to the ability of fish to avoid predators, recognize kin, and synchronize reproduction (Baldwin et al. 2003). Copper (Cu) has been shown to impair olfaction in juvenile freshwater life stages of salmonids (including Pacific salmon and trout) in some laboratory experiments; and in the United States, public concerns have been expressed that current regulatory criteria for Cu in fresh water are not adequately protective of olfactory function in salmonids (e.g., OSU 2007; Pearson 2007). These concerns have largely been raised because some Cu concentrations that have caused olfactory impairment in salmonids in the laboratory are less than Cu concentrations that have been shown to reduce salmonid survival, growth, or reproduction (the effects endpoints that are typically considered in deriving ambient water quality criteria). However, two important and interrelated points that must be considered: (1) freshwater Cu criteria are "driven" by the sensitivities of several invertebrate species that are more sensitive than the olfactory impairment threshold in salmonids when (2) the influence of water chemistry on Cu bioavailability is properly considered in deriving Cu criteria. Bioavailability refers to the ability of various chemical forms of Cu to interact with receptors on the surface(s) of organisms and thus directly cause toxicity or uptake by the organisms. The toxicity of Cu and other metals to aquatic organisms is a function of water chemistry. For example, acute Cu toxicity in fresh water generally decreases as pH, water hardness (Ca2+ and Mg2+), alkalinity, and dissolved organic carbon (DOC) concentrations increase (Meyer et al. 2007). The U.S. Environmental Protection Agency (USEPA) has recommended hardness-based freshwater aquatic life criteria for Cu and other metals since the 1980s (e.g., USEPA 1985); and hardness-based metals criteria decrease (i.e., become more restrictive) as water hardness decreases. More recently, the USEPA has recommended freshwater aquatic life criteria for Cu based on the biotic ligand model (BLM; USEPA 2007), which accounts for the influence of multiple water chemistry parameters, including DOC, pH, alkalinity, Ca2+, Mg2+, and several other cations and anions. The BLM-based Cu criteria generally decrease as DOC concentration, pH, alkalinity, and water hardness decrease. Because DOC has a stronger influence on Cu bioavailability than water hardness, hardness-based and BLM-based Cu criteria can differ considerably. For example, in water that has low DOC and high hardness, the hardness-based Cu criterion would be relatively high (because it is driven by the high hardness) but the BLM-based Cu criterion would be relatively low (because it is driven by the low DOC). Thus, any evaluation of the protectiveness of Cu criteria against a given effect, such as olfactory impairment, must properly account for the chemistry of the exposure water. Meyer et al. (2013) compiled data on Cu-induced olfactory impairment and olfactory-induced behavioral effects from tests in which BLM parameters were measured. They demonstrated that the USEPA's BLM-based freshwater life criteria for Cu are protective against olfactory impairment, because it adequately accounts for water chemistry (whereas the USEPA's hardness-based Cu criteria are not consistently protective). Olfactory impairment by Cu is now receiving increased attention in Canada and Europe (e.g., Wall 2013; Stang 2013). Accordingly, in this paper we have expanded the analysis of Meyer et al. (2013) to consider copper guidelines from various other countries and whether these guidelines are protective against olfactory impairment.

Feb 23, 2014

By G. V. R. Landman

In order to obtain a better understanding of the explosion risk at the coal face, anomalies in the ignition sensitivity for different modes of ignition of hybrid mixtures of dust, methane and air were studied. Results indicated that the explosible behaviour of the working environment is highly dependent upon the ignition source and the fuel composition. For example, depending on the ignition source, the same hybrid mixture can be inert or extremely explosible. In conclusion, it is stressed how the explosion risk can be expressed in terms of a safety factor which takes into account the influence of both the fuel and the ignition source.

Jan 1, 1994

By Ghislain Bournival, Seher Ata, Graeme J. Jameson

A common method to prevent bubbles from coalescing in a flotation cell is by the addition of surfactants, called frothers. The gas dispersion properties in a column were tested for solutions of 1-pentanol, tri(propylene glycol) methyl ether, and poly(propylene glycol) in the presence of sodium chloride. The dependency of surfactant on the gas holdup can be divided into regions. It seemed that for a sufficiently low concentration of surfactant, even a stronger surfactant could show a transition in gas holdup from constant/decreasing to increasing with concentration. This region, however, was not marked by a decrease in the average bubble size. In addition, PPG gave higher gas holdup values while averaging larger bubbles. On the other hand, sodium chloride mostly affected the gas holdup when the concentration was high enough to prevent bubble coalescence. Another parameter affecting the gas holdup was the superficial gas velocity. A linear dependency was found between the two under a bubbly flow regime. The current study showed that both surfactants and salt could slightly affect the influence of the superficial gas velocity on the gas holdup.

Jan 1, 2014

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By S. Kobayashi, N. Ohara, T. Aoki, S. Sakurai, M. Iwano, M. Shimo, I. Otsuka

"This project is the upgrading of a commuter line of approximately 76 km to improve the railway system in Istanbul metropolitan area. Railway tracks have been connected between Asia and Europe through a tunnel under the Bosphorus Strait. The length of these underground structures sums up 13.6 km. In this paper, the observational construction management based on field measurement performed at large scale underground railway station (Sirkeci station) constructed by means of New Austrian Tunneling Method (NATM) is described and the mechanism for generation of ground surface settlement above this station is discussed.Buildings above Sirkeci station are overcrowded. About 60% of the buildings are made of reinforced-concrete (RC) and others are of brick. Based on the investigation into the predicted settlement and inclination, necessary actions such as structural reinforcement and soil improvement have been conducted for dilapidated buildings.Rock mass around Sirkeci station consists of alternative strata of sandstone and mudstone. It is overall soft rock with an elastic modulus of 150 MPa, partly including fractured zones. Overburden is about 30 to 40 m. The thickness of unconsolidated sand layer distributed on the bedrock is about 10 m. As a result of in-situ permeability tests, the coefficient of permeability of the sand layer is about 1.0x10-3 cm/s. Fill layer of about 10 to 25 m in thickness covers the sand layer at the ground surface. The fill layer contains a lot of artificial waste like splinters of wood, brick chips and mortar chips, etc. in addition to gravel, sand, silt and shells. The coefficient of permeability of fill layer is estimated to be 1.0 x10-2 cm/s, which is one-order greater than that of the sand layer. Fill layer consists of ancient city ruins of ages respectively from the Eastern Roman Empire, the Byzantine Empire and the Ottoman Empire and has a lot of gaps.The underground part of the Sirkeci station was excavated through a ventilation shaft. Ground surface settlement occurred more than predicted. Therefore, back analyses were performed in order to precisely predict the next-step settlement. However, back analyses with elasto-plastic models could not simulate the actual phenomena and hence, an anisotropic-damage-parameter model developed by Sakurai (1999) was adopted for the back analysis. Furthermore, as the excavation of tunnel proceeded, the ground surface settlement exceeded the predicted value again. Based on the monitoring results, it seemed that pore water pressure decreased by the tunnel excavation resulted in the soft rock and soil to be contracted due to the increase in the effective confining pressure. A coupled hydraulic-mechanical analysis was applied to explain the relationship between decreased pore water pressure and ground surface settlement. The settlement due to drainage from tunnel wall was well-estimated in the coupled hydraulic-mechanical analysis.However, further settlement occurred more than predicted again and again. Though it was very difficult to clarify the reason of the large settlement, it was recognized that the unexpected ground surface settlement resulted from the existence of the large gaps in the fill layer that was greatly compressed. The final settlement reached up to 327 mm."

Jan 1, 2015

By D. W. Feng

Thiosulfate as an alternative lixiviant for gold has received much attention in recent years due to the growing environmental concerns over the use of cyanide. Cu(II) is used to catalyze the oxidation of gold and ammonia is to stabilize Cu(II) in alkaline solution. However, the presence of Cu(II) enhances the oxidative degradation of thiosulfate. The high consumption of reagents has made thiosulfate leaching uneconomical to date, in comparison with cyanide leaching. Therefore, further investigations are required to leaching under low reagent concentrations over extended periods where reagent consumption is low and gold leaching rate is low as well. It is thus necessary to find additives to enhance gold dissolution in the thiosulfate leaching system. Electrochemical studies using rotating gold disc showed that the oxidation of gold in ammoniacal thiosulfate solution increased significantly in the presence of a small amount of thiourea and the beneficial effect increased with an increase in the thiourea concentration up to 7.2 mM. Thiourea improved gold extraction in the thiosulfate leaching of gold from a sulfide ore under low reagent concentrations. Excessive addition of thiourea inhibited the leaching of the gold ore. The decomposition of thiosulfate was reduced with the presence of thiourea. X-ray Photoelectron Spectroscopy (XPS) results indicated that thiou-rea likely decomposed to sulfide and formed gold sulfide species at the gold surface.

Jan 1, 2014

By A. H. Duffield

"Forming part of the Prairie Evaporites, the sylvinite layer mined at Alwinsal underlies the Blairmore quicksands and the water-bearing Devonian formations. Production is achieved by a method of trackless, continuous mining of rooms, leaving pillars for natural support. The paper describes the development of the mine, and the equipment and organization employed in the operation and maintenance of the underground facilities."

Jan 1, 1972

By Susanne Pignolet-Brandom

QEM*SEM is an automated scanning electron microscope/computer system that characterizes samples with regard to mineral modal abundances, mineral grain and particle sizes, mineral associations, and particle surface areas. Additional information, based on the classification of particles according to the area percentage of a mineral of interest, can be obtained for samples of particulates. QEM*SEM is capable of analyzing a wide variety of materials although it was originally developed for applications to the minerals industry.

Jan 1, 1988

By George Aristorenas, Carlos Englert, Jesús Gómez

"Laboratory test data of strain softening soils exhibit the development of a maximum (peak) shear strength followed by a decrease in the strength with continued straining. The rate of strength loss decreases such that an asymptotic minimum value, known as the residual strength, is approached. This paper presents an investigation of the evolution of strength degradation in excavation supported soils that exhibit strain softening behavior. The paper presents a numerical investigation of excavation support of slicken-sided clay, and results of shear testing on materials with similar strain softening behavior. A strain softening constitutive law is presented that can be used with the finite element computer software Plaxis for analysis of excavation support. A typical design section of a deep excavation support in stiff, fissured clay is presented that illustrates the limitations and conservatism of the residual strength approach for excavation support design. Finally, a discussion is presented on the impact of stiffer walls such as diaphragm walls, compared to less stiff systems such as sheet piles, on the design parameters.INTRODUCTIONIn the Washington, D.C. metropolitan area, the Potomac Formation is generally composed of stiff, fissured clays. Geotechnical engineers often associate the presence of slicken-sided planes within the formation as evidence that the soil cannot develop its peak strength. Although it is unclear how old and continuous these slicken-sided planes are, their occurrence, persistence and orientation appear to be somewhat random. Due to this uncertainty, the design of open cut slopes in these materials is often conservatively performed assuming residual shear strength values. This design approach may be justified for long-term open cuts when there is limited amount of geotechnical information and in view of back stability analyses of past slope failures. Furthermore, the lack of confinement in open cuts allows relatively high shear strains near the surface and toe throughout their existence, which promote mobilization of post-peak strength values and the ensuing progressive failure. Indeed, such behavior has been discussed in the past (Skempton, 1970; Schnabel et. al., 1982; Derrenbacher, 1998). A thorough study by Mesri et. al. (2003) of numerous slope failures concludes that the lower bound strength for stability analysis of non-failed slopes is the fully softened strength, which is intermediate between the peak and residual strengths, but that part of the slip surface may be in a residual condition prior to failure."

Jan 1, 2015

By Henrique Dias Gatti Turrer

O projeto Minas-Rio da Anglo American iniciou suas operações em agosto de 2014 e tem capacidade para produção de 26,5 milhões de toneladas naturais por ano de pellet feed. O sistema contempla a exploração e concentração da jazida localizada no município de Conceição do Mato Dentro (MG), bombeamento do concentrado por 529 km até o município de São João da Barra (RJ), onde ocorrem a filtragem, estocagem e embarque do produto final através de navios. Desde a concepção do projeto até os dias de hoje, diversos estudos foram realizados objetivando-se entender o comportamento das diferentes litologias de minérios nas etapas de processamento mineral. Desses, os mais relevantes focaram nas duas principais litologias do depósito: o itabirito resultante da intemperização da matriz (IF) e o próprio saprólito (IT). Os principais pontos de investigação foram o comportamento dos mesmos perante as etapas de cominuição e concentração. O objetivo desse trabalho é apresentar uma revisão bibliográfica das diversas comparações de desempenho perante a cominuição dessas duas litologias. Além disso, são apresentados e discutidos resultados inéditos do desempenho na flotação quando concentrado separadamente ou como uma mistura. Os resultados disponíveis na literatura mostram que, ao contrário do que se imagina, o itabirito natural não apresenta consumo energético significativamente maior nas etapas de cominuição. Os testes de flotação, por sua vez, mostraram que o desempenho é diferenciado, em função do grau de liberação dos mesmos.

Aug 16, 2017

By Edelink Efrain Tinoco Falero

Na atualidade a produção e a utilização de DRI estão aumentando nos países desenvolvidos, principalmente devido à redução do preço do gás natural e do sucesso da nova tecnologia de extração de gás de xisto. Os custos operacionais e os problemas ambientais são, efetivamente, os fatores tecnológicos importantes a serem considerados na otimização da produção de DRI. Portanto, o teor de carbono do DRI tornou-se essencial em virtude da capacidade de gerar energia química no banho de aço, complementando assim a eletricidade em FEA, e as contribuições exotérmicas da oxidação de Si e C nos conversores LD. Este trabalho faz parte de um programa completo de cooperação entre a companhia de mineração Samarco e o Grupo de Siderurgia da PUC-Rio, lidando com as equações cinéticas da metalização e carburização simultânea em fornos de redução direta. Para este efeito, o reator foi dividido em três zonas internas: Redução, Transição e zona de resfriamento. Além disso, também foram consideradas três regiões concêntricas: periférica, média e centro. Á partir desses resultados, para um tipo de pelotas RD específico, mistura de gases utilizados nas instalações industriais e similar flui-dinâmica do processo, as equações cinéticas de metalização e carburização foram estabelecidas para cada zona. Um programa computacional METCARB, totalmente baseado nessas equações cinéticas, foi então concebido. Finalmente, uma validação adicional procedeu-se tendo em conta duas corridas operacionais industriais.

Aug 17, 2017

By K. E. Yassin, A. Yehia, M. Amar

Phosphate fines (size ≤ 45 μm), from the Red Sea Region, Egypt, were subjected to beneficiation process to recover the phosphorite grains from such fines. The sample is characterized by low P2O5 content (18.78%) associated with gangue minerals such as silica (22.77% SiO2) and carbonate (2.01% MgO) indicating its low grade. Phosphate pre-concentrate was prepared by gravity separation, using Falcon, where 63.37% of the phosphate, with 24.94% P2O5, 1.46% MgO, and 10.54% SiO2, was firstly recovered reducing the mass flow to the subsequent beneficiation process. However, the gravity tailing was the feed for the reverse phosphate flotation using bench scale column flotation where oleic acid was used as a carbonate gangue collector and amylase enzyme as a phosphate depressant. Under the appropriate flotation conditions (0.1% amylase, 5·10−4 mol/dm3 oleic acid, and temp. 30 °C), phospho-concentrate assaying 0.61% MgO, 13.14% SiO2, and 27.85% P2O5 with a P2O5 recovery of 55.45%, was finally obtained without the use of expensive depressants, e.g., phosphoric acid or sodium silicate. A tentative flow sheet for the whole process was postulated.

By Rainer Antretter

The city of Garmisch-Partenkirchen in southern Germany is located at a main transit road to Tyrol in Austria and suffers of a very heavy traffic load. Therefore, the Kramertunnel as a by-pass tunnel is built to release/mitigate the traffic through the city centre. The 3,600 m long single tube road tunnel is designed with a parallel but smaller emergency tunnel and with cross passages, fitted with single- and doublesided emergency bays, a vent shaft, and an intermediate ceiling to separate fresh air supply from the road traffic. The tunnel, concrete lined along its entire length provided the challenge to find smart formwork solutions for quick set-up, repositioning, setup and pouring. Three particularly specific sections are discussed in this paper.

Jun 13, 2023

By Brian V. Roulston

Potash is Canada&apos;s leading industrial mineral in terms of value of production, with 11.1 M tonnes of muriate of potash produced in 1992 for a value in excess of $1 billion U.S. Each tonne of potash produced generates about 2 tonnes of waste salt, together with slimes and brine. The disposal of these waste products, particularly the salt and slimes which are discharged on the surface, has recently become an environmental concern. This concern is forcing companies and regulatory authorities to review disposal practices. In New Brunswick, on Canada&apos;s east coast, Potash Company of America operates a mine at which 2 M tonnes of potash ore and 0.5 M tonnes of rock salt are mined each year. The mine is situated in an environmentally sensitive area, noted for its dairy farming and salmon angling. In such an area it was recognized that the storage of waste on surface would be unacceptable, and the mine was designed around this principle. Three main waste streams - salt, slimes, and brine - must be managed as an integral part of the mining system. Around 1.5 M tonnes of fine salt tailings from the milling process and the rock salt screening operation, are sent directly to the active cut-and-fill potash stopes to be used as backfill. Slimes and excess brine from the mill are piped underground as a slurry to be discharged into one of the basin shaped stopes created by mining of the rock salt. While the slimes settle out, the clarified brine is withdrawn from part of the stope to be pumped to surface as a feedstock for the evaporator - a process which recovers the contained potash values in the brine. By designing a system which integrates the mining, processing and disposal of all product streams, and by careful production planning, it has been shown that zero effluent potash mining is possible and points the way for the industry in the future.

Jan 1, 1995

This paper investigates the effects of solids concentration and the addition of Dispersant S40 on the flowability of original and ground limestone slurries. A rotational viscometer with a concentric cylinder geometry and a controlled-stress rheometer with a cone-and-plate geometry were used to characterize the rheological behaviors of limestone slurries. The rheological behavior of original limestone slurries (<100 µm) is transformed through different types of flows with increasing solids concentration. The use of Dispersant S40 can improve the slurry flowability by decreasing viscosity and eliminating Casson yield stress. It is therefore used as a grinding aid for the wet ultrafine grinding of limestone. The rheological behaviors of ground limestone slurries vary with grinding from a starting dilatant flow-ability to a resulting pseudoplastic one with an evident Casson yield stress in combination with a thixotropic character. The appearance of pseudoplastic flowability combining thixotropy is related to the fineness of a ground product and its specific surface area, which are both correlated to solids concentration and the additive amount of Dispersant S40. In addition, the accurate rheological characterization of time-dependent fluids is dependent on the instruments used and operation conditions.

Jan 1, 2007

By Marc C. Bétournay

A mine production locomotive, the world?s first applied industrial fuelcell vehicle, has been designed and tested in the context of a number of proof-of-concept projects supported by the Fuelcell Propulsion Institute, an international consortium of stakeholders dedicated to facilitate the commercialization of fuelcell vehicles. The locomotive?s simple electric-powered motor and controller system was ideal to study a number of requirements related to fuelcell power application: hydrogen power plant operation, underground hydrogen use, risk and regulatory requirements, production performance versus the conventional battery-powered locomotive version under measured duty cycles and production requirements, power plant design improvements for other fuelcell vehicles, and cost-benefit aspects. This article will focus on the design and testing aspects of this project which has led to successful performance demonstrations of the vehicle under surface and underground conditions at two mines. It will also present information on the creation of a safe, reliable and efficient power plant which fulfilled its design objectives, including longer productivity time for a given vehicle fill-up.

May 1, 2003

By C Spandler, S W. Richards G Rosenbaum, R J. Holm

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.The recent and active magmatic arcs of eastern Papua New Guinea (PNG) and the Solomon Islands are well endowed with sulfide mineralisation and include deposits such as Ladolam, Panguna and Solwara 1. The majority of the mineral systems in this belt are younger than four million years old, with some deposits remaining active to the present day as exemplified by active hydrothermal systems on the island of Lihir. The geodynamic setting that led to the formation of these deposits is still unresolved, with, for example, both the Pacific and Solomon Sea plates considered responsible for the formation of the Ladolam deposit on the island of Lihir under different models. In order to understand and characterise the formation of south-west Pacific mineral deposits, we must first reconstruct the complex geodynamic evolution of the region. New kinematic reconstructions show that while mineral systems in eastern PNG and the Solomon Islands are hosted within a single arc related to subduction at the New Britain and San Cristobal trenches, variable and discrete geodynamic settings exist within both the upper and lower plates throughout this region, which give rise to distinct mineralised corridors. Most notably, this region is host to: the Solwara 1 deposit, which occurs within a major transtensional corridor in the eastern Bismarck Sea the Ladolam deposit (Lihir), which is interpreted to have formed above but in relation to tearing of the subducting slab the Panguna deposit, which is related to structure in the subducting slab marginal to the actively spreading Woodlark Basin.An evaluation of the nature and variability of these diverse geodynamic settings through time can provide us with a better understanding of the relationship between the active south-west Pacific magmatic arcs and mineral deposit formation. It may also provide insights into the diverse array of deposit settings at ancient convergent margins, with applications in mineral prospectivity studies.CITATION:Holm, R J, Richards, S W, Rosenbaum, G and Spandler, C, 2015. Disparate tectonic settings for mineralisation in an active arc, eastern Papua New Guinea and the Solomon Islands, in Proceedings PACRIM 2015 Congress, pp 165–170 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By I. Tinto

"IntroductionEnvironmental pollution problems, caused by gases or effluents, by high noise levels or from air borne dust, are placing increasing demands of the operators, from statutory authorities, and from the general public, to adopt more stringent dust control measures. This requires that a successful plant dust control program be an integral part of any plant operation. While a successful environmental program is a key factor in maintaining productivity and good labour relations, anticipation of future environmental regulations during the plant design phase can avoid the high cost of plant upgrading, or dealing with pulmonary conditions in the work force in subsequent years.Particulate removal, conventionally called dust collection, involves the removal of coarse- and fine-particulates from the airstream. Although generally limited to that required for contro!Hng plant generated air emissions, particulate control equipment also has a wide application for air cleaning and filtration inside the plant, as well as for recovery of usable products.In the late 1950s and early 1960s the public became more concerned with the problems of air pollution. This increasing concern was stirred by an awareness of the extremes to which water pollution had progressed in many of the rivers and lakes, by increasing perception of air pollution as detected by visible smog and harsh chemical odors, by the alarming rate of increase of smog plagued cities and communities, and by specific incidents where ill health could be traced to specific episodes of air pollution. Particle size is perhaps the most important single factor affecting particulate control. Large particles (over 5 microns) constitute the major mass fraction of most sources of emission and economical control equipment dqes exist for their efficient control. However, while these larger particles frequently represent the source of soiling and unsightly smoke plumes, they are not a major health problem as they tend to settle relatively quickly, are more easily scrubbed from the atmosphere by rain, and are not able to penetrate the respiratory system. By far the most important form of particulate air pollution is the fine particulate, (below 3 microns) which is harmful to the pulmonary system. The adverse effects caused by this particulate matter on human health are for the most part related to injury to the surfaces of the respiratory system. Particulate material in the respiratory tract may produce injury itself, or it may act in conjunction with gases, altering their sites or their modes of action. A combination of particulates and gases may produce an effect that is greater than the sum of the effects caused by either individually (i.e. synergistic effect)."

Jan 1, 1989

This report summarizes the work performed and results achieved in the period from 18 June 1971 through 18 October 1971 under Phase I (Task 1: Literature and Industry Search; Task 2: Conceptual Design and Evaluation; and Task 3: Concept Selection and Preliminary Design) in substantiation of the drill/impregnation machine concept recommended for detailed design in Phase II. Also included as Task 5 are recommendations for an experimental investigation to be conducted during Phase II. The report is submitted for approval and authorization to proceed to Phase II.

Jan 1, 1972

This paper presents a theoretical investigation on the ionic equilibrium of Fe(III)?Ni(II)?H2SO4?H2O system. A non-ideal speciation model is developed to calculate the concentration distribution of iron and nickel species in a mixed ferric and nickel sulphate aqueous solution over the pH range from 0 to 4 and temperature from 25 to 100°C. A series of speciation diagrams for iron and nickel species is plotted with the effects of ionic strength and temperature on the equilibrium constants being taken into account. The ionic strength-dependent equilibrium constant is treated through a semi-empirical Vasil&apos;eV equation, which is based on an extended Debye?Hückel theory. A Helgeson model is applied to extrapolate the equilibrium constant to elevated temperature. The ionic equilibrium reactions are described by a group of numerical equations containing the temperature and ionic strength-dependent equilibrium constants, which are solved by the Newton-Raphson method. The speciation model is also applied to estimate the hydrogen ion activities and corresponding pH values. The calculated pH values are in agreement with the experimentally measured pH, and are compared to literature data and pH values produced by the Visual MINTEQ® program (a computer code for the calculation of chemical equilibrium in natural aqueous system). This investigation provides a deep insight into the ionic equilibrium behavior of a mixed metal sulphate aqueous system which commonly occurs in hydrometallurgical processing. Keywords: speciation, chemical modelling, thermodynamics, iron, nickel

Sep 1, 2012