Search Documents

By Michael A. Linkous, Mark J. Zdunczyk

Silica in the form of sand and sandstone is one of the most common, and at the same time, unique industrial minerals. Found in every rock type of every geologic age and virtually everywhere in the world, silica is used in products that touch just about every aspect of daily life. Imagine a world in the 1990s without computer chips, fiber optics, or glass, and you have just begun to understand how important silica is to the quality of life we enjoy. The elements silicon (Si) and oxygen (0) comprise roughly 60% of the earth's lithosphere to a depth of about 16 km. The crystal structure of silicon dioxide consists of one atom of silicon bonded to four surrounding atoms of oxygen to form a three-dimensional network of SiO, tetrahedra. This network makes up the mineral quartz (Murphy and Henderson, 1983), the most common detrital mineral in most sandstones. Quartz is also a major constituent of many igneous and metamorphic rocks and is widespread as a siliceous cementing agent in various rock types. Although quartz is common, sandstones, quartzites, and pegmatites and the unconsolidated sediments derived from them that have a silica content high enough and pure enough to meet today's market demands for quality and consistency are not common. USES AND SPECIFICATIONS Silica sand that is mined and processed for industrial uses must conform to the chemical and physical specifications set by customers. In the United States almost half of the silica sand produced is used in the manufacture of glass. Other important products include foundry sand, ground silica, blasting sand, and fracturing sand. Glass Sand Silica is the principal glass-forming oxide in a glass batch. Glass manufacturers develop model specifications for each source of silica sand used. These specifications broadly define the limits and ranges for chemical and physical properties of the sand and are used by the manufacturer in calculating the desired batch mix or formula. Some specifications may be critical to a glassmaker and require very stringent limits on the quantity of impurities in the sand. For example, the total iron oxide content of a batch is extremely crucial when making white or flint glasses (Mills, 1983). Iron is present in almost every raw material used in a glass batch and must be carefully controlled in order to obtain a consistent color in the finished product. It is difficult, however, for a raw material supplier to tightly control the chemistry of a naturally occurring material such as silica sand. To a great extent the commercial quality of a sand is determined by its geologic history. Realizing this, glass producers tailor their model specifications to each source of approved material. In general, a glass company is concerned most about the consistency of raw materials on a day-to-day basis. Soda-lime-silica glass was the earliest type of manmade glass (Baker-Can, 1967) and still accounts for most of the glass manufactured for commercial use today (Mills, 1983). It is relatively easy to melt and shape and is less expensive per ton to produce than most other types of glass (Baker-Can, 1967). Soda-lime-silica glass is used in fabricating containers, flat glass products, incandescent and fluorescent lamps, glass fiber, and many other products. Heavy minerals such as ilmenite, leucoxene, kyanite, and zircon are impurities on which strict limits are placed for a glass batch. Because of their refractory nature they either do not melt or only partially melt, which results in stones or feathers in finished glass. Aluminosilicates such as kyanite also contribute unwanted alumina to the batch as they partially melt. Limits are especially rigid for refractory mineral grains coarser than 0.60 to 0.425 mm (30 to 40 mesh). [Tables 1 and 2] present typical specifications for silica sand used in flat glass and container glass products. The percentages shown represent an average of many companies7 specifications.

Jan 1, 1994

By T DePetris, B B. Beamish

There has been a gradual increase in the volume of internationally traded thermal and coking coal, with emphasis on blending of coals rather than single coal usage. New Zealand can take advantage of this situation, especially with its low ash and sulphur content coals. However, there is a need to clarify the thermal and coking behaviour of these coals as they relate to other market players, to benefit both the consumer and supplier. The high volatile matter contents of New Zealand coking coals are due to their high vitrinite content, which causes them to demonstrate stronger coking properties over a wider rank range than Gondwana coals. These same high vitrinite levels appear to correspond with lower initial softening temperatures than for Gondwana coals of similar rank. Preliminary results using thermogravimetric analysis also suggest that New Zealand high volatile bituminous coals can be used to substitute for higher rank Gondwana coals in combustion processes.

Jan 1, 1994

By S. A. Richards

Business planning in the coal' industry revolves around the production and quality forecast. It is difficult to accurately estimate costs and revenues until the production forecast is made. At mines where production comes from multiple sections, quality is tied to each section's production. Blending becomes a part of the planning process. In order to respond to rapidly changing business climate, a reliable program is needed to accurately forecast the effects of changes in key parameters affecting the production. This paper discusses an efficient, intuitive, and economical approach to underground coal mine planning program which uses a PC-based relational database as the programming platform to forecast production and quality. The program was developed at a major coal company. The relational nature of the production planning data, the programming algorithm, and the underlying principles are discussed in this paper.

Jan 1, 1994

By M. T. Ityokumbul

The liquid phase mixing in Western Research Centre (WRC) pilot plant flotation column with diameter of 0.76 m has been characterized using a salt tracer. The process variables studied were gas and liquid flow rates. The response of the column to a tracer pulse input was monitored at three axial and two radial locations. For all the experimental conditions investigated in the present study, radial and axial concentration gradients were not observed. It is thus concluded that the 2 tph flotation column is behaving as a well mixed tank. This finding is consistent with the observed poor recoveries of coarse fractions in the column flotation circuit. Based on the findings of this report, it is recommended that several schemes of reducing the backmixing be implemented and evaluated for their effectiveness in improving the column recoveries.

Jan 1, 1994

By David R. Lentz

At True Hill in southwestern New Brunswick, low-grade porphyry-style Bi-8n-Mo greisen mineralization is associated with the cupola of an epizonal granite porphyry (granite) that also exhibits three episodes of brecciation. The first episode of brecciation is an in situ, 8 m to 10 m wide transitional zone of net-veined to coarse-grained "blocky" endogranitic mesobreccia that is chloritized and greisenized and hosts weak disseminated minerali.zation. In a zone closer to the host rockgranite contact, angular fine- to coarse-grained endogranitic mesobreccia with greisenized matrix is superimposed on the earlier transitional breccia. The latest episode is fault-controlled and consists of quartz- and chalcedony-hosted sub-angular to rounded fine-grained "pebble" mesobreccias that crosscut and brecciate the other breccia types, as well as the adjacent altered metasedimentary country rocks. The first two episodes of brecciation are magmatic-hydrothermal in origin related to hydrofracturing of the granite carapace and are accompanied by greisenization and mineralization, whereas the post-mineralization, silica-hosted, "pebble" mesobreccias related to hydromagmatic, low-temperature fluid circulation and/or boiling along faults near the contact. These magrnatichydrothermal and hydromagrnatic mesobreccias are similar to those associated with W-Mo-Bi porphyry-greisen mineralization at the Mount Pleasant deposit.

Jan 1, 1994

By J. Hartikainen

19 papers were allocated to this session by the paper classification committee, 8 related to bored piles, 5 to continuous flight auger piles (CFA piles), 3 to slurry trenches, 2 to both bored piles and slurry trenches, one of them also dealing with root piles. There were no papers dealing with root piles only, as root filling is a different technique. One paper concerns sheet piling (Table 1). Table 1. Papers for session 1: Recent Technological Developments in Deep Foundations with Soil Excavation. [ ] Table 2. Classification of pile type in Belgium - van Impe W.F. /10/. [ ] Trends in piling Trends in piling in Central Europe were studied by van Impe for his brilliant lecture to the Finnish Civil Engineering Society. He claimed that bored piling is on the decrease and CFA pilling on the increase (Table 2). Thus the numbers of papers presented here do not conform to recent developments or trends. The papers submitted arc of course influenced largely by the fact, observable in Table 3, that bored piling is

Jan 1, 1994

By M. D. Bath

Minproc Engineers Inc. (Minproc) recently completed the construction and start-up of a process facility to treat 14,000 t/d of gold-silver ore at Kori Kollo, Bolivia. The comminution circuit consists of crushing and SAG-ball mill grinding. Breakage characteristics of the ore were determined and a circuit model developed. This enabled variations of the circuit to be simulated, and evaluated in terms of predicted performance to provide the criteria for final engineering design. Subsequently, analysis of the operating circuit provided data for circuit model-fitting. The validity of the original model and circuit performance predictions are discussed.

Jan 1, 1994

By H. Maleki

The U.S. Bureau of Mines pioneered the use of borehole deformation gauges and overcoring techniques to measure in situ stress. These measurements provide input to structural mine design and support selection for specific geologic conditions. This paper presents recent stress measurements in a western U.S. coal mine where the orientation of the stress field remained relatively unchanged over distances of several kilometers. The horizontal stress magnitude increased with depth of cover and in relation to major geologic structures. Local variations in roof stress profiles were used to develop generic models relating stress arching to strata stiffness and the inelastic behavior of mine roof.

Jan 1, 1994

By Ezra L. Kotzin

Foundry sands used to make molds and cores have been very important to foundrymen since metal casting began hundreds of years ago. They are now used in two basic ways, either in an uncured green state, grain-bonded with clay, or in a set cured state achieved with sand that, mixed with resins or oils, is cured by baking or by chemical reaction. The term sand, as generally used in foundry applications, may best be defined as material composed of granular particles of mineral matter, ranging in size from 0.5 to 2 mm in diameter. The particulate nature of the material may be the result of natural disaggregation or result from crushing and screening of rock or ceramic materials; crushed and screened products are sometimes referred to as "manufactured sand." Based on their origin, the raw materials for foundry sands will vary in grain shape, grain composition, relative surface, grain size, and grain distribution patterns. These properties, in addition to their chemical analyses, sintering point and expansion characteristics play an important part in the choice of sands used as the base molding or core aggregate in metal casting. Sands with different origins may be blended to produce specific compositions and grain size distributions. Early raw material requirements based on silica sand were simple, but as sand/core/mold technology became more sophisticated and binder technology continued to be developed, the physical properties of foundry sands became more critical. Silica sand is composed of quartz, along with, in most cases, small amounts of feldspar, mica, clay, and other common minerals. Although silica sand is still by far the most widely used base material in production of molds and cores used in metal casting, other natural mineral sands have their own unique characteristics and fill an important niche in special applications. As a result, the term sand, as applied to raw materials used in metal casting, has been logically extended to include granular materials composed of a group of minerals other than quartz. With increased use in advanced foundry technology, natural sands composed predominantly of zircon, chromite, staurolite, or aluminum silicate minerals and of granularized chromite or olivine, have become more than just alternate materials and are now commonly classified as sands when the grains are sand-sized. Foundry sand may therefore be considered under two categories: silica sands and non-silica sands.

Jan 1, 1994

By B. C. Jena

In a chromite smelting process for the production of high-carbon ferrochromium, the slag composition profoundly affects operating conditions and the economic performance of the process. For a Canadian chromite concentrate, optimum slag composition and operating temperature were determined by process simulation with a computer model, which is based on parameters, such as the minimisation of slag volume, liquidus temperature, electrical energy consumption and chromium losses. Chromium recoveries are identified for slag compositions spanning wide concentration ranges within the quaternary system MgO-AI2O3- SiO2-CaO. The simulated data are compared with the experimental results.

Jan 1, 1994

By Ronald H. Church

Dewatering of mine waste slurries has been successfully accomplished by the proper use of polymers in flocculating the fine particulate matter suspended in the slurry streams. Conventional treatment of fine waste slurries usually involves some form of impoundment treatment or storage. These impoundments present unique environmental problems. When filled to capacity, the impoundments are usually unloaded with a dragline and transported to a separate disposal area. The U.S. Bureau of Mines has conducted dewatering studies utilizing polymer technology in combination with a mobile field test unit designed by the Bureau. The purpose of these studies was to determine if the fine waste slurry from the mining operation could be successfully dewatered. Results of the investigation have shown that the slurry can be dewatered successfully. The dewatered products obtained from the tests ranged from 45 to 50pct solids. This material continued to dewater, approaching 70 pct solids within 24 h, and could be easily handled using conventional transportation equipment including conveyor belts.

Jan 1, 1994

By L. Xu, N. I. Jayaraman, R. Bhaskar

The objective of this study is to develop a better understanding of the collection characteristics of dust measurement instruments used in mine dust control research with respect to properties of quartz and coal dust. Coal and quartz dust of narrow sues, with aerodynamic median diameters being approximately 2 µm, 4 µm and 10 µm, with quartz contents of l0%, 20%, 30%, 40% and 50%, were released in an aerosol characterization chamber using a fluidized bed aerosol generator. Dust was collected in MSA personal gravimetric samplers with l0-mm nylon cyclones, total dust samplers and Sierra 298 inertial cascade impactors. The samples were analyzed for mass and quartz content. A total of 21 experiments were performed for this study. The mass and quartz collection efficiencies of the total and respirable dust samplers and the impactor were determined. The data show that the amount of dust collected by the respirable dust sampler (respirable + oversize dust trapped in the cyclone pre-classifier) was, in general, less than the amount collected by the total dust sampler. The amount of dust collected by the impactor was higher than that collected by the total dust sampler. Quartz analyses of the airborne dust samples showed that the total dust and respirable dust samplers (including oversize dust) collect less quartz dust than at inertial impactor. The larger the median particle sire of the quartz and coal mixture, the lower the quart content of the dust collected in the samplers. For all three sires, the impactor was a better collector of quartz than the other instruments.

Jan 1, 1994

By J. G. Groppo

Hyperbaric filtration was evaluated at the laboratory scale for dewatering fine coal cleaned by froth flotation. A laboratory pressure filtration procedure is described to obtain uniform cake structure from dilute slurries containing a significant amount of coarse material. Baseline tests were conducted varying filter operating parameters such as driving force, time, cake thickness, percent solids, viscosity and pH to determine optimum operating conditions for eventual application on a continuous pilot scale hyperbaric filter.

Jan 1, 1994

By R. C. Chaturvedi, S. B. Padwal

"Padwal and Chaturvedi have developed the model based on M-K theory, considering Hosford's yield criterion and critical thickness strain criterion"" to predict the sheet metal forming limits under simple (constant) strain ratio paths. This analysis has been extended in this paper to predict the sheet metal forming limits under complex strain paths. The effects of exponent ""a"" in Hosford's yield criterion and strain paths on the forming limits under complex strain paths are studied using this analysis. The predictions of the present analysis are compared, both for simple and complex strain paths, with experimental results of Ishigaki for A.K. steel and also with the predictions of Rao and Chaturvedi's model. The quantitative analysis of the error in predicting the forming limits has also been carried out using a method suggested by the authors earlier.1. INTRODUCTIONThe constant strain ratio condition has been assumed in the theories developed for prediction of forming limit diagrams (FLO). In actual forming operation, this condition is seldom satisfied. Even in the case of simple single stage press formed components, the strain path becomes curved and non-linear. In the case of pressings with complex shapes, or multiple stages of forming, the changes in strain path are more pronounced and even abrupt.Experimental study of the forming limits, under two stage strain paths, by Ishigaki [1], has shown that the forming limits are path dependent. It has been observed that the forming limits lower than that under simple strain paths, may be obtained under certain strain paths (when the first stage strain path is either equibiaxial tension or uniaxial tension, followed by the second stage strain path as plane strain). Rasmussen's work [2J, on the theoretical study of forming limits under curvilinear strains paths, has shown that a large drop in formability can result from very small changes in strain path. Thus if a deformation process gives rise to failures due to plastic instability, the failure is not necessarily due to insufficient formability of the material. In such cases, FLOs based on constant strain ratio path should not be used directly in predicting the success or failure of the forming operation. Thus the knowledge of forming limits under complex strain paths is of great importance to the interpretation of press-shop problems."

Jan 1, 1994

By T. C. Page, P. C. Gibson, M. A. Miller, J. D. Sell

[The Yarnell gold deposit in the Weaver mining district, Yavapai County, Arizona, occurs in a structurally controlled, hydrothermally altered zone in a 1700 Ma granodioritic intrusive. Both potassic and sericitically altered rocks around and above the low-angle, northeast striking Yarnell fault are known to host economic gold mineralization. A wider envelope of weakly-propylitic altered rock also occurs in this area. During mineralization, strong sericitization accompanied several stages of quartz (±adularia) veining, stockwork formation, localized silicification and potassic replacement, in association with deposition of specularite, pyrite (now oxidized) and gold. The footwall of the fault is also sericitically altered but poorly mineralized. Mineralization along the Yarnell fault continues both northeast and southwest from the main deposit, although the thickness of the zone and associated alter avian envelope diminish away from the orebody A sample of undo formed illite taken from the Yarnell fault zone was K/Ar dated at 69 + 1.6 Ma. This date reflects a minimum age for both mineralization and latest movement on the fault. Gold mineralization is accompanied by modest increases in Ag, As. Cu and Mo content. Both CO2- and H2O- rich fluid inclusions were studied and suggest mesothermal pressures and temperatures of formation for the deposit. Ninety-six reverse circulation holes and four diamond drill holes outline a bulk-minable mineral reserve of'4.1 million tons at 0.051 oz of Au per ton. An additional 2.7 million tons at 0.017 oz of Au per ton occurs in a low-grade zone above and subparallel to the main mineralized zone. Total calculated mineral inventory stands at 6.8 million tons at a grade of 0.038 oz of Au per ton, with a waste-to-ore ratio of 1.45:1. Column leach tests indicate that cyanide heap leach gold recoveries should exceed 70%.]

Jan 1, 1994

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

By Ken Norris

"Campbell Mine which has been in continuous operation since 1949 has undergone numerous operational changes in the past 3 years. This paper describes the process changes which have occurred at the Campbell Mill since 1991. The paper discusses the engineering, construction and startup of the effluent treatment circuit, the new oxide filtering and merrill-crowe precipitation circuit, and the changes to the pressure oxidation circuit. Particular attention is paid to startup problems and solutions to these problems. A review of the benefits and results of these process changes is also discussed. Future changes are also briefly reviewed with anticipated goals and expectations.IntroductionCampbell Mine is a gold mine 100% owned and operated by Placer Dome Canada. It is located in Balmertown, Ontario which is located 300 kilometres northeast of Winnipeg, Manitoba. The Campbell Mine has been in continuous operation since 1949, producing nearly 8,000,000 ounces. In 1993 Campbell Mine is budgeted to produce 289, 750 ounces of gold at a cash cost of $157 US/ounce. Daily mill tonnage is budgeted for 1,430 tons/day but has milled as high as 1,600 tons/day on a consistent basis. Recovery in 1993 is 93.4% and is budgeted to average 94.5% in 1994.In the 1992 edition of the proceedings of the Canadian Mineral Processors conference I described the changes that were made at Campbell starting in 1989. This paper continues where the 1992 paper ended and discusses the changes to the Campbell mill since that lime. The changes to Campbell since January 1992 have been numerous with capital expenditure in the mill exceeding $14.1 million. This paper describes three primary projects since that lime: the effluent treatment project ($5.5 million), the oxide leach/filtering and merrill-crowe project ($4.6 million) and the pretreatment project ($2.81 million). The focus of this paper is to highlight the justification of each project, the design and engineering, and some of the initial operational problems and solutions applied to those problems."

Jan 1, 1994

By A. Kaina

The San Luis deposit is one of the few documented gold deposits on a detachment surface. This paper presents mineralogic and geochemical data that was gathered to characterize the mineralization, classify the ore deposit, and provide details of the ore forming process. Included are data on the paragenesis; alteration-mineral assemblages major and trace element geochemistry, and fluid inclusions. The San Luis deposit occurs on the western slope of the Sangre de Cristo Mountains adjacent to the San Luis Basin about 5 miles northeast of the town of San Luis in Costillo County, south-central Colorado. Mineralization was discovered in the district in the early 17th century. Production began in 1890 on lead-silver ores from which the district took the name the old name of "El Plomo". From 1897 through 1934 gold was intermittently produced. Battle Mountain Gold Company took an option on the property in 1987 and proved on ore body comprising an eastern block that has 1,277,300 t ore at a grade of 1.68 g/t and a western block of 9,744,000 t with a grade of 1.34 g/t. Production began in 1990. A companion paper by Benson (1994) describes the San Luis district and the ore body, hence the reader is referred to this or Robert and David (1990) for details of the geology from which the following is summarized.

Jan 1, 1994

By David J. Howard, Christine Broadbridge, David C. Paine

"High pressure vapor/solid reactions offer an opportunity for novel synthesis and processing of thin film materials and structures for electronic, optical, and magnetic applications. In this paper we review the use of two high pressure techniques that operate from 25 to 1000 atm (2.5 to 100 MPa) to fabricate thin film oxide structures from Si1-xGex deposited on Si wafers. High pressure synthesis enables temperature-independent control of reaction rates in the oxidation of this multicomponent semiconductor system and hence offers the opportunity to form thennodynamically metastable Si1-xGex<h from the alloy. The thermodynamics of the Si-Ge-0 system are reviewed and a method is described that utilizes selective chemical reduction (via H2 gas) of Si1-xGcx<h to form Ge precipitates in an SiO2 matrix. IntroductionAlloys of Si1-xGex grown epitaxially on Si substrates by chemical vapor deposition (CYD) and molecular beam epitaxy (MBE) have been used to create high performance microelectronic devices1. These devices show improved performance over conventional Si technology because they exploit the Si/Si 1-xGex band-gap discontinuity and take advantage of higher hole mobilities in the Ge containing alloys. While a range of devices based on heteroepitaxial systems have been demonstrated, the Si1_xGex alloys are of particular interest because they are most closely compatable with standard Si device processing. One disadvantage of Si-based materials systems is that they are not typically useful emitters of light. This is important since the use of light (rather than electrons) for transmitting and processing signals into, out of, and within Si-based microelectronics would represent a major technological advance in microelectronics-based communication and computer technologies. Nevertheless, through the use of innovative processing techniques it may be possible to use the Si1_xGex/Si heteroepitaxial system in integrated microelectronic/light-wave technologies."

Jan 1, 1994

By Mark Stephenson, Paul Henharen

"The objective in the mineral processing of primary ores is to liberate and effectively recover each individual economically viable diamond with minimal reduction in its potential value.There are three distinctive phases in diamond processing:Feed PreparationWhere the diamonds are liberated and waste material finer than the economically selected cut-off size is rejected. In this section we will discuss the various techniques utilised worldwide to effect feed preparation.Primary ProcessingWhere the diamonds are recovered into a high grade concentrate suitable for the more expensive and selective final recovery process. In this section we will discuss the development of primary processing from jigs and pans to the more current techniques utilised worldwide.Final RecoveryWhere there is selective rejection of waste particles until only diamonds remain. The diamonds may then be acidised prior to packing and marketing.Within these distinct phases a variety of unit processes have been utilised and this paper will discuss their relative merits, limitations and suitability in respect to the various stages of diamond project development from prospecting through to production.Basic capital and operating costs are compared for the autogenous milling route developed in the CIS and the crushing and scrubbing route utilised in the west."

Jan 1, 1994