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By Scott A. Trebilcock

Nautilus Minerals Inc the world?s leader in exploration and development of deep ocean mineral resources is today focused on the recovery of high grade copper-gold from in seafloor massive sulphide mineralization. These mineralized belts, analogous to land based volcanogenic massive sulphides (VMS) deposits are located near tectonic plate boundaries of the Western Pacific and around the world. Nautilus; first development project is Solwara 1 located in benign waters in Papua New Guinea. Since 2006 the company has completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit for a deep ocean mineral project and the first NI 43-101 compliant seafloor massive sulphide resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of the first mineral extraction system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cutting removal systems will all be adapted at Solwara 1. Key contractors to the project have all been selected for their deepwater experience, creativity and determination to launch this new industry. Innovation is at the forefront of Nautilus? success to date. This paper gives an overview of the Solwara 1 development and describes the exploration and production technologies adapted for seafloor mineral extraction.

May 1, 2010

By C. J. K. Purdy, H. E. Jamieson

"The comprehensive assessment of the environmental impacts of mining rare earth element (REE) deposits depends on a sound knowledge of the mobility of REEs in low-temperature aqueous environments. Temperature, pH and water chemistry are important factors controlling the aqueous mobility of REEs, while REEs are known to readily form complexes with both inorganic and organic ligands, and it has been shown that sorption and colloid formation may play an important part in dictating REE transport in the low temperature weathering environment. Ore and host rock mineralogy is also a key factor controlling the extent to which REEs are leached from mine waste. INTRODUCTIONThe aqueous mobility of rare earth elements (REEs) has commonly been explored in the past due to their potential application as tracers of geochemical processes in aqueous systems. REE mobility in low-temperature solutions has been shown to be dependent on the pH, temperature, ionic strength, and solution chemistry. For example, the aqueous transport of REEs can be modified by complexation with organic and inorganic ligands (Johannesson & Zhou, 1999; Klungness & Byrne, 2000; Luo & Byrne, 2004; Schijf & Byrne, 2004; Tang & Johannesson, 2010; Wood, 1990, 1993), or through sorption to suspended particles and colloids (Bau, 1999; Quinn, Byrne, & Schijf, 2004, 2006a, 2006b, 2007; Sholkovitz, 1995). Here we review the coordination chemistry, sorption behaviour and potential colloid association of REEs with respect to low temperature aquatic settings.RARE EARTH ELEMENT CHEMISTRYREEs include lanthanum to lutetium of Group IIIA in the periodic table. All share very similar chemical and physical properties. Often included in REE studies is another Group IIIA element, yttrium owing to its similar properties, and occasionally scandium, although its considerably smaller ionic radius makes for different properties and will not be discussed further here. The REEs are often subdivided into the light REEs (LREE), La to Sm, and the heavy REEs (HREE), Eu to Lu, which also usually include Y (hence are often referred to as YREE). The REE may be subdivided further into the LREEs, middle REEs (MREEs), and HREEs, in which case each classification includes La-Nd, Pm to Ho, and Er to Lu as well as Y, respectively, although definitions vary throughout the literature."

Jan 1, 2012

By Akiyoshi Horiuchi, Manabu Kanno, Shigeki Sato, Taro Aichi

"AKITA ZINC Co., Ltd. (Iijima Zinc Refinery), jointly owned by DOWA METALS & MINING Co., Ltd.(DMM), has used the company’s own hematite process for iron control since the beginning of operations in 1971. The hematite process consists of reductive leaching with SO2 gas and iron removal in autoclaves by high temperature hydrolysis. This process enhances not only zinc recovery but also the recovery of gold, silver, copper, lead and rare metals, which is carried out at another DOWA metallurgical plant. All by-products produced in the hematite process are marketed and sold. This paper presents an overview of the hematite process and the recent process improvements made.INTRODUCTION DMM carries out mining and smelting activities for precious metals, PGMs, rare metals and base metals such as copper, lead and zinc. It owns KOSAKA SMELTING & REFINING, producing copper and lead, and the AKITA ZINC Co., Ltd. (AZC) in Akita Prefecture. DOWA is a specialized smelting company which has established a metallurgical complex for copper, lead and zinc, including a recycling business. AZC was established in 1971 at a production capacity of 72,000 t/y zinc; it is jointly owned by DMM and five other non-ferrous metal companies. AZC has increased its capacity continuously and now produces 210,000 t/y of zinc. Figure 1 shows the changes in zinc production and capacity at AZC."

Jan 1, 2016

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By R. Dawes, B. R. Davis, T. LeBel, C. Pelow

Settling of copper, lead, and other metals in slags is an important part of overall recovery of metals, both in primary and secondary operations. The impact of slag reduction on settling is not well known. This is important since the cycle time for slag cleaning can be significantly changed with reduction of slag, through a decrease in slag viscosity and growth of metal/sulphide particles. KPM has worked with a number of primary and secondary recyclers to better understand how reduction of slag can improve overall operation. In this presentation, we describe the type of test work and analysis done and how this information can be used to guide improvements in metal recovery from slags. INTRODUCTION Typically, copper smelter slags contain about 1-2% copper, both in the form of copper and copper sulphide beads and dissolved copper oxide in the slag (converter slags are recycled to the smelter). With the average grade of world copper deposits close to 0.7%, it is practical to recovery copper from these slags. This is done routinely by one of two methods. The first method uses slow cooling in large ladles or beds to grow particles of copper sulphide. The slag is then crushed, milled, and floated for copper recovery. The slow cooling promotes precipitation and growing of the sulphide particles from the solution and then, the slag can then be milled to recover the copper through froth flotation. A consideration of this process includes the energy cost related to grinding, the use of water, capital cost for ladles, and the availability of tailing dumps. At the same time, the retreatment of the Cu concentrate produced in the mill will displace fresh concentrate, which ultimately results in a reduction of the throughput. The second method is the so-called “slag cleaning” and is based on the settling of copper and copper sulphides particles dispersed in the slag. This is achieved by decreasing its viscosity by increasing the slag temperature and reducing the iron spinel solid phases (magnetite) that increase the apparent viscosity of the slag. Typically, the reduction does not extend to the reduction of copper, and soluble copper (mainly as oxide) and fine matte particles remain at concentrations typically at or above 0.5% (Cardona et al., 2011; Cardona, 2011). This is an improvement on 20 years ago when slag was sent to dumps at 1% or less (Demetrio et al., 2000).

Jan 1, 2019

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By D. Bouchard, M. Forté, A. Charette

A transparent replica of a casting die was built to achieve a better understanding of the filling mechanisms of aluminum in high pressure die casting. Water and tomato paste were respectively used as analogues for the Newtonian liquid aluminum and the non-Newtonian semi-solid aluminum. The transparent die was installed on an industrial casting press and filling was filmed with a high-speed camera. Differences between the Newtonian and non-Newtonian fluids are presented and discussed.

Jan 1, 2006

By A. K. Alzo?ubi

Block toppling in natural rock slopes has been under investigation since the 1970?s. De Freitas and Watters (1973) introduced the term ?toppling? to describe the movements of rock slopes by rotation in steeply dipping beds. The Lornex pit case history from British Columbia (Canada) was chosen to study the effect of mining on the stability of toppling rock slopes. A discrete element approach that allows fracturing of intact material was applied successfully to model the composite rock slide-rock topple movement. Three main movement modes were observed in the field and the numerical model; the sliding of the top of the slope exposed normal scarps, the toppling at the middle part of the slope exposed obsequent scarps facing opposite to the slope face, and dilation of the rock caused by fracturing at the toe formed loose material. The development of the rupture surface at the toe of the slope was traced and did not evolve into a continuous rupture surface throughout the slope both in the field and the numerical simulation. Good agreement was achieved between the deformations recorded in the field and the numerical simulation.

Jun 1, 2012

By Ross G. Bertinshaw

"The Line Creek Mine of Crows Nest Resources started mining coal in the fall of 1981. There are seven mineable seams with thicknesses ranging from 1.5 to 13 metres and with dips varying from 0 degrees to 60 degrees. This, together with internal partings and the very friable nature of the coal, creates a number of mining problems.The coal is divided into zones depending on the dip of the seam. Each zone requires a different mining technique to ensure optimum recovery and low dilution while still keeping fines to a minimum.Line Creek employs a combination of hydraulic front shovels and backhoes to mine its coal without blasting or use of dozers. This has been very successful in reducing the proportion of fine coal hauled to the plant, thus improving quality control and reducing costs in coal processing.There have been a number of other benefits from the use of excavators instead of more conventional methods. These include better selectivity, good cleanup, reduction in traffic at the face and lower cost.IntroductionThe Line Creek Mine is situated approximately 25 km north of Sparwood in southeastern British Columbia (Fig. I). Preproduction stripping began in J98J with the first coal shipments made in 1982. In 1983 the mine produced 2.1 million tonnes of raw coal.Similar to other East Kootenay coals, the seams at Line Creek are characterized by their friability, producing a large proportion of fine coal during mining. In an attempt to reduce these fines Crows Nest Resources has instituted the use of hydraulic excavators to mine and load the coal.Hydraulic excavators offer other substantial advantages over front-end loaders and dozers, which has been the conventional system in other mines in the area."

Jan 1, 1985

By J. Stiksma, J. Dennett, R. Kalanchey, J. Ji, M. Collins, T. Chan, R. Berezowsky

A pilot plant campaign has been conducted by Sherritt Technologies in support of Eldorado Gold Corporation’s evaluation of pressure oxidation technology for the treatment of refractory gold concentrates from the Certej deposit in Romania. Four separate concentrates, containing 3.5 to 5.4 g/t Au, 13.0 to 14.5% S2- and 12.0 to 32.5 g/t Ag, were tested in the eight-day campaign. The major gold-bearing mineral was pyrite. Preliminary batch tests indicated that gold extraction from the oxidized concentrates in subsequent cyanide leaching was adversely affected by the presence of organic carbon in the pressure oxidation feed when chloride in solution was at an elevated level. As such, the process conditions that were tested during the pilot plant operation were selected to either counteract the negative impact of the organic carbon, or to deactivate it during pressure oxidation. Both process routes proved feasible, yielding gold extraction of 95 to 98% in cyanide leaching of the oxidized concentrates. Silver extraction was typically in the range of 80 to 90%, provided that the oxidized concentrates were also processed in a lime boil step prior to cyanide leaching.

Jan 1, 2014

By T. Sakai

Present authors have succeeded in single pass large draught rolling of AZ31 and ZK60A magnesium alloy sheets below 200 °C without heating rolls by raising rolling speed above 1000 m/min. Heavy reduction larger than 60% can be applied by single pass high speed rolling even at room temperature. The rolled sheets showed fine recrystallized microstructure by dynamic recrystallization. The improvement of workability at lower rolling temperature is due to temperature rise by plastic working. In high speed rolling, almost all of the work done by plastic deformation is converted into the heat that raises the temperature of the sheet during rolling because the heat did not flow out of the sheet by conduction and radiation within very short time.

Jan 1, 2006

By S. Zakaria

"Inco's Automated Haulage Truck System (AHT) is a revolutionary automatic guided vehicle that performs all load, haul and dump operations without human intervention. The high level of sophistication and the short period it has been in operation has only allowed a select few Inco personnel to become familiar with the ART operation and maintenance. As an aid to operations an expert system using the knowledge gained from the experienced specialists was implemented in the field.The AHT operating and maintenance assistance expert system will reason through the information given, arrive at conclusions and give advice to operations, technical and management personnel. It will provide comprehensive real-time troubleshooting assistance for the hydraulic, electrical and mechanical subsystems of the ART. The ART expert system has many benefits to Inco which include increased skill levels of ART operations and maintenance personnel, reduction in ART downtime, standardization of troubleshooting procedures and reduction in ART operating and maintenance costs. In the future, the expert system application will be linked to SCADA (Supervisory Control and Data Acquisition), maintenance and statistical software to display current and historical trends of variables from a centralized historical database. As well, a wide variety of features will be integrated into the system including AutoCad drawings, graphics, photographs, voice and video capabilities."

Jan 1, 1994

By W. Almdal

"To compete in the ever expanding global market, companies must continuously improve. Benchmarking, a tool that can help determine where the best areas for improvement are, is more than comparing measures, it is comparing how business is carried out and how decisions are made. The key to success is in integrating benchmarking results into the organization, so that those most affected by the results own them and are empowered to use them as a positive change agent. This is a necessary step to achieving substantive change to practices and achieving optimum performance improvement. IntroductionBenchmarking is a powerful tool that can assist in the continuous goal of improvement. Benchmarking is more than comparing productivity rates or unit costs, it is seeking out best practices and assimilating them into a business to provide a positive change agent.Benchmarking is a continuous process - is time consuming, labour intensive, and requires a lot of discipline. There are no easy answers and no easy solutions, just a lot of work. The results, however, are nothing short of spectacular. More and more companies are adopting benchmarking practices because it is a key tool of the learning organization and will become part of the way business is done, part of the way it is managed. Business must change to stay ahead or to get ahead and benchmarking can accelerate the process of business change. Improvements in an organization can happen faster and more effectively with a benchmarking approach."

Jan 1, 1994

By Jean-Luc Collins

"This paper shows how simple reliability concepts such as mean time between failures and mean repair time can be used efficiently to help increase equipment availability and so reduce the economic losses associated with unreliability.More specifically, the paper shows how these simple concepts can be used in maintaining an appropriate balance between fleet failure and repair rates and how they can be used for setting up priority repair rules f or queuing equipment.IntroductionA profitable mining operation must handle large quantities of ore and waste at the lowest possible cost. To achieve this objective, the operation must optimize the productivity of its fleets of equipment by efficient management of the time element. Figure I shows some basic equipment activities in an open pit operation while Figure 2 shows a tree diagram describing some time elements of these activities.It should be noted that the only time a piece of equipment can generate a profit is when it can be found in the operating status. In order to maximize this time element, the sum of the other time elements must be minimized because the total time is always fixed.This paper shows the application of simple techniques capable of reducing the waiting time for repair (maintenance delay) by using simple reliability concepts."

Jan 1, 1988

By Norman J. Tienkaivip, Christopher J. Preston

"This paper describes the use of electronics for physical measurement and computer analysis in both open-pit and underground mining operations for the ultimate purpose of optimizing production blasts. Techniques in monitoring single borehole blasts using both pressure and vibration sensors to establish in-situ dynamic rock properties are outlined, including characterization of multiple borehole production blasts with regard to stress generation.Once field derived measurements are computer analyzed, they are channelled as input parallel to other data, such as the explosives thermochemical performance properties generated by a sophisticated computer program called ""HT-65"" into BLASPA . BLASPA, a blast simulation computer program, then couples these input with a mathematical model which defines the blasting processes. Aspects such as the blast geometry, explosive loads and distribution, hook-up, and costs are studied. The final output table gives specific blast performance or quality factors for each blast procedure. These results are then easily compared and rapidly optimized to achieve maximum performance at lowest blasting and drilling cost."

Jan 1, 1984

By McGill Metals Processing Centre, S. Chang, L. Calzado, X. K. Cao, C. H. Hsin, M. Isac

"Due to the increasingly stringent cleanliness requirements for final steel products, there has been a growing interest in the possible use of micro-bubbles for the removal of inclusions with diameters smaller than ~50µm, present within the steel passing through a steelmaking tundish. However, several technological barriers have prevented the adoption of this technique in industry. These are related to a) the generation of micro-bubbles in liquid steel, b) the measurement of bubble size distributions, and c) the optimization of bubble injection conditions to create micro-bubbles. In the present study, a novel Aqueous Particle Sensor (APS) system was developed for the in-situ, on-line, detection of micro-bubbles in water, generated by a newly designed full-scale ladle shroud, located at McGill Metal Processing Centre (MMPC). Measurement results from the sensor were validated against bubble size data collected through a high speed camera and post-processed through the commercial software, Image J.Control variables and orthogonal experiments were designed to assess the dependence of average micro-bubble sizes and bubble size distributions on key experimental parameters. Those chosen were the air inlet flowrate, the distance of the gas injection port from the slide gate, and the number of injection ports used. The investigation demonstrated that the APS system can be successfully adapted to detect micro-bubbles up to ~800 micron diameters. Using this novel sensor, it was shown that multi-port injection using low air inlet flowrates, closer to the slide gate, were useful in forming small micro-bubbles within the flow through the ladle shroud. The results from the APS system were compared and validated against data resulting from an optical technique. INTRODUCTIONModern industry expects increasingly stringent cleanliness requirements for final cast products. Therefore, the numbers and sizes of inclusions need to be strictly controlled in steelmaking operations. Thus, the cleanliness of steel products depends on the amount, morphology and size distributions of nonmetallic inclusions in steel (Zhang L. & Thomas B., 2003). Since large, deep, tundishes provide longer nominal residence times for liquid steel passing through it to the exit SEN’s, this can provide the ideal place to separate inclusions, and bubbles can assist by removing help attach inclusions and float them to the top surface."

Jan 1, 2016

By T. F. Pugsley, D. Gignac

"The historical background to the project dates back to the mid-30s with the discovery of surface sulphide showings in the Cape Smith-Wakeham Bay ultramafic belt. In the mid1950s, orderly exploration commenced with an extensive work program by Asarco, INCO, Lemoine, Falconbridge and Raglan Nickel Mines Ltd. on exploration permits. In 1966, Falconbridge and Raglan Nickel Mines interests merged. Extensive exploration, drilling, under- ground delineation of the Donaldson orebody and the construction of basic infrastructure such as camps, airfield, road links from Douglas Harbour to Donaldson and Katinniq, a distance of 60 km, were completed.Production project design at that time consisted of plans for a 50 000 mt per year nickel mining and concentrating operation, including a 2000 person community and smelter at Douglas Harbour. These plans unravelled in the mid-70s due to high capital costs, poor nickel market conditions and the realization that the Raglan orebodies were not large enough to economically support the construction of green field smelter and refinery facilities for processing Raglan production. Nickel market conditions in the late 70s and early 80swere generally poor, resulting in further delays on production plans.While recognizing the very high potential to discover increased tonnages of high grade(3% Ni) in excess of 20 million tonnes, the project was deferred into the late 80s when a serious re-evaluation of exploration potential occurred and the requirement to prove up additional reserves resulted in an underground exploration program at Katinniq covering the period 1990-1992."

Jan 1, 1996

By E. M. De Souza, P. Lausch, D. O. DeGagné, J. F. Archibald

"The potential use of industrial and municipal waste glass as a partial pozzolanic replacement for Normal Portland cement in mine backfill has been investigated. Considerable quantities of glass are currently discarded into landfill sites at high cost to municipal and industrial users with no foreseeable environmental benefits being gained by such disposal. This research study was undertaken to assess the viability of using ground waste glass materials as partial binder replacement of Portland cement fractionswithin consolidated mine backfill materials. The program was implemented to review various factors that could influence successful incorporation of glass waste replacement of cement, these factors being the feasibility of glass waste procurement, determination of process economics and the physical and chemical suitability of ground waste glass materials to generate adequate backfill strength when replacing Normal Portland cement fractions. A series of laboratory assessment trials were established to evaluate backfill component characteristics and mixture strength properties for both standard Portland cement-consolidated and blended Portland cement/ground waste glass-consolidated backfill materials. Side-by-side review of the strength behaviour of various component backfill/cement mixtures was designed to permit comparative evaluation of the capabilities of ground waste glass and Portland cement products as backfill consolidating agents"

Jan 1, 1995

By Bob Drew, Goran Vukovic, Bojan Zivanovic, Klaus Gamweger

Reaction bath temperature is a major factor in processing liquid metals and in many applications where a balance between process duration and temperature has to be found to run a procedure efficiently. Also extremes of temperature can decrease the output of a process if too cold or even make it impossible, conversely overheating can be detrimental to both the product and furnace integrity. With the help of the new online temperature measurement system very accurate monitoring of the process is possible in contrast to the current routine practice where the temperature is measured periodically with dip thermocouples. The system works with a digital, fiber optic pyrometer, which is embedded in a refractory housing. Installation in the lining is possible below liquid level as nitrogen is blown to keep the system open and to ensure continuous sight from the optical head of the pyrometer to the molten metal through the tuyere. This permanent temperature measurement gives optimal process control with the potential of taking appropriate actions at an early stage enabling proactive process control. Therefore energy savings and even process endpoint detections can be realized.

Jan 1, 2015